Steel and iron - Determination of phosphorus content - Phosphovanadomolybdate spectrophotometric method (ISO 10714:2024)

The method is applicable with the following limitations: phosphorus contents between 0,001 0 % (m/m) and 1,0 % (m/m), application ranges and test portions in table 1 depending on the concentration of the interfering elements (arsenic, hafnium, niobium, tantalum, titanium, tungsten).

Stahl und Eisen - Bestimmung des Phosphorgehaltes - Spektrophotometrisches Phosphovanadomolybdat-Verfahren (ISO 10714:2024)

Die vorliegende Internationale Norm legt ein fotometrisches Verfahren zur Bestimmung des Phosphorgehaltes von Eisen und Gusseisen mit folgenden Einschränkungen fest.
Das Verfahren ist bei Phosphoranteilen zwischen 0,001 0 % (Masseanteil) und 1,0 % (Masseanteil) anwendbar.

Aciers et fontes - Détermination des teneurs en phosphore - Méthode spectrophotométrique au phosphomolybdovanadate (ISO 10714:2024)

Le présent document spécifie une méthode spectrophotométrique pour la détermination du phosphore dans les aciers et les fontes.
La méthode est applicable aux teneurs en phosphore comprises entre 0,001 0 % (en masse) et 1,0 % (en masse).

Jeklo in železo - Določevanje fosforja - Fosforovanadomolibdatna spektrofotometrijska metoda (ISO 10714:2024)

Ta metoda se uporablja z naslednjimi omejitvami: vsebnost fosforja med 0,0010 % (m/m) in 1,0 % (m/m), območja uporabe ter preskusni deli v preglednici 1 glede na koncentracijo motečih elementov (arzen, hafnij, niobij, tantal, titan, volfram).

General Information

Status
Published
Public Enquiry End Date
31-Jan-2024
Publication Date
18-Aug-2024
Technical Committee
Current Stage
6060 - National Implementation/Publication (Adopted Project)
Start Date
08-Aug-2024
Due Date
13-Oct-2024
Completion Date
19-Aug-2024

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SLOVENSKI STANDARD
01-oktober-2024
Jeklo in železo - Določevanje fosforja - Fosforovanadomolibdatna
spektrofotometrijska metoda (ISO 10714:2024)
Steel and iron - Determination of phosphorus content - Phosphovanadomolybdate
spectrophotometric method (ISO 10714:2024)
Stahl und Eisen - Bestimmung des Phosphorgehaltes - Spektrophotometrisches
Phosphovanadomolybdat-Verfahren (ISO 10714:2024)
Aciers et fontes - Détermination des teneurs en phosphore - Méthode
spectrophotométrique au phosphomolybdovanadate (ISO 10714:2024)
Ta slovenski standard je istoveten z: EN ISO 10714:2024
ICS:
77.040.30 Kemijska analiza kovin Chemical analysis of metals
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

EN ISO 10714
EUROPEAN STANDARD
NORME EUROPÉENNE
July 2024
EUROPÄISCHE NORM
ICS Supersedes EN ISO 10714:2002
English Version
Steel and iron - Determination of phosphorus content -
Phosphovanadomolybdate spectrophotometric method
(ISO 10714:2024)
Aciers et fontes - Détermination des teneurs en Stahl und Eisen - Bestimmung des Phosphorgehaltes -
phosphore - Méthode spectrophotométrique au Spektrophotometrisches Phosphovanadomolybdat-
phosphomolybdovanadate (ISO 10714:2024) Verfahren (ISO 10714:2024)
This European Standard was approved by CEN on 24 July 2024.

CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this
European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references
concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN
member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by
translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management
Centre has the same status as the official versions.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway,
Poland, Portugal, Republic of North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Türkiye and
United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION

EUROPÄISCHES KOMITEE FÜR NORMUNG

CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2024 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN ISO 10714:2024 E
worldwide for CEN national Members.

Contents Page
European foreword . 3

European foreword
This document (EN ISO 10714:2024) has been prepared by Technical Committee ISO/TC 17 "Steel" in
collaboration with Technical Committee CEN/TC 459/SC 2 “Methods of chemical analysis for iron and
steel ” the secretariat of which is held by SIS.
This European Standard shall be given the status of a national standard, either by publication of an
identical text or by endorsement, at the latest by January 2025, and conflicting national standards shall
be withdrawn at the latest by January 2025.
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. CEN shall not be held responsible for identifying any or all such patent rights.
This document supersedes EN ISO 10714:2002.
Any feedback and questions on this document should be directed to the users’ national standards
body/national committee. A complete listing of these bodies can be found on the CEN website.
According to the CEN-CENELEC Internal Regulations, the national standards organizations of the
following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria,
Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland,
Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Republic of
North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Türkiye and the
United Kingdom.
Endorsement notice
The text of ISO 10714:2024 has been approved by CEN as EN ISO 10714:2024 without any modification.

International
Standard
ISO 10714
Second edition
Steel and iron — Determination
2024-07
of phosphorus content —
Phosphovanadomolybdate
spectrophotometric method
Aciers et fontes — Détermination des teneurs en phosphore —
Méthode spectrophotométrique au phosphomolybdovanadate
Reference number
ISO 10714:2024(en) © ISO 2024
ISO 10714:2024(en)
© ISO 2024
All rights reserved. Unless otherwise specified, or required in the context of its implementation, no part of this publication may
be reproduced or utilized otherwise in any form or by any means, electronic or mechanical, including photocopying, or posting on
the internet or an intranet, without prior written permission. Permission can be requested from either ISO at the address below
or ISO’s member body in the country of the requester.
ISO copyright office
CP 401 • Ch. de Blandonnet 8
CH-1214 Vernier, Geneva
Phone: +41 22 749 01 11
Email: copyright@iso.org
Website: www.iso.org
Published in Switzerland
ii
ISO 10714:2024(en)
Contents Page
Foreword .iv
1 Scope . 1
2 Normative references . 1
3 Terms and definitions . 1
4 Principle . 1
5 Reagents . 2
6 Apparatus . 3
7 Sampling and sample preparation . 4
8 Procedure . 4
8.1 Test portion .4
8.2 Blank test .4
8.3 Determination .4
8.3.1 Preparation of the test solution .4
8.3.2 Colour development and extraction .5
8.3.3 Spectrophotometric measurements .5
8.4 Establishment of the calibration curve .5
8.4.1 Preparation of calibration solutions .5
8.4.2 Spectrophotometric measurements .6
8.4.3 Plotting the calibration curve .6
9 Expression of results . 6
9.1 Method of calculation .6
9.2 Precision . . .6
10 Test report . 7
Annex A (informative) Additional information on the international interlaboratory test . 8
Annex B (informative) Graphical presentation of precision data . 9
Bibliography .10

iii
ISO 10714:2024(en)
Foreword
ISO (the International Organization for Standardization) is a worldwide federation of national standards
bodies (ISO member bodies). The work of preparing International Standards is normally carried out through
ISO technical committees. Each member body interested in a subject for which a technical committee
has been established has the right to be represented on that committee. International organizations,
governmental and non-governmental, in liaison with ISO, also take part in the work. ISO collaborates closely
with the International Electrotechnical Commission (IEC) on all matters of electrotechnical standardization.
The procedures used to develop this document and those intended for its further maintenance are described
in the ISO/IEC Directives, Part 1. In particular, the different approval criteria needed for the different types
of ISO document should be noted. This document was drafted in accordance with the editorial rules of the
ISO/IEC Directives, Part 2 (see www.iso.org/directives).
ISO draws attention to the possibility that the implementation of this document may involve the use of (a)
patent(s). ISO takes no position concerning the evidence, validity or applicability of any claimed patent
rights in respect thereof. As of the date of publication of this document, ISO had not received notice of (a)
patent(s) which may be required to implement this document. However, implementers are cautioned that
this may not represent the latest information, which may be obtained from the patent database available at
www.iso.org/patents. ISO shall not be held responsible for identifying any or all such patent rights.
Any trade name used in this document is information given for the convenience of users and does not
constitute an endorsement.
For an explanation of the voluntary nature of standards, the meaning of ISO specific terms and expressions
related to conformity assessment, as well as information about ISO's adherence to the World Trade
Organization (WTO) principles in the Technical Barriers to Trade (TBT), see www.iso.org/iso/foreword.html.
This document was prepared by Technical Committee ISO/TC 17, Steel, Subcommittee SC 1, Methods of
determination of chemical composition, in collaboration with the European Committee for Standardization
(CEN) Technical Committee CEN/TC 459, ECISS - European Committee for Iron and Steel Standardization, in
accordance with the Agreement on technical cooperation between ISO and CEN (Vienna Agreement).
This second edition cancels and replaces the first edition (ISO 10714:1992), which has been technically
revised.
The main changes are as follows:
— a complete revaluation of the precision data.
Any feedback or questions on this document should be directed to the user’s national standards body. A
complete listing of these bodies can be found at www.iso.org/members.html.

iv
International Standard ISO 10714:2024(en)
Steel and
...

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