iTeh StandardsiTeh Standards
EURUSD
Your shopping cart is empty.
CEN

EN 16166:2021

(Main)

Soil, treated biowaste and sludge - Determination of adsorbed organically bound halogens (AOX)

Soil, treated biowaste and sludge - Determination of adsorbed organically bound halogens (AOX)

This document specifies an operationally defined method for the direct determination of organically bound halogens (chlorine, bromine and iodine) adsorbed and occluded to the sample matrix. AOX being a methodologically defined parameter, it is essential that the procedure is applied without any modification.
This document is intended for analysis of sludge, treated biowaste or soil in concentrations ranging from 5 mg/kg dry matter. The upper limit and exact concentration range covered depend on the instrumentation used for determination.
NOTE This method can also be applied to other environmental solid matrices, provided the user has verified the applicability.

Boden, behandelter Bioabfall und Schlamm - Bestimmung von adsorbierten organisch gebundenen Halogenen (AOX)

Dieses Dokument legt ein praktisches Konventionsverfahren zur direkten Bestimmung von adsorbierten organisch gebundenen Halogenen (Chlor, Brom und Iod) in verschiedenen Probenmatrices fest. Da es sich bei AOX um einen methodisch definierten Parameter handelt, ist es wichtig, dass das Verfahren unverändert angewendet wird.
Dieses Dokument ist für die Untersuchung von Schlamm, behandeltem Bioabfall oder Boden in Konzentrationen im Bereich ab 5 mg/kg Trockenmasse vorgesehen. Der obere Grenzwert und der tatsächlich erfasste Konzentrationsbereich hängen von dem zur Bestimmung verwendeten Gerät ab.
ANMERKUNG   Dieses Verfahren kann auch auf weitere feste Umweltmatrices angewendet werden, sofern der Anwender die Anwendbarkeit bestätigt hat.

Boues, biodéchets traités et sols - Détermination des composés organiques halogénés adsorbés (AOX)

Le présent document spécifie une méthode opérationnelle définie pour la détermination directe des composés organiques halogénés (chlore, brome et iode) adsorbés et occlus dans la matrice d’échantillon. Comme les AOX constituent un paramètre défini sur le plan méthodologique, il est essentiel que le mode opératoire soit appliqué sans aucune modification.
Le présent document est destiné à l’analyse des boues, des biodéchets traités ou des sols de concentrations à partir de 5 mg/kg de matière sèche. La limite supérieure et la gamme exacte de concentrations dépendent de l’appareillage utilisé pour la détermination.
NOTE Cette méthode peut également être appliquée à d’autres matrices solides environnementales, sous réserve que l’utilisateur ait vérifié son applicabilité.

Tla, obdelani biološki odpadki in blato - Določevanje adsorbiranih organsko vezanih halogenov (AOX)

Ta evropski standard opisuje empirično metodo za neposredno določevanje organsko vezanega klora, broma in joda (ne pa fluora), adsorbiranih in vezanih v matrico vzorca. V določevanje so vključeni nehlapni organsko vezani halogeni, sposobni adsorbcije na aktiviran ogljik v vodni fazi vzorca pred sušenjem ali adsorbirani na površino vzorca.
Namen tega evropskega standarda je analiza blata, obdelanih bioloških odpadkov ali tal v koncentracijah od 5 mg/kg do približno 6 g/kg suhe snovi. Natančno območje koncentracije je odvisno od instrumentov, uporabljenih za določevanje.

General Information

Status
Published
Publication Date
21-Dec-2021
Withdrawal Date
29-Jun-2022
ICS
13.030.01 - Wastes in general
13.080.10 - Chemical characteristics of soils
Technical Committee
CEN/TC 444 - Environmental characterization
Drafting Committee
CEN/TC 444/WG 3 - Inorganic analysis
Current Stage
6060 - Definitive text made available (DAV) - Publishing
Start Date
22-Dec-2021
Due Date
18-Jan-2022
Completion Date
22-Dec-2021
Directive
86/278/EEC - Protection of the environment, and in particular of the soil, when sewage sludge is used in agriculture
Mandate
M/330 - Mandate given to CEN for the development of horizontal standards in the fields of sludge, biowaste and soil.
Ref Project
SIST EN 16166:2022 - Soil, treated biowaste and sludge - Determination of adsorbed organically bound halogens (AOX)

Relations

Replaces
EN 16166:2012 - Sludge, treated biowaste and soil - Determination of adsorbable organically bound halogens (AOX)
Effective Date
29-Dec-2021

Buy Standard

EN 16166:2022EN 16166:2022
PreviousNext
Standard
EN 16166:2022
English language
16 pages
sale 10% off
Preview
sale 10% off
Preview
e-Library read for
1 day

Standards Content (Sample)

SLOVENSKI STANDARD
SIST EN 16166:2022
01-marec-2022
Nadomešča:
SIST EN 16166:2013
Tla, obdelani biološki odpadki in blato - Določevanje adsorbiranih organsko
vezanih halogenov (AOX)
Soil, treated biowaste and sludge - Determination of adsorbed organically bound
halogens (AOX)
Boden, behandelter Bioabfall und Schlamm - Bestimmung von adsorbierten organisch
gebundenen Halogenen (AOX)
Boues, biodéchets traités, sols et sédiments - Détermination des composés organiques
halogénés adsorbables (AOX)
Ta slovenski standard je istoveten z: EN 16166:2021
ICS:
13.030.20 Tekoči odpadki. Blato Liquid wastes. Sludge
13.080.10 Kemijske značilnosti tal Chemical characteristics of
soils
SIST EN 16166:2022 en,fr,de
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

---------------------- Page: 1 ----------------------
SIST EN 16166:2022

---------------------- Page: 2 ----------------------
SIST EN 16166:2022


EN 16166
EUROPEAN STANDARD

NORME EUROPÉENNE

December 2021
EUROPÄISCHE NORM
ICS 13.030.01; 13.080.10 Supersedes EN 16166:2012
English Version

Soil, treated biowaste and sludge - Determination of
adsorbed organically bound halogens (AOX)
Boues, biodéchets traités, sols et sédiments - Boden, behandelter Bioabfall und Schlamm -
Détermination des composés organiques halogénés Bestimmung von adsorbierten organisch gebundenen
adsorbables (AOX) Halogenen (AOX)
This European Standard was approved by CEN on 22 November 2021.

CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this
European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references
concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN
member.

This European Standard exists in three official versions (English, French, German). A version in any other language made by
translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management
Centre has the same status as the official versions.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway,
Poland, Portugal, Republic of North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and
United Kingdom.





EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION

EUROPÄISCHES KOMITEE FÜR NORMUNG

CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2021 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN 16166:2021 E
worldwide for CEN national Members.

---------------------- Page: 3 ----------------------
SIST EN 16166:2022
EN 16166:2021 (E)
Contents Page
European foreword . 3
Introduction . 4
1 Scope . 5
2 Normative references . 5
3 Terms and definitions . 5
4 Principle . 5
5 Interferences . 5
6 Reagents . 6
7 Apparatus . 7
7.1 Apparatus for combustion and detection . 7
7.2 Equipment for adsorption . 7
7.3 Equipment for sample preparation . 7
8 Sample storage and pretreatment .
...

Questions, Comments and Discussion

Ask us and Technical Secretary will try to provide an answer. You can facilitate discussion about the standard in here.

This May Also Interest You

CEN
EN 15936:2022(Main)
Soil, waste, treated biowaste and sludge - Determination of total organic carbon (TOC) by dry combustion
SIST EN 15936:2022

This document specifies two methods for the determination of total organic carbon (TOC) in sludge, treated biowaste, soil and waste samples containing more than 0,1 % carbon in relation to the dry mass (dm).
NOTE   This method can also be applied to other environmental solid matrices, provided the user has verified the applicability.

  • Standard
    23 pages
    English language
    sale 10% off
    e-Library read for
    1 day
CEN
EN 17503:2022(Main)
Soil, sludge, treated biowaste and waste - Determination of polycyclic aromatic hydrocarbons (PAH) by gas chromatography (GC) and high performance liquid chromatography (HPLC)
SIST EN 17503:2023

This document specifies different methods for quantitative determination of 16 polycyclic aromatic hydrocarbons (PAH) (see Table 2) in soil, sludge, treated biowaste, and waste, using GC-MS or HPLC-UV-DAD/FLD covering a wide range of PAH contamination levels (see Table 2).
NOTE   The method can be applied to sediments provided that validity is demonstrated by the user.
When using fluorescence detection, acenaphthylene cannot be measured.
[Table 2 -Target analytes of this document]
The limit of detection depends on the determinants, the equipment used, the quality of chemicals used for the extraction of the sample and the clean-up of the extract.
Under the conditions specified in this document, the lower limit of application from 10 μg/kg (expressed as dry matter) for soils, sludge and biowaste to 100 μg/kg (expressed as dry matter) for solid waste can be achieved. For some specific samples (e.g. bitumen) the limit of 100 μg/kg cannot be reached.
Sludge, waste and treated biowaste can differ in properties as well as in the expected contamination levels of PAH and presence of interfering substances. These differences make it impossible to describe one general procedure. This document contains decision tables based on the properties of the sample and the extraction and clean-up procedure to be used.
The method can be applied to the analysis of other PAH not specified in the scope, provided suitability is proven by proper in-house validation experiments.
Sampling is not part of this standard. In dependence of the materials, the following standards need to be considered, e.g. EN 14899, ISO 5667-12 and EN ISO 5667-13.

  • Standard
    53 pages
    English language
    sale 10% off
    e-Library read for
    1 day
CEN
EN 17322:2020(Main)
Environmental Solid Matrices - Determination of polychlorinated biphenyls (PCB) by gas chromatography - mass selective detection (GC-MS) or electron-capture detection (GC-ECD)
SIST EN 17322:2020

This document specifies methods for quantitative determination of seven selected polychlorinated biphenyls (PCB28, PCB52, PCB101, PCB118, PCB138, PCB153 and PCB180) in soil, sludge, sediment, treated biowaste, and waste using GC-MS and GC-ECD (see Table 2).
The limit of detection depends on the determinants, the equipment used, the quality of chemicals used for the extraction of the sample and the clean-up of the extract.
Under the conditions specified in this document, lower limit of application from 1 μg/kg (expressed as dry matter) for soils, sludge and biowaste to 10 μg/kg (expressed as dry matter) for solid waste can be achieved. For some specific samples the limit of 10 μg/kg cannot be reached.
Sludge, waste and treated biowaste may differ in properties, as well as in the expected contamination levels of PCB and presence of interfering substances. These differences make it impossible to describe one general procedure. This document contains decision tables based on the properties of the sample and the extraction and clean-up procedure to be used.
NOTE   The analysis of PCB in insulating liquids, petroleum products, used oils and aqueous samples is referred to in EN 61619, EN 12766-1 and EN ISO 6468 respectively.
The method can be applied to the analysis of other PCB congeners not specified in the scope, provided suitability is proven by proper in-house validation experiments.

  • Standard
    45 pages
    English language
    sale 10% off
    e-Library read for
    1 day
  • Standard
    45 pages
    English language
    sale 10% off
    e-Library read for
    1 day
CEN
EN 16190:2018(Main)
Soil, treated biowaste and sludge - Determination of dioxins and furans and dioxin-like polychlorinated biphenyls by gas chromatography with high resolution mass selective detection (HR GC-MS)
SIST EN 16190:2019

This draft European Standard specifies a method for quantitative determination of 17 2,3,7,8-chlorine substituted dibenzo-p-dioxins and dibenzofurans and dioxin-like polychlorinated biphenyls in sludge, treated biowaste and soil using liquid column chromatographic clean-up methods and GC/HRMS.
The analytes to be determined with this European Standard are listed in Table 1.
(...)
The limit of detection depends on the kind of sample, the congener, the equipment used and the quality of chemicals used for extraction and clean-up. Under the conditions specified in this European Standard, limits of detection better than 1 ng/kg (expressed as dry matter) can be achieved.
This method is "performance based". It is allowed to modify the method if all performance criteria given in this method are met.
NOTE   In principle this method can also be applied for sediments, mineral wastes and for vegetation. It is the responsibility of the user of this European Standard to validate the application for these matrices. For measurement in complex matrices like fly ashes adsorbed on vegetation it can be necessary to further improve the clean-up. This can also apply to sediments and mineral wastes.

  • Standard
    46 pages
    English language
    sale 10% off
    e-Library read for
    1 day
CEN
EN 16171:2016(Main)
Sludge, treated biowaste and soil - Determination of elements using inductively coupled plasma mass spectrometry (ICP-MS)
SIST EN 16171:2017

This European Standard specifies a method for the determination of the following elements in aqua regia or nitric acid digests of sludge, treated biowaste and soil:
Aluminium (Al), antimony (Sb), arsenic (As), barium (Ba), beryllium (Be), bismuth (Bi), boron (B), cadmium (Cd), calcium (Ca), cerium (Ce), cesium (Cs), chromium (Cr), cobalt (Co), copper (Cu), dysprosium (Dy), erbium (Er), europium (Eu), gadolinium (Gd), gallium (Ga), germanium (Ge), gold (Au), hafnium (Hf), holmium (Ho), indium (In), iridium (Ir), iron (Fe), lanthanum (La), lead (Pb), lithium (Li), lutetium (Lu), magnesium (Mg), manganese (Mn), mercury (Hg), molybdenum (Mo), neodymium (Nd), nickel (Ni), palladium (Pd), phosphorus (P), platinum (Pt), potassium (K), praseodymium (Pr), rhenium (Re), rhodium (Rh), rubidium (Rb), ruthenium (Ru), samarium (Sm), scandium (Sc), selenium (Se), silicon (Si), silver (Ag), sodium (Na), strontium (Sr), sulfur (S), tellurium (Te), terbium (Tb), thallium (Tl), thorium (Th), thulium (Tm), tin (Sn), titanium (Ti), tungsten (W), uranium (U), vanadium (V), ytterbium(Yb), yttrium (Y), zinc (Zn), and zirconium (Zr).
The working range depends on the matrix and the interferences encountered.
The method detection limit of the method is between 0,1 mg/kg dry matter and 2,0 mg/kg dry matter for most elements. The limit of detection will be higher in cases where the determination is likely to be interfered (see Clause 4) or in case of memory effects (see e.g. 8.3 of EN ISO 17294-1:2006).
The method has been validated for the elements given in Table A.1 (sludge), Table A.2 (compost) and Table A.3 (soil). The method is applicable for the other elements listed above, provided the user has verified the applicability.

  • Standard
    25 pages
    English language
    sale 10% off
    e-Library read for
    1 day
CEN
EN 16175-2:2016(Main)
Sludge, treated biowaste and soil - Determination of mercury - Part 2: Cold-vapour atomic fluorescence spectrometry (CV-AFS)
SIST EN 16175-2:2017

This European Standard specifies a method for the determination of mercury in aqua regia or nitric acid digests of sludge, treated biowaste and soil, obtained according to EN 16173 or EN 16174 using cold-vapour atomic fluorescence spectrometry (CV-AFS). The lower working range limit is 0,003 mg/kg (dry matter basis).

  • Standard
    12 pages
    English language
    sale 10% off
    e-Library read for
    1 day
CEN
EN 16175-1:2016(Main)
Sludge, treated biowaste and soil - Determination of mercury - Part 1: Cold-vapour atomic absorption spectrometry (CV-AAS)
SIST EN 16175-1:2017

This European Standard specifies a method for the determination of mercury in aqua regia or nitric acid digests of sludge, treated biowaste and soil, obtained according to EN 16173 or EN 16174 using cold-vapour atomic absorption spectrometry (CV-AAS). The lower working range limit is 0,03 mg/kg (dry matter basis).

  • Standard
    13 pages
    English language
    sale 10% off
    e-Library read for
    1 day
CEN
EN 16169:2012(Main)
Sludge, treated biowaste and soil - Determination of Kjeldahl nitrogen
SIST EN 16169:2013

This European Standard specifies the determination of Kjeldahl nitrogen according to the Kjeldahl procedure in sludge, treated biowaste and soil.
Nitrate and nitrite are not included.
Compounds with nitrogen bound in N-N, N-O linkages and some heterocycles (pyridines) are only partially determined.
The limit of detection (LOD) is usually 0,03 % nitrogen, and the limit of quantification (LOQ) is 0,1 % nitrogen (using 0,25 mol/l sulfuric acid for titration).

  • Standard
    12 pages
    English language
    sale 10% off
    e-Library read for
    1 day
CEN
EN 16168:2012(Main)
Sludge, treated biowaste and soil - Determination of total nitrogen using dry combustion method
SIST EN 16168:2013

This European Standard specifies the determination of total nitrogen (organic and inorganic) according to the procedure of Dumas in sludge, treated biowaste and soil. A typical limit of detection is 0,02 % nitrogen, and a typical limit of quantification is 0,08 % nitrogen.

  • Standard
    11 pages
    English language
    sale 10% off
    e-Library read for
    1 day
CEN
EN 16173:2012(Main)
Sludge, treated biowaste and soil - Digestion of nitric acid soluble fractions of elements
SIST EN 16173:2013

This European Standard specifies a method for microwave digestion of sludge, treated biowaste and soil using nitric acid.
This method is applicable for microwave-assisted nitric acid digestion of sludge, treated biowaste and soils for the following elements:
Aluminium (Al), antimony (Sb), arsenic (As), barium (Ba), beryllium (Be), bismuth (Bi), boron (B), cadmium (Cd), calcium (Ca), cerium (Ce), cesium (Cs), chromium (Cr), cobalt (Co), copper (Cu), dysprosium (Dy), erbium (Er), europium (Eu), gadolinium (Gd), gallium (Ga), germanium (Ge), gold (Au), hafnium (Hf), holmium (Ho), indium (In), iridium (Ir), iron (Fe), lanthanum (La), lead (Pb), lithium (Li), lutetium (Lu), magnesium (Mg), manganese (Mn), mercury (Hg), molybdenum (Mo), neodymium (Nd), nickel (Ni), palladium (Pd), phosphorus (P), platinum (Pt), potassium (K), praseodymium (Pr), rubidium (Rb), rhenium (Re), rhodium (Rh), ruthenium (Ru), samarium (Sm), scandium (Sc), selenium (Se), silicon (Si), sodium (Na), strontium (Sr), sulphur (S), tellurium (Te), terbium (Tb), thallium (Tl), thorium (Th), thulium (Tm), tin (Sn), titanium (Ti), tungsten (W), uranium (U), vanadium (V), ytterbium (Yb), yttrium (Y), zinc (Zn), and zirconium (Zr).
This European Standard may also be applicable for the digestion of other elements.
Digestion with nitric acid will not necessarily accomplish total decomposition of the sample. The extracted analyte concentrations may not necessarily reflect the total content in the sample.

  • Standard
    11 pages
    English language
    sale 10% off
    e-Library read for
    1 day