EN 15309:2007
(Main)Characterization of waste and soil - Determination of elemental composition by X-ray fluorescence
Characterization of waste and soil - Determination of elemental composition by X-ray fluorescence
This European Standard specifies the procedure for a quantitative determination of major and trace element concentrations in homogeneous solid waste, soil and soil-like material by energy dispersive X-ray fluorescence (EDXRF) spectrometry or wavelength dispersive X-ray fluorescence (WDXRF) spectrometry using a calibration with matrix-matched standards.
This European Standard is applicable for the following elements: Na, Mg, Al, Si, P, S, Cl, K, Ca, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, As, Se, Br, Rb, Sr, Y, Zr, Nb, Mo, Ag, Cd, Sn, Sb, Te, I, Cs, Ba, Ta, W, Hg, Tl, Pb, Bi, Th and U. Concentration levels between approximately 0,000 1 % and 100 % can be determined depending on the element and the instrument used.
Charakterisierung von Abfällen und Böden - Bestimmung der elementaren Zusammensetzung durch Röntgenfluoreszenz-Analyse
Caractérisation des déchets et du sol - Détermination de la composition élémentaire par fluorescence X
La présente norme européenne décrit le mode opératoire de détermination quantitative des concentrations en éléments majeurs et en éléments traces dans les sols, les matériaux de type sol et les déchets solides homogènes à l’aide de spectromètres de fluorescence X à dispersion d’énergie (EDXRF) ou de spectromètres de fluorescence X à dispersion de longueur d’onde (WDXRF), en utilisant un étalonnage réalisé avec des matériaux de référence adaptés à la matrice.
La présente norme européenne est applicable aux éléments suivants : Na, Mg, Al, Si, P, S, Cl, K, Ca, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, As, Se, Br, Rb, Sr, Y, Zr, Nb, Mo, Ag, Cd, Sn, Sb, Te, I, Cs, Ba, Ta, W, Hg, Tl, Pb, Bi, Th et U. Il est possible de déterminer des niveaux de concentration compris entre 0,0001 % et 100 % selon l’élément dosé et l’instrument utilisé.
Karakterizacija odpadkov in zemljine - Določevanje elementne sestave z rentgensko fluorescenco
General Information
Standards Content (Sample)
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.Characterization of waste and soil - Determination of elemental composition by X-ray fluorescenceCaractérisation des déchets et du sol - Détermination de la composition élémentaire par fluorescence XCharakterisierung von Abfällen und Böden - Bestimmung der elementaren Zusammensetzung durch Röntgenfluoreszenz-AnalyseTa slovenski standard je istoveten z:EN 15309:2007SIST EN 15309:2007en13.080.10Chemical characteristics of soils13.030.10Trdni odpadkiSolid wastesICS:SLOVENSKI
STANDARDSIST EN 15309:200701-oktober-2007
EUROPEAN STANDARDNORME EUROPÉENNEEUROPÄISCHE NORMEN 15309May 2007ICS 13.030.10; 13.080.10 English VersionCharacterization of waste and soil - Determination of elementalcomposition by X-ray fluorescenceCaractérisation des déchets et du sol - Détermination de lacomposition élémentaire par fluorescence XCharakterisierung von Abfällen und Böden - Bestimmungder elementaren Zusammensetzung durchRöntgenfluoreszenz-AnalyseThis European Standard was approved by CEN on 22 March 2007.CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this EuropeanStandard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such nationalstandards may be obtained on application to the CEN Management Centre or to any CEN member.This European Standard exists in three official versions (English, French, German). A version in any other language made by translationunder the responsibility of a CEN member into its own language and notified to the CEN Management Centre has the same status as theofficial versions.CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Cyprus, Czech Republic, Denmark, Estonia, Finland,France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal,Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom.EUROPEAN COMMITTEE FOR STANDARDIZATIONCOMITÉ EUROPÉEN DE NORMALISATIONEUROPÄISCHES KOMITEE FÜR NORMUNGManagement Centre: rue de Stassart, 36
B-1050 Brussels© 2007 CENAll rights of exploitation in any form and by any means reservedworldwide for CEN national Members.Ref. No. EN 15309:2007: E
Semi-quantitative screening analysis of waste, sludge and soil samples.20 Annex B (informative)
Examples for operational steps of the sample preparation for soil and waste samples.23 Annex C (informative)
Suggested analytical lines, crystals and operating conditions.29 Annex D (informative)
List of reference materials applicable for XRF-analysis.31 Annex E (informative)
Validation.32 Bibliography.40
Annex A which provides a total element characterisation at a semi-quantitative level. The calibration is based on matrix-independent calibration curves, previously set up by the manufacturer.
X-radiation as it passes through an absorbing medium, expressed in units of cm2/g. The mass absorption coefficient is a function of the wavelength of the absorbed radiation and the atomic number of the absorbing element 3.11 polarised excitation X-ray spectrometer energy dispersive X-ray spectrometer where the excitation is performed by polarised radiation and the emitted X-ray fluorescence radiation is detected along the direction of polarisation 3.12 powder sample analyte sample submitted as a powder for direct measurement in the sample cup 3.13 precision closeness of agreement of results obtained by applying the method several times under prescribed conditions [ISO 5725-2:1994] 3.14 pressed pellet analyte sample prepared by pressing milled material into a disk 3.15 primary X-rays X-rays by which the sample is radiated 3.16 quality control sample stable sample with known contents, e.g. certified reference material (CRM) used to monitor instrument and calibration performance
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