CEN/TS 17332:2019
(Main)Construction products: Assessment of release of dangerous substances - Analysis of organic substances in eluates
Construction products: Assessment of release of dangerous substances - Analysis of organic substances in eluates
This document specifies existing methods for the determination of specific organic substances in aqueous eluates from leaching of construction products.
The following parameters are covered: pH, electrical conductivity, biocides, bisphenol A, BTEX, dioxins and furans, DOC, epichlorohydrin, mineral oil, nonylphenols, PAH, PBDE, PCB, dioxin-like PCB, PCP, phenols and phthalates.
NOTE 1 Methods still under development or available at national level only are listed in Annex B for certain amines, AOX, and biocidal and plant protection products.
NOTE 2 Methods that have not been validated for aqueous eluates from leaching of construction products, because no suitable material was available at the time of the robustness validation, only are listed in Annex B. This applies to organotin compounds.
The methods in this document come from different fields, mainly the analysis of water, and are applicable for the eluates from construction products. They are validated for eluates of the product types listed in Annex A.
NOTE 3 Construction products include, e.g. mineral-based products, bituminous products, wood-based products, polymer-based products and metals. This document includes analytical methods for all matrices except metals.
The selection of the method to be applied is based on the product matrix and the required sensitivity.
Bauprodukte: Bewertung der Freisetzung von gefährlichen Stoffen - Analyse von organischen Stoffen in Eluaten
Dieses Dokument legt vorhandene Verfahren zur Bestimmung spezifischer organischer Stoffe in wässrigen Eluaten fest, die durch die Auslaugung von Bauprodukten gewonnen wurden.
Die folgenden Parameter sind abgedeckt: pH, elektrische Leitfähigkeit, Biozide, Bisphenol A, BTEX, Dioxine und Furane, DOC, Epichlorhydrin, Mineralöl, Nonylphenole, PAK, PBDE, PCB, dioxinähnliche PCB, PCP, Phenole und Phthalate.
ANMERKUNG 1 Noch in der Entwicklung befindliche Verfahren oder solche, die ausschließlich auf nationaler Ebene vorhanden sind, sind für bestimmte Amine, AOX und Biozid- und Pflanzenschutzmittel in Anhang B aufgeführt.
ANMERKUNG 2 Verfahren, die für durch Auslaugung aus Bauprodukten gewonnene wässrige Eluate nicht validiert wurden, da zum Zeitpunkt der Robustheitsvalidierung kein geeignetes Material verfügbar war, sind lediglich in Anhang B aufgeführt. Dies betrifft Organozinnverbindungen.
Die Verfahren in diesem Dokument stammen aus unterschiedlichen Bereichen, hauptsächlich der Wasser-analyse, und sind für Eluate aus Bauprodukten anwendbar. Sie sind für die Eluate der in Anhang A aufge-führten Produkttypen validiert.
ANMERKUNG 3 Zu Bauprodukten zählen unter anderem mineralische Produkte, bituminöse Produkte, Holzprodukte, Polymerprodukte und Metalle. Dieses Dokument enthält analytische Verfahren für alle Matrizen mit Ausnahme von Metallen.
Die Auswahl des anzuwendenden Verfahrens basiert auf der Produktmatrix und der erforderlichen Empfindlichkeit.
Produits de construction: Evaluation de l'émission de substances dangereuses - Analyse des substances organiques contenues dans les éluats
Gradbeni proizvodi - Ocenjevanje sproščanja nevarnih snovi - Analiza organskih snovi v izlužkih
Ta tehnična specifikacija določa obstoječe metode za določanje nehlapnih organskih snovi v vodnih izlužkih za kvantifikacijo sproščanja iz gradbenih proizvodov. Zajema naslednje substance: fenoli, PAH, PCB, ftalati, PBDE, organokositrove spojine, dioksini in furani, biocidi in izdelki za zaščito rastlin. Izbira uporabljene metode temelji na matrici izdelka in zahtevani občutljivosti.
General Information
Relations
Standards Content (Sample)
SLOVENSKI STANDARD
01-julij-2019
Gradbeni proizvodi - Ocenjevanje sproščanja nevarnih snovi - Analiza organskih
snovi v izlužkih
Construction products - Assessment of release of dangerous substances - Analysis of
organic substances in eluates
Bauprodukte - Bewertung der Freisetzung von gefährlichen Stoffen - Analyse von
nichtflüchtigen organischen Stoffen in Eluaten
Produits de construction - Evaluation de l'émission de substances dangereuses -
Analyse des substances organiques contenues dans les éluats
Ta slovenski standard je istoveten z: CEN/TS 17332:2019
ICS:
13.020.99 Drugi standardi v zvezi z Other standards related to
varstvom okolja environmental protection
91.100.01 Gradbeni materiali na Construction materials in
splošno general
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.
CEN/TS 17332
TECHNICAL SPECIFICATION
SPÉCIFICATION TECHNIQUE
May 2019
TECHNISCHE SPEZIFIKATION
ICS 91.100.01
English Version
Construction products: Assessment of release of
dangerous substances - Analysis of organic substances in
eluates
Produits de construction: Evaluation de l'émission de Bauprodukte: Bewertung der Freisetzung von
substances dangereuses - Analyse des substances gefährlichen Stoffen - Analyse von organischen Stoffen
organiques contenues dans les éluats in Eluaten
This Technical Specification (CEN/TS) was approved by CEN on 11 February 2019 for provisional application.
The period of validity of this CEN/TS is limited initially to three years. After two years the members of CEN will be requested to
submit their comments, particularly on the question whether the CEN/TS can be converted into a European Standard.
CEN members are required to announce the existence of this CEN/TS in the same way as for an EN and to make the CEN/TS
available promptly at national level in an appropriate form. It is permissible to keep conflicting national standards in force (in
parallel to the CEN/TS) until the final decision about the possible conversion of the CEN/TS into an EN is reached.
CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania,
Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland,
Turkey and United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION
EUROPÄISCHES KOMITEE FÜR NORMUNG
CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2019 CEN All rights of exploitation in any form and by any means reserved Ref. No. CEN/TS 17332:2019 E
worldwide for CEN national Members.
Contents Page
European foreword . 3
Introduction . 4
1 Scope . 5
2 Normative references . 5
3 Terms and definitions . 6
4 Abbreviations . 8
5 Sample preparation . 8
6 Blank determination . 9
7 Interferences . 9
8 Selection of the suitable test method . 9
9 Expression of results . 11
10 Test report . 11
Annex A (informative) Validation of eluates from construction products . 12
Annex B (informative) Overview of methods still under development, alternative methods
and methods for biocidal and plant protection products . 13
Bibliography . 15
European foreword
This document (CEN/TS 17332:2019) has been prepared by Technical Committee CEN/TC 351
“Construction products: Assessment of release of dangerous substances”, the secretariat of which is
held by NEN.
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. CEN shall not be held responsible for identifying any or all such patent rights.
This document has been prepared under a mandate given to CEN by the European Commission and
the European Free Trade Association.
According to the CEN-CENELEC Internal Regulations, the national standards organizations of the
following countries are bound to announce this Technical Specification: Austria, Belgium, Bulgaria,
Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia,
France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta,
Netherlands, Norway, Poland, Portugal, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden,
Switzerland, Turkey and the United Kingdom.
Introduction
This Technical Specification deals with the determination of organic substances in eluates which have
been obtained by leaching of construction products.
Following an extended evaluation of available methods for content and eluate analysis in construction
products (CEN/TR 16045 [1]) it was concluded that eluate analysis methods are very similar to
analytical methods used to determine organic substances in water. The present document is similar in
structure to EN 16192 [2].
This standard is part of a modular horizontal approach and belongs to the analytical step. An overview
of all modules which belong to a chain of measurement and the manner how modules are selected is
given in CEN/TR 16220 [3].
In the growing amount of product and sector oriented test methods it was recognized that many steps
in test procedures are or could be used in test procedures for many products, materials and sectors. It
was supposed that, by careful determination of these steps and selection of specific questions within
these steps, elements of the test procedure could be described in a way that can be used for all
materials and products or for all materials and products with certain specifications.
In this context a horizontal modular approach is adopted in CEN/TC 351. 'Horizontal' means that the
methods can be used for a wide range of materials and products with certain properties. 'Modular'
means that a test standard developed in this approach concerns a specific step in assessing a property
and not the whole 'chain of measurement' (from sampling to analyses). A beneficial feature of this
approach is that 'modules' can be replaced by better ones without jeopardizing the standard 'chain'.
The use of modular horizontal standards implies the drawing of test schemes as well. Before executing
a test on a certain material or product to determine certain characteristics it is necessary to draw up a
protocol in which the adequate modules are selected and together form the basis for the entire test
procedure.
This module relates to CEN/TS 16637-1 [4], CEN/TS 16637-2 and CEN/TS 16637-3.
1 Scope
This document specifies existing methods for the determination of specific organic substances in
aqueous eluates from leaching of construction products.
The following parameters are covered: pH, electrical conductivity, biocides, bisphenol A, BTEX, dioxins
and furans, DOC, epichlorohydrin, mineral oil, nonylphenols, PAH, PBDE, PCB, dioxin-like PCB, PCP,
phenols and phthalates.
NOTE 1 Methods still under development or available at national level only are listed in Annex B for certain
amines, AOX, and biocidal and plant protection products.
NOTE 2 Methods that have not been validated for aqueous eluates from leaching of construction products,
because no suitable material was available at the time of the robustness validation, only are listed in Annex B.
This applies to organotin compounds.
The methods in this document come from different fields, mainly the analysis of water, and are
applicable for the eluates from construction products. They are validated for eluates of the product
types listed in Annex A.
NOTE 3 Construction products include, e.g. mineral-based products, bituminous products, wood-based
products, polymer-based products and metals. This document includes analytical methods for all matrices except
metals.
The selection of the method to be applied is based on the product matrix and the required sensitivity.
2 Normative references
The following documents are referred to in the text in such a way that some or all of their content
constitutes requirements of this document. For dated references, only the edition cited applies. For
undated references, the latest edition of the referenced document (including any amendments)
applies.
EN 1484, Water analysis — Guidelines for the determination of total organic carbon (TOC) and dissolved
organic carbon (DOC)
EN 12673, Water quality — Gas chromatographic determination of some selected chlorophenols in water
EN 14207, Water quality — Determination of epichlorohydrin
EN 15637, Foods of plant origin — Determination of pesticide residues using LC-MS/MS following
methanol extraction and clean-up using diatomaceous earth
CEN/TS 16637-2, Construction products — Assessment of release of dangerous substances — Part 2:
Horizontal dynamic surface leaching test
CEN/TS 16637-3, Construction products — Assessment of release of dangerous substances — Part 3:
Horizontal up-flow percolation test
EN 16687:2015, Construction products — Assessment of release of dangerous substances - Terminology
EN 16694, Water quality — Determination of selected polybrominated diphenyl ether (PBDE) in whole
water samples — Method using solid phase extraction (SPE) with SPE-disks combined with gas
chromatography-mass spectrometry (GC-MS)
EN 27888, Water quality — Determination of electrical conductivity (ISO 7888)
EN ISO 5667-3, Water quality — Sampling — Part 3: Preservation and handling of water samples (ISO
5667-3)
EN ISO 9377-2, Water quality — Determination of hydrocarbon oil index — Part 2: Method using solvent
extraction and gas chromatography (ISO 9377-2)
EN ISO 10523, Water quality — Determination of pH (ISO 10523)
EN ISO 14402, Water quality — Determination of phenol index by flow analysis (FIA and CFA) (ISO
14402)
EN ISO 15680, Water quality — Gas-chromatographic determination of a number of monocyclic
aromatic hydrocarbons, naphthalene and several chlorinated compounds using purge-and-trap and
thermal desorption (ISO 15680)
EN ISO 17294-1:2006, Water quality — Application of inductively coupled plasma mass spectrometry
(ICP-MS) — Part 1: General guidelines (ISO 17294-1:2004)
EN ISO 18856, Water quality — Determination of selected phthalates using gas chromatography/mass
spectrometry (ISO 18856)
EN ISO 18857-2, Water quality — Determination of selected alkylphenols — Part 2: Gas
chromatographic-mass spectrometric determination of alkylphenols, their ethoxylates and bisphenol A in
non-filtered samples following solid-phase extraction and derivatisation (ISO 18857-2)
ISO 17858, Water quality — Determination of dioxin-like polychlorinated biphenyls — Method using gas
chromatography/mass spectrometry
ISO 18073, Water quality — Determination of tetra- to octa-chlorinated dioxins and furans — Method
using isotope dilution HRGC/HRMS
ISO 20595, Water quality — Determination of selected highly volatile organic compounds in water —
Method using gas chromatography and mass spectrometry by static headspace technique (HS-GC-MS)
ISO 28540, Water quality — Determination of 16 polycyclic aromatic hydrocarbons (PAH) in water —
Method using gas chromatography with mass spectrometric detection (GC-MS)
3 Terms and definitions
For the purposes of this document, the following terms and definitions apply.
ISO and IEC maintain terminological databases for use in standardization at the following addresses:
— IEC Electropedia: available at http://www.electropedia.org/
— ISO Online browsing platform: available at http://www.iso.org/obp
3.1
alternative method
method calibrated against the reference test method used to determine a value of
release/emission/content of substances directly correlating with the test results from the reference
test method
Note 1 to entry: An alternative method can be, e.g. a modified reference test method or an indirect test method
which is based on another test method. See also “indirect test”.
Note 2 to entry: In type testing reference test methods have always to be used.
[SOURCE: EN 16687:2015, 4.1.5]
3.2
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