ASTM F2931-15
(Guide)Standard Guide for Analytical Testing of Substances of Very High Concern in Materials and Products
Standard Guide for Analytical Testing of Substances of Very High Concern in Materials and Products
SIGNIFICANCE AND USE
5.1 The REACH Candidate list classifies substances as SVHCs thus making them subject to possible authorization. Compliance to the REACH regulation requires that any identified SVHC be present at a concentration of less than 0.1 % (w/w) of the total article weight to avoid triggering a reporting obligation. This guide is intended to assist in the identification of available test methods for quantitative analysis of the substance(s) of interest.
5.2 When possible, industry accepted standard test methods are cited. However, industry vetted test methods are not available for all of the substances contained in the REACH Candidate List. Thus, some caution and due diligence must be exercised when applying some of the methods listed in this guide.
5.3 In some cases, test methods for the identification and quantification of a specific substance are not available. An example would include CoCl2. Methods currently in practice involve the individual determination of Co and Cl concentrations and use other sources of information or chemical judgment to assign the expected CoCl2 concentration. This approach obviously has its limitations and pitfalls and must be used judiciously.
5.4 Under the REACH regulation, EU manufacturers, importers or distributors of articles containing more than 0.1 % (w/w) of a substance that the Agency has listed as being an SVHC shall provide their customers with the name of the substance and information allowing the safe use of the article. Producers and distributors of articles containing SVHC shall also supply the same information to consumers, upon request. In situations where this information is not readily available from the supply chain it is incumbent upon the supplier to collect this information through actual chemical analysis or other means. This guide is intended to assist in the selection of appropriate test methods in the event that chemical analysis is required.
SCOPE
1.1 This guide contains a list of potential test methods for the analysis of Substances of Very High Concern (SVHC) as designated by ECHA, the European Chemicals Agency. Information on the test methods cited is publicly available and is drawn from a variety of sources. The guide is intended to assist in the selection of test methods that are applicable for the SVHCs identified.
1.2 The specific SVHCs covered within this guide are compiled from the ECHA Candidate List of Substances of Very High Concern. This list is also referred to as the REACH Candidate List.
1.3 This guide specifically addresses methods for the analysis of SVHCs in products. It is not intended to cover the many and varied analysis challenges associated in the manufacturing environment.
1.4 Limitations:
1.4.1 This guide is intended to provide a compilation of available test methods for the SVHCs listed on the ECHA Candidate list and is not intended to be exhaustive. The test methods within this guide are not the only ones available for any specific substances and this guide does not recommend any specific test method.
1.4.2 Test methods for specific substances at the detection limits required for REACH reporting are not always available. In some cases, it is necessary to deduce the quantity of substance present through the analysis and quantification of its elements. Although this approach is routinely used some degree of uncertainty exists in the final result due to the reduced specificity of the test method.
1.4.3 Although this guide is intended to be updated on a periodic basis to capture new developments in the field, there is no assurance that the information provided is the most current.
1.5 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate ...
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Designation: F2931 − 15
StandardGuide for
Analytical Testing of Substances of Very High Concern in
1
Materials and Products
This standard is issued under the fixed designation F2931; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope 1.5 The values stated in SI units are to be regarded as
standard. No other units of measurement are included in this
1.1 This guide contains a list of potential test methods for
standard.
the analysis of Substances of Very High Concern (SVHC) as
1.6 This standard does not purport to address all of the
designated by ECHA, the European Chemicals Agency. Infor-
safety concerns, if any, associated with its use. It is the
mation on the test methods cited is publicly available and is
responsibility of the user of this standard to establish appro-
drawnfromavarietyofsources.Theguideisintendedtoassist
priate safety and health practices and determine the applica-
in the selection of test methods that are applicable for the
bility of regulatory limitations prior to use.
SVHCs identified.
1.2 The specific SVHCs covered within this guide are
2. Referenced Documents
compiledfromtheECHACandidateListofSubstancesofVery
2
2.1 ASTM Standards:
High Concern. This list is also referred to as the REACH
D1257 Specification for High-Gravity Glycerin
Candidate List.
D1385 Test Method for Hydrazine in Water
1.3 This guide specifically addresses methods for the analy-
D1971 Practices for Digestion of Water Samples for Deter-
sis of SVHCs in products. It is not intended to cover the many
minationofMetalsbyFlameAtomicAbsorption,Graphite
and varied analysis challenges associated in the manufacturing
Furnace Atomic Absorption, Plasma Emission
environment.
Spectroscopy, or Plasma Mass Spectrometry
D3335 Test Method for Low Concentrations of Lead,
1.4 Limitations:
Cadmium, and Cobalt in Paint by Atomic Absorption
1.4.1 This guide is intended to provide a compilation of
Spectroscopy
available test methods for the SVHCs listed on the ECHA
D3545 Test Method for Alcohol Content and Purity of
Candidate list and is not intended to be exhaustive. The test
Acetate Esters by Gas Chromatography
methods within this guide are not the only ones available for
D4309 Practice for Sample Digestion Using Closed Vessel
anyspecificsubstancesandthisguidedoesnotrecommendany
Microwave Heating Technique for the Determination of
specific test method.
Total Metals in Water
1.4.2 Test methods for specific substances at the detection
D5831 Test Method for Screening Fuels in Soils
limits required for REACH reporting are not always available.
D7065 Test Method for Determination of Nonylphenol,
In some cases, it is necessary to deduce the quantity of
BisphenolA, p-tert -Octylphenol, Nonylphenol Monoeth-
substance present through the analysis and quantification of its
oxylate and Nonylphenol Diethoxylate in Environmental
elements. Although this approach is routinely used some
Waters by Gas Chromatography Mass Spectrometry
degree of uncertainty exists in the final result due to the
D7485 Test Method for Determination of Nonylphenol,
reduced specificity of the test method.
p-tert-Octylphenol, Nonylphenol Monoethoxylate and
1.4.3 Although this guide is intended to be updated on a
Nonylphenol Diethoxylate in Environmental Waters by
periodic basis to capture new developments in the field, there
Liquid Chromatography/Tandem Mass Spectrometry
is no assurance that the information provided is the most
E1621 Guide for ElementalAnalysis by Wavelength Disper-
current.
sive X-Ray Fluorescence Spectrometry
F2576 Terminology Relating to Declarable Substances in
Materials
1
This guide is under the jurisdiction of ASTM Committee F40 on Declarable
Substances in Materials and is the direct responsibility of Subcommittee F40.02 on
2
Management Practices and Guides. For referenced ASTM standards, visit the ASTM website, www.astm.org, or
Current edition approved May 1, 2015. Published June 2015. Originally contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
approved in 2011. Last previous edition approved in 2014 as F2931 – 14. DOI: Standards volume information, refer to the standard’s Document Summary page on
10.1520/F2931-15. the ASTM website.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1
---------------------- Page: 1 ----------------------
F2931 − 15
3
2.2 European Commission: 3.3.2 AED—Atomic Emission Detection
Article 57 of the European Union Regulation #1907/2006
3.3.3 AES—Atomic Emission Spectrometry
4
2.3 International Electrotechnical Commission TC111:
...
This document is not an ASTM standard and is intended only to provide the user of an ASTM standard an indication of what changes have been made to the previous version. Because
it may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current version
of the standard as published by ASTM is to be considered the official document.
Designation: F2931 − 14 F2931 − 15
Standard Guide for
Analytical Testing of Substances of Very High Concern in
1
Materials and Products
This standard is issued under the fixed designation F2931; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope
1.1 This guide contains a list of potential test methods for the analysis of Substances of Very High Concern (SVHC) as
designated by ECHA, the European Chemicals Agency. Information on the test methods cited is publicly available and is drawn
from a variety of sources. The guide is intended to assist in the selection of test methods that are applicable for the SVHCs
identified.
1.2 The specific SVHCs covered within this guide are compiled from the ECHA Candidate List of Substances of Very High
Concern. This list is also referred to as the REACH Candidate List.
1.3 This guide specifically addresses methods for the analysis of SVHCs in products. It is not intended to cover the many and
varied analysis challenges associated in the manufacturing environment.
1.4 Limitations:
1.4.1 This guide is intended to provide a compilation of available test methods for the SVHCs listed on the ECHA Candidate
list and is not intended to be exhaustive. The test methods within this guide are not the only ones available for any specific
substances and this guide does not recommend any specific test method.
1.4.2 Test methods for specific substances at the detection limits required for REACH reporting are not always available. In
some cases, it is necessary to deduce the quantity of substance present through the analysis and quantification of its elements.
Although this approach is routinely used some degree of uncertainty exists in the final result due to the reduced specificity of the
test method.
1.4.3 Although this guide is intended to be updated on a periodic basis to capture new developments in the field, there is no
assurance that the information provided is the most current.
1.5 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility
of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory
limitations prior to use.
2. Referenced Documents
2
2.1 ASTM Standards:
D1257 Specification for High-Gravity Glycerin
D1385 Test Method for Hydrazine in Water
D1971 Practices for Digestion of Water Samples for Determination of Metals by Flame Atomic Absorption, Graphite Furnace
Atomic Absorption, Plasma Emission Spectroscopy, or Plasma Mass Spectrometry
D3335 Test Method for Low Concentrations of Lead, Cadmium, and Cobalt in Paint by Atomic Absorption Spectroscopy
D3545 Test Method for Alcohol Content and Purity of Acetate Esters by Gas Chromatography
D4309 Practice for Sample Digestion Using Closed Vessel Microwave Heating Technique for the Determination of Total Metals
in Water
D5831 Test Method for Screening Fuels in Soils
1
This guide is under the jurisdiction of ASTM Committee F40 on Declarable Substances in Materials and is the direct responsibility of Subcommittee F40.02 on
Management Practices and Guides.
Current edition approved April 1, 2014May 1, 2015. Published May 2014June 2015. Originally approved in 2011. Last previous edition approved in 20132014 as
D3984 – 13.F2931 – 14. DOI: 10.1520/F2931-14.10.1520/F2931-15.
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM Standards
volume information, refer to the standard’s Document Summary page on the ASTM website.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1
---------------------- Page: 1 ----------------------
F2931 − 15
D7065 Test Method for Determination of Nonylphenol, Bisphenol A, p-tert -Octylphenol, Nonylphenol Monoethoxylate and
Nonylphenol Diethoxylate in Environmental Waters by Gas Chromatography Mass Spectrometry
D7485 Test Method for Determination of Nonylphenol, p-tert-Octylphenol, Nonylphenol Monoethoxylate and Nonylphenol
Diethoxylate in Environmental Waters by Liquid Chromatography/Tandem Mass Spectrometry
...
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