ASTM D4362-13

Standard Specification for Propane Thermophysical Property Tables

ABSTRACT
This specification covers methyl n-amyl ketone (98 % grade) for use in paint, varnish, lacquer, and related products. The apparent specific gravity, color, distillation range, water, acidity, and purity of the material shall be tested to meet the requirements prescribed.
SCOPE
1.1 The thermophysical property tables for propane are used in calculating the pressure-volume-temperature (PVT), thermodynamic, and transport properties of propane for process design and operations. Two tables provide properties at the conditions of liquid-vapor equilibrium (saturation properties), one for liquid and one for vapor, at temperatures between 90K and the critical point, 380K. A third table provides properties at selected  T, p points for the equilibrium phase at temperatures between 90K and 600K at pressures to 20 MPa. The tables were developed by the National Institute of Standards and Technology from a Standard Reference Database product REFPROP, version 9.0.  
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

General Information

• Status: Historical
• Publication Date: 31-Oct-2013
• ICS: 75.160.30 - Gaseous fuels
• Technical Committee: D03 - Gaseous Fuels
• Drafting Committee: D03.08 - Thermophysical Properties

Relations

• Replaces: ASTM D4362-08 - Standard Specification for Propane Thermophysical Property Tables
• Effective Date: 01-Nov-2013
• Replaced By: ASTM D4362-19 - Standard Specification for Propane Thermophysical Property Tables
• Effective Date: 01-Apr-2019

Standards Content (Sample)

NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation:D4362 −13
Standard Specification for
1
Propane Thermophysical Property Tables
This standard is issued under the fixed designation D4362; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope 3.2.1 Thermophysical Properties of Propane Liquid at
Vapor-Liquid Equilibrium, in SI units. See Table 1.
1.1 The thermophysical property tables for propane are used
3.2.2 Thermophysical Properties of Propane Vapor at
in calculating the pressure-volume-temperature (PVT),
Vapor-Liquid Equilibrium, in SI units. See Table 2
thermodynamic, and transport properties of propane for pro-
3.2.3 Thermophysical Properties of Propane Along Isobars,
cessdesignandoperations.Twotablesprovidepropertiesatthe
in SI units. See Table 3.
conditions of liquid-vapor equilibrium (saturation properties),
one for liquid and one for vapor, at temperatures between 90K 3.3 The symbols are:
and the critical point, 380K.Athird table provides properties at T, temperature (K)
-1
selected T, p points for the equilibrium phase at temperatures ρ, molar density (mol·L )
-1
between 90K and 600K at pressures to 20 MPa. The tables H, molar enthalpy (J·mol )
-1 -1
were developed by the National Institute of Standards and S, molar entropy (J·K ·mol )
-1 -1
Technology from a Standard Reference Database product C , constant volume molar heat capacity (J·K ·mol )
v
-1 -1
REFPROP, version 9.0. C , constant pressure molar heat capacity (J·K ·mol )
p
-1
c, speed of sound (m·s )
1.2 The values stated in SI units are to be regarded as
η, viscosity (µPa·s)
standard. No other units of measurement are included in this
-1 -1
λ, thermal conductivity (mW·m ·K )
standard.
3.4 The tabulated thermophysical properties are:
-1
2. Applicability
ρ, molar density (mol·L )
-1
2.1 These tables apply only to pure gaseous propane. They H, molar enthalpy (J·mol )
-1 -1
S, molar entropy (J·K ·mol )
may also be used in mathematical models and tables for the
-1 -1
C , constant volume molar heat capacity (J·K ·mol )
thermophysical properties of mixtures containing propane.
v
-1 -1
C , constant pressure molar heat capacity (J·K ·mol )
p
-1
3. Tables
c, speed of sound (m·s )
η, viscosity (µPa·s)
3.1 These tables were produced by equations from a com-
-1 -1
λ, thermal conductivity (mW·m ·K )
puter package, “NIST Standard Reference Database 23; Ref-
erence Fluid Thermodynamic and Transport Properties Data-
4. Additional Information
2
base (REFPROP): Version 9.0.” A wide selection of units (SI
4.1 Reference state properties are required to calculate the
units, engineering units, chemical units) and additional prop-
thermodynamic properties enthalpy and entropy from an equa-
erties are available with this program.
tion of state formulation. The reference state properties used
3.2 These thermophysical property tables are:
are those specified by the International Institute of Refrigera-
tion (IIR): enthalpy, H= 200 J/g, and entropy, S= 1 J/(g· K), for
1
This specification is under the jurisdiction of ASTM Committee D03 on
the saturated liquid at 273.15K (0°C).
Gaseous Fuels and is the direct responsibility of Subcommittee D03.08 on
4.2 The molar mass of propane is 44.096 g/mol.
Thermophysical Properties.
Current edition approved Nov. 1, 2013. Published December 2013. Originally
approved in 1984. Last previous edition approved in 2008 as D4362 – 08. DOI: 5. Keywords
10.1520/D4362-13.
2 5.1 natural gas; propane gas tables; thermodynamic proper-
Available from Standard Reference Data, National Institute of Standards and
Technology (NIST), 100 Bureau Drive, Stop 3460, Gaithersburg, MD 20899. ties of propane; transport properties of propane
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1

---------------------- Page: 1 ----------------------
D4362−13
TABLE 1 Thermophysical Properties of Propane Liquid at Vapor-Liquid Equilibrium
Tp ρ HS C C c ηλ
v p
-1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1
K MPa mol·L J·mol J·mol ·K J·mol ·K J·mol ·K m·s µPa·s mW·m ·K
90 9.6910E-10 16.520 -8292.7 -57.241 59.512 84.645 2106.1 7394.7 206.63
92 1.9788E-09 16.473 -8123.3 -55.380 59.421 84.730 2092.4 6358.7 206.01
94 3.9100E-09 16.426 -7953.8 -53.557 59.340 84.820 2078.8 5517.7 205.35
96 7.4917E-09 16.379 -7784.1 -51.770 59.269 84.916 2065.1 4827.0 204.66
98 1.3947E-08 16.333 -7614.1 -50.018 59.206 85.016 2051.5 4253.9 203.94
100 2.5272E-08 16.286 -7444.0 -48.299 59.150 85.119 2037.8 3773.9 203.19
102 4.4646E-08 16.240 -7273.7 -46.613 59.100 85.226 2024.1 3368.8 202.42
104 7.7011E-08 16.193 -7103.1 -44.957 59.057 85.336 2010.4 3024.2 201.62
1
...

This document is not an ASTM standard and is intended only to provide the user of an ASTM standard an indication of what changes have been made to the previous version. Because
it may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current version
of the standard as published by ASTM is to be considered the official document.
Designation: D4362 − 08 D4362 − 13
Standard Specification for
1
Propane Thermophysical Property Tables
This standard is issued under the fixed designation D4362; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope
1.1 The thermophysical property tables for propane are for use used in the calculation of the calculating the pressure-volume-
temperature (PVT), thermodynamic, and transport properties of propane for process design and operations. Tables are provided for
gaseous and liquid propane at temperatures between 90 and 600 K at pressures to 20 MPa. One table provides properties at the
conditions of liquid-vapor equilibrium (saturation properties). The other Two tables provide properties at the conditions of
liquid-vapor equilibrium (saturation properties), one for liquid and one for vapor, at temperatures between 90K and the critical
point, 380K. A third table provides properties at selected T,p points for the equilibrium phase at those conditions. temperatures
between 90K and 600K at pressures to 20 MPa. The tables were developed by the National Institute of Standards and Technology
from a Standard Reference Database product REFPROP, version 8.0.9.0.
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
2. Applicability
2.1 These tables apply directly only to pure gaseous propane. However, it is expected that they may find substantial useThey
may also be used in mathematical models and tables for the thermophysical properties of mixtures containing propane.
3. Tables
3.1 These tables were produced by equations from a computer package, “NIST Standard Reference Database 23; Reference
2
Fluid Thermodynamic and Transport Properties Database (REFPROP): Version 9.0.” A wide selection of units (SI units,
engineering units, chemical units) and additional properties are available with this program.
3.2 These thermophysical property tables are:
3.2.1 Thermophysical Properties of Coexisting Gaseous and Liquid Propane, Propane Liquid at Vapor-Liquid Equilibrium, in
SI units. See Table 1.
3.2.2 Thermophysical Properties of Propane Vapor at Vapor-Liquid Equilibrium, in SI units. See Table 2
3.2.3 Thermophysical Properties of Propane Along Isobars, in SI units. See Table 23.
3.3 The tabulated thermophysical properties symbols are:
T, temperature (K)
-1
ρ, molar density (mol·l(mol·L )
-1
H, molar enthalpy (J·mol )
-1 -1
S, molar entropy (J·K ·mol )
-1 -1
C , constant volume molar heat capacity (J·K ·mol )
v
-1 -1
C , constant pressure molar heat capacity (J·K ·mol )
p
-1
c, speed of sound (m·s )
η, viscosity (μPa·s)
-1 -1
λ, thermal conductivity (mW·m ·K )
3.4 The tabulated thermophysical properties are:
-1
ρ, molar density (mol·L )
-1
H, molar enthalpy (J·mol )
-1 -1
S, molar entropy (J·K ·mol )
1
This specification is under the jurisdiction of ASTM Committee D03 on Gaseous Fuels and is the direct responsibility of Subcommittee D03.08 on Thermophysical
Properties.
Current edition approved Dec. 1, 2008Nov. 1, 2013. Published January 2009December 2013. Originally approved in 1984. Last previous edition approved in 20032008
as D4362 – 93 (2003).D4362 – 08. DOI: 10.1520/D4362-08.10.1520/D4362-13.
2
Available from Standard Reference Data, National Institute of Standards and Technology (NIST), 100 Bureau Drive, Stop 3460, Gaithersburg, MD 20899.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1

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D4362 − 13
TABLE 1 Thermophysical Properties of Coexisting Gaseous and Liquid Propane
T p ρ H S C C c η λ
v p
-1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1
K MPa mol·l J·mol J·mol ·K J·mol ·K J·mol ·K m·s μPa·s mW·m ·K
90 9.69E-10 16.520 -21348 87.53 59.51 84.64 2106.1 7395 206.6
90 9.69E-10 1.3E-09 3270.8 361.07 31.24 39.55 146.59 2.744 1.919
92 1.98E-09 16.473 -21178 89.40 59.42 84.73 2092.4 6359 206.0
92 1.98E-09 2.59E-09 3350.2 356.01 31.58 39.90 148.03 2.790 2.017
94 3.91E-09 16.426 -21009 91.22 59.34 84.82 2078.8 5518 205.4
94 3.91E-09 5E-09 3430.4 351.21 31.93 40.25 149.46 2.837 2.115
96 7.49E-09 16.379 -20839 93.00 59.27 84.92 2065.1 4827 204.7
96 7.49E-09 9.39E-09 3511.2 346.65 32.28 40.59 150.88 2.884 2.214
98 1.39E-08 16.333 -20669 94.76 59.21 85.02 2051.5
...