SIST EN ISO 10370:2015
(Main)Petroleum products - Determination of carbon residue - Micro method (ISO 10370:2014)
Petroleum products - Determination of carbon residue - Micro method (ISO 10370:2014)
This International Standard specifies a method for the determination of the amount of carbon residue,
in the range 0,10 % (m/m) to 30,0 % (m/m), left after evaporation and pyrolysis of petroleum products
under specified conditions.
NOTE 1 The carbon residue value serves as an approximation of the tendency of petroleum products to
form carbonaceous deposits under similar degradation conditions, and may be useful in the assessment of
relative carbon-forming tendencies of products within the same class. In this case, care should be taken in the
interpretation of results.
For products which yield a residue in excess of 0,10 % (m/m), the test results are equivalent to those
obtained by the Conradson carbon residue test (see ISO 6615[1]) in the range of 0,10 (m/m) to 25,0 (m/m)
(for details see Annex A).
This International Standard is also applicable to petroleum products which consist essentially of
distillate material, and which may yield a carbon residue below 0,10 % (m/m). On such materials, a
10 % (V/V) distillation residue is prepared by the procedure described in 7.3.1 and 7.3.2 before analysis.
Both ash-forming constituents, as defined by ISO 6245[2] and non-volatile additives present in the sample
add to the carbon residue value and are included in the total value reported.
NOTE 2 The presence of organic nitrates incorporated in certain distillate fuels will yield abnormally high
values for the carbon residue. The presence of alkyl nitrate in the fuel may be detected by ISO 13759.[3]
Mineralölerzeugnisse - Bestimmung des Koksrückstandes - Mikroverfahren (ISO 10370:2014)
Diese Internationale Norm legt ein Verfahren zur Bestimmung der Koksrückstandsmenge im Bereich von 0,10 % (m/m) bis 30,0 % (m/m) fest, die nach einer Verdampfung und Pyrolyse von Mineralölerzeugnissen unter festgelegten Bedingungen übrigbleibt.
ANMERKUNG 1 Der Wert des Koksrückstands dient als ein Annäherungswert für die Tendenz von Mineralöl-erzeugnissen unter ähnlichen Zersetzungsbedingungen kohlenstoffhaltige Ablagerungen zu bilden, und kann für die Bewertung der relativen koksbildenden Tendenzen von Erzeugnissen derselben Klasse nützlich sein. In diesem Fall sollten die Ergebnisse sorgfältig ausgewertet werden.
Für Erzeugnisse mit einer Rückstandsmenge von mehr als 0,10 % (m/m) sind die Prüfergebnisse gleich denen, die mittels Conradson-Verfahren zur Bestimmung des Koksrückstands (siehe Referenz [1]) im Bereich von 0,10 % (m/m) bis 0,25 % (m/m) erhalten werden (in Bezug auf Einzelheiten siehe Anhang A).
Diese Internationale Norm gilt auch für Mineralölerzeugnisse, die hauptsächlich aus Destillaten bestehen und die einen Koksrückstand unter 0,10 % (m/m) aufweisen können. Bei diesen wird vor der Analyse mittels dem in 7.3.1 und 7.3.2 beschriebenen Verfahren ein Destillationsrückstand von 10 % (V/V) hergestellt.
Sowohl aschebildende Komponenten nach ISO 6245 als auch in der Probe vorhandene nichtflüchtige Additive/Zusätze tragen zum Koksrückstandswert bei und werden im berichteten Gesamtwert berücksichtigt.
ANMERKUNG 2 Die Anwesenheit von organischen Nitraten in bestimmten Destillat-Kraft- und Brennstoffen führt zu ungewöhnlich hohen Koksrückstandswerten. Die Anwesenheit von Alkylnitrat kann nach ISO 13759 [2] nachgewiesen werden.
Produits pétroliers - Détermination du résidu de carbone - Méthode micro (ISO 10370:2014)
ISO 10370:2014 spécifie une méthode pour la détermination de la quantité de résidu de carbone obtenue après évaporation et pyrolyse d'un produit pétrolier dans des conditions spécifiques. La méthode s'applique aux produits dont le résidu de carbone est compris entre 0,10 % (m/m) et 30,0 % (m/m).
NOTE 1 La valeur de résidu de carbone donne une idée de la tendance de produits pétroliers à former des dépôts carbonés dans des conditions de dégradation similaires. Elle peut être utile dans l'évaluation des tendances relatives à former des matières carbonées de produits d'une même catégorie. Il est recommandé dans ce cas d'être prudent dans l'interprétation des résultats.
Pour les produits dont le résidu de carbone est supérieur à 0,10 % (m/m), les résultats sont équivalents à ceux obtenus suivant l'essai de résidu de carbone Conradson (voir ISO 6615[1]) dans l'intervalle compris entre 0,10 % (m/m) et 25,0 % (m/m) (pour de plus amples précisions, se reporter à l'Annexe A).
ISO 10370:2014 peut également s'appliquer aux produits pétroliers constitués essentiellement de distillats et dont le résidu de carbone est inférieur à 0,10 % (m/m). Sur de tels produits, un résidu de distillation de 10 % (V/V) est préparé selon le mode opératoire donné en 7.3.1 et 7.3.2 avant analyse.
Les constituants formant des cendres, tels que définis dans l'ISO 6245,[2] ainsi que les additifs non volatils présents dans l'échantillon, augmentent la valeur du résidu de carbone et leur contribution est incluse dans la valeur totale reportée.
NOTE 2 Les nitrates organiques additionnés dans certains combustibles distillés conduisent à des valeurs anormalement élevées de résidu de carbone. La présence de nitrates d'alkyle dans un combustible peut être détectée selon la méthode d'essai ISO 13759[3].
Naftni proizvodi - Določevanje koksnega ostanka - Mikro metoda (ISO 10370:2014)
Ta mednarodni standard določa metodo za določevanje deleža koksnega ostanka,
v razponu od 0,10 % (m/m) do 30,0 % (m/m), ki se ohrani po izparevanju in pirolizi naftnih proizvodov
pod predvidenimi pogoji.
OPOMBA 1: Vrednost koksnega ostanka služi kot približek nagnjenosti naftnih proizvodov k
formiranju ogljikovih nanosov pri podobnih pogojih razpada in je lahko v pomoč pri ocenjevanju relativne nagnjenosti proizvodov k formiranju ogljika znotraj istega razreda. V tem primeru naj bi se posebna pozornost posvetila razlagi rezultatov.
Pri proizvodih z ostankom več kot 0,10 % (m/m) so rezultati preskusov ekvivalentni tistim,
ki so bili pridobljeni s preskusom za določanje koksnega ostanka po Conradsonu (glejte ISO 6615[1]) v razponu od 0,10 (m/m) do 25,0 (m/m) (za podrobnosti glejte dodatek A).
Ta mednarodni standard se uporablja tudi za naftne proizvode, ki so v glavnem sestavljeni iz destilatnih materialov in pri katerih je lahko koksni ostanek pod 0,10 % (m/m). Pri takih materialih
se 10% (V/V) destilacijski ostanek pripravi pred analizo s postopkom, opisanim v točkah 7.3.1 in 7.3.2.
Sestavine v prahu, kot je določeno v standardu ISO 6245[2], in nehlapni aditivi v vzorcu
prispevajo k vrednosti koksnega ostanka in so vključeni v izmerjeni skupni vrednosti.
OPOMBA 2: Prisotnost organskih nitratov, ki so vsebovani v določenih destilatnih gorivih, poskrbi za neobičajno visoke vrednosti koksnega ostanka. Prisotnost alkil nitrata v gorivu se lahko zazna z uporabo standarda ISO 13759.[3]
General Information
Relations
Standards Content (Sample)
SLOVENSKI STANDARD
SIST EN ISO 10370:2015
01-januar-2015
1DGRPHãþD
SIST EN ISO 10370:1998
1DIWQLSURL]YRGL'RORþHYDQMHNRNVQHJDRVWDQND0LNURPHWRGD ,62
Petroleum products - Determination of carbon residue - Micro method (ISO 10370:2014)
Mineralölerzeugnisse - Bestimmung des Koksrückstandes - Mikroverfahren (ISO
10370:2014)
Produits pétroliers - Détermination du résidu de carbone - Méthode micro (ISO
10370:2014)
Ta slovenski standard je istoveten z: EN ISO 10370:2014
ICS:
75.080 Naftni proizvodi na splošno Petroleum products in
general
SIST EN ISO 10370:2015 en
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.
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SIST EN ISO 10370:2015
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SIST EN ISO 10370:2015
EUROPEAN STANDARD
EN ISO 10370
NORME EUROPÉENNE
EUROPÄISCHE NORM
November 2014
ICS 75.080 Supersedes EN ISO 10370:1995
English Version
Petroleum products - Determination of carbon residue - Micro
method (ISO 10370:2014)
Produits pétroliers - Détermination du résidu de carbone - Mineralölerzeugnisse - Bestimmung des Koksrückstandes -
Méthode micro (ISO 10370:2014) Mikroverfahren (ISO 10370:2014)
This European Standard was approved by CEN on 9 August 2014.
CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European
Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national
standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by translation
under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same
status as the official versions.
CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania,
Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United
Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION
EUROPÄISCHES KOMITEE FÜR NORMUNG
CEN-CENELEC Management Centre: Avenue Marnix 17, B-1000 Brussels
© 2014 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN ISO 10370:2014 E
worldwide for CEN national Members.
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SIST EN ISO 10370:2015
EN ISO 10370:2014 (E)
Contents Page
Foreword .3
2
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SIST EN ISO 10370:2015
EN ISO 10370:2014 (E)
Foreword
This document (EN ISO 10370:2014) has been prepared by Technical Committee ISO/TC 28 “Petroleum
products and lubricants” in collaboration with CEN/TC 19 “Gaseous and liquid fuels, lubricants and related
products of petroleum, synthetic and biological origin” the secretariat of which is held by NEN.
This European Standard shall be given the status of a national standard, either by publication of an identical
text or by endorsement, at the latest by May 2015, and conflicting national standards shall be withdrawn at the
latest by May 2015.
Attention is drawn to the possibility that some of the elements of this document may be the subject of patent
rights. CEN [and/or CENELEC] shall not be held responsible for identifying any or all such patent rights.
This document supersedes EN ISO 10370:1995.
According to the CEN-CENELEC Internal Regulations, the national standards organizations of the following
countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech
Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece,
Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal,
Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdom.
Endorsement notice
The text of ISO 10370:2014 has been approved by CEN as EN ISO 10370:2014 without any modification.
3
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SIST EN ISO 10370:2015
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SIST EN ISO 10370:2015
INTERNATIONAL ISO
STANDARD 10370
Second edition
2014-11-01
Petroleum products — Determination
of carbon residue — Micro method
Produits pétroliers — Détermination du résidu de carbone —
Méthode micro
Reference number
ISO 10370:2014(E)
©
ISO 2014
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SIST EN ISO 10370:2015
ISO 10370:2014(E)
COPYRIGHT PROTECTED DOCUMENT
© ISO 2014
All rights reserved. Unless otherwise specified, no part of this publication may be reproduced or utilized otherwise in any form
or by any means, electronic or mechanical, including photocopying, or posting on the internet or an intranet, without prior
written permission. Permission can be requested from either ISO at the address below or ISO’s member body in the country of
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Web www.iso.org
Published in Switzerland
ii © ISO 2014 – All rights reserved
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SIST EN ISO 10370:2015
ISO 10370:2014(E)
Contents Page
Foreword .iv
1 Scope . 1
2 Normative references . 1
3 Terms and definitions . 1
4 Principle . 2
5 Reagents and materials . 2
6 Apparatus . 2
7 Sample preparation . 4
7.1 General instructions . 4
7.2 Regular procedure . 5
7.3 Modified procedure . 5
8 Sample transfer . 5
9 Test procedure . 6
10 Calculation . 6
11 Expression of results . 7
12 Precision . 7
12.1 General . 7
12.2 Repeatability, r .7
12.3 Reproducibility, R .7
13 Test report . 8
Annex A (informative) Relationship of carbon residue (micro method) to carbon residue
(Conradson method) . 9
Bibliography .10
© ISO 2014 – All rights reserved iii
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SIST EN ISO 10370:2015
ISO 10370:2014(E)
Foreword
ISO (the International Organization for Standardization) is a worldwide federation of national standards
bodies (ISO member bodies). The work of preparing International Standards is normally carried out
through ISO technical committees. Each member body interested in a subject for which a technical
committee has been established has the right to be represented on that committee. International
organizations, governmental and non-governmental, in liaison with ISO, also take part in the work.
ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of
electrotechnical standardization.
The procedures used to develop this document and those intended for its further maintenance are
described in the ISO/IEC Directives, Part 1. In particular the different approval criteria needed for the
different types of ISO documents should be noted. This document was drafted in accordance with the
editorial rules of the ISO/IEC Directives, Part 2 (see www.iso.org/directives).
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. ISO shall not be held responsible for identifying any or all such patent rights. Details of
any patent rights identified during the development of the document will be in the Introduction and/or
on the ISO list of patent declarations received (see www.iso.org/patents).
Any trade name used in this document is information given for the convenience of users and does not
constitute an endorsement.
For an explanation on the meaning of ISO specific terms and expressions related to conformity
assessment, as well as information about ISO’s adherence to the WTO principles in the Technical Barriers
to Trade (TBT) see the following URL: Foreword — Supplementary information.
The committee responsible for this document is ISO/TC 28, Petroleum products and lubricants.
This second edition cancels and replaces the first edition (ISO 10370:1993). Apart from updates regarding
reference fuels and chemicals, the results of an interlaboratory study carried out by the Energy Institute
in the UK on the 10 % volume distillation residue procedure for middle distillates using 4 ml vials and
automatic distillation units, have been incorporated. It also incorporates ISO 10370:1993/Cor1:1996.
iv © ISO 2014 – All rights reserved
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SIST EN ISO 10370:2015
INTERNATIONAL STANDARD ISO 10370:2014(E)
Petroleum products — Determination of carbon residue
— Micro method
WARNING — The use of this International Standard may involve hazardous materials,
operations, and equipment. This International Standard does not purport to address all of the
safety problems associated with its use. It is the responsibility of the user of this International
Standard to establish appropriate safety and health practices and determine the applicability of
regulatory limitations prior to use.
1 Scope
This International Standard specifies a method for the determination of the amount of carbon residue,
in the range 0,10 % (m/m) to 30,0 % (m/m), left after evaporation and pyrolysis of petroleum products
under specified conditions.
NOTE 1 The carbon residue value serves as an approximation of the tendency of petroleum products to
form carbonaceous deposits under similar degradation conditions, and may be useful in the assessment of
relative carbon-forming tendencies of products within the same class. In this case, care should be taken in the
interpretation of results.
For products which yield a residue in excess of 0,10 % (m/m), the test results are equivalent to those
[1]
obtained by the Conradson carbon residue test (see ISO 6615 ) in the range of 0,10 (m/m) to 25,0 (m/m)
(for details see Annex A).
This International Standard is also applicable to petroleum products which consist essentially of
distillate material, and which may yield a carbon residue below 0,10 % (m/m). On such materials, a
10 % (V/V) distillation residue is prepared by the procedure described in 7.3.1 and 7.3.2 before analysis.
[2]
Both ash-forming constituents, as defined by ISO 6245 and non-volatile additives present in the sample
add to the carbon residue value and are included in the total value reported.
NOTE 2 The presence of organic nitrates incorporated in certain distillate fuels will yield abnormally high
[3]
values for the carbon residue. The presence of alkyl nitrate in the fuel may be detected by ISO 13759.
2 Normative references
The following documents, in whole or in part, are normatively referenced in this document and are
indispensable
...
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