ASTM D1319-08
(Test Method)Standard Test Method for Hydrocarbon Types in Liquid Petroleum Products by Fluorescent Indicator Adsorption
Standard Test Method for Hydrocarbon Types in Liquid Petroleum Products by Fluorescent Indicator Adsorption
SIGNIFICANCE AND USE
The determination of the total volume % of saturates, olefins, and aromatics in petroleum fractions is important in characterizing the quality of petroleum fractions as gasoline blending components and as feeds to catalytic reforming processes. This information is also important in characterizing petroleum fractions and products from catalytic reforming and from thermal and catalytic cracking as blending components for motor and aviation fuels. This information is also important as a measure of the quality of fuels, such as specified in Specification D 1655.
SCOPE
1.1 This test method covers the determination of hydrocarbon types over the concentration ranges from 5 to 99 volume % aromatics, 0.3 to 55 volume % olefins, and 1 to 95 volume % saturates in petroleum fractions that distill below 315°C. This test method may apply to concentrations outside these ranges, but the precision has not been determined. Samples containing dark-colored components that interfere in reading the chromatographic bands cannot be analyzed.
Note 1—For the determination of olefins below 0.3 volume %, other test methods are available, such as Test Method D 2710.
1.2 This test method is intended for use with full boiling range products. Cooperative data have established that the precision statement does not apply to narrow boiling petroleum fractions near the 315°C limit. Such samples are not eluted properly, and results are erratic.
1.3 The applicability of this test method to products derived from fossil fuels other than petroleum, such as coal, shale, or tar sands, has not been determined, and the precision statement may or may not apply to such products.
1.4 This test method has two precision statements depicted in tables. The first table is applicable to unleaded fuels that do not contain oxygenated blending components. It may or may not apply to automotive gasolines containing lead antiknock mixtures. The second table is applicable to oxygenate blended (for example, MTBE, ethanol) automotive spark ignition fuel samples with a concentration range of 13–40 volume percent aromatics, 4–33 volume percent olefins, and 45–68 volume percent saturates.
1.5 The oxygenated blending components, methanol, ethanol, methyl-tert-butylether (MTBE), tert-amylmethylether (TAME), and ethyl-tert-butylether (ETBE), do not interfere with the determination of hydrocarbon types at concentrations normally found in commercial blends. These oxygenated components are not detected since they elute with the alcohol desorbent. Other oxygenated compounds shall be individually verified. When samples containing oxygenated blending components are analyzed, correct the results to a total-sample basis.
1.6 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.7 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For specific warning statements, see Section 7, 8.1, and 10.5.
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Designation: D1319 – 08
Designation: 156/97
Standard Test Method for
Hydrocarbon Types in Liquid Petroleum Products by
1
Fluorescent Indicator Adsorption
This standard is issued under the fixed designation D1319; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
This standard has been approved for use by agencies of the Department of Defense.
1. Scope* 1.5 The oxygenated blending components, methanol, etha-
nol, methyl-tert-butylether (MTBE), tert-amylmethylether
1.1 This test method covers the determination of hydrocar-
(TAME), and ethyl-tert-butylether (ETBE), do not interfere
bontypesovertheconcentrationrangesfrom5to99volume %
with the determination of hydrocarbon types at concentrations
aromatics, 0.3 to 55 volume % olefins, and 1 to 95 volume %
normally found in commercial blends. These oxygenated
saturates in petroleum fractions that distill below 315°C. This
components are not detected since they elute with the alcohol
test method may apply to concentrations outside these ranges,
desorbent. Other oxygenated compounds shall be individually
but the precision has not been determined. Samples containing
verified. When samples containing oxygenated blending com-
dark-colored components that interfere in reading the chro-
ponentsareanalyzed,correcttheresultstoatotal-samplebasis.
matographic bands cannot be analyzed.
1.6 The values stated in SI units are to be regarded as
NOTE 1—For the determination of olefins below 0.3 volume %, other
standard. No other units of measurement are included in this
test methods are available, such as Test Method D2710.
standard.
1.2 This test method is intended for use with full boiling
1.7 This standard does not purport to address all of the
range products. Cooperative data have established that the
safety concerns, if any, associated with its use. It is the
precisionstatementdoesnotapplytonarrowboilingpetroleum
responsibility of the user of this standard to establish appro-
fractions near the 315°C limit. Such samples are not eluted
priate safety and health practices and determine the applica-
properly, and results are erratic.
bility of regulatory limitations prior to use. For specific
1.3 The applicability of this test method to products derived
warning statements, see Section 7, 8.1, and 10.5.
from fossil fuels other than petroleum, such as coal, shale, or
2. Referenced Documents
tar sands, has not been determined, and the precision statement
2
may or may not apply to such products.
2.1 ASTM Standards:
1.4 This test method has two precision statements depicted
D86 Test Method for Distillation of Petroleum Products at
in tables. The first table is applicable to unleaded fuels that do
Atmospheric Pressure
not contain oxygenated blending components. It may or may
D1655 Specification for Aviation Turbine Fuels
not apply to automotive gasolines containing lead antiknock
D2710 Test Method for Bromine Index of Petroleum Hy-
mixtures. The second table is applicable to oxygenate blended
drocarbons by Electrometric Titration
(for example, MTBE, ethanol) automotive spark ignition fuel
D3663 Test Method for Surface Area of Catalysts and
samples with a concentration range of 13–40 volume percent
Catalyst Carriers
aromatics, 4–33 volume percent olefins, and 45–68 volume
D4057 Practice for Manual Sampling of Petroleum and
percent saturates.
Petroleum Products
D4815 Test Method for Determination of MTBE, ETBE,
TAME, DIPE, tertiary-Amyl Alcohol and C to C Alco-
1 4
1
This test method is under the jurisdiction of ASTM Committee D02 on
hols in Gasoline by Gas Chromatography
Petroleum Products and Lubricants and is the direct responsibility of Subcommittee
D5599 Test Method for Determination of Oxygenates in
D02.04.0C on Liquid Chromatography.
In the IP, this test method is under the jurisdiction of the Standardization
Committee. This test method has been approved by the sponsoring committees and
2
accepted by the cooperating societies in accordance with established procedures. For referenced ASTM standards, visit the ASTM website, www.astm.org, or
Current edition approved Oct. 15, 2008. Published October 2008. Originally contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
´1
approved in 1954. Last previous edition approved in 2003 as D1319–03 . DOI: Standards volume information, refer to the standard’s Document Summary page on
10.1520/D1319-08. the ASTM website.
*A Summary of Changes section appears at the end of this standard.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.
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This document is not anASTM standard and is intended only to provide the user of anASTM standard an indication of what changes have been made to the previous version. Because
it may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current version
of the standard as published by ASTM is to be considered the official document.
An American National Standard
´1
Designation:D1319–03 Designation: D 1319 – 08
Designation: 156/97
Standard Test Method for
Hydrocarbon Types in Liquid Petroleum Products by
1
Fluorescent Indicator Adsorption
This standard is issued under the fixed designation D 1319; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
This standard has been approved for use by agencies of the Department of Defense.
1
´ NOTE—Footnote 7 and Table2 were updated editorially in June 2006.
1. Scope*
1.1 This test method covers the determination of hydrocarbon types over the concentration ranges from 5 to 99 volume %
aromatics, 0.3 to 55 volume % olefins, and 1 to 95 volume % saturates in petroleum fractions that distill below 315°C. This test
method may apply to concentrations outside these ranges, but the precision has not been determined. Samples containing
dark-colored components that interfere in reading the chromatographic bands cannot be analyzed.
NOTE 1—For the determination of olefins below 0.3 volume %, other test methods are available, such as Test Method D 2710.
1.2 This test method is intended for use with full boiling range products. Cooperative data have established that the precision
statement does not apply to narrow boiling petroleum fractions near the 315°C limit. Such samples are not eluted properly, and
results are erratic.
1.3 The applicability of this test method to products derived from fossil fuels other than petroleum, such as coal, shale, or tar
sands, has not been determined, and the precision statement may or may not apply to such products.
1.4 This test method has two precision statements depicted in tables. The first table is applicable to unleaded fuels that do not
contain oxygenated blending components. It may or may not apply to automotive gasolines containing lead antiknock mixtures.
The second table is applicable to oxygenate blended (for example, MTBE, ethanol) automotive spark ignition fuel samples with
a concentration range of 13–40 volume percent aromatics, 4–33 volume percent olefins, and 45–68 volume percent saturates.
1.5 The oxygenated blending components, methanol, ethanol, methyl-tert-butylether (MTBE), tert-amylmethylether (TAME),
and ethyl-tert-butylether (ETBE), do not interfere with the determination of hydrocarbon types at concentrations normally found
in commercial blends. These oxygenated components are not detected since they elute with the alcohol desorbent. Other
oxygenated compounds shall be individually verified. When samples containing oxygenated blending components are analyzed,
correct the results to a total-sample basis.
1.6The values stated in SI units are to be regarded as standard.
NOTE1—For the determination of olefins below 0.3 volume %, other test methods are available, such as Test Method D2710.
1.6 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.7 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility
of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory
limitations prior to use. For specific hazardwarning statements, see Section 7, 8.1, and 10.5.
1
This test method is under the jurisdiction ofASTM Committee D02 on Petroleum Products and Lubricants and is the direct responsibility of Subcommittee D02.04.0C
on Hydrocarbon Analysis. Liquid Chromatography.
In the IP, this test method is under the jurisdiction of the Standardization Committee. This test method has been approved by the sponsoring committees and accepted by
the cooperating societies in accordance with established procedures.
Current edition approved Nov. 1, 2003. Published January 2004. Originally approved in 1954. Last previous edition approved in 2002 as D1319–02a.
´1
Current edition approved Oct. 15, 2008. Published October 2008. Originally approved in 1954. Last previous edition approved in 2003 as D 1319–03 .
*A Summary of Changes section appears at the end of this standard.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.
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D1319–08
2. Referenced Documents
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2.1 ASTM Standards:
D 8
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