Water quality - Sampling - Part 1: Guidance on the design of sampling programmes and sampling techniques (ISO 5667-1:2023)

This document sets out the general principles for, and provides guidance on, the design of sampling programmes and sampling techniques for all aspects of sampling of water (including waste waters, sludges, effluents, suspended solids and sediments).
It does not include detailed instructions for specific sampling situations, which are covered in the various other parts of ISO 5667 and in ISO 19458.

Wasserbeschaffenheit - Probenahme - Teil 1: Anleitung zur Erstellung von Probenahmeprogrammen und Probenahmetechniken (ISO 5667-1:2023)

Qualité de l'eau - Échantillonnage - Partie 1: Recommandations relatives à la conception des programmes et des techniques d’échantillonnage (ISO 5667-1:2023)

Le présent document énonce les principes généraux et fournit des recommandations relatives à la conception des programmes et des techniques d'échantillonnage, en tenant compte de tous les aspects relatifs à l'échantillonnage des eaux (y compris des eaux résiduaires, des boues, des effluents, des matières en suspension et des sédiments).
Il n'inclut pas de consignes détaillées pour les cas d'échantillonnages spécifiques, qui sont couvertes par les différentes autres parties de l'ISO 5667 et dans l'ISO 19458.

Kakovost vode - Vzorčenje - 1. del: Navodilo za načrtovanje programov in tehnik vzorčenja (ISO 5667-1:2023)

Ta dokument določa splošna načela ter zagotavlja smernice za načrtovanje programov vzorčenja in tehnik vzorčenja za vse vidike vzorčenja vode (vključno z odpadnimi vodami, blatom, izlivi, neraztopljenimi trdnimi snovmi in usedlinami).
Ne zajema podrobnih navodil za specifične okoliščine vzorčenja, ki so obravnavane v različnih drugih delih standardov ISO 5667 in ISO 19458.

General Information

Status
Published
Public Enquiry End Date
14-Dec-2022
Publication Date
11-May-2023
Technical Committee
Current Stage
6060 - National Implementation/Publication (Adopted Project)
Start Date
21-Apr-2023
Due Date
26-Jun-2023
Completion Date
12-May-2023

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SLOVENSKI STANDARD
SIST EN ISO 5667-1:2023
01-junij-2023
Nadomešča:
SIST EN ISO 5667-1:2022
Kakovost vode - Vzorčenje - 1. del: Navodilo za načrtovanje programov in tehnik
vzorčenja (ISO 5667-1:2023)
Water quality - Sampling - Part 1: Guidance on the design of sampling programmes and
sampling techniques (ISO 5667-1:2023)
Wasserbeschaffenheit - Probenahme - Teil 1: Anleitung zur Erstellung von
Probenahmeprogrammen und Probenahmetechniken (ISO 5667-1:2023)
Qualité de l'eau - Échantillonnage - Partie 1: Recommandations relatives à la conception
des programmes et des techniques d’échantillonnage (ISO 5667-1:2023)
Ta slovenski standard je istoveten z: EN ISO 5667-1:2023
ICS:
13.060.45 Preiskava vode na splošno Examination of water in
general
SIST EN ISO 5667-1:2023 en,fr,de
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

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SIST EN ISO 5667-1:2023

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SIST EN ISO 5667-1:2023


EN ISO 5667-1
EUROPEAN STANDARD

NORME EUROPÉENNE

April 2023
EUROPÄISCHE NORM
ICS 13.060.45 Supersedes EN ISO 5667-1:2022
English Version

Water quality - Sampling - Part 1: Guidance on the design
of sampling programmes and sampling techniques (ISO
5667-1:2023)
Qualité de l'eau - Échantillonnage - Partie 1: Wasserbeschaffenheit - Probenahme - Teil 1: Anleitung
Recommandations relatives à la conception des zur Erstellung von Probenahmeprogrammen und
programmes et des techniques d'échantillonnage (ISO Probenahmetechniken (ISO 5667-1:2023)
5667-1:2023)
This European Standard was approved by CEN on 8 January 2023.

CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this
European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references
concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN
member.

This European Standard exists in three official versions (English, French, German). A version in any other language made by
translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management
Centre has the same status as the official versions.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway,
Poland, Portugal, Republic of North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Türkiye and
United Kingdom.





EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION

EUROPÄISCHES KOMITEE FÜR NORMUNG

CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2023 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN ISO 5667-1:2023 E
worldwide for CEN national Members.

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SIST EN ISO 5667-1:2023
EN ISO 5667-1:2023 (E)
Contents Page
European foreword . 3

2

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SIST EN ISO 5667-1:2023
EN ISO 5667-1:2023 (E)
European foreword
This document (EN ISO 5667-1:2023) has been prepared by Technical Committee ISO/TC 147 "Water
quality" in collaboration with Technical Committee CEN/TC 230 “Water analysis” the secretariat of
which is held by DIN.
This European Standard shall be given the status of a national standard, either by publication of an
identical text or by endorsement, at the latest by October 2023, and conflicting national standards shall
be withdrawn at the latest by October 2023.
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. CEN shall not be held responsible for identifying any or all such patent rights.
This document supersedes EN ISO 5667-1:2022.
Any feedback and questions on this document should be directed to the users’ national standards
body/national committee. A complete listing of these bodies can be found on the CEN website.
According to the CEN-CENELEC Internal Regulations, the national standards organizations of the
following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria,
Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland,
Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Republic of
North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Türkiye and the
United Kingdom.
Endorsement notice
The text of ISO 5667-1:2023 has been approved by CEN as EN ISO 5667-1:2023 without any
modification.


3

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SIST EN ISO 5667-1:2023

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SIST EN ISO 5667-1:2023
INTERNATIONAL ISO
STANDARD 5667-1
Fourth edition
2023-03
Water quality — Sampling —
Part 1:
Guidance on the design of sampling
programmes and sampling techniques
Qualité de l'eau — Échantillonnage —
Partie 1: Recommandations relatives à la conception des programmes
et des techniques d’échantillonnage
Reference number
ISO 5667-1:2023(E)
© ISO 2023

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SIST EN ISO 5667-1:2023
ISO 5667-1:2023(E)
COPYRIGHT PROTECTED DOCUMENT
© ISO 2023
All rights reserved. Unless otherwise specified, or required in the context of its implementation, no part of this publication may
be reproduced or utilized otherwise in any form or by any means, electronic or mechanical, including photocopying, or posting on
the internet or an intranet, without prior written permission. Permission can be requested from either ISO at the address below
or ISO’s member body in the country of the requester.
ISO copyright office
CP 401 • Ch. de Blandonnet 8
CH-1214 Vernier, Geneva
Phone: +41 22 749 01 11
Email: copyright@iso.org
Website: www.iso.org
Published in Switzerland
ii
  © ISO 2023 – All rights reserved

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SIST EN ISO 5667-1:2023
ISO 5667-1:2023(E)
Contents Page
Foreword . vi
1 Scope . 1
2 Normative references . 1
3 Terms and definitions . 1
4 General safety precautions . 1
4.1 General . 1
4.2 Safety of personnel . 1
4.3 General environmental considerations . 2
5 Design of sampling programmes .2
5.1 General . 2
5.2 Sampling personnel . 3
5.3 Broad objectives for the design of sampling programmes . 3
5.4 Specific considerations in relation to variability . 5
5.5 Identifying the sampling location . 5
6 Characteristics and conditions affecting sampling . 6
6.1 General . 6
6.2 Variations from normal sampling conditions . 7
7 Standards for sampling from water . 7
7.1 Introduction . 7
7.2 General standards in the 5667 series . 7
7.2.1 General . 7
7.2.2 ISO 5667-3, Water quality — Sampling — Part 3: Preservation and
handling of water samples . 7
7.2.3 ISO 5667-14, Water quality — Sampling — Part 14: Guidance on quality
assurance and quality control of environmental water sampling and
handling . 7
7.2.4 ISO 5667-15, Water quality — Sampling — Part 15: Guidance on the
preservation and handling of sludge and sediment samples . 7
7.2.5 ISO 5667-16, Water quality — Sampling — Part 16: Guidance on biotesting
of samples . 8
7.2.6 ISO 5667-20, Water quality — Sampling — Part 20: Guidance on the use
of sampling data for decision making — Compliance with thresholds and
classification systems . 8
7.2.7 ISO 5667-24, Water quality — Sampling — Part 24: Guidance on the
auditing of water quality sampling . 8
7.2.8 ISO/TS 5667-25, Water quality — Sampling — Part 25: Guideline on the
validation of the storage time of water samples . 8
7.3 Standards outside the 5667 series that provide guidance on sampling programmes
in specific areas . 9
7.3.1 General . 9
7.3.2 ISO 19458, Water quality — Sampling for microbiological analysis . 9
7.4 Standards within the ISO 5667 series providing specific guidance on the sampling
of a range waters . 9
7.4.1 General . 9
7.4.2 ISO 5667-4, Water quality — Sampling — Part 4: Guidance on sampling
from lakes, natural and man-made . 9
7.4.3 ISO 5667-5, Water quality — Sampling — Part 5: Guidance on sampling of
drinking water from treatment works and piped distribution systems . 9
7.4.4 ISO 5667-6, Water quality — Sampling — Part 6: Guidance on sampling of
rivers and streams . 10
7.4.5 ISO 5667-7, Water quality — Sampling — Part 7: Guidance on sampling of
water and steam in boiler plants . 10
iii
© ISO 2023 – All rights reserved

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SIST EN ISO 5667-1:2023
ISO 5667-1:2023(E)
7.4.6 ISO 5667-8, Water quality — Sampling — Part 8: Guidance on the sampling
of wet deposition . 10
7.4.7 ISO 5667-9, Water quality — Sampling — Part 9: Guidance on sampling
from marine waters . 10
7.4.8 ISO 5667-10, Water quality — Sampling — Part 10: Guidance on sampling
of waste water . 11
7.4.9 ISO 5667-11, Water quality — Sampling — Part 11: Guidance on sampling
of groundwaters. 11
7.4.10 ISO 5667-12, Water quality — Sampling — Part 12: Guidance on sampling
of bottom sediments from rivers, lakes and estuarine areas . 11
7.4.11 ISO 5667-13, Water quality — Sampling — Part 13: Guidance on sampling
of sludges . 11
7.4.12 ISO 5667-17, Water quality — Sampling — Part 17: Guidance on sampling
of bulk suspended solids .12
7.4.13 ISO 5667-19, Water quality — Sampling — Part 19: Guidance on sampling
in marine sediments .12
7.4.14 ISO 5667-21, Water quality — Sampling— Part 21: Guidance on sampling
of drinking water distributed by tankers or means other than distribution
pipes.12
7.4.15 ISO 5667-22, Water quality — Sampling — Part 22: Guidance on the design
and installation of groundwater monitoring points.13
7.4.16 ISO 5667-26, Water quality — Sampling — Part 26: Guidance on sampling
for the parameters of the oceanic carbon dioxide system .13
8 Time and frequency of sampling .13
8.1 General .13
8.2 Water quality management programmes . 14
8.3 Quality characterization programmes . 14
8.4 Programmes for investigation of causes of contamination . 14
8.5 Statistical considerations . . 14
8.5.1 Establishment of sampling programmes . 14
8.5.2 Random and systematic variations of water quality .15
8.6 Duration of sampling occasion and composite samples . 16
9 Flow measurements and situations justifying flow measurements for water quality
purposes .16
9.1 General . 16
9.2 Direction of flow . 16
9.3 Velocity of flow . 17
9.4 Discharge rate . 17
9.5 Flow profile. 17
9.6 Cross-sectional area . 17
9.7 Justification for flow measurements in water quality control management . 17
9.7.1 Treatment plant loads . 17
9.7.2 Dilution effects (flux calculations) . 18
9.7.3 Mass flow calculations . 18
9.7.4 Transport of contaminants and rates of recovery . 18
9.7.5 Flow-related parameters . 18
9.7.6 Groundwaters . 18
9.8 Methods available for flow measurement . 18
10 Current sampling techniques .19
10.1 General . 19
10.2 Spot samples . 20
10.3 Periodic samples (discontinuous) . 20
10.3.1 Periodic samples taken at fixed time-intervals (time-dependent) or
constant time constant volume (CTCV) sampling .20
10.3.2 Periodic samples taken at fixed flow-intervals (volume-dependent) or
constant time variable volume (CTVV) sampling .20
iv
  © ISO 2023 – All rights reserved

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SIST EN ISO 5667-1:2023
ISO 5667-1:2023(E)
10.3.3 Periodic samples taken at fixed flow-intervals (flow-dependent) or
constant volume variable time (CVVT) sampling . 21
10.4 Continuous samples . 21
10.4.1 Continuous samples taken at fixed flow rates (time-continuous sampling) . 21
10.4.2 Continuous samples taken at variable flow rates (flow-continuous sampling) . 21
10.5 Series sampling . 21
10.6 Composite samples . 21
10.7 Large-volume samples . 21
11 Passive sampling .22
12 Sampling equipment for physical or chemical characteristics .22
12.1 General .22
12.2 Sampling containers . 23
12.2.1 General .23
12.2.2 Types of sample container . 23
12.3 Equipment for spot sampling . . 24
12.4 Sampling equipment for sediments . 24
12.4.1 Grab or dredge sampling . 24
12.4.2 Core samplers . .25
12.5 Sampling equipment for dissolved gases and volatile materials . 25
12.6 Sampling equipment for radioactivity characteristics . 25
12.7 Sampling equipment for biological and microbiological characteristics .26
12.8 Automatic sampling equipment .26
12.9 Sampling equipment for passive sampling . 26
12.10 Sampling equipment for suspended sediments . 27
13 Quality assurance and quality control of environmental water sampling and
handling .27
13.1 General . 27
13.2 Sources of contamination . 27
13.3 Control or prevention of contamination .28
14 Transport to, and storage of samples at, the depot or laboratory .28
15 Sample identification and records . .29
15.1 General .29
15.2 Data management . 29
15.3 Samples that can be used for legal purposes .30
Annex A (informative) Diagrams illustrating types of periodic and continuous sampling .31
Annex B (informative) Diagram illustrating types of field paperwork and labels .34
Annex C (informative) Alternative and emerging sampling techniques .36
Annex D (informative) Preparation of sampling equipment .38
Bibliography .39
v
© ISO 2023 – All rights reserved

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SIST EN ISO 5667-1:2023
ISO 5667-1:2023(E)
Foreword
ISO (the International Organization for Standardization) is a worldwide federation of national standards
bodies (ISO member bodies). The work of preparing International Standards is normally carried out
through ISO technical committees. Each member body interested in a subject for which a technical
committee has been established has the right to be represented on that committee. International
organizations, governmental and non-governmental, in liaison with ISO, also take part in the work.
ISO collaborates closely with the International Electrotechnical Commis
...

SLOVENSKI STANDARD
oSIST prEN ISO 5667-1:2022
01-december-2022
Kakovost vode - Vzorčenje - 1. del: Navodilo za načrtovanje programov in tehnik
vzorčenja (ISO/FDIS 5667-1:2022)
Water quality - Sampling - Part 1: Guidance on the design of sampling programmes and
sampling techniques (ISO/FDIS 5667-1:2022)
Qualité de l'eau - Échantillonnage - Partie 1 : recommandations relatives à la conception
des programmes et des techniques déchantillonnage (ISO/FDIS 5667-1:2022)
Ta slovenski standard je istoveten z: prEN ISO 5667-1
ICS:
13.060.45 Preiskava vode na splošno Examination of water in
general
oSIST prEN ISO 5667-1:2022 en,fr,de
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

---------------------- Page: 1 ----------------------
oSIST prEN ISO 5667-1:2022

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oSIST prEN ISO 5667-1:2022
FINAL
INTERNATIONAL ISO/FDIS
DRAFT
STANDARD 5667-1
ISO/TC 147/SC 6
Water quality — Sampling —
Secretariat: BSI
Voting begins on:
Part 1:
2022-09-14
Guidance on the design of sampling
Voting terminates on:
programmes and sampling techniques
2022-12-07
Qualité de l'eau — Échantillonnage —
Partie 1: Recommandations relatives à la conception des programmes
et des techniques d’échantillonnage
ISO/CEN PARALLEL PROCESSING
RECIPIENTS OF THIS DRAFT ARE INVITED TO
SUBMIT, WITH THEIR COMMENTS, NOTIFICATION
OF ANY RELEVANT PATENT RIGHTS OF WHICH
THEY ARE AWARE AND TO PROVIDE SUPPOR TING
DOCUMENTATION.
IN ADDITION TO THEIR EVALUATION AS
Reference number
BEING ACCEPTABLE FOR INDUSTRIAL, TECHNO-
ISO/FDIS 5667-1:2022(E)
LOGICAL, COMMERCIAL AND USER PURPOSES,
DRAFT INTERNATIONAL STANDARDS MAY ON
OCCASION HAVE TO BE CONSIDERED IN THE
LIGHT OF THEIR POTENTIAL TO BECOME STAN-
DARDS TO WHICH REFERENCE MAY BE MADE IN
NATIONAL REGULATIONS. © ISO 2022

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oSIST prEN ISO 5667-1:2022
ISO/FDIS 5667-1:2022(E)
FINAL
INTERNATIONAL ISO/FDIS
DRAFT
STANDARD 5667-1
ISO/TC 147/SC 6
Water quality — Sampling —
Secretariat: BSI
Voting begins on:
Part 1:
Guidance on the design of sampling
Voting terminates on:
programmes and sampling techniques
Qualité de l'eau — Échantillonnage —
Partie 1: Recommandations relatives à la conception des programmes
et des techniques d’échantillonnage
COPYRIGHT PROTECTED DOCUMENT
© ISO 2022
ISO/CEN PARALLEL PROCESSING
All rights reserved. Unless otherwise specified, or required in the context of its implementation, no part of this publication may
be reproduced or utilized otherwise in any form or by any means, electronic or mechanical, including photocopying, or posting on
the internet or an intranet, without prior written permission. Permission can be requested from either ISO at the address below
or ISO’s member body in the country of the requester.
RECIPIENTS OF THIS DRAFT ARE INVITED TO
ISO copyright office
SUBMIT, WITH THEIR COMMENTS, NOTIFICATION
OF ANY RELEVANT PATENT RIGHTS OF WHICH
CP 401 • Ch. de Blandonnet 8
THEY ARE AWARE AND TO PROVIDE SUPPOR TING
CH-1214 Vernier, Geneva
DOCUMENTATION.
Phone: +41 22 749 01 11
IN ADDITION TO THEIR EVALUATION AS
Reference number
Email: copyright@iso.org
BEING ACCEPTABLE FOR INDUSTRIAL, TECHNO-
ISO/FDIS 5667-1:2022(E)
Website: www.iso.org
LOGICAL, COMMERCIAL AND USER PURPOSES,
DRAFT INTERNATIONAL STANDARDS MAY ON
Published in Switzerland
OCCASION HAVE TO BE CONSIDERED IN THE
LIGHT OF THEIR POTENTIAL TO BECOME STAN-
DARDS TO WHICH REFERENCE MAY BE MADE IN
ii
  © ISO 2022 – All rights reserved
NATIONAL REGULATIONS. © ISO 2022

---------------------- Page: 4 ----------------------
oSIST prEN ISO 5667-1:2022
ISO/FDIS 5667-1:2022(E)
Contents Page
Foreword . vi
1 Scope . 1
2 Normative references . 1
3 Terms and definitions . 1
4 General safety precautions . 1
4.1 General . 1
4.2 Safety of personnel . 1
4.3 General environmental considerations . 2
5 Design of sampling programmes .2
5.1 General . 2
5.2 Sampling personnel . 3
5.3 Broad objectives for the design of sampling programmes . 3
5.4 Specific considerations in relation to variability . 5
5.5 Identifying the sampling location . 5
6 Characteristics and conditions affecting sampling . 6
6.1 General . 6
6.2 Variations from normal sampling conditions . 7
7 Standards for sampling from water . 7
7.1 Introduction . 7
7.2 General standards in the 5667 series . 7
7.2.1 General . 7
7.2.2 ISO 5667-3, Water quality — Sampling — Part 3: Preservation and
handling of water samples . 7
7.2.3 ISO 5667-14, Water quality — Sampling — Part 14: Guidance on quality
assurance and quality control of environmental water sampling and
handling . 7
7.2.4 ISO 5667-15, Water quality — Sampling — Part 15: Guidance on the
preservation and handling of sludge and sediment samples . 7
7.2.5 ISO 5667-16, Water quality — Sampling — Part 16: Guidance on biotesting
of samples . 8
7.2.6 ISO 5667-20, Water quality — Sampling — Part 20: Guidance on the use
of sampling data for decision making — Compliance with thresholds and
classification systems . 8
7.2.7 ISO 5667-24, Water quality — Sampling — Part 24: Guidance on the
auditing of water quality sampling . 8
7.2.8 ISO/TS 5667-25, Water quality — Sampling — Part 25: Guideline on the
validation of the storage time of water samples . 8
7.3 Standards outside the 5667 series that provide guidance on sampling programmes
in specific areas . 9
7.3.1 General . 9
7.3.2 ISO 19458, Water quality — Sampling for microbiological analysis . 9
7.4 Standards within the ISO 5667 series providing specific guidance on the sampling
of a range waters . 9
7.4.1 General . 9
7.4.2 ISO 5667-4, Water quality — Part 4: Guidance on sampling from lakes,
natural and man-made . 9
7.4.3 ISO 5667-5, Water quality — Part 5: Guidance on sampling of drinking
water from treatment works and piped distribution systems . 9
7.4.4 ISO 5667-6, Water quality — Part 6: Guidance on sampling of rivers and
streams . 10
7.4.5 ISO 5667-7, Water quality — Part 7: Guidance on sampling of water and
steam in boiler plants . 10
iii
© ISO 2022 – All rights reserved

---------------------- Page: 5 ----------------------
oSIST prEN ISO 5667-1:2022
ISO/FDIS 5667-1:2022(E)
7.4.6 ISO 5667-8, Water quality — Part 8: Guidance on the sampling of wet
deposition . 10
7.4.7 ISO 5667-9, Water quality — Part 9: Guidance on sampling from marine
waters. 10
7.4.8 ISO 5667-10, Water quality — Part 10: Guidance on sampling of waste water . 11
7.4.9 ISO 5667-11, Water quality — Part 11: Guidance on sampling of
groundwaters . 11
7.4.10 ISO 5667-12, Water quality — Part 12: Guidance on sampling of bottom
sediments from rivers, lakes and estuarine areas . 11
7.4.11 ISO 5667-13, Water quality — Part 13: Guidance on sampling of sludges . 11
7.4.12 ISO 5667-17, Water quality — Part 17: Guidance on sampling of bulk
suspended solids .12
7.4.13 ISO 5667-19, Water quality — Part 19: Guidance on sampling in marine
sediments .12
7.4.14 ISO 5667-21, Water quality — Part 21: Guidance on sampling of drinking
water distributed by tankers or means other than distribution pipes .12
7.4.15 ISO 5667-22, Water quality — Part 22: Guidance on the design and
installation of groundwater monitoring points .13
7.4.16 ISO 5667-26, Water quality — Sampling — Part 26: Guidance on sampling
for the parameters of the oceanic carbon dioxide system .13
8 Time and frequency of sampling .13
8.1 General .13
8.2 Water quality management programmes . 14
8.3 Quality characterization programmes . 14
8.4 Programmes for investigation of causes of contamination . 14
8.5 Statistical considerations . . 14
8.5.1 Establishment of sampling programmes . 14
8.5.2 Random and systematic variations of water quality .15
8.6 Duration of sampling occasion and composite samples . 16
9 Flow measurements and situations justifying flow measurements for water quality
purposes .16
9.1 General . 16
9.2 Direction of flow . 16
9.3 Velocity of flow . 17
9.4 Discharge rate . 17
9.5 Flow profile. 17
9.6 Cross-sectional area . 17
9.7 Justification for flow measurements in water quality control management . 17
9.7.1 Treatment plant loads . 17
9.7.2 Dilution effects (flux calculations) . 17
9.7.3 Mass flow calculations . 18
9.7.4 Transport of contaminants and rates of recovery . 18
9.7.5 Flow-related parameters . 18
9.7.6 Groundwaters . 18
9.8 Methods available for flow measurement . 18
10 Current sampling techniques .19
10.1 General . 19
10.2 Spot samples . 20
10.3 Periodic samples (discontinuous) . 20
10.3.1 Periodic samples taken at fixed time-intervals (time-dependent) or
constant time constant volume (CTCV) . 20
10.3.2 Periodic samples taken at fixed flow-intervals (volume-dependent) or
constant time variable volume (CTVV) . 20
10.3.3 Periodic samples taken at fixed flow-intervals (flow-dependent) or
constant volume variable time sampling (CVVT) .20
10.4 Continuous samples . 21
10.4.1 Continuous samples taken at fixed flow rates (time-continuous samples) . 21
iv
  © ISO 2022 – All rights reserved

---------------------- Page: 6 ----------------------
oSIST prEN ISO 5667-1:2022
ISO/FDIS 5667-1:2022(E)
10.4.2 Continuous samples taken at variable flow rates (flow-continuous samples). 21
10.5 Series sampling . 21
10.6 Composite samples . 21
10.7 Large-volume samples . 21
11 Passive sampling .22
12 Sampling equipment for physical or chemical characteristics .22
12.1 General .22
12.2 Sampling containers . 22
12.2.1 General .22
12.2.2 Types of sample container . 23
12.3 Equipment for spot sampling . . 24
12.4 Sampling equipment for sediments . 24
12.4.1 Grab or dredge sampling . 24
12.4.2 Core samplers . .25
12.5 Sampling equipment for dissolved gases and volatile materials . 25
12.6 Sampling equipment for radioactivity characteristics . 25
12.7 Sampling equipment for biological and microbiological characteristics .25
12.8 Automatic sampling equipment .26
12.9 Sampling equipment for passive sampling . 26
12.10 Sampling equipment for suspended sediments . 26
13 Quality assurance and quality control of environmental water sampling and
handling .27
13.1 General . 27
13.2 Sources of contamination . 27
13.3 Control or prevention of contamination . 27
14 Transport to, and storage of samples at, the depot or laboratory .28
15 Sample identification and records . .29
15.1 General .29
15.2 Data management . 29
15.3 Samples that can be used for legal purposes .30
Annex A (informative) Diagrams illustrating types of periodic and continuous samples .31
Annex B (informative) Diagram illustrating types of field paperwork and labels etc .34
Annex C (informative) Alternative and emerging sampling techniques .36
Annex D (informative) Preparation of sampling equipment .38
Bibliography .39
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oSIST prEN ISO 5667-1:2022
ISO/FDIS 5667-1:2022(E)
Foreword
ISO (the International Organization for Standardization) is a worldwide federation of national standards
bodies (ISO member bodies). The work of preparing International Standards is normally carried out
through ISO technical committees. Each member body interested in a subject for which a technical
committee has been established has the right to be represented on that committee. International
organizations, governmental and non-governmental, in liaison with ISO, also take part in the work.
ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of
electrotechnical standardization.
The procedures used to develop this document and those intended for its further maintenance are
described in the ISO/IEC Directives, Part 1. In particular, the different approval criteria needed for the
different types of ISO documents should be noted. This document was drafted in accordance with the
editorial rules of the ISO/IEC Directives, Part 2 (see www.iso.org/directives).
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. ISO shall not be held responsible for identifying any or all such patent rights. Details of
any patent rights identified during the development of the document will be in the Introduction and/or
on the ISO list of patent declarations received (see www.iso.org/patents).
Any trade name used in this document is information given for the convenience of users and does not
constitute an endorsement.
For an explanation of the voluntary nature of standards, the meaning of ISO specific terms and
expressions related to conformity assessment, as well as information about ISO's adherence to
the World Trade Organization (WTO) principles in the Technical Barriers to Trade (TBT) see
www.iso.org/iso/foreword.html.
This document was prepared by Technical Committee ISO/TC 147, Water quality, Subcommittee SC 6,
Sampling (general methods), in collaboration with the European Committee for Standardization (CEN)
Technical Committee CEN/TC 230, Water analysis, in accordance with the Agreement on technical
cooperation between ISO and CEN (Vienna Agreement).
This fourth edition cancels and replaces the third edition (ISO 5667-1:2020), of which it constitutes a
minor revision. The changes compared to the previous edition are as follows:
— corrections have been made to 10.3 and associated cross references to Annex A;
— subclauses have been included in Clause 7 referring to the most recent additions to the ISO 5667
series.
A list of all parts in the ISO 5667 series can be found on the ISO website.
Any feedback or questions on this document should be directed to the user’s national standards body. A
complete listing of these bodies can be found at www.iso.org/members.html.
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oSIST prEN ISO 5667-1:2022
FINAL DRAFT INTERNATIONAL STANDARD ISO/FDIS 5667-1:2022(E)
Water quality — Sampling —
Part 1:
Guidance on the design of sampling programmes and
sampling techniques
1 Scope
This document sets out the general principles for, and provides guidance on, the design of sampling
programmes and sampling techniques for all aspects of sampling of water (including waste waters,
sludges, effluents, suspended solids and sediments).
This document does not include detailed instructions for specific sampling situations, which are
covered in various other parts of ISO 5667 and in ISO 19458.
2 Normative references
There are no normative references.
3 Terms and definitions
No terms and definitions are listed in this document.
ISO and IEC ma
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