Test on gases evolved during combustion of materials from cables - Part 1: Determination of the halogen acid gas content

This part of IEC 60754 specifies the apparatus and procedure for the determination of the amount of halogen acid gas, other than hydrofluoric acid, evolved during the combustion of compounds based on halogenated polymers and compounds containing halogenated additives taken from electric or optical fibre cable constructions. NOTE 1 This test method is not able to determine hydrofluoric acid. A suitable method may be found in IEC 60684-2. NOTE 2 This test method may be used to test materials to be used in cable manufacture, but a declaration of cable performance should not be made based on such a test. NOTE 3 The relevant cable standard should indicate which components of the cable should be tested. NOTE 4 For the purposes of this standard, the term “electric cable” covers all insulated metallic conductor cables used for the conveyance of energy or signals. The method specified in this standard is intended for the testing of individual components used in a cable construction. The use of this method will enable the verification of requirements which are stated in the appropriate cable specification for individual components of a cable construction. NOTE 5 By agreement between the producer and purchaser, the methodology given in this standard may be used to test combinations of materials representing a cable construction, but a declaration of cable performance to this standard should not be made based on such a test. Information on such a method is given in Annex A. For reasons of precision this method is not recommended for reporting values of halogen acid evolved less than 5 mg/g of the sample taken.

Prüfung der bei der Verbrennung der Werkstoffe von Kabeln und isolierten Leitungen entstehenden Gase -- Teil 1: Bestimmung des Gehaltes an Halogenwasserstoffsäure

Essai sur les gaz émis lors de la combustion des matériaux prélevés sur câbles -- Partie 1: Détermination de la quantité de gaz acide halogéné

La CEI 60754-1:2011 décrit l'appareillage et la procédure d'essai pour la détermination de la quantité de gaz acide halogéné, autre que l'acide fluorhydrique, émis au cours de la combustion de mélanges à base de polymères halogénés et de mélanges contenant des additifs halogénés prélevés sur un câble électrique ou à fibre optique. La présente méthode décrite dans cette norme est destinée à être utilisée pour l'analyse des composants individuels utilisés dans la construction d'un câble. L'emploi de cette méthode d'essai permettra de vérifier les exigences qui sont établies dans la spécification du câble pour les composants individuels du câble. Les modifications techniques importantes par rapport aux publications antérieures sont les suivantes:
  - amélioration définition des exigences de sécurité relatives au piégeage des gaz et à l'utilisation des réactifs;
- introduction de recommandations pour la préparation des éprouvettes d'essai pour une meilleure combustion;
- améliorations du mode opératoire pour établir le régime de chauffage;
- amélioration de l'expression des tolérances et précisions;
- définition de la procédure d'un essai à blanc;
- introduction d'une annexe informative donnant des détails sur la méthodologie pour la détermination de la quantité de gaz acides halogénés contenus dans un échantillon représentatif de la construction du câble.
Elle a le statut d'une publication groupée de sécurité conformément au Guide CEI 104.

Ugotavljanje nastajanja plinov pri gorenju kabelskih materialov - 1. del: Ugotavljanje količine plina halogenske kisline (IEC 60754-1:2011)

Ta del standarda IEC 60754 določa napravo in postopek za ugotavljanje količine plina halogenske kisline, ki ni fluorovodikova kislina, nastale pri gorenju spojin, ki temeljijo na halogeniranih polimerih, in gorenju spojin, ki vsebujejo halogenirane dodatke iz konstrukcij električnih ali optičnih kablov. OPOMBA 1: s to preskusno metodo ni mogoče določiti fluorovodikove kisline. Primerno metodo je mogoče poiskati v standardu IEC 60684-2. OPOMBA 2: ta preskusna metoda se lahko uporabi za preskušanje materialov, ki so namenjeni uporabi pri izdelavi kablov, a deklaracija zmogljivosti kabla naj ne bi temeljila na takem preskusu. OPOMBA 3: ustrezni standard za kable navaja, katere komponente kabla je treba testirati. OPOMBA 4: za namen tega standarda pojem »električni kabel« zajema vse izolirane kovinske vodnike, ki se uporabljajo za prenos energije ali signalov. Metoda, določena v tem standardu, je namenjena preskušanju posameznih komponent, ki se uporabljajo pri izdelavi kablov. Uporaba te metode bo omogočila preverjanje zahtev, ki so navedene v ustrezni kabelski specifikaciji za posamezne komponente kabelske zgradbe. OPOMBA 5: po dogovoru med proizvajalcem in kupcem se metodologija, podana v tem standardu, lahko uporablja za testiranje kombinacij materialov, ki predstavljajo zgradbo kabla, vendar deklaracija o zmogljivosti kabla k temu standardu naj ne bi temeljila na takem preskusu. Informacije o takšnem načinu so podane v dodatku A. Zaradi natančnosti ta metoda ni priporočljiva za poročanje o vrednosti halogenske kisline z manj kot 5 mg/g odvzetega vzorca.

General Information

Status
Published
Publication Date
18-May-2014
Technical Committee
Current Stage
6060 - National Implementation/Publication (Adopted Project)
Start Date
05-May-2014
Due Date
10-Jul-2014
Completion Date
19-May-2014

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SLOVENSKI STANDARD
SIST EN 60754-1:2014
01-junij-2014
1DGRPHãþD
SIST EN 50267-1:1999
SIST EN 50267-2-1:1999
SIST EN 50267-2-2:1999
SIST EN 50267-2-3:1999
8JRWDYOMDQMHQDVWDMDQMDSOLQRYSULJRUHQMXNDEHOVNLKPDWHULDORYGHO
8JRWDYOMDQMHNROLþLQHSOLQDKDORJHQVNHNLVOLQH ,(&
Test on gases evolved during combustion of materials from cables - Part 1:
Determination of the halogen acid gas content
Prüfung der bei der Verbrennung der Werkstoffe von Kabeln und isolierten Leitungen
entstehenden Gase -- Teil 1: Bestimmung des Gehaltes an Halogenwasserstoffsäure
Essai sur les gaz émis lors de la combustion des matériaux prélevés sur câbles -- Partie
1: Détermination de la quantité de gaz acide halogéné
Ta slovenski standard je istoveten z: EN 60754-1:2014
ICS:
13.220.40 Sposobnost vžiga in Ignitability and burning
obnašanje materialov in behaviour of materials and
proizvodov pri gorenju products
29.060.20 Kabli Cables
SIST EN 60754-1:2014 en
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

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SIST EN 60754-1:2014

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SIST EN 60754-1:2014

EUROPEAN STANDARD
EN 60754-1

NORME EUROPÉENNE
April 2014
EUROPÄISCHE NORM

ICS 13.220.40; 29.020; 29.060.20 Supersedes EN 50267-1:1998 (partially), EN 50267-2-1:1998 (partially), EN 50267-2-2:1998
(partially), EN 50267-2-3:1998 (partially)


English version


Test on gases evolved during combustion of materials from cables -
Part 1: Determination of the halogen acid gas content
(IEC 60754-1:2011 + corrigendum Nov. 2013)


Essai sur les gaz émis lors de la Prüfung der bei der Verbrennung der
combustion des matériaux prélevés Werkstoffe von Kabeln und isolierten
sur câbles - Leitungen entstehenden Gase -
Partie 1: Détermination de la quantité Teil 1: Bestimmung des Gehaltes an
de gaz acide halogéné Halogenwasserstoffsäure
(CEI 60754-1:2011 + corrigendum Nov. (IEC 60754-1:2011 + Corrigendum Nov.
2013) 2013)



This European Standard was approved by CENELEC on 2014-01-27. CENELEC members are bound to comply
with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard
the status of a national standard without any alteration.

Up-to-date lists and bibliographical references concerning such national standards may be obtained on
application to the CEN-CENELEC Management Centre or to any CENELEC member.

This European Standard exists in three official versions (English, French, German). A version in any other
language made by translation under the responsibility of a CENELEC member into its own language and notified
to the CEN-CENELEC Management Centre has the same status as the official versions.

CENELEC members are the national electrotechnical committees of Austria, Belgium, Bulgaria, Croatia, Cyprus,
the Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany,
Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, the Netherlands, Norway, Poland,
Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdom.

CENELEC
European Committee for Electrotechnical Standardization
Comité Européen de Normalisation Electrotechnique
Europäisches Komitee für Elektrotechnische Normung

CEN-CENELEC Management Centre: Avenue Marnix 17, B - 1000 Brussels


© 2014 CENELEC - All rights of exploitation in any form and by any means reserved worldwide for CENELEC members.
Ref. No. EN 60754-1:2014 E

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SIST EN 60754-1:2014
EN 60754-1:2014 - 2 -
Foreword
This document (EN 60754-1:2014) consists of the text of IEC 60754-1:2011 +
corrigendum November 2013, prepared by IEC/TC 20 "Electric cables".

The following dates are fixed:
(dop) 2015-01-27
• latest date by which the document has to be
implemented at national level by
publication of an identical national
standard or by endorsement
(dow) 2017-01-27
• latest date by which the national
standards conflicting with the
document have to be withdrawn

This document supersedes EN 50267-1:1998 (PART), EN 50267-2-1:1998 (PART),
EN 50267-2-2:1998 (PART) and EN 50267-2-3:1998 (PART).

Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. CENELEC [and/or CEN] shall not be held responsible for identifying any or all such
patent rights.

This standard covers the Principle Elements of the Safety Objectives for Electrical Equipment
Designed for Use within Certain Voltage Limits (LVD - 2006/95/EC).

Endorsement notice
The text of the International Standard IEC 60754-1:2011 + corrigendum November 2013 was
approved by CENELEC as a European Standard without any modification.
In the official version, for Bibliography, the following note has to be added for the standard indicated :

IEC 60684-2 NOTE Harmonized as EN 60684-2.

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SIST EN 60754-1:2014
- 3 - EN 60754-1:2014
Annex ZA
(normative)

Normative references to international publications
with their corresponding European publications

The following documents, in whole or in part, are normatively referenced in this document and are
indispensable for its application. For dated references, only the edition cited applies. For undated
references, the latest edition of the referenced document (including any amendments) applies.

NOTE  When an international publication has been modified by common modifications, indicated by (mod), the relevant EN/HD
applies.

Publication Year Title EN/HD Year

ISO 385 - Laboratory glassware - Burettes EN ISO 385 -


ISO 1042 - Laboratory glassware - One-mark EN ISO 1042 -
volumetric flasks


ISO 3696 - Water for analytical laboratory use - EN ISO 3696 -
Specification and test methods

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SIST EN 60754-1:2014

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SIST EN 60754-1:2014
IEC 60754-1
®

Edition 3.0 2011-11
INTERNATIONAL
STANDARD
NORME
INTERNATIONALE
GROUP SAFETY PUBLICATION
PUBLICATION GROUPÉE DE SÉCURITÉ


Test on gases evolved during combustion of materials from cables –
Part 1: Determination of the halogen acid gas content

Essai sur les gaz émis lors de la combustion des matériaux prélevés sur câbles
– Partie 1: Détermination de la quantité de gaz acide halogéné

INTERNATIONAL
ELECTROTECHNICAL
COMMISSION
COMMISSION
ELECTROTECHNIQUE
PRICE CODE
INTERNATIONALE
CODE PRIX S
ICS 13.220.40; 29.020; 29.060.20 ISBN 978-2-88912-715-3

® Registered trademark of the International Electrotechnical Commission
Marque déposée de la Commission Electrotechnique Internationale

---------------------- Page: 7 ----------------------

SIST EN 60754-1:2014
– 2 – 60754-1 © IEC:2011
CONTENTS
FOREWORD . 4
INTRODUCTION . 6
1 Scope . 7
2 Normative references . 7
3 Terms and definitions . 7
4 Test method principle . 8
5 Test apparatus . 8
5.1 General . 8
5.2 Tube furnace . 8
5.3 Quartz glass tube . 8
5.4 Combustion boats . 8
5.5 Bubbling devices for gases . 9
5.6 Air supply system . 9
5.7 Analytical balance . 10
5.8 Laboratory glassware . 10
5.9 Reagents . 10
6 Test specimen . 10
6.1 General . 10
6.2 Conditioning of specimen . 10
6.3 Mass of specimen . 11
7 Test procedure . 11
7.1 General . 11
7.2 Test apparatus and arrangement . 11
7.3 Heating procedure . 11
7.3.1 Determination of heating regime . 11
7.3.2 Test specimen heating procedure . 11
7.4 Washing procedure . 12
7.5 Determination of halogen acid content . 12
7.5.1 Blank test . 12
7.5.2 Material test . 12
7.5.3 Halogen acid content calculation . 13
8 Evaluation of the test results . 13
9 Performance requirement . 13
10 Test report. 13
Annex A (informative) Determination of the halogen acid gas content of a sample
representative of a cable construction . 20
Bibliography . 21

Figure 1 – Device for inserting combustion boat and test specimen . 15
Figure 2 – Example of a gas washing bottle . 16
Figure 3 – Test apparatus: method 1 – Use of synthetic or compressed air from a
bottle . 17
Figure 4 – Test apparatus: method 2 – Use of laboratory compressed air supply . 18

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SIST EN 60754-1:2014
60754-1 © IEC:2011 – 3 –
Figure 5 – Test apparatus: method 3 – Use of ambient air sucked by means of a
suction pump . 19

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SIST EN 60754-1:2014
– 4 – 60754-1 © IEC:2011
INTERNATIONAL ELECTROTECHNICAL COMMISSION
____________

TEST ON GASES EVOLVED DURING
COMBUSTION OF MATERIALS FROM CABLES –

Part 1: Determination of the halogen acid gas content


FOREWORD
1) The International Electrotechnical Commission (IEC) is a worldwide organization for standardization comprising
all national electrotechnical committees (IEC National Committees). The object of IEC is to promote
international co-operation on all questions concerning standardization in the electrical and electronic fields. To
this end and in addition to other activities, IEC publishes International Standards, Technical Specifications,
Technical Reports, Publicly Available Specifications (PAS) and Guides (hereafter referred to as “IEC
Publication(s)”). Their preparation is entrusted to technical committees; any IEC National Committee interested
in the subject dealt with may participate in this preparatory work. International, governmental and non-
governmental organizations liaising with the IEC also participate in this preparation. IEC collaborates closely
with the International Organization for Standardization (ISO) in accordance with conditions determined by
agreement between the two organizations.
2) The formal decisions or agreements of IEC on technical matters express, as nearly as possible, an international
consensus of opinion on the relevant subjects since each technical committee has representation from all
interested IEC National Committees.
3) IEC Publications have the form of recommendations for international use and are accepted by IEC National
Committees in that sense. While all reasonable efforts are made to ensure that the technical content of IEC
Publications is accurate, IEC cannot be held responsible for the way in which they are used or for any
misinterpretation by any end user.
4) In order to promote international uniformity, IEC National Committees undertake to apply IEC Publications
transparently to the maximum extent possible in their national and regional publications. Any divergence
between any IEC Publication and the corresponding national or regional publication shall be clearly indicated in
the latter.
5) IEC itself does not provide any attestation of conformity. Independent certification bodies provide conformity
assessment services and, in some areas, access to IEC marks of conformity. IEC is not responsible for any
services carried out by independent certification bodies.
6) All users should ensure that they have the latest edition of this publication.
7) No liability shall attach to IEC or its directors, employees, servants or agents including individual experts and
members of its technical committees and IEC National Committees for any personal injury, property damage or
other damage of any nature whatsoever, whether direct or indirect, or for costs (including legal fees) and
expenses arising out of the publication, use of, or reliance upon, this IEC Publication or any other IEC
Publications.
8) Attention is drawn to the Normative references cited in this publication. Use of the referenced publications is
indispensable for the correct application of this publication.
9) Attention is drawn to the possibility that some of the elements of this IEC Publication may be the subject of
patent rights. IEC shall not be held responsible for identifying any or all such patent rights.
International Standard IEC 60754-1 has been prepared by IEC technical committee 20:
Electric cables.
It has the status of a group safety publication in accordance with IEC Guide 104.
This third edition cancels and replaces the second edition, published in 1994, and constitutes
a technical revision.
The significant technical changes with respect to the previous edition are as follows:
– improved definition of safety requirements relating to capture of gases and use of
reagents;
– introduction of guidance on preparation of test specimens for a more even combustion;
– improvements to the procedure for establishing the heating regime;
– improved expression of tolerances and precision;

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SIST EN 60754-1:2014
60754-1 © IEC:2011 – 5 –
– definition of the procedure for the blank test;
– introduction of an informative annex giving details of a methodology for the determination
of the halogen acid gas content of a sample representative of a cable construction.
The text of this standard is based on the following documents:
FDIS Report on voting
20/1266/FDIS 20/1276/RVD

Full information on the voting for the approval of this standard can be found in the report on
voting indicated in the above table.
This publication has been drafted in accordance with the ISO/IEC Directives, Part 2.
A list of all the parts in the IEC 60754 series, published under the general title Test on gases
evolved during combustion of materials from cables, can be found on the IEC website.
The committee has decided that the contents of this publication will remain unchanged until
the stability date indicated on the IEC web site under "http://webstore.iec.ch" in the data
related to the specific publication. At this date, the publication will be
• reconfirmed,
• withdrawn,
• replaced by a revised edition, or
• amended.

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SIST EN 60754-1:2014
– 6 – 60754-1 © IEC:2011
INTRODUCTION
IEC 60754 consists of the following parts, under the general title Test on gases evolved
during combustion of materials from cables:
– Part 1: Determination of the halogen acid gas content
– Part 2: Determination of acidity (by pH measurement) and conductivity
IEC 60754-1 was developed due to concerns expressed by cable users over the amount of
acid gas which is evolved when some cable insulating, sheathing and other materials are
burned, as this acid can cause extensive damage to electrical and electronic equipment not
involved in the fire itself.
This standard provides a method for determining the amount of acid gases evolved by burning
cable components so that limits can be agreed for cable specifications. As the test is not
carried out on a complete cable test piece, for a hazard assessment the actual material
volumes of the cable components should be taken into consideration.

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SIST EN 60754-1:2014
60754-1 © IEC:2011 – 7 –
TEST ON GASES EVOLVED DURING
COMBUSTION OF MATERIALS FROM CABLES –

Part 1: Determination of the halogen acid gas content



1 Scope
This part of IEC 60754 specifies the apparatus and procedure for the determination of the
amount of halogen acid gas, other than hydrofluoric acid, evolved during the combustion of
compounds based on halogenated polymers and compounds containing halogenated
additives taken from electric or optical fibre cable constructions.
NOTE 1 This test method is not able to determine hydrofluoric acid. A suitable method may be found in
IEC 60684-2.
NOTE 2 This test method may be used to test materials to be used in cable manufacture, but a declaration of
cable performance should not be made based on such a test.
NOTE 3 The relevant cable standard should indicate which components of the cable should be tested.
NOTE 4 For the purposes of this standard, the term “electric cable” covers all insulated metallic conductor cables
used for the conveyance of energy or signals.
The method specified in this standard is intended for the testing of individual components
used in a cable construction. The use of this method will enable the verification of
requirements which are stated in the appropriat
...

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