CEN ISO/TS 2610:2023
(Main)Analysis of natural gas - Biomethane - Determination of amines content (ISO/TS 2610:2022)
Analysis of natural gas - Biomethane - Determination of amines content (ISO/TS 2610:2022)
This document specifies the determination of the concentration of alkanolamines in biomethane. The measurement method involves thermal desorption gas chromatography with flame ionization and/or mass spectrometry detectors (TD-GC-MS/FID). The described method is specifically developed for the analysis of five amine compounds, namely:
— monoethanolamine (MEA);
— diglycolamine (DGA);
— diethanolamine (DEA);
— N-methyldiethanolamine (MDEA);
— piperazine (PZ).
Information about the compounds is given in Annex A.
Analyse von Erdgas - Biomethan - Bestimmung des Amingehalts (ISO/TS 2610:2022)
Dieses Dokument legt die Bestimmung der Konzentration von Aminoalkohole in Biomethan fest. Das Messverfahren umfasst die Thermodesorber-Gaschromatographie mit Flammenionisations- und/oder Massenspektrometriedetektoren (TD-GC-MS/FID). Das beschriebene Verfahren wurde speziell für die Analyse von fünf Aminverbindungen entwickelt, und zwar:
Monoethanolamin (MEA);
Diglycolamin (DGA);
Diethanolamin (DEA);
N-Methyldiethanolamin (MDEA);
Piperazin (PZ).
Informationen zu den Verbindungen sind in Anhang A angeführt.
Analyse du gaz naturel - Biométhane - Détermination de la teneur en amines (ISO/TS 2610:2022)
Analiza zemeljskega plina - Biometan - Določevanje aminov (ISO/TS 2610:2022)
Ta dokument določa metodo za ugotavljanje koncentracije amino alkoholov v biometanu. Merilna metoda vključuje plinsko kromatografijo s toplotno desorpcijo, pri kateri se uporabljajo plamensko ionizacijski detektorji in/ali detektorji za masno spektrometrijo (TD-GC-MS/FID). Opisana metoda je bila posebej razvita za analizo petih aminovih spojin, in sicer:
– monoetanolamina (MEA);
– diglikolamina (DGA);
– dietanolamina (DEA);
– N-metildietanolamina (MDEA);
– piperazina (PZ).
Informacije o teh spojinah so podane v dodatku A.
General Information
Standards Content (Sample)
SLOVENSKI STANDARD
01-september-2023
Analiza zemeljskega plina - Biometan - Določevanje aminov (ISO/TS 2610:2022)
Analysis of natural gas - Biomethane - Determination of amines content (ISO/TS
2610:2022)
Analyse von Erdgas - Biomethan - Bestimmung des Amingehalts (ISO/TS 2610:2022)
Analyse du gaz naturel - Biométhane - Détermination de la teneur en amines (ISO/TS
2610:2022)
Ta slovenski standard je istoveten z: CEN ISO/TS 2610:2023
ICS:
75.060 Zemeljski plin Natural gas
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.
CEN ISO/TS 2610
TECHNICAL SPECIFICATION
SPÉCIFICATION TECHNIQUE
July 2023
TECHNISCHE SPEZIFIKATION
ICS 75.060
English Version
Analysis of natural gas - Biomethane - Determination of
amines content (ISO/TS 2610:2022)
Analyse du gaz naturel - Biométhane - Détermination Analyse von Erdgas - Biomethan - Bestimmung des
de la teneur en amines (ISO/TS 2610:2022) Amingehalts (ISO/TS 2610:2022)
This Technical Specification (CEN/TS) was approved by CEN on 26 June 2023 for provisional application.
The period of validity of this CEN/TS is limited initially to three years. After two years the members of CEN will be requested to
submit their comments, particularly on the question whether the CEN/TS can be converted into a European Standard.
CEN members are required to announce the existence of this CEN/TS in the same way as for an EN and to make the CEN/TS
available promptly at national level in an appropriate form. It is permissible to keep conflicting national standards in force (in
parallel to the CEN/TS) until the final decision about the possible conversion of the CEN/TS into an EN is reached.
CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway,
Poland, Portugal, Republic of North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Türkiye and
United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION
EUROPÄISCHES KOMITEE FÜR NORMUNG
CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2023 CEN All rights of exploitation in any form and by any means reserved Ref. No. CEN ISO/TS 2610:2023 E
worldwide for CEN national Members.
Contents Page
European foreword . 3
European foreword
The text of ISO/TS 2610:2022 has been prepared by Technical Committee ISO/TC 193 "Natural gas” of
the International Organization for Standardization (ISO) and has been taken over as
transport and biomethane for injection in the natural gas grid” the secretariat of which is held by
AFNOR.
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. CEN shall not be held responsible for identifying any or all such patent rights.
This document has been prepared under a Standardization Request given to CEN by the European
Commission and the European Free Trade Association.
Any feedback and questions on this document should be directed to the users’ national standards body.
A complete listing of these bodies can be found on the CEN website.
According to the CEN-CENELEC Internal Regulations, the national standards organizations of the
following countries are bound to announce this Technical Specification: Austria, Belgium, Bulgaria,
Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland,
Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Republic of
North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Türkiye and the
United Kingdom.
Endorsement notice
The text of ISO/TS 2610:2022 has been approved by CEN as CEN ISO/TS 2610:2023 without any
modification.
TECHNICAL ISO/TS
SPECIFICATION 2610
First edition
2022-08
Analysis of natural gas — Biomethane
— Determination of amines content
Analyse du gaz naturel — Biométhane — Détermination de la teneur
en amines
Reference number
ISO/TS 2610:2022(E)
ISO/TS 2610:2022(E)
© ISO 2022
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Published in Switzerland
ii
ISO/TS 2610:2022(E)
Contents Page
Foreword .iv
Introduction .v
1 Scope . 1
2 Normative references . 1
3 Terms and definitions . 1
4 Reference conditions .2
5 Principle . 2
6 Reagents and equipment . 2
7 Sampling . 3
8 Preparation of the calibration tubes .3
9 Analysis . . 4
9.1 Thermal desorption . 4
9.2 Program temperature of the GC separation . 4
9.3 Sample analysis . . 4
9.4 Quantification method . 5
10 Performance characteristics . 5
11 Calculations . 5
12 Test report . 6
Annex A (informative) Characteristics of the amines to be quantified . 8
Bibliography . 9
iii
ISO/TS 2610:2022(E)
Foreword
ISO (the International Organization for Standardization) is a worldwide federation of national standards
bodies (ISO member bodies). The work of preparing International Standards is normally carried out
through ISO technical committees. Each member body interested in a subject for which a technical
committee has been established has the right to be represented on that committee. International
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ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of
electrotechnical standardization.
The procedures used to develop this document and those intended for its further maintenance are
described in the ISO/IEC Directives, Part 1. In particular, the different approval criteria needed for the
different types of ISO documents should be noted. This document was drafted in accordance with the
editorial rules of the ISO/IEC Directives, Part 2 (see www.iso.org/directives).
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. ISO shall not be held responsible for identifying any or all such patent rights. Details of
any patent rights identified during the development of the document will be in the Introduction and/or
on the ISO list of patent declarations received (see www.iso.org/patents).
Any trade name used in this document is information given for the convenience of users and does not
constitute an endorsement.
For an explanation of the voluntary nature of standards, the meaning of ISO specific terms and
expressions related to conformity assessment, as well as information about ISO's adherence to
the World Trade Organization (WTO) principles in the Technical Barriers to Trade (TBT), see
www.iso.org/iso/foreword.html.
This document was prepared by Technical Committee ISO/TC 193, Natural gas, Subcommittee SC 1,
Analysis of natural gas.
Any feedback or questions on this document should be directed to the user’s national standards body. A
complete listing of these bodies can be found at www.iso.org/members.html.
iv
ISO/TS 2610:2022(E)
Introduction
[7]
This document was developed in response to biomethane specifications such as EN 16723 (all parts) .
In other regions, other specifications can apply for biomethane.
In the process of biogas upgrading into biomethane, alkanolamines are used for removing of sulphur-
containing components and carbon dioxide. Due to this reason, trace level of these components can
be present in biomethane. This method is suited for the detection of these components as well as the
determination of their concentration. To inject biomethane into natural gas grids and to use it as an
automotive fuel, it needs to meet specifications. For amines the maximum limit value in biomethane is
3 [7]
set as 10 mg/m is set in EN 16723 (all parts) . Other specifications can state other thresholds.
v
TECHNICAL SPECIFICATION ISO/TS 2610:2022(E)
Analysis of natural gas — Biomethane — Determination of
amines content
1 Scope
This document specifies the determination of the concentration of alkanolamines in biomethane. The
measurement method involves thermal desorption gas chromatography with flame ionization and/or
mass spectrometry detectors (TD-GC-MS/FID). The described method is specifically developed for the
analysis of five amine compounds, namely:
— monoethanolamine (MEA);
— diglycolamine (DGA);
— diethanolamine (DEA);
— N-methyldiethanolamine (MDEA);
— piperazine (PZ).
Information about the compounds is given in Annex A.
2 Normative references
The following documents are referred to in the text in such a way that some or all of their content
constitutes requirements of this document. For dated references, only the edition cited applies. For
undated references, the latest edition of the referenced document (including any amendments) applies.
ISO 10715, Natural gas — Sampling guidelines
ISO 14532, Natural gas — Vocabulary
ISO 16000-6, Indoor air — Part 6: Determination of organic compounds (VVOC, VOC, SVOC) in indoor and
test chamber air by active sampling on sorbent tubes, thermal desorption and gas chromatography using
MS or MS F
...
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