ASTM D2359-08

Standard Specification for Refined Benzene-535

ABSTRACT
This specification covers a grade of benzene known as refined benzene-535. Different tests shall be performed in order to determine the following properties of refined benzene-535: minimum purity, maximum toluene content, maximum sulfur content, maximum thiophene content, maximum nonaromatic hydrocarbon content, maximum nitrogen content, water content, maximum acid wash color, appearance, maximum color, 1,4 dioxane content, and minimum solidification point with anhydrous basis.
SCOPE
1.1 This specification covers a grade of benzene known as refined benzene-535.
1.2 The following applies to all specified limits in this standard: for purposes of determining conformance with this standard, an observed value or a calculated value shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E 29.
1.3 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.
1.4 Consult current OSHA regulations, supplier's Material Safety Data Sheets, and local regulations for all materials used in this specification.

General Information

• Status: Historical
• Publication Date: 30-Nov-2008
• ICS: 71.080.15 - Aromatic hydrocarbons
• ICS: 75.140 - Waxes, bituminous materials and other petroleum products
• Technical Committee: D16 - Aromatic, Industrial, Specialty and Related Chemicals
• Drafting Committee: D16.01 - Benzene, Toluene, Xylenes, Cyclohexane and Their Derivatives

Relations

• Replaces: ASTM D2359-07 - Standard Specification for Refined Benzene-535
• Effective Date: 01-Dec-2008
• Replaced By: ASTM D2359-09 - Standard Specification for Refined Benzene-535
• Effective Date: 01-Jun-2009
• Referred By: ASTM D4735-19 - Standard Test Method for Determination of Trace Thiophene in Refined Benzene by Gas Chromatography
• Effective Date: 01-Dec-2008
• Referred By: ASTM D4790-23 - Standard Terminology of Aromatic Hydrocarbons and Related Chemicals
• Effective Date: 01-Dec-2008
• Referred By: ASTM D7011-15(2019) - Standard Test Method for Determination of Trace Thiophene in Refined Benzene by Gas Chromatography and Sulfur Selective Detection
• Effective Date: 01-Dec-2008

Standards Content (Sample)

NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation: D 2359 – 08
Standard Specification for
1
Refined Benzene-535
This standard is issued under the fixed designation D 2359; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope* D 3437 Practice for Sampling and Handling Liquid Cyclic
Products
1.1 This specification covers a grade of benzene known as
D 4492 Test Method for Analysis of Benzene by Gas
refined benzene-535.
Chromatography
1.2 The following applies to all specified limits in this
D 5386 Test Method for Color of Liquids UsingTristimulus
standard: for purposes of determining conformance with this
Colorimetry
standard, an observed value or a calculated value shall be
D 6069 Test Method for Trace Nitrogen in Aromatic Hy-
rounded off “to the nearest unit” in the last right-hand digit
drocarbons by Oxidative Combustion and Reduced Pres-
used in expressing the specification limit, in accordance with
sure Chemiluminescence Detection
the rounding-off method of PracticeE29.
D 6304 Test Method for Determination of Water in Petro-
1.3 The values stated in SI units are to be regarded as the
leum Products, Lubricating Oils, and Additives by Coulo-
standard. The values given in parentheses are for information
metric Karl Fischer Titration
only.
D 6875 Test Method for Solidification Point of Industrial
1.4 Consult current OSHA regulations, supplier’s Material
Organic Chemicals by Thermistor
Safety Data Sheets, and local regulations for all materials used
D 7183 Test Method for Determination of Total Sulfur in
in this specification.
Aromatic Hydrocarbons and Related Chemicals by Ultra-
2. Referenced Documents
violet Fluorescence
2
D 7184 Test Method for Ultra Low Nitrogen in Aromatic
2.1 ASTM Standards:
Hydrocarbons by Oxidative Combustion and Reduced
D 848 Test Method for Acid Wash Color of Industrial
Pressure Chemiluminescence Detection
Aromatic Hydrocarbons
D 7375 Test Method for Trace Quantities of Water in
D 852 Test Method for Solidification Point of Benzene
Aromatic Hydrocarbons and Their Mixtures by Coulom-
D 1209 Test Method for Color of Clear Liquids (Platinum-
etric Karl Fischer Titration
Cobalt Scale)
E29 Practice for Using Significant Digits in Test Data to
D 1685 TestMethodforTracesofThiopheneinBenzeneby
Determine Conformance with Specifications
Spectrophotometry
E 1064 Test Method for Water in Organic Liquids by
Coulometric Karl Fischer Titration
1
This specification is under the jurisdiction of ASTM Committee D16 on
2.2 Other Document:
Aromatic Hydrocarbons and Related Chemicals and is the direct responsibility of
Subcommittee D16.01 on Benzene, Toluene, Xylenes, Cyclohexane and Their OSHA Regulations, 29 CFR paragraphs 1910.1000 and
3
Derivatives.
1910.1200
Current edition approved Dec. 1, 2008. Published December 2008. Originally
approved in 1966. Last previous edition approved in 2007 as D 2359 – 07.
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or
3
contact ASTM Customer Service at [e-mail]
...

This document is not an ASTM standard and is intended only to provide the user of an ASTM standard an indication of what changes have been made to the previous version. Because
it may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current version
of the standard as published by ASTM is to be considered the official document.
Designation:D2359–06 Designation: D 2359 – 08
Standard Specification for
1
Refined Benzene-535
This standard is issued under the fixed designation D 2359; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope*
1.1 This specification covers a grade of benzene known as refined benzene-535.
1.2 The following applies to all specified limits in this standard: for purposes of determining conformance with this standard,
an observed value or a calculated value shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing
the specification limit, in accordance with the rounding-off method of Practice E 29.
1.3
1.3 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.
1.4 Consult current OSHA regulations, supplier’s Material Safety Data Sheets, and local regulations for all materials used in
this specification.
2. Referenced Documents
2
2.1 ASTM Standards:
D 848 Test Method for Acid Wash Color of Industrial Aromatic Hydrocarbons
D 852 Test Method for Solidification Point of Benzene
D 1209 Test Method for Color of Clear Liquids (Platinum-Cobalt Scale)
D 1685 Test Method for Traces of Thiophene in Benzene by Spectrophotometry
D 3437 Practice for Sampling and Handling Liquid Cyclic Products
D 4492 Test Method for Analysis of Benzene by Gas Chromatography
D 5386 Test Method for Color of Liquids Using Tristimulus Colorimetry
D5453Test Method for Determination of Total Sulfur in Light Hydrocarbons, Spark Ignition Engine Fuel, Diesel Engine Fuel,
and Engine Oil by Ultraviolet Fluorescence
D 6069 Test Method for Trace Nitrogen in Aromatic Hydrocarbons by Oxidative Combustion and Reduced Pressure
Chemiluminescence Detection
D 6304 Test Method for Determination of Water in Petroleum Products, Lubricating Oils, and Additives by Coulometric Karl
Fischer Titration
D 6875 Test Method for Solidification Point of Industrial Organic Chemicals by Thermistor
D 7183 Test Method for Determination of Total Sulfur in Aromatic Hydrocarbons and Related Chemicals by Ultraviolet
Fluorescence
D 7184 Test Method for Ultra Low Nitrogen in Aromatic Hydrocarbons by Oxidative Combustion and Reduced Pressure
Chemiluminescence Detection
D 7375 Test Method for Trace Quantities of Water inAromatic Hydrocarbons and Their Mixtures by Coulometric Karl Fischer
Titration
E29 Practice for Using Significant Digits in Test Data to Determine Conformance with Specifications
E 1064 Test Method for Water in Organic Liquids by Coulometric Karl Fischer Titration
2.2 Other Document: OSHA Regulations, 29CFR, paragraphs 1910.1000 and 1910.1200
3
OSHA Regulations, 29 CFR paragraphs 1910.1000 and 1910.1200
1
This specification is under the jurisdiction ofASTM Committee D16 onAromatic Hydrocarbons and Related Chemicals and is the direct responsibility of Subcommittee
D16.01 on Benzene, Toluene, Xylenes, Cyclohexane and Their Derivatives.
Current edition approved JuneDec. 1, 2006.2008. Published June 2006.December 2008. Originally approved in 1966. Last previous edition approved in 20022007 as
D 2359 – 027.
2
For referencedASTM standards, visit theASTM website, www.astm.org, or contactASTM Customer Service at [e-mail]. ForAnnualBookofASTMStandards
volume information, refer to the standard’s Document Summary page on the ASTM website.
3
Available from Superintendent of Documents, U.S. Government Printing Office, Washington, DC. 20402.
3
Available from U.S. Government Printing Office Superintendent of Documents, 732 N. Capitol St., NW, Mail Stop: SDE, Washington, DC 20401, http://
www.access.gpo.gov.
*ASummary of Changes section appears at the end of this standard.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.
1

---------------------- Page: 1 ----------------------
D2359–08
3. Properties
3.1 Refined benzene-535 shall conform to the following requirements:
ASTM Test
Property Specification
A
Method
Purity, min, weight % 99.80 D 4492
Toluene, max, weight % 0.10 D 4492
Sulfur, max, mg/kg (if needed) D 5453
Sulfur, max, mg/kg (if needed) D 7183
Thiophene, max, mg/kg 1 D 1685
Nonaromatic hydrocarbons, max, 0.15 D 4492
weight %
Nitrogen, max, mg/kg (if needed) D 6069
Nitrogen, max, mg/kg (if needed) D 6069 or D 7184
Water (if needed)
...

This document is not an ASTM standard and is intended only to provide the user of an ASTM standard an indication of what changes have been made to the previous version. Because
it may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current version
of the standard as published by ASTM is to be considered the official document.
Designation:D2359–07 Designation: D 2359 – 08
Standard Specification for
1
Refined Benzene-535
This standard is issued under the fixed designation D 2359; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope*
1.1 This specification covers a grade of benzene known as refined benzene-535.
1.2 The following applies to all specified limits in this standard: for purposes of determining conformance with this standard,
an observed value or a calculated value shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing
the specification limit, in accordance with the rounding-off method of Practice E 29.
1.3 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.
1.4 Consult current OSHA regulations, supplier’s Material Safety Data Sheets, and local regulations for all materials used in
this specification.
2. Referenced Documents
2
2.1 ASTM Standards:
D 848 Test Method for Acid Wash Color of Industrial Aromatic Hydrocarbons
D 852 Test Method for Solidification Point of Benzene
D 1209 Test Method for Color of Clear Liquids (Platinum-Cobalt Scale)
D 1685 Test Method for Traces of Thiophene in Benzene by Spectrophotometry
D 3437 Practice for Sampling and Handling Liquid Cyclic Products
D 4492 Test Method for Analysis of Benzene by Gas Chromatography
D 5386 Test Method for Color of Liquids Using Tristimulus Colorimetry
D 6069 Test Method for Trace Nitrogen in Aromatic Hydrocarbons by Oxidative Combustion and Reduced Pressure
Chemiluminescence Detection
D 6304 Test Method for Determination of Water in Petroleum Products, Lubricating Oils, and Additives by Coulometric Karl
Fischer Titration
D 6875 Test Method for Solidification Point of Industrial Organic Chemicals by Thermistor
D 7183 Test Method for Determination of Total Sulfur in Aromatic Hydrocarbons and Related Chemicals by Ultraviolet
Fluorescence
D 7184 Test Method for Ultra Low Nitrogen in Aromatic Hydrocarbons by Oxidative Combustion and Reduced Pressure
Chemiluminescence Detection
D 7375 Test Method for Trace Quantities of Water inAromatic Hydrocarbons and Their Mixtures by Coulometric Karl Fischer
Titration
E29 Practice for Using Significant Digits in Test Data to Determine Conformance with Specifications
E 1064 Test Method for Water in Organic Liquids by Coulometric Karl Fischer Titration
2.2 Other Document:
3
OSHA Regulations, 29 CFR paragraphs 1910.1000 and 1910.1200
1
This specification is under the jurisdiction ofASTM Committee D16 onAromatic Hydrocarbons and Related Chemicals and is the direct responsibility of Subcommittee
D16.01 on Benzene, Toluene, Xylenes, Cyclohexane and Their Derivatives.
Current edition approved JuneDec. 1, 2007.2008. Published July 2007.December 2008. Originally approved in 1966. Last previous edition approved in 20062007 as
D 2359 – 067.
2
For referencedASTM standards, visit theASTM website, www.astm.org, or contactASTM Customer Service at [e-mail]. ForAnnualBookofASTMStandards
volume information, refer to the standard’s Document Summary page on the ASTM website.
3
Available from U.S. Government Printing Office Superintendent of Documents, 732 N. Capitol St., NW, Mail Stop: SDE, Washington, DC 20401, http://
www.access.gpo.gov.
*ASummary of Changes section appears at the end of this standard.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.
1

---------------------- Page: 1 ----------------------
D2359–08
3. Properties
3.1 Refined benzene-535 shall conform to the following requirements:
ASTM Test
Property Specification
A
Method
Purity, min, weight % 99.80 D 4492
Toluene, max, weight % 0.10 D 4492
Sulfur, max, mg/kg (if needed) D 7183
Thiophene, max, mg/kg 1 D 1685
Nonaromatic hydrocarbons, max, 0.15 D 4492
weight %
Nitrogen, max, mg/kg (if needed) D 6069 or D 7184
Water (if needed) D 6304 or E 1064
Water (if needed) D 6304 or
E 1064 or
D 7375
Acid wash color, max pass with 1 D 848
B
Appearance .
Color, max, Pt–Co scale 20 D 1209 or D 5386
1,4 Dioxane (if needed) D 4492
Solidification point, anhydrous 5.35 D 852 or D 6875
basis, min, °C
______________
A
If more than one method is listed, the producer and user should agree on the referee method.
B
Clear liquid free of sediment and ha
...