Chemicals used for treatment of water intended for human consumption - Aluminium iron(III) chloride (monomeric) and aluminium iron(III) chloride hydroxide (monomeric)

This European Standard is applicable to aluminium iron(III) chloride (monomeric) and aluminium iron(III) chloride hydroxide (monomeric) used for treatment of water intended for human consumption. It describes the characteristics and specifies the requirements for aluminium iron(III) chloride (monomeric) and aluminium iron(III) chloride hydroxide (monomeric) and refers to the corresponding test methods. It also gives information on their use in water treatment.

Produkte zur Aufbereitung von Wasser für den menschlichen Gebrauch - Aluminium-Eisen(III)chlorid (Monomer) und Aluminium-Eisen(III)hydroxydchlorid (Monomer)

Diese Europäische Norm gilt für Aluminium-Eisen(III)chlorid (Monomer) und Aluminium-Eisen(III)hydroxidchlorid (Monomer) zur Aufbereitung von Wasser für den menschlichen Gebrauch. Sie beschreibt Eigenschaften von Aluminium-Eisen(III)chlorid (Monomer) und Aluminium-Eisen(III)hydroxidchlorid (Monomer), legt deren Anforderungen fest und gibt Hinweise auf entsprechende analytische Methoden. Sie gibt auch Informationen für die Anwendung in der Wasseraufbereitung.

Produits chimiques utilisés pour le traitement de l'eau destinée a la consommation humaine - Chlorure et hydroxychlorure d'aluminium et de fer(III) (monomeres)

Cette Norme européenne est applicable aux chlorure et hydroxychlorure d'aluminium et de fer(III) (monomeres), utilisés pour le traitement de l'eau destinée a la consommation humaine. Elle décrit les caractéristiques et précise les prescriptions des chlorure et hydroxychlorure d'aluminium et de fer(III) (monomeres) et donne la référence des méthodes d'analyse. Elle donne les informations pour leur emploi dans le traitement de l'eau.

Kemikalije, ki se uporabljajo za pripravo pitne vode – Aluminijev železov (III) klorid in aluminijev železov (III) klorid hidroksid

General Information

Status
Withdrawn
Publication Date
30-Nov-2002
Withdrawal Date
28-Feb-2005
Current Stage
9900 - Withdrawal (Adopted Project)
Start Date
01-Mar-2005
Due Date
01-Mar-2005
Completion Date
01-Mar-2005

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SLOVENSKI STANDARD
SIST EN 935:2002
01-december-2002
Kemikalije, ki se uporabljajo za pripravo pitne vode – Aluminijev železov (III) klorid
in aluminijev železov (III) klorid hidroksid
Chemicals used for treatment of water intended for human consumption - Aluminium iron
(III) chloride (monomeric) and aluminium iron(III) chloride hydroxide (monomeric)
Produkte zur Aufbereitung von Wasser für den menschlichen Gebrauch - Aluminium-
Eisen(III)chlorid (Monomer) und Aluminium-Eisen(III)hydroxydchlorid (Monomer)
Produits chimiques utilisés pour le traitement de l'eau destinée a la consommation
humaine - Chlorure et hydroxychlorure d'aluminium et de fer(III) (monomeres)
Ta slovenski standard je istoveten z: EN 935:2001
ICS:
13.060.20 Pitna voda Drinking water
71.100.80 .HPLNDOLMH]DþLãþHQMHYRGH Chemicals for purification of
water
SIST EN 935:2002 en
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

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SIST EN 935:2002

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SIST EN 935:2002
EUROPEAN STANDARD
EN 935
NORME EUROPÉENNE
EUROPÄISCHE NORM
October 2001
ICS 71.100.80
English version
Chemicals used for treatment of water intended for human
consumption - Aluminium iron(III) chloride (monomeric) and
aluminium iron(III) chloride hydroxide (monomeric)
Produits chimiques utilisés pour le traitement de l'eau Produkte zur Aufbereitung von Wasser für den
destinée à la consommation humaine - Chlorure et menschlichen Gebrauch - Aluminium-Eisen(III) Chlorid
hydroxychlorure d'aluminium et de fer(III) (monomères) (Monomer) und Aluminium-Eisen(III) Hydroxydchlorid
(Monomer)
This European Standard was approved by CEN on 29 September 2001.
CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European
Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national
standards may be obtained on application to the Management Centre or to any CEN member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by translation
under the responsibility of a CEN member into its own language and notified to the Management Centre has the same status as the official
versions.
CEN members are the national standards bodies of Austria, Belgium, Czech Republic, Denmark, Finland, France, Germany, Greece,
Iceland, Ireland, Italy, Luxembourg, Netherlands, Norway, Portugal, Spain, Sweden, Switzerland and United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION
EUROPÄISCHES KOMITEE FÜR NORMUNG
Management Centre: rue de Stassart, 36  B-1050 Brussels
© 2001 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN 935:2001 E
worldwide for CEN national Members.

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SIST EN 935:2002
EN 935:2001 (E)
Contents
page
Foreword .3
Introduction .4
1 Scope .5
2 Normative references.5
3 Description .5
3.1 Identification.5
3.2 Commercial form.6
3.3 Physical properties.6
3.4 Chemical properties .7
4 Purity criteria .7
4.1 General .7
4.2 Composition of commercial product.8
4.3 Impurities and main by-products.8
4.4 Toxic substances .8
5 Test methods .8
5.1 Sampling .8
5.2 Analyses.9
6 Labelling - Transportation - Storage .9
6.1 Means of delivery.9
6.2 Risk and safety labelling according to the EU Directives .10
6.3 Transportation regulations and labelling.10
6.4 Marking .11
6.5 Storage.11
Annex A (informative)  General information on aluminium iron(III) chloride (monomeric) and aluminium
iron(III) chloride hydroxide (monomeric).12
A.1 Origin.12
A.2 Use.12
Annex B (normative) General rules relating to safety.14
B.1 Rules for safe handling and use .14
B.2 Emergency procedures.14
Bibliography .15
2

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SIST EN 935:2002
EN 935:2001 (E)
Foreword
This European Standard has been prepared by Technical Committee CEN/TC 164 "Water supply", the secretariat
of which is held by AFNOR.
This European Standard shall be given the status of a national standard, either by publication of an identical text or
by endorsement, at the latest by April 2002, and conflicting national standards shall be withdrawn at the latest by
April 2002.
This European Standard refers to the EU Directive 80/778/EEC (see [1]) of 15 July 1980, however it will be revised
in future in order to take account of the new EU Directive 98/83/EEC (see [3]).
Annex A is informative.
Annex B is normative.
According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following
countries are bound to implement this European Standard: Austria, Belgium, Czech Republic, Denmark, Finland,
France, Germany, Greece, Iceland, Ireland, Italy, Luxembourg, Netherlands, Norway, Portugal, Spain, Sweden,
Switzerland and the United Kingdom.
3

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SIST EN 935:2002
EN 935:2001 (E)
Introduction
In respect of potential adverse effects on the quality of water intended for human consumption, caused by the
product covered by this standard :
a) this standard provides no information as to whether the product may be used without restriction in any of the
Member States of the EU or EFTA ;
b) it should be noted that, while awaiting the adoption of verifiable European criteria, existing national regulations
concerning the use and/or the characteristics of this product remain in force.
4

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SIST EN 935:2002
EN 935:2001 (E)
1 Scope
This European Standard is applicable to aluminium iron(III) chloride (monomeric) and aluminium iron(III)
chloride hydroxide (monomeric) used for treatment of water intended for human consumption. It describes the
characteristics and specifies the requirements for aluminium iron(III) chloride (monomeric) and aluminium
iron(III) chloride hydroxide (monomeric) and refers to the corresponding test methods. It also gives information
on their use in water treatment.
2 Normative references
This European Standard incorporates by dated or undated reference, provisions from other publications. These
normative references are cited at the appropriate places in the text, and the publications are listed hereafter. For
dated references, subsequent amendments to or revisions of any of these publications apply to this European
Standard only when incorporated in it by amendment or revision. For undated references the latest edition of the
publication referred to applies (including amendments).
EN 1302, Chemicals used for treatment of water intended for human consumption – Aluminium-based coagulants –
Analytical methods.
ISO 3165, Sampling of chemical products for industrial use – Safety in sampling.
ISO 6206, Chemical products for industrial use - Sampling – Vocabulary.
3 Description
3.1 Identification
3.1.1 Chemical name
a) Aluminium iron(III) chloride (monomeric);
b) Aluminium iron(III) chloride hydroxide (monomeric).
3.1.2 Synonym or common names
For Aluminium iron(III) chloride hydroxide (monomeric): bauxite or clay hydroxide chloride.
3.1.3 Relative molecular mass
Variable (see 3.1.4).
3.1.4 Empirical formula
Al Fe (OH) Cl with (a + b) = 3 and x = 0,67 to 0,99 for aluminium iron chlorides
x 1-x a b
x = 0,80 to 0,99 for aluminium iron chloride hydroxides
a = 0 to 1,05
b = 3 to 1,95
a = 0 for aluminium iron(III) chloride (monomeric) products, and these products normally have a detectable free
acidity (see 5.2)
5

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SIST EN 935:2002
EN 935:2001 (E)
3.1.5 Chemical formula
Variable (see 3.1.4).
1)
3.1.6 CAS Registry Number
The following is a list of CAS Registry Numbers for products or their components.
AlCl : 7446-70-0.
3
FeCl : 7705-08-0.
3
Al(OH) Cl : 1327-41-9 with (a + b) = 3 and a less than 1,05.
a b
Al(OH)Cl : 14215-15-7.
2
2)
3.1.7 EINECS reference
The following is a list of EINECS reference numbers for products or their components.
AlCl : 231-208-1.
3
FeCl : 231-729-4.
3
Al(OH) Cl : 215-477-2.
a b
Al(OH)Cl : 238-071-7.
2
3.2 Commercial form
The products are available as liquids.
3.3 Physical properties
3.3.1 Appearance
The products are a yellow to brown liquids.
3.3.2 Density
The density depends on the particular composition, especially the aluminium ion content, expressed as percentage
by mass (% (m/m)) of aluminium.
Typical value : 1,3 g/ml for Al 5,3 % (m/m).
3.3.3 Solubility in water
Aluminium iron(III) chloride (monomeric) and aluminium iron(III) chloride hydroxide (monomeric) are fully miscible
with water.
NOTE Depending on the particular product, dilute solutions can hydrolyze and form a precipitate.

1)
Chemical Abstracts Service Registry Number.
2)
European inventory of Existing Commercial chemical Substances.
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