ASTM D2369-01e1

Standard Test Method for Volatile Content of Coatings

SCOPE
1.1 This test method describes a procedure for the determination of the weight percent volatile content of solventborne and waterborne coatings. Test specimens are heated at 110 + 5oC for 60 min.
Note 1--The coatings used in these round-robin studies represented air-dried, air-dried oxidizing, heat-cured baking systems, and also included multicomponent paint systems.
1.2 Sixty minutes at 110 + 5oC is a general purpose test method based on the precision obtained with both solventborne and waterborne coatings (see Section 9). These coatings (single package, heat cured) are commonly applied in factories to automobiles, metal containers, flat (coil) metal and large appliances, and many other metal parts.
1.3 This test method is viable for coatings wherein one or more parts may, at ambient conditions, contain liquid coreactants that are volatile until a chemical reaction has occurred with another component of the multi-package system.
Note 2--Committee D01 has run round-robin studies on volatiles of multicomponent paint systems. The only change in procedure is to premix the weighed components in the correct proportions and allow the specimens to stand at room temperature for 1 h prior to placing them into the oven.
1.4 This test method may not be applicable to all types of coatings. Other procedures may be substituted with mutual agreement between the producer and the user.
Note 3--If unusual decomposition or degradation of the specimen occurs during heating, the actual time and temperature used to cure the coating in practice may be substituted for the time and temperature specified in this test method, subject to mutual agreement between the producer and the user. The U.S. EPA Reference Method 24 specifies 110 + 5oC for 1 h for coatings.
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.For a specific hazard statement see 7.4.1.

General Information

• Status: Historical
• Publication Date: 09-Jan-2001
• ICS: 87.040 - Paints and varnishes
• Technical Committee: D01 - Paint and Related Coatings, Materials, and Applications
• Drafting Committee: D01.21 - Chemical Analysis of Paints and Paint Materials

Relations

• Replaces: ASTM D2369-01 - Standard Test Method for Volatile Content of Coatings
• Effective Date: 10-Jan-2001
• Replaced By: ASTM D2369-03 - Standard Test Method for Volatile Content of Coatings
• Effective Date: 10-Jan-2003
• Referred By: ASTM D5327-97(2021)e1 - Standard Practice for Evaluating and Comparing Transfer Efficiency of Spray Applied Coatings Under General Laboratory Conditions
• Effective Date: 10-Jan-2001
• Referred By: ASTM D6763-16(2022) - Standard Guide for Testing Exterior Wood Stains and Clear Water Repellents
• Effective Date: 10-Jan-2001
• Referred By: ASTM C156-20 - Standard Test Method for Water Loss [from a Mortar Specimen] Through Liquid Membrane-Forming Curing Compounds for Concrete
• Effective Date: 10-Jan-2001
• Referred By: ASTM D5324-16(2022) - Standard Guide for Testing Water-Borne Architectural Coatings
• Effective Date: 10-Jan-2001
• Referred By: ASTM F940-99(2019)e1 - Standard Practice for Quality Control Receipt Inspection Procedures for Protective Coatings (Paint), Used in Marine Construction and Shipbuilding
• Effective Date: 10-Jan-2001
• Referred By: ASTM D3960-05(2018) - Standard Practice for Determining Volatile Organic Compound (VOC) Content of Paints and Related Coatings
• Effective Date: 10-Jan-2001
• Referred By: ASTM D6266-00a(2023) - Standard Test Method for Determining the Amount of Volatile Organic Compound (VOC) Released From Waterborne Automotive Coatings and Available for Removal in a VOC Control Device (Abatement)
• Effective Date: 10-Jan-2001
• Referred By: ASTM D5325-03(2021) - Standard Test Method for Determination of Weight Percent Volatile Content of Water-Borne Aerosol Paints
• Effective Date: 10-Jan-2001
• Referred By: ASTM C1315-19 - Standard Specification for Liquid Membrane-Forming Compounds Having Special Properties for Curing and Sealing Concrete
• Effective Date: 10-Jan-2001
• Referred By: ASTM D4764-01(2023) - Standard Test Method for Determination by X-ray Fluorescence Spectroscopy of Titanium Dioxide Content in Paint
• Effective Date: 10-Jan-2001
• Referred By: ASTM D7768-12(2018) - Standard Test Method for Speciated Organic Volatile Content of Waterborne Multi-Component Coatings by Gas Chromatography
• Effective Date: 10-Jan-2001
• Referred By: ASTM D4209-07(2019) - Standard Practice for Determining Volatile and Nonvolatile Content of Cellulosics, Emulsions, Resin Solutions, Shellac, and Varnishes
• Effective Date: 10-Jan-2001
• Referred By: ASTM D6886-18 - Standard Test Method for Determination of the Weight Percent Individual Volatile Organic Compounds in Waterborne Air-Dry Coatings by Gas Chromatography
• Effective Date: 10-Jan-2001

Standards Content (Sample)

NOTICE: This standard has either been superceded and replaced by a new version or discontinued.
Contact ASTM International (www.astm.org) for the latest information.
e1
Designation: D 2369 – 01
Standard Test Method for
1
Volatile Content of Coatings
This standard is issued under the fixed designation D 2369; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (e) indicates an editorial change since the last revision or reapproval.
This standard has been approved for use by agencies of the Department of Defense.
1
e NOTE—Paragraph 5.1 was corrected editorially to +/- 0.1 mg in June 2001.
1. Scope bility of regulatory limitations prior to use. For a specific
hazard statement see 7.4.1.
1.1 This test method describes a procedure for the determi-
nation of the weight percent volatile content of solventborne
2. Referenced Documents
and waterborne coatings. Test specimens are heated at 110 6
2.1 ASTM Standards:
5°C for 60 min.
2
D 1193 Specification for Reagent Water
NOTE 1—The coatings used in these round-robin studies represented
D 3925 Practice for Sampling Liquid Paints and Related
air-dried, air-dried oxidizing, heat-cured baking systems, and also in-
3
Pigmented Coatings
cluded multicomponent paint systems.
E 145 Specification for Gravity-Convection and Forced-
4
1.2 Sixty minutes at 110 6 5°C is a general purpose test
Ventilation Ovens
method based on the precision obtained with both solventborne
E 180 Practice for Determining the Precision of ASTM
and waterborne coatings (see Section 9). These coatings (single
Methods for Analysis and Testing of Industrial and Spe-
5
package, heat cured) are commonly applied in factories to
cialty Chemicals
automobiles, metal containers, flat (coil) metal and large
2.2 Other Standards:
appliances, and many other metal parts.
EPA Reference Method 24—Determination of Volatile
1.3 This test method is viable for coatings wherein one or
Matter Content, Density, Volume Solids, and Weight
6
more parts may, at ambient conditions, contain liquid coreac-
Solids of Surface Coatings
tants that are volatile until a chemical reaction has occurred
3. Summary of Test Method
with another component of the multi-package system.
3.1 A designated quantity of coating specimen is weighed
NOTE 2—Committee D-1 has run round-robin studies on volatiles of
into an aluminum foil dish containing 3 mL of an appropriate
multicomponent paint systems. The only change in procedure is to premix
the weighed components in the correct proportions and allow the solvent, dispersed, and heated in an oven at 110 6 5°C for 60
specimens to stand at room temperature for 1 h prior to placing them into
min. The percent volatile is calculated from the loss in weight.
the oven.
4. Significance and Use
1.4 This test method may not be applicable to all types of
4.1 This test method is the procedure of choice for deter-
coatings. Other procedures may be substituted with mutual
mining volatiles in coatings for the purpose of calculating the
agreement between the producer and the user.
volatile organic content in coatings under specified test condi-
NOTE 3—If unusual decomposition or degradation of the specimen
tions. The weight percent solids content (nonvolatile matter)
occurs during heating, the actual time and temperature used to cure the
may be determined by difference. This information is useful to
coating in practice may be substituted for the time and temperature
the paint producer and user and to environmental interests for
specified in this test method, subject to mutual agreement between the
producer and the user. The U.S. EPA Reference Method 24 specifies 110 determining the volatiles emitted by coatings.
6 5°C for 1 h for coatings.
5. Apparatus
1.5 This standard does not purport to address all of the
5.1 Analytical Balance, capable of weighing 60.1 mg.
safety concerns, if any, associated with its use. It is the
5.2 Aluminum Foil Dishes, 58 mm in diameter by 18 mm
responsibility of the user of this standard to establish appro-
high with a smooth (planar) bottom surface. Precondition the
priate safety and health practices and determine the applica-
2
Annual Book of ASTM Standards, Vol 11.01.
1 3
This test method is under the jurisdiction of ASTM Committee D01 on Paint Annual Book of ASTM Standards, Vol 06.01.
4
and Related Coatings, Materials, and Applications and is the direct responsibility of Annual Book of ASTM Standards, Vol 14.04.
5
Subcommittee D01.21 on Chemical Analysis of Paints and Paint Materials. Annual Book of ASTM Standards, Vol 15.05.
6
Current edition approved Jan. 10, 2001. Published March 2001. Originally Available from Superintendent of Documents, U.S. Government Printing
published as D 2369 – 65 T. Last previous edition D 2369 – 98. Office, Washington, DC 20402.
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