ASTM D7095-17
(Test Method)Standard Test Method for Rapid Determination of Corrosiveness to Copper from Petroleum Products Using a Disposable Copper Foil Strip
Standard Test Method for Rapid Determination of Corrosiveness to Copper from Petroleum Products Using a Disposable Copper Foil Strip
SIGNIFICANCE AND USE
4.1 Crude petroleum contains sulfur compounds, most of which are removed during refining. However, of the sulfur compounds remaining in the petroleum product, some can have a corroding action on various metals, including copper, and this corrosivity is not necessarily related to the total sulfur content. The effect can vary according to the chemical types of sulfur compounds present. This copper foil strip corrosion test is designed to assess the relative degree of corrosivity of a petroleum product towards copper and copper-containing alloys using a shorter test duration than that specified in Test Method D130.
4.2 Some sulfur species may become corrosive to copper only at higher temperatures. Thus, higher test temperatures, particularly 100 °C (212 °F), may be used to test some products by the pressure vessel procedure.
SCOPE
1.1 This test method covers the determination of the corrosiveness to copper of aviation gasoline, aviation turbine fuel, automotive gasoline, natural gasoline, or other hydrocarbons having a vapor pressure no greater than 124 kPa (18 psi), cleaners (for example, Stoddard solvent), kerosine, diesel fuel, distillate fuel oil, lubricating oil, and other petroleum products.
1.2 The values stated in SI units are to be regarded as the standard.
1.2.1 Exception—The values in parentheses are provided for information only.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For specific warning statements, see 6.1, 10.1.1, and Annex A2.
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
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This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the
Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
Designation: D7095 − 17
Standard Test Method for
Rapid Determination of Corrosiveness to Copper from
1
Petroleum Products Using a Disposable Copper Foil Strip
This standard is issued under the fixed designation D7095; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
INTRODUCTION
This test method is similar in nature to theTest Method D130 test method, but involves three major
differences. Firstly, a single-use copper foil strip is used in place of the Test Method D130 multi-use
copper strip. Secondly, a different polishing technique is used in preparing the copper foil strip, which
uses a commercially available scouring-pad in place of the initial and final polishing techniques
described in Test Method D130. Thirdly, this test method involves a shorter analysis time of 45 min
for all product types as compared to the Test Method D130 method requirements, which are longer;
for example, two or three hours.
1. Scope* 2. Referenced Documents
2
2.1 ASTM Standards:
1.1 This test method covers the determination of the corro-
B152/B152M Specification for Copper Sheet, Strip, Plate,
siveness to copper of aviation gasoline, aviation turbine fuel,
and Rolled Bar
automotive gasoline, natural gasoline, or other hydrocarbons
D130 Test Method for Corrosiveness to Copper from Petro-
having a vapor pressure no greater than 124 kPa (18 psi),
leum Products by Copper Strip Test
cleaners (for example, Stoddard solvent), kerosine, diesel fuel,
D396 Specification for Fuel Oils
distillate fuel oil, lubricating oil, and other petroleum products.
D975 Specification for Diesel Fuel Oils
1.2 The values stated in SI units are to be regarded as the
D1655 Specification for Aviation Turbine Fuels
standard.
D1838 TestMethodforCopperStripCorrosionbyLiquefied
1.2.1 Exception—Thevaluesinparenthesesareprovidedfor
Petroleum (LP) Gases
information only.
D4057 Practice for Manual Sampling of Petroleum and
Petroleum Products
1.3 This standard does not purport to address all of the
D4177 Practice for Automatic Sampling of Petroleum and
safety concerns, if any, associated with its use. It is the
Petroleum Products
responsibility of the user of this standard to establish appro-
D6615 Specification for Jet B Wide-Cut Aviation Turbine
priate safety, health, and environmental practices and deter-
Fuel
mine the applicability of regulatory limitations prior to use.
E1 Specification for ASTM Liquid-in-Glass Thermometers
For specific warning statements, see 6.1, 10.1.1, and Annex
2.2 ASTM Adjuncts:
A2.
3
ASTM Copper Strip Corrosion Standard
1.4 This international standard was developed in accor-
dance with internationally recognized principles on standard-
3. Summary of Test Method
ization established in the Decision on Principles for the
Development of International Standards, Guides and Recom-
3.1 A polished copper foil strip is immersed in a specific
mendations issued by the World Trade Organization Technical volume of the sample being tested and heated under conditions
Barriers to Trade (TBT) Committee.
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or
contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
1
This test method is under the jurisdiction of ASTM Committee D02 on Standards volume information, refer to the standard’s Document Summary page on
Petroleum Products, Liquid Fuels, and Lubricants and is the direct responsibility of the ASTM website.
3
SubcommitteeD02.05onPropertiesofFuels,PetroleumCokeandCarbonMaterial. Available from ASTM International Headquarters. Request Adjunct No.
Current edition approved Oct. 1, 2017. Published October 2017. Originally ADJD0130. Names of suppliers in the United Kingdom can be obtained from
approved in 2004. Last previous edition approved in 2014 as D7095 – 04 (2014). Energy Institute, 61 New Cavendish St., London,WIM 8AR, United Kingdom. One
DOI: 10.1520/D7095-17. Master Standard is held at Energy Institute for reference.
*A Summary of Changes section appears at the end of this standard
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1
---------------------- Page: 1 ----------------------
D7095 − 17
oftemperatureandtimethatarespecifictotheclassofmaterial
being tested. At the end of the heating period, the copper foil
strip is removed, washed, and the color and tarnish level
assessed against the ASTM Copper Strip Corrosion Standard.
4. Significanc
...
This document is not an ASTM standard and is intended only to provide the user of an ASTM standard an indication of what changes have been made to the previous version. Because
it may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current version
of the standard as published by ASTM is to be considered the official document.
Designation: D7095 − 04 (Reapproved 2014) D7095 − 17
Standard Test Method for
Rapid Determination of Corrosiveness to Copper from
1
Petroleum Products Using a Disposable Copper Foil Strip
This standard is issued under the fixed designation D7095; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
INTRODUCTION
This test method is similar in nature to the Test Method D130 test method, but involves three major
differences. Firstly, a single-use copper foil strip is used in place of the Test Method D130 multi-use
copper strip. Secondly, a different polishing technique is used in preparing the copper foil strip, which
uses a commercially available scouring-pad in place of the initial and final polishing techniques
described in Test Method D130. Thirdly, this test method involves a shorter analysis time of 45
minutes 45 min for all product types as compared to the Test Method D130 method requirements,
which are longer; for example, two or three hours.
1. Scope Scope*
1.1 This test method covers the determination of the corrosiveness to copper of aviation gasoline, aviation turbine fuel,
automotive gasoline, natural gasoline, or other hydrocarbons having a vapor pressure no greater than 124 kPa (18 psi), 124 kPa
(18 psi), cleaners (for example, Stoddard solvent), kerosine, diesel fuel, distillate fuel oil, lubricating oil, and other petroleum
products.
1.2 The values stated in SI units are to be regarded as the standard. The values in parentheses are provided for information only.
1.2.1 Exception—The values in parentheses are provided for information only.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility
of the user of this standard to establish appropriate safety safety, health, and healthenvironmental practices and determine the
applicability of regulatory limitations prior to use. For specific warning statements, see 6.1, 10.1.1, and Annex A2.
1.4 This international standard was developed in accordance with internationally recognized principles on standardization
established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued
by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
2. Referenced Documents
2
2.1 ASTM Standards:
B152/B152M Specification for Copper Sheet, Strip, Plate, and Rolled Bar
D130 Test Method for Corrosiveness to Copper from Petroleum Products by Copper Strip Test
D396 Specification for Fuel Oils
D975 Specification for Diesel Fuel Oils
D1655 Specification for Aviation Turbine Fuels
D1838 Test Method for Copper Strip Corrosion by Liquefied Petroleum (LP) Gases
D4057 Practice for Manual Sampling of Petroleum and Petroleum Products
D4177 Practice for Automatic Sampling of Petroleum and Petroleum Products
D6615 Specification for Jet B Wide-Cut Aviation Turbine Fuel
E1 Specification for ASTM Liquid-in-Glass Thermometers
1
This test method is under the jurisdiction of ASTM Committee D02 on Petroleum Products, Liquid Fuels, and Lubricants and is the direct responsibility of Subcommittee
D02.05 on Properties of Fuels, Petroleum Coke and Carbon Material.
Current edition approved May 1, 2014Oct. 1, 2017. Published July 2014October 2017. Originally approved in 2004. Last previous edition approved in 20092014 as
D7095 - 04 (2009).D7095 – 04 (2014). DOI: 10.1520/D7095-04R14.10.1520/D7095-17.
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM Standards
volume information, refer to the standard’s Document Summary page on the ASTM website.
*A Summary of Changes section appears at the end of this standard
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1
---------------------- Page: 1 ----------------------
D7095 − 17
2.2 ASTM Adjuncts:
3
ASTM Copper Strip Corrosion Standard
3. Summary of Test Method
3.1 A polished copper foil strip is immersed in a specific volume of the sample being tested and heated under conditions of
temperature and time that are specific to the class of material being tested. At the end of the heating period, the copper foil strip
is removed, washed, and the color and tarnish level assess
...
NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation: D7095 − 17
Standard Test Method for
Rapid Determination of Corrosiveness to Copper from
1
Petroleum Products Using a Disposable Copper Foil Strip
This standard is issued under the fixed designation D7095; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
INTRODUCTION
This test method is similar in nature to the Test Method D130 test method, but involves three major
differences. Firstly, a single-use copper foil strip is used in place of the Test Method D130 multi-use
copper strip. Secondly, a different polishing technique is used in preparing the copper foil strip, which
uses a commercially available scouring-pad in place of the initial and final polishing techniques
described in Test Method D130. Thirdly, this test method involves a shorter analysis time of 45 min
for all product types as compared to the Test Method D130 method requirements, which are longer;
for example, two or three hours.
1. Scope* 2. Referenced Documents
2
2.1 ASTM Standards:
1.1 This test method covers the determination of the corro-
B152/B152M Specification for Copper Sheet, Strip, Plate,
siveness to copper of aviation gasoline, aviation turbine fuel,
and Rolled Bar
automotive gasoline, natural gasoline, or other hydrocarbons
D130 Test Method for Corrosiveness to Copper from Petro-
having a vapor pressure no greater than 124 kPa (18 psi),
leum Products by Copper Strip Test
cleaners (for example, Stoddard solvent), kerosine, diesel fuel,
D396 Specification for Fuel Oils
distillate fuel oil, lubricating oil, and other petroleum products.
D975 Specification for Diesel Fuel Oils
1.2 The values stated in SI units are to be regarded as the
D1655 Specification for Aviation Turbine Fuels
standard.
D1838 Test Method for Copper Strip Corrosion by Liquefied
1.2.1 Exception—The values in parentheses are provided for
Petroleum (LP) Gases
information only.
D4057 Practice for Manual Sampling of Petroleum and
Petroleum Products
1.3 This standard does not purport to address all of the
D4177 Practice for Automatic Sampling of Petroleum and
safety concerns, if any, associated with its use. It is the
Petroleum Products
responsibility of the user of this standard to establish appro-
D6615 Specification for Jet B Wide-Cut Aviation Turbine
priate safety, health, and environmental practices and deter-
Fuel
mine the applicability of regulatory limitations prior to use.
E1 Specification for ASTM Liquid-in-Glass Thermometers
For specific warning statements, see 6.1, 10.1.1, and Annex
A2. 2.2 ASTM Adjuncts:
3
ASTM Copper Strip Corrosion Standard
1.4 This international standard was developed in accor-
dance with internationally recognized principles on standard-
3. Summary of Test Method
ization established in the Decision on Principles for the
Development of International Standards, Guides and Recom- 3.1 A polished copper foil strip is immersed in a specific
mendations issued by the World Trade Organization Technical volume of the sample being tested and heated under conditions
Barriers to Trade (TBT) Committee.
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or
contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
1
This test method is under the jurisdiction of ASTM Committee D02 on Standards volume information, refer to the standard’s Document Summary page on
Petroleum Products, Liquid Fuels, and Lubricants and is the direct responsibility of the ASTM website.
3
Subcommittee D02.05 on Properties of Fuels, Petroleum Coke and Carbon Material. Available from ASTM International Headquarters. Request Adjunct No.
Current edition approved Oct. 1, 2017. Published October 2017. Originally ADJD0130. Names of suppliers in the United Kingdom can be obtained from
approved in 2004. Last previous edition approved in 2014 as D7095 – 04 (2014). Energy Institute, 61 New Cavendish St., London, WIM 8AR, United Kingdom. One
DOI: 10.1520/D7095-17. Master Standard is held at Energy Institute for reference.
*A Summary of Changes section appears at the end of this standard
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1
---------------------- Page: 1 ----------------------
D7095 − 17
of temperature and time that are specific to the class of material
being tested. At the end of the heating period, the copper foil
strip is removed, washed, and the color and tarnish level
assessed against the ASTM Copper Strip Corrosion Standard.
4. Significance and Use
4.1 Crude petroleum contains sulfur compounds, most of
which are removed during refining. However,
...
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