EN 16319:2013+A1:2015

Fertilizers and liming materials - Determination of cadmium, chromium, lead and nickel by inductively coupled plasma-atomic emission spectrometry (ICP-AES) after aqua regia dissolution

This European Standard specifies a method for the determination of the content of cadmium, chromium, nickel and lead in fertilizers with inductively coupled plasma atomic emission spectrometry (ICP-AES) after extraction with aqua regia. Limits of quantification are dependent on the sample matrix as well as on the instrument, but can roughly be expected to be 0,3 mg/kg for Cd and 1 mg/kg for Cr, Ni and Pb.
NOTE   Due to significant interference from Cu, Fe and Mn, no valid results can be reported using this method for fertilizer matrices containing high concentrations (>/= 10 %) of these micro-nutrients.

Düngemittel und Kalkdünger - Bestimmung von Cadmium, Chrom, Blei und Nickel mit Atomemissionsspektrometrie mit induktiv gekoppeltem Plasma (ICP-AES) nach Königswasseraufschluss

Diese Europäische Norm legt ein Verfahren zur Bestimmung des Gehalts an Cadmium, Chrom, Nickel und Blei in Düngemitteln mit Atomemissionsspektrometrie mit induktiv gekoppeltem Plasma (ICP-AES) nach Königswasseraufschluss fest. Die Bestimmungsgrenzen sind sowohl von der Probenmatrix als auch vom verwendeten Gerät abhängig, werden jedoch etwa bei 0,3 mg/kg für Cd und 1 mg/kg für Cr, Ni und Pb erwartet.
ANMERKUNG   Aufgrund signifikanter Störungen durch Cu, Fe und Mn können bei Anwendung dieses Verfahrens für Düngemittelmatrizes mit hohen Konzentrationen (≥ 10 %) dieser Spurennährstoffe keine zuverlässigen Ergebnisse ausgewiesen werden.

Engrais et amendements minéraux basiques - Détermination du cadmium, chrome, plomb et nickel par spectrométrie d'émission atomique avec plasma induit par haute fréquence (ICP-AES) après digestion à l'eau régale

La présente norme européenne spécifie une méthode permettant de déterminer la teneur en cadmium, chrome, nickel et plomb dans les engrais par spectrométrie d’émission atomique avec plasma à couplage inductif (ICP-AES) après extraction à l’eau régale. Les limites de quantification dépendent de la matrice de l’échantillon ainsi que de l’instrument, mais peuvent être attendues de l’ordre de 0,3 mg/kg pour Cd et 1 mg/kg pour Cr, Ni et Pb.
NOTE Du fait d’une interférence significative du Cu, Fe et Mn, aucun résultat valide ne peut être donné en utilisant cette méthode pour les matrices engrais contenants des concentrations élevés (≥ 10%) en ces oligo-éléments.

Gnojila in sredstva za apnjenje - Določevanje kadmija, kroma, svinca in niklja z atomsko emisijsko spektrometrijo z induktivno sklopljeno plazmo (ICP/AES) po raztapljanju v zlatotopki (vključno z dopolnilom A1)

Ta evropski standard določa metodo za določevanje vsebnosti kadmija, kroma, niklja in svinca v gnojilih z atomsko emisijsko spektrometrijo z induktivno sklopljeno plazmo (ICP-AES) po ekstrakciji z zlatotopko. Meje kvantifikacije so odvisne od matrice vzorca in instrumenta, vendar za Cd običajno znašajo približno 0,3 mg/kg, za Cr, Ni in Pb pa 1 mg/kg.
OPOMBA: Zaradi znatne interference primesi Cu, Fe in Mn ni mogoče posredovati nobenih veljavnih rezultatov s to metodo za matrice gnojil, ki vsebujejo visoke koncentracije teh mikro hranil (>/= 10 %).

General Information

• Status: Published
• Publication Date: 22-Dec-2015
• ICS: 65.080 - Fertilizers
• Technical Committee: CEN/TC 260 - Fertilizers and liming materials
• Drafting Committee: CEN/TC 260/WG 7 - Chemical analysis
• Current Stage: 9093 - Decision to confirm - Review Enquiry
• Completion Date: 27-Aug-2019
• Mandate: M/418 - Standardization mandate M/335 assigned to CEN concerning the modernisation of the methods of analysis of fertilizers
• Ref Project: SIST EN 16319:2013+A1:2016 - Fertilizers and liming materials - Determination of cadmium, chromium, lead and nickel by inductively coupled plasma-atomic emission spectrometry (ICP-AES) after aqua regia dissolution

Relations

• Merged From: EN 16319:2013/FprA1:2015 - Fertilizers and liming materials - Determination of cadmium, chromium, lead and nickel by inductively coupled plasma-atomic emission spectrometry (ICP-AES) after aqua regia dissolution
• Effective Date: 21-Oct-2015
• Merged From: EN 16319:2013 - Fertilizers - Determination of trace elements - Determination of cadmium, chromium, lead and nickel by inductively coupled plasma-atomic emission spectrometry (ICP-AES) after aqua regia dissolution
• Effective Date: 21-Oct-2015

Standards Content (Sample)

2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.Düngemittel und Kalkdünger - Bestimmung von Cadmium, Chrom, Blei und Nickel mit Atomemissionsspektrometrie mit induktiv gekoppeltem Plasma (ICP-AES) nach KönigswasseraufschlussEngrais et amendements minéraux basiques - Détermination du cadmium, chrome, plomb et nickel par spectrométrie d'émission atomique avec plasma induit par haute fréquence (ICP-AES) après digestion à l'eau régaleFertilizers and liming materials - Determination of cadmium, chromium, lead and nickel by inductively coupled plasma-atomic emission spectrometry (ICP-AES) after aqua regia dissolution65.080GnojilaFertilizersICS:Ta slovenski standard je istoveten z:EN 16319:2013+A1:2015SIST EN 16319:2013+A1:2016en,fr,de01-marec-2016SIST EN 16319:2013+A1:2016SLOVENSKI
STANDARDSIST EN 16319:20131DGRPHãþD



SIST EN 16319:2013+A1:2016



EUROPEAN STANDARD NORME EUROPÉENNE EUROPÄISCHE NORM
EN 16319:2013+A1
December
t r s w ICS
x wä r z r Supersedes EN
s x u s {ã t r s uEnglish Version
Fertilizers and liming materials æ Determination of cadmiumá chromiumá lead and nickel by inductively after aqua regia dissolution Engrais et amendements minéraux basiques æ Détermination du cadmiumá chromeá plomb et nickel par spectrométrie d 5émission atomique avec plasma l 5eau régale
This European Standard was approved by CEN on
s w September
t r s u and includes Amendment
s approved by CEN on
y November
t r s wä
egulations which stipulate the conditions for giving this European Standard the status of a national standard without any alterationä Upætoædate lists and bibliographical references concerning such national standards may be obtained on application to the CENæCENELEC Management Centre or to any CEN memberä
translation under the responsibility of a CEN member into its own language and notified to the CENæCENELEC Management Centre has the same status as the official versionsä
CEN members are the national standards bodies of Austriaá Belgiumá Bulgariaá Croatiaá Cyprusá Czech Republicá Denmarká Estoniaá Finlandá Former Yugoslav Republic of Macedoniaá Franceá Germanyá Greeceá Hungaryá Icelandá Irelandá Italyá Latviaá Lithuaniaá Luxembourgá Maltaá Netherlandsá Norwayá Polandá Portugalá Romaniaá Slovakiaá Sloveniaá Spainá Swedená Switzerlandá Turkey andUnited Kingdomä
EUROPEAN COMMITTEE FOR STANDARDIZATION COMITÉ EUROPÉEN DE NORMALISATION EUROPÄISCHES KOMITEE FÜR NORMUNG
CEN-CENELEC Management Centre:
Avenue Marnix 17,
B-1000 Brussels
9
t r s w CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Membersä Refä Noä EN
s x u s {ã t r s u ªA sã t r s w ESIST EN 16319:2013+A1:2016



EN 16319:2013+A1:2015 (E) 2 Contents Page European foreword . 3 1 Scope . 4 2 Normative references . 4 3 Terms and definitions . 4 4 Principle . 4 5 Sampling and sample preparation . 4 6 Reagents . 4 7 Apparatus . 5 8 Procedure. 6 8.1 General . 6 8.2 Preparation of the test solution . 7 8.2.1 General . 7 8.2.2 Preparation . 7 8.3 Preparation of the test solution for the correction of matrix effect
...