Standard Specification for Low Toluene Low Dioxane (LTLD) Benzene

ABSTRACT
This specification covers the requirements for a grade of benzene known as low toluene low dioxane (LTLD) benzene. Sampled materials shall meet specified values of the following physical and chemical properties: purity; toluene content; sulfur content; thiophene content; nonaromatic hydrocarbons content; nitrogen content; acid wash color; color in Pt-Co scale; 1,4 dioxane content; anhydrous basis solidification point; water content; and total chlorides.
SCOPE
1.1 This specification covers a grade of benzene known as Low Toluene Low Dioxane (LTLD) Benzene.  
1.2 The following applies to all specified limits in this standard: for purposes of determining conformance with this standard, an observed value or a calculated value shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.  
1.3 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.  
1.4 Consult current OSHA regulations, supplier’s Safety Data Sheets, and local regulations for all materials used in this specification.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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Publication Date
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Standards Content (Sample)

This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the
Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
Designation: D7185 −19
Standard Specification for
1
Low Toluene Low Dioxane (LTLD) Benzene
This standard is issued under the fixed designation D7185; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope D5194 Test Method for Trace Chloride in Liquid Aromatic
Hydrocarbons
1.1 This specification covers a grade of benzene known as
D5386 Test Method for Color of Liquids Using Tristimulus
Low Toluene Low Dioxane (LTLD) Benzene.
Colorimetry
1.2 The following applies to all specified limits in this
D5808 Test Method for Determining Chloride in Aromatic
standard: for purposes of determining conformance with this
Hydrocarbons and Related Chemicals by Microcoulom-
standard, an observed value or a calculated value shall be
etry
rounded off “to the nearest unit” in the last right-hand digit
D6875 Test Method for Solidification Point of Industrial
used in expressing the specification limit, in accordance with
Organic Chemicals by Thermistor
the rounding-off method of Practice E29.
D7011 Test Method for Determination of Trace Thiophene
1.3 The values stated in SI units are to be regarded as the
in Refined Benzene by Gas Chromatography and Sulfur
standard. The values given in parentheses are for information
Selective Detection
only.
D7183 Test Method for Determination of Total Sulfur in
Aromatic Hydrocarbons and Related Chemicals by Ultra-
1.4 Consult current OSHA regulations, supplier’s Safety
Data Sheets, and local regulations for all materials used in this violet Fluorescence
specification. D7184 Test Method for Ultra Low Nitrogen in Aromatic
Hydrocarbons by Oxidative Combustion and Reduced
1.5 This international standard was developed in accor-
Pressure Chemiluminescence Detection
dance with internationally recognized principles on standard-
D7359 Test Method for Total Fluorine, Chlorine and Sulfur
ization established in the Decision on Principles for the
in Aromatic Hydrocarbons and Their Mixtures by Oxida-
Development of International Standards, Guides and Recom-
tive Pyrohydrolytic Combustion followed by Ion Chroma-
mendations issued by the World Trade Organization Technical
tography Detection (Combustion Ion Chromatography-
Barriers to Trade (TBT) Committee.
CIC)
2. Referenced Documents
D7360 Test Method for Analysis of Benzene by Gas Chro-
2
matography with External Calibration
2.1 ASTM Standards:
D7457 Test Method for Determining Chloride in Aromatic
D848 Test Method for Acid Wash Color of Industrial Aro-
Hydrocarbons and Related Chemicals by Microcoulom-
matic Hydrocarbons
etry
D852 Test Method for Solidification Point of Benzene
D3437 Practice for Sampling and Handling Liquid Cyclic D7504 Test Method for Trace Impurities in Monocyclic
Aromatic Hydrocarbons by Gas Chromatography and
Products
D4735 Test Method for Determination of Trace Thiophene Effective Carbon Number
in Refined Benzene by Gas Chromatography D7536 Test Method for Chlorine in Aromatics by Mono-
chromatic Wavelength Dispersive X-ray Fluorescence
Spectrometry
1
This specification is under the jurisdiction of ASTM Committee D16 on
D8005 Test Method for Color of Clear Liquids (Platinum-
Aromatic, Industrial, Specialty and Related Chemicals and is the direct responsi-
bility of Subcommittee D16.01 on Benzene, Toluene, Xylenes, Cyclohexane and
Cobalt Scale)
Their Derivatives.
E29 Practice for Using Significant Digits in Test Data to
Current edition approved Nov. 1, 2019. Published November 2019. Originally
Determine Conformance with Specifications
approved in 2006. Last previous edition approved in 2017 as D7185 – 17. DOI:
10.1520/D7185-19. E1064 Test Method for Water in Organic Liquids by Coulo-
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or
metric Karl Fischer Titration
contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
E2680 Test Method for Appearance of Clear, Transparent
Standards volume information, refer to the standard’s Document Summary page on
the ASTM website. Liquids (Visual Inspection Procedure)
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1

---------------------- Page: 1 ----------------------
D7185 − 19
2.2 Other Document:
A
If more than one method is listed for a property, the producer and user should
OSHA Regulations, 29 CFR paragraphs 1910.1000 and
3 agree on the referee test method.
1910.1200
3.2 See Section 5 for non-mandatory supplementary re-
3. Prop
...

This document is not an ASTM standard and is intended only to provide the user of an ASTM standard an indication of what changes have been made to the previous version. Because
it may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current version
of the standard as published by ASTM is to be considered the official document.
Designation: D7185 − 17 D7185 − 19
Standard Specification for
1
Low Toluene Low Dioxane (LTLD) Benzene
This standard is issued under the fixed designation D7185; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope
1.1 This specification covers a grade of benzene known as Low Toluene Low Dioxane (LTLD) Benzene.
1.2 The following applies to all specified limits in this standard: for purposes of determining conformance with this standard,
an observed value or a calculated value shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing
the specification limit, in accordance with the rounding-off method of Practice E29.
1.3 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.
1.4 Consult current OSHA regulations, supplier’s Safety Data Sheets, and local regulations for all materials used in this
specification.
1.5 This international standard was developed in accordance with internationally recognized principles on standardization
established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued
by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
2. Referenced Documents
2
2.1 ASTM Standards:
D848 Test Method for Acid Wash Color of Industrial Aromatic Hydrocarbons
D852 Test Method for Solidification Point of Benzene
3
D1685 Test Method for Traces of Thiophene in Benzene by Spectrophotometry (Withdrawn 2009)
D3437 Practice for Sampling and Handling Liquid Cyclic Products
3
D4492 Test Method for Analysis of Benzene by Gas Chromatography (Withdrawn 2018)
D4735 Test Method for Determination of Trace Thiophene in Refined Benzene by Gas Chromatography
D5194 Test Method for Trace Chloride in Liquid Aromatic Hydrocarbons
D5386 Test Method for Color of Liquids Using Tristimulus Colorimetry
D5808 Test Method for Determining Chloride in Aromatic Hydrocarbons and Related Chemicals by Microcoulometry
D6304 Test Method for Determination of Water in Petroleum Products, Lubricating Oils, and Additives by Coulometric Karl
Fischer Titration
D6875 Test Method for Solidification Point of Industrial Organic Chemicals by Thermistor
D7011 Test Method for Determination of Trace Thiophene in Refined Benzene by Gas Chromatography and Sulfur Selective
Detection
D7183 Test Method for Determination of Total Sulfur in Aromatic Hydrocarbons and Related Chemicals by Ultraviolet
Fluorescence
D7184 Test Method for Ultra Low Nitrogen in Aromatic Hydrocarbons by Oxidative Combustion and Reduced Pressure
Chemiluminescence Detection
D7359 Test Method for Total Fluorine, Chlorine and Sulfur in Aromatic Hydrocarbons and Their Mixtures by Oxidative
Pyrohydrolytic Combustion followed by Ion Chromatography Detection (Combustion Ion Chromatography-CIC)
D7360 Test Method for Analysis of Benzene by Gas Chromatography with External Calibration
D7375 Test Method for Trace Quantities of Water in Aromatic Hydrocarbons and Their Mixtures by Coulometric Karl Fischer
3
Titration (Withdrawn 2017)
1
This specification is under the jurisdiction of ASTM Committee D16 on Aromatic, Industrial, Specialty and Related Chemicals and is the direct responsibility of
Subcommittee D16.01 on Benzene, Toluene, Xylenes, Cyclohexane and Their Derivatives.
Current edition approved June 1, 2017Nov. 1, 2019. Published June 2017November 2019. Originally approved in 2006. Last previous edition approved in 20162017 as
D7185 – 16.D7185 – 17. DOI: 10.1520/D7185-17.10.1520/D7185-19.
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM Standards
volume information, refer to the standard’s Document Summary page on the ASTM website.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1

---------------------- Page: 1 ----------------------
D7185 − 19
D7457 Test Method for Determining Chloride in Aromatic Hydrocarbons and Related Chemicals by Microcoulometry
D7504 Test Method for Trace Impurities in Monocyclic Aromatic Hydrocarbons by Gas Chromatography and Effective Carbon
Number
D7536 Test Method for Chlorine in Aromatics by Monochromatic Wavelength Dispersive X-ray Fluores
...

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