SIST EN ISO 22818:2021
(Main)Textiles - Determination of short-chain chlorinated paraffins (SCCP) and middle-chain chlorinated paraffins (MCCP) in textile products out of different matrices by use of gas chromatography negative ion chemical ionization mass spectrometry (GC-NCI-MS) (ISO 22818:2021)
Textiles - Determination of short-chain chlorinated paraffins (SCCP) and middle-chain chlorinated paraffins (MCCP) in textile products out of different matrices by use of gas chromatography negative ion chemical ionization mass spectrometry (GC-NCI-MS) (ISO 22818:2021)
This document specifies a chromatographic method to determine the amount of short-chain chlorinated paraffins (SCCPs: C10-C13) and middle-chain chlorinated paraffins (MCCPs: C14-C17) in textile articles, especially in polymer of the coated fabrics, prints made of polymer and buttons made of polymer (e.g. polyvinylchloride) by means of solvent extraction and gas chromatography negative ion chemical ionization mass spectrometry (GC-NCI-MS).
Textilien - Bestimmung von SCCP und MCCP in textilen Produkten aus verschiedener Matrices mittels GC-NCI-MS (ISO 22818:2021)
Dieses Dokument legt ein chromatographisches Verfahren zur Bestimmung der Menge an kurzkettigen (SCCP: C10 C13) und mittelkettigen (MCCP: C14 C17) chlorierten Paraffinen in Textilartikeln, insbesondere in poly¬merbeschichteten Textilien, Drucken aus Polymer und Knöpfen aus Polymer (z. B. Polyvinylchlorid), mittels Lösemittelextraktion und Gaschromatographie mit massenspektrometrischer Detektion nach negativer chemischer Ionisierung (GC-NCI-MS) fest.
Textiles - Détermination de paraffines chlorées à chaîne courte (PCCC) et de paraffines chlorées à chaîne moyenne (PCCM) dans des produits textiles sur différentes matrices par chromatographie en phase gazeuse couplée à la spectrométrie de masse avec ionisation chimique négative (GC-NCI-MS) (ISO 22818:2021)
Le présent document spécifie une méthode chromatographique permettant de déterminer la quantité de paraffines chlorées à chaîne courte (PCCC: C10-C13) et de paraffines chlorées à chaîne moyenne (PCCM: C14-C17) présentes dans les articles textiles, en particulier dans le polymère des supports textiles revêtus, dans les imprimés en polymère et dans les boutons fabriqués en polymère (par exemple, polychlorure de vinyle) au moyen d'une extraction par solvant et de la méthode par chromatographie en phase gazeuse couplée à la spectrométrie de masse avec ionisation chimique négative (GC-NCI-MS).
Tekstil - Določevanje kloriranih parafinov s kratkimi verigami (SCCP) in kloriranih parafinov srednje verige (MCCP) v tekstilnih izdelkih iz različnih matric z uporabo plinske kromatografije z masno spektrometrijo s kemično ionizacijo negativnih ionov (GC-NCI-MS) (ISO 22818:2021)
General Information
Standards Content (Sample)
SLOVENSKI STANDARD
01-junij-2021
Tekstil - Določevanje kloriranih parafinov s kratkimi verigami (SCCP) in kloriranih
parafinov srednje verige (MCCP) v tekstilnih izdelkih iz različnih matric z uporabo
plinske kromatografije z masno spektrometrijo s kemično ionizacijo negativnih
ionov (GC-NCI-MS) (ISO 22818:2021)
Textiles - Determination of short-chain chlorinated paraffins (SCCP) and middle-chain
chlorinated paraffins (MCCP) in textile products out of different matrices by use of gas
chromatography negative ion chemical ionization mass spectrometry (GC-NCI-MS) (ISO
22818:2021)
Textilien - Bestimmung von SCCP und MCCP in textilen Produkten aus verschiedener
Matrices mittels GC-NCI-MS (ISO 22818:2021)
Textiles - Détermination de paraffines chlorées à chaîne courte (PCCC) et de paraffines
chlorées à chaîne moyenne (PCCM) dans des produits textiles sur différentes matrices
par chromatographie en phase gazeuse couplée à la spectrométrie de masse avec
ionisation chimique négative (GC-NCI-MS) (ISO 22818:2021)
Ta slovenski standard je istoveten z: EN ISO 22818:2021
ICS:
59.080.01 Tekstilije na splošno Textiles in general
71.040.50 Fizikalnokemijske analitske Physicochemical methods of
metode analysis
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.
EN ISO 22818
EUROPEAN STANDARD
NORME EUROPÉENNE
March 2021
EUROPÄISCHE NORM
ICS 59.060.01
English Version
Textiles - Determination of short-chain chlorinated
paraffins (SCCP) and middle-chain chlorinated paraffins
(MCCP) in textile products out of different matrices by use
of gas chromatography negative ion chemical ionization
mass spectrometry (GC-NCI-MS) (ISO 22818:2021)
Textiles - Détermination de paraffines chlorées à Textilien - Bestimmung von SCCP und MCCP in textilen
chaîne courte (PCCC) et de paraffines chlorées à chaîne Produkten aus verschiedener Matrices mittels GC-NCI-
moyenne (PCCM) dans des produits textiles sur MS (ISO 22818:2021)
différentes matrices par chromatographie en phase
gazeuse couplée à la spectrométrie de masse avec
ionisation chimique négative (GC-NCI-MS) (ISO
22818:2021)
This European Standard was approved by CEN on 13 March 2021.
CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this
European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references
concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN
member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by
translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management
Centre has the same status as the official versions.
CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway,
Poland, Portugal, Republic of North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and
United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION
EUROPÄISCHES KOMITEE FÜR NORMUNG
CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2021 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN ISO 22818:2021 E
worldwide for CEN national Members.
Contents Page
European foreword . 3
European foreword
This document (EN ISO 22818:2021) has been prepared by Technical Committee ISO/TC 38 "Textiles"
in collaboration with Technical Committee CEN/TC 248 “Textiles and textile products” the secretariat of
which is held by BSI.
This European Standard shall be given the status of a national standard, either by publication of an
identical text or by endorsement, at the latest by September 2021, and conflicting national standards
shall be withdrawn at the latest by September 2021.
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. CEN shall not be held responsible for identifying any or all such patent rights.
According to the CEN-CENELEC Internal Regulations, the national standards organizations of the
following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria,
Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland,
Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Republic of
North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the
United Kingdom.
Endorsement notice
The text of ISO 22818:2021 has been approved by CEN as EN ISO 22818:2021 without any modification.
INTERNATIONAL ISO
STANDARD 22818
First edition
2021-03
Textiles — Determination of short-
chain chlorinated paraffins (SCCP)
and middle-chain chlorinated
paraffins (MCCP) in textile products
out of different matrices by use
of gas chromatography negative
ion chemical ionization mass
spectrometry (GC-NCI-MS)
Textiles — Détermination de paraffines chlorées à chaîne courte
(PCCC) et de paraffines chlorées à chaîne moyenne (PCCM) dans des
produits textiles sur différentes matrices par chromatographie en
phase gazeuse couplée à la spectrométrie de masse avec ionisation
chimique négative (GC-NCI-MS)
Reference number
ISO 22818:2021(E)
©
ISO 2021
ISO 22818:2021(E)
© ISO 2021
All rights reserved. Unless otherwise specified, or required in the context of its implementation, no part of this publication may
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ISO 22818:2021(E)
Contents Page
Foreword .iv
Introduction .v
1 Scope . 1
2 Normative references . 1
3 Terms and definitions . 1
4 Principle . 1
5 Reagents . 1
6 Apparatus . 2
7 Preparation of test specimens . 3
8 Procedure. 3
8.1 Extraction of test specimen . 3
8.2 Sulfuric acid clean-up . 3
8.3 Preparation of the calibration solutions . 3
8.3.1 Preparation of SCCPs calibration solution (5 µg/ml) with 59 % Cl . 3
8.3.2 Preparation of SCCPs calibration solution (50 µg/ml) with 59 % Cl . 3
8.3.3 Preparation of SCCPs calibration solution (75 µg/ml) with 59 % Cl . 3
8.3.4 Preparation of MCCPs calibration solution (5 µg/ml) with 55 % Cl . 3
8.3.5 Preparation of MCCPs calibration solution (50 µg/ml) with 55 % Cl . 4
8.3.6 Preparation of MCCPs calibration solution (75 µg/ml) with 55 % Cl . 4
8.3.7 Daily calibration . 4
8.4 GC-MS determination . 4
9 Expression of results . 5
9.1 Evaluation . 5
9.2 Determination of the recovery rate of the IS . 5
9.3 Interferences . 5
9.3.1 Interferences of MCCPs masses . 5
9.3.2 Interferences of SCCPs masses . 6
10 Test report . 6
Annex A (normative) Integration with peak shape evaluation (PSE) . 7
Annex B (informative) Chromatographic parameters.12
Annex C (informative) Reliability of method .14
Bibliography .15
ISO 22818:2021(E)
Foreword
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