Construction products: Assessment of release of dangerous substances - Analysis of organic substances in eluates

This document specifies existing methods for the determination of specific organic substances in aqueous eluates from leaching of construction products.
The following parameters are covered: pH, electrical conductivity, biocides, bisphenol A, BTEX, dioxins and furans, DOC, epichlorohydrin, mineral oil, nonylphenols, PAH, PBDE, PCB, dioxin-like PCB, PCP, phenols and phthalates.
NOTE 1   Methods still under development or available at national level only are listed in Annex B for certain amines, AOX, and biocidal and plant protection products.
NOTE 2   Methods that have not been validated for aqueous eluates from leaching of construction products, because no suitable material was available at the time of the robustness validation, only are listed in Annex B. This applies to organotin compounds.
The methods in this document come from different fields, mainly the analysis of water, and are applicable for the eluates from construction products. They are validated for eluates of the product types listed in Annex A.
NOTE 3   Construction products include, e.g. mineral-based products, bituminous products, wood-based products, polymer-based products and metals. This document includes analytical methods for all matrices except metals.
The selection of the method to be applied is based on the product matrix and the required sensitivity.

Bauprodukte: Bewertung der Freisetzung von gefährlichen Stoffen - Analyse von organischen Stoffen in Eluaten

Dieses Dokument legt vorhandene Verfahren zur Bestimmung spezifischer organischer Stoffe in wässrigen Eluaten fest, die durch die Auslaugung von Bauprodukten gewonnen wurden.
Die folgenden Parameter sind abgedeckt: pH, elektrische Leitfähigkeit, Biozide, Bisphenol A, BTEX, Dioxine und Furane, DOC, Epichlorhydrin, Mineralöl, Nonylphenole, PAK, PBDE, PCB, dioxinähnliche PCB, PCP, Phenole und Phthalate.
ANMERKUNG 1   Noch in der Entwicklung befindliche Verfahren oder solche, die ausschließlich auf nationaler Ebene vorhanden sind, sind für bestimmte Amine, AOX und Biozid- und Pflanzenschutzmittel in Anhang B aufgeführt.
ANMERKUNG 2   Verfahren, die für durch Auslaugung aus Bauprodukten gewonnene wässrige Eluate nicht validiert wurden, da zum Zeitpunkt der Robustheitsvalidierung kein geeignetes Material verfügbar war, sind lediglich in Anhang B aufgeführt. Dies betrifft Organozinnverbindungen.
Die Verfahren in diesem Dokument stammen aus unterschiedlichen Bereichen, hauptsächlich der Wasser-analyse, und sind für Eluate aus Bauprodukten anwendbar. Sie sind für die Eluate der in Anhang A aufge-führten Produkttypen validiert.
ANMERKUNG 3   Zu Bauprodukten zählen unter anderem mineralische Produkte, bituminöse Produkte, Holzprodukte, Polymerprodukte und Metalle. Dieses Dokument enthält analytische Verfahren für alle Matrizen mit Ausnahme von Metallen.
Die Auswahl des anzuwendenden Verfahrens basiert auf der Produktmatrix und der erforderlichen Empfindlichkeit.

Produits de construction: Evaluation de l'émission de substances dangereuses - Analyse des substances organiques contenues dans les éluats

Gradbeni proizvodi - Ocenjevanje sproščanja nevarnih snovi - Analiza organskih snovi v izlužkih

Ta tehnična specifikacija določa obstoječe metode za določanje nehlapnih organskih snovi v vodnih izlužkih za kvantifikacijo sproščanja iz gradbenih proizvodov.  Zajema naslednje substance: fenoli, PAH, PCB, ftalati, PBDE, organokositrove spojine, dioksini in furani, biocidi in izdelki za zaščito rastlin. Izbira uporabljene metode temelji na matrici izdelka in zahtevani občutljivosti.

General Information

Status
Published
Publication Date
07-May-2019
Current Stage
6060 - Definitive text made available (DAV) - Publishing
Due Date
08-May-2019
Completion Date
08-May-2019

Buy Standard

Technical specification
-TS CEN/TS 17332:2019
English language
16 pages
sale 10% off
Preview
sale 10% off
Preview

e-Library read for
1 day

Standards Content (sample)

SLOVENSKI STANDARD
SIST-TS CEN/TS 17332:2019
01-julij-2019
Gradbeni proizvodi - Ocenjevanje sproščanja nevarnih snovi - Analiza organskih
snovi v izlužkih

Construction products - Assessment of release of dangerous substances - Analysis of

organic substances in eluates
Bauprodukte - Bewertung der Freisetzung von gefährlichen Stoffen - Analyse von
nichtflüchtigen organischen Stoffen in Eluaten
Produits de construction - Evaluation de l'émission de substances dangereuses -
Analyse des substances organiques contenues dans les éluats
Ta slovenski standard je istoveten z: CEN/TS 17332:2019
ICS:
13.020.99 Drugi standardi v zvezi z Other standards related to
varstvom okolja environmental protection
91.100.01 Gradbeni materiali na Construction materials in
splošno general
SIST-TS CEN/TS 17332:2019 en,fr,de

2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

---------------------- Page: 1 ----------------------
SIST-TS CEN/TS 17332:2019
---------------------- Page: 2 ----------------------
SIST-TS CEN/TS 17332:2019
CEN/TS 17332
TECHNICAL SPECIFICATION
SPÉCIFICATION TECHNIQUE
May 2019
TECHNISCHE SPEZIFIKATION
ICS 91.100.01
English Version
Construction products: Assessment of release of
dangerous substances - Analysis of organic substances in
eluates

Produits de construction: Evaluation de l'émission de Bauprodukte: Bewertung der Freisetzung von

substances dangereuses - Analyse des substances gefährlichen Stoffen - Analyse von organischen Stoffen

organiques contenues dans les éluats in Eluaten

This Technical Specification (CEN/TS) was approved by CEN on 11 February 2019 for provisional application.

The period of validity of this CEN/TS is limited initially to three years. After two years the members of CEN will be requested to

submit their comments, particularly on the question whether the CEN/TS can be converted into a European Standard.

CEN members are required to announce the existence of this CEN/TS in the same way as for an EN and to make the CEN/TS

available promptly at national level in an appropriate form. It is permissible to keep conflicting national standards in force (in

parallel to the CEN/TS) until the final decision about the possible conversion of the CEN/TS into an EN is reached.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,

Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania,

Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland,

Turkey and United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION
EUROPÄISCHES KOMITEE FÜR NORMUNG
CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels

© 2019 CEN All rights of exploitation in any form and by any means reserved Ref. No. CEN/TS 17332:2019 E

worldwide for CEN national Members.
---------------------- Page: 3 ----------------------
SIST-TS CEN/TS 17332:2019
CEN/TS 17332:2019 (E)
Contents Page

European foreword ...................................................................................................................................................... 3

Introduction .................................................................................................................................................................... 4

1 Scope .................................................................................................................................................................... 5

2 Normative references .................................................................................................................................... 5

3 Terms and definitions ................................................................................................................................... 6

4 Abbreviations ................................................................................................................................................... 8

5 Sample preparation ....................................................................................................................................... 8

6 Blank determination ..................................................................................................................................... 9

7 Interferences .................................................................................................................................................... 9

8 Selection of the suitable test method ....................................................................................................... 9

9 Expression of results ................................................................................................................................... 11

10 Test report ....................................................................................................................................................... 11

Annex A (informative) Validation of eluates from construction products .............................................. 12

Annex B (informative) Overview of methods still under development, alternative methods

and methods for biocidal and plant protection products .............................................................. 13

Bibliography ................................................................................................................................................................. 15

---------------------- Page: 4 ----------------------
SIST-TS CEN/TS 17332:2019
CEN/TS 17332:2019 (E)
European foreword

This document (CEN/TS 17332:2019) has been prepared by Technical Committee CEN/TC 351

“Construction products: Assessment of release of dangerous substances”, the secretariat of which is

held by NEN.

Attention is drawn to the possibility that some of the elements of this document may be the subject of

patent rights. CEN shall not be held responsible for identifying any or all such patent rights.

This document has been prepared under a mandate given to CEN by the European Commission and

the European Free Trade Association.

According to the CEN-CENELEC Internal Regulations, the national standards organizations of the

following countries are bound to announce this Technical Specification: Austria, Belgium, Bulgaria,

Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia,

France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta,

Netherlands, Norway, Poland, Portugal, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden,

Switzerland, Turkey and the United Kingdom.
---------------------- Page: 5 ----------------------
SIST-TS CEN/TS 17332:2019
CEN/TS 17332:2019 (E)
Introduction

This Technical Specification deals with the determination of organic substances in eluates which have

been obtained by leaching of construction products.

Following an extended evaluation of available methods for content and eluate analysis in construction

products (CEN/TR 16045 [1]) it was concluded that eluate analysis methods are very similar to

analytical methods used to determine organic substances in water. The present document is similar in

structure to EN 16192 [2].

This standard is part of a modular horizontal approach and belongs to the analytical step. An overview

of all modules which belong to a chain of measurement and the manner how modules are selected is

given in CEN/TR 16220 [3].

In the growing amount of product and sector oriented test methods it was recognized that many steps

in test procedures are or could be used in test procedures for many products, materials and sectors. It

was supposed that, by careful determination of these steps and selection of specific questions within

these steps, elements of the test procedure could be described in a way that can be used for all

materials and products or for all materials and products with certain specifications.

In this context a horizontal modular approach is adopted in CEN/TC 351. 'Horizontal' means that the

methods can be used for a wide range of materials and products with certain properties. 'Modular'

means that a test standard developed in this approach concerns a specific step in assessing a property

and not the whole 'chain of measurement' (from sampling to analyses). A beneficial feature of this

approach is that 'modules' can be replaced by better ones without jeopardizing the standard 'chain'.

The use of modular horizontal standards implies the drawing of test schemes as well. Before executing

a test on a certain material or product to determine certain characteristics it is necessary to draw up a

protocol in which the adequate modules are selected and together form the basis for the entire test

procedure.
This module relates to CEN/TS 16637-1 [4], CEN/TS 16637-2 and CEN/TS 16637-3.
---------------------- Page: 6 ----------------------
SIST-TS CEN/TS 17332:2019
CEN/TS 17332:2019 (E)
1 Scope

This document specifies existing methods for the determination of specific organic substances in

aqueous eluates from leaching of construction products.

The following parameters are covered: pH, electrical conductivity, biocides, bisphenol A, BTEX, dioxins

and furans, DOC, epichlorohydrin, mineral oil, nonylphenols, PAH, PBDE, PCB, dioxin-like PCB, PCP,

phenols and phthalates.

NOTE 1 Methods still under development or available at national level only are listed in Annex B for certain

amines, AOX, and biocidal and plant protection products.

NOTE 2 Methods that have not been validated for aqueous eluates from leaching of construction products,

because no suitable material was available at the time of the robustness validation, only are listed in Annex B.

This applies to organotin compounds.

The methods in this document come from different fields, mainly the analysis of water, and are

applicable for the eluates from construction products. They are validated for eluates of the product

types listed in Annex A.

NOTE 3 Construction products include, e.g. mineral-based products, bituminous products, wood-based

products, polymer-based products and metals. This document includes analytical methods for all matrices except

metals.

The selection of the method to be applied is based on the product matrix and the required sensitivity.

2 Normative references

The following documents are referred to in the text in such a way that some or all of their content

constitutes requirements of this document. For dated references, only the edition cited applies. For

undated references, the latest edition of the referenced document (including any amendments)

applies.

EN 1484, Water analysis — Guidelines for the determination of total organic carbon (TOC) and dissolved

organic carbon (DOC)

EN 12673, Water quality — Gas chromatographic determination of some selected chlorophenols in water

EN 14207, Water quality — Determination of epichlorohydrin

EN 15637, Foods of plant origin — Determination of pesticide residues using LC-MS/MS following

methanol extraction and clean-up using diatomaceous earth

CEN/TS 16637-2, Construction products — Assessment of release of dangerous substances — Part 2:

Horizontal dynamic surface leaching test

CEN/TS 16637-3, Construction products — Assessment of release of dangerous substances — Part 3:

Horizontal up-flow percolation test

EN 16687:2015, Construction products — Assessment of release of dangerous substances - Terminology

EN 16694, Water quality — Determination of selected polybrominated diphenyl ether (PBDE) in whole

water samples — Method using solid phase extraction (SPE) with SPE-disks combined with gas

chromatography-mass spectrometry (GC-MS)
EN 27888, Water quality — Determination of electrical conductivity (ISO 7888)

EN ISO 5667-3, Water quality — Sampling — Part 3: Preservation and handling of water samples (ISO

5667-3)
---------------------- Page: 7 ----------------------
SIST-TS CEN/TS 17332:2019
CEN/TS 17332:2019 (E)

EN ISO 9377-2, Water quality — Determination of hydrocarbon oil index — Part 2: Method using solvent

extraction and gas chromatography (ISO 9377-2)
EN ISO 10523, Water quality — Determination of pH (ISO 10523)

EN ISO 14402, Water quality — Determination of phenol index by flow analysis (FIA and CFA) (ISO

14402)

EN ISO 15680, Water quality — Gas-chromatographic determination of a number of monocyclic

aromatic hydrocarbons, naphthalene and several chlorinated compounds using purge-and-trap and

thermal desorption (ISO 15680)

EN ISO 17294-1:2006, Water quality — Application of inductively coupled plasma mass spectrometry

(ICP-MS) — Part 1: General guidelines (ISO 17294-1:2004)

EN ISO 18856, Water quality — Determination of selected phthalates using gas chromatography/mass

spectrometry (ISO 18856)

EN ISO 18857-2, Water quality — Determination of selected alkylphenols — Part 2: Gas

chromatographic-mass spectrometric determination of alkylphenols, their ethoxylates and bisphenol A in

non-filtered samples following solid-phase extraction and derivatisation (ISO 18857-2)

ISO 17858, Water quality — Determination of dioxin-like polychlorinated biphenyls — Method using gas

chromatography/mass spectrometry

ISO 18073, Water quality — Determination of tetra- to octa-chlorinated dioxins and furans — Method

using isotope dilution HRGC/HRMS

ISO 20595, Water quality — Determination of selected highly volatile organic compounds in water —

Method using gas chromatography and mass spectrometry by static headspace technique (HS-GC-MS)

ISO 28540, Water quality — Determination of 16 polycyclic aromatic hydrocarbons (PAH) in water —

Method using gas chromatography with mass spectrometric detection (GC-MS)
3 Terms and definitions
For the purposes of this document, the following terms and definitions apply.

ISO and IEC maintain terminological databases for use in standardization at the following addresses:

— IEC Electropedia: available at http://www.electropedia.org/
— ISO Online browsing platform: available at http://www.iso.org/obp
3.1
alternative method
method calibrated against the reference test method used to determine a value of

release/emission/content of substances directly correlating with the test results from the reference

test method

Note 1 to entry: An alternative method can be, e.g. a modified reference test method or an indirect test method

which is based on another test method. See also “indirect test”.
Note 2 to entry: In type testing reference test methods have always to be used.
[SOURCE: EN 16687:2015, 4.1.5]
---------------------- Page: 8 ----------------------
SIST-TS CEN/TS 17332:2019
CEN/TS 17332:2019 (E)
3.2
blank value

test result obtained by carrying out the test procedure in the absence of a test portion

Note 1 to entry: A blank value is expressed in the same units as for presenting the test results as usual for that

test.
[SOURCE: EN 16687:2015, 4.1.10]
3.3
eluate
solution obtained from a leaching test
[SOURCE: EN 16687:2015, 4.2.7]
3.4
laboratory sample
sample or subsample(s) sent to or received by the laboratory
[SOURCE: EN 16687:2015, 3.2.1]
3.5
leaching test

laboratory test for the determination of the release of matter from a construction product into water

or an aqueous solution
3.6
method detection limit
MDL

smallest analyte concentration that can be detected with a specified analytical method including

sample preparation with a defined statistical probability

[SOURCE: EN ISO 17294-1:2006, 3.12, modified – “including sample preparation” added, symbol

replaced by abbreviation]
3.7
sample
portion of material selected from a larger quantity of material
[SOURCE: EN 16687:2015, 3.1.5]
3.8
test portion
analytical portion

amount of the test sample taken for testing/analysis purposes, usually of known weight or volume

[SOURCE: EN 16687:2015, 3.2.3]
3.9
test sample

sample, prepared from the laboratory sample, from which test portions are removed for testing or

analysis
[SOURCE: EN 16687:2015, 3.2.2]
---------------------- Page: 9 ----------------------
SIST-TS CEN/TS 17332:2019
CEN/TS 17332:2019 (E)
4 Abbreviations
For the purposes of this document, the following abbreviations apply.
AED atomic-emission detector
AOX adsorbable organically bound halogens
BTEX alkylated benzenes: sum of benzene, toluene, ethylbenzene and xylenes
CFA continuous flow analysis

DIBt Deutsches Institut für Bautechnik (German Centre of Competence for Construction,

www.dibt.de)
DOC dissolved organic carbon
ECD electron capture detector
EOTA European Organisation for Technical Assessment
FIA flow injection analysis
GC gas chromatography
HPLC high performance liquid chromatography
NOTE High pressure liquid chromatography is an (outdated) synonym.
LLE liquid-liquid extraction, also known as solvent extraction and partitioning
MS mass spectrometry;
mass selective detection
NP nonylphenol(s)
PAH polycyclic aromatic hydrocarbon(s)
PBDE polybrominated diphenyl ether(s)
PCB polychlorinated biphenyl(s)
PCP pentachlorophenol
SPE solid phase extraction
TOC total organic carbon
TR Technical Report (ISO, CEN or EOTA)
TS Technical Specification (ISO, CEN or EOTA)
5 Sample preparation

Laboratory samples for analysis are obtained according to leaching standards, such as

...

Questions, Comments and Discussion

Ask us and Technical Secretary will try to provide an answer. You can facilitate discussion about the standard in here.