EN 17306:2023
(Main)Liquid petroleum products - Determination of distillation characteristics at atmospheric pressure - Micro-distillation
Liquid petroleum products - Determination of distillation characteristics at atmospheric pressure - Micro-distillation
This document specifies a laboratory method for the determination of the distillation characteristics of light and middle distillates derived from petroleum and related products of synthetic or biological origin with initial boiling points above 20 °C and end-points below approximately 400 °C, at atmospheric pressure utilizing an automatic micro distillation apparatus.
This test method is applicable to such products as light and middle distillates, automotive spark-ignition engine fuels, automotive spark-ignition engine fuels containing up to 20 % (V/V) ethanol, aviation gasolines, aviation turbine fuels, (paraffinic) diesel fuels, FAME (B100), diesel blends up to 30 % (V/V) fatty acid methyl esters (FAME), special petroleum spirits, naphtha’s, white spirits, kerosene’s, burner fuels, and marine fuels.
The test method is also applicable to hydrocarbons with a narrow boiling range, like organic solvents or oxygenated compounds.
The test method is designed for the analysis of distillate products; it is not applicable to products containing appreciable quantities of residual material.
WARNING - The use of this document can involve hazardous materials, operations and equipment. This document does not purport to address all of the safety problems associated with its use. It is the responsibility of user of this document to take appropriate measures to ensure the safety and health of personnel prior to application of the document, and to fulfil statutory and regulatory requirements for this purpose.
NOTE For the purpose of this document, the expression "% (V/V)" is used to represent the volume fraction.
Flüssige Mineralölerzeugnisse - Bestimmung der Destillationseigenschaften bei atmosphärischem Druck - Mikrodestillation
Dieses Dokument legt ein Laboratoriumsverfahren zur Bestimmung der Destillationseigenschaften von Leicht- und Mitteldestillaten aus Mineralöl und verwandten Produkten mit synthetischem oder biologischem Ursprung, die bei atmosphärischem Druck einen Destillationsbeginn oberhalb von 20 °C und Destillationsendpunkte unterhalb von etwa 400 °C haben, unter Verwendung eines automatischen Mikrodestillationsgeräts fest.
Dieses Prüfverfahren ist anwendbar auf Produkte wie Leicht- und Mitteldestillate, Ottokraftstoffe, Ottokraftstoffe mit einem Ethanolgehalt von bis zu 20 % (V/V), Flugbenzine, Flugturbinenkraftstoffe, (paraffinische) Dieselkraftstoffe, FAME (B100), Dieselkraftstoffmischungen mit bis zu 30 % (V/V) Fettsäuremethylester (FAME), spezielle Petroleumbenzine, Naphthas (Rohbenzine), Testbenzine, Kerosin, Brennstoffe für Brenner und Schifffahrtsbrennstoffe.
Das Prüfverfahren ist auch auf Kohlenwasserstoffe mit einem engen Siedebereich anwendbar, wie z. B. organische Lösemittel oder sauerstoffhaltige Verbindungen.
Das Prüfverfahren ist für die Analyse von Destillatprodukten ausgelegt; es ist nicht auf Produkte anwendbar, die beträchtliche Mengen an Rückstandsmaterial enthalten.
WARNUNG — Die Anwendung dieses Dokuments kann die Anwendung gefährlicher Stoffe, Arbeitsgänge und Geräte mit sich bringen. Dieses Dokument beansprucht nicht, alle damit verbundenen Sicherheitsprobleme zu behandeln. Es liegt in der Verantwortung des Anwenders dieses Dokuments, vor dessen Anwendung geeignete Maßnahmen für die Sicherheit und den Gesundheitsschutz des Personals zu ergreifen, und dafür Sorge zu tragen, dass behördliche und gesetzliche Maßnahmen eingehalten werden.
ANMERKUNG Für den Zweck dieses Dokuments wird der Ausdruck „% (V/V)“ verwendet, um den Volumenanteil darzustellen.
Produits pétroliers liquides - Détermination des caractéristiques de distillation à la pression atmosphérique - Microdistillation
Le présent document spécifie une méthode de laboratoire pour la détermination des caractéristiques de distillation des distillats légers et moyens dérivés du pétrole et des produits connexes d'origine synthétique ou biologique dont le point d’ébullition initial est supérieur à 20 °C et le point final inférieur à environ 400 °C, à la pression atmosphérique, à l'aide d'un appareil de microdistillation automatique.
Cette méthode d'essai est applicable à des produits tels que les distillats légers et moyens, les carburants pour moteurs à allumage commandé, les carburants pour moteurs à allumage commandé contenant jusqu'à 20 % (V/V) d'éthanol, les essences aviation, les carburants pour turbines aviation, les carburants diesel (paraffiniques), les mélanges gazoles contenant jusqu'à 30 % (V/V) d'esters méthyliques d'acides gras (EMAG), les EMAG (B100), les essences spéciales, le naphta, le white spirit, le kérosène, les combustibles pour brûleurs et les carburants marins.
Cette méthode d'essai s'applique également aux hydrocarbures présentant un intervalle de distillation étroit, tels que les solvants organiques ou les composés oxygénés.
La méthode d'essai est conçue pour l'analyse des produits de distillation ; elle ne s'applique pas aux produits qui contiennent des quantités appréciables de matières résiduelles.
AVERTISSEMENT — L'utilisation du présent document peut impliquer la mise en œuvre de produits, d'opérations et d'équipements à caractère dangereux. La présente norme ne prétend pas aborder tous les problèmes de sécurité associés à son utilisation. Il incombe aux utilisateurs du présent document de prendre les mesures appropriées pour assurer la sécurité et préserver la santé du personnel avant son application, et de satisfaire aux exigences légales et réglementaires applicables à cet effet.
NOTE: Pour les besoins de ce document, l'expression "% (V/V)" est utilisée pour représenter la fraction volumique.
Tekoči naftni proizvodi - Določanje destilacijskih značilnosti pri atmosferskem tlaku - Mikrodestilacija
Ta dokument določa laboratorijsko metodo za določanje destilacijskih značilnosti lahkih in srednjih destilatov iz naftnih ter sorodnih proizvodov iz naravnih ali sintetičnih virov, ki imajo začetno vrelišče nad 20 °C in končno točko pod približno 400 °C, pri atmosferskem tlaku z avtomatsko aparaturo za mikrodestilacijo.
Ta preskusna metoda se uporablja za proizvode, kot so lahki in srednji destilati, gorivo za motorna vozila z motorjem z vžigom na iskro, gorivo za motorna vozila z motorjem z vžigom na iskro, ki vsebuje do 20 % etanola, letalski bencin, gorivo za letalske turbine, (parafinsko) dizelsko gorivo, metilni estri maščobnih kislin (FAME) – B100, mešanice dizla, ki vsebujejo do 30 % metilnih estrov maščobnih kislin, specialni bencin, nafta, beli špirit, kerozin, kurilno olje in ladijsko gorivo.
Uporablja se tudi za ogljikovodike z majhnim območjem vrelišča, kot so organska topila ali kisikove spojine.
Ta preskusna metoda je zasnovana za analizo destilacijskih proizvodov in se ne uporablja za proizvode, ki vsebujejo znatne količine ostankov materiala.
General Information
Relations
Standards Content (Sample)
SLOVENSKI STANDARD
01-januar-2024
Nadomešča:
SIST EN 17306:2019
Tekoči naftni proizvodi - Določanje destilacijskih značilnosti pri atmosferskem
tlaku - Mikrodestilacija
Liquid petroleum products - Determination of distillation characteristics at atmospheric
pressure - Micro-distillation
Flüssige Mineralölerzeugnisse - Bestimmung der Destillationseigenschaften bei
atmosphärischem Druck - Mikrodestillation
Produits pétroliers liquides - Détermination des caractéristiques de distillation à la
pression atmosphérique - Micro-distillation
Ta slovenski standard je istoveten z: EN 17306:2023
ICS:
75.160.20 Tekoča goriva Liquid fuels
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.
EN 17306
EUROPEAN STANDARD
NORME EUROPÉENNE
November 2023
EUROPÄISCHE NORM
ICS 75.160.20 Supersedes EN 17306:2019
English Version
Liquid petroleum products - Determination of distillation
characteristics at atmospheric pressure - Micro-distillation
Produits pétroliers liquides - Détermination des Flüssige Mineralölerzeugnisse - Bestimmung der
caractéristiques de distillation à la pression Destillationseigenschaften bei atmosphärischem Druck
atmosphérique - Microdistillation - Mikrodestillation
This European Standard was approved by CEN on 18 September 2023.
CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this
European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references
concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN
member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by
translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management
Centre has the same status as the official versions.
CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway,
Poland, Portugal, Republic of North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Türkiye and
United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION
EUROPÄISCHES KOMITEE FÜR NORMUNG
CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2023 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN 17306:2023 E
worldwide for CEN national Members.
Contents Page
European foreword . 4
Introduction . 5
1 Scope . 6
2 Normative references . 6
3 Terms and definitions. 6
4 Principle . 8
5 Reagents and materials . 8
6 Apparatus . 9
6.1 Micro distillation unit . 9
6.2 Barometer for calibration . 9
6.3 Sampling device . 9
6.4 Waste beaker . 9
7 Sampling . 9
8 Apparatus preparation . 10
9 Calibration, verification and quality control . 10
9.1 General . 10
9.2 Calibration . 10
9.2.1 General . 10
9.2.2 Temperature measurement system . 10
9.2.3 Ambient pressure measuring device . 11
9.2.4 Differential pressure measuring device . 11
9.3 Instrument verification . 11
10 Procedure . 11
11 Calculation . 12
12 Expression of results . 13
13 Precision . 13
13.1 General . 13
13.2 Repeatability, r . 13
13.3 Reproducibility, R . 15
13.4 Bias . 16
13.5 Relative bias . 16
13.6 Repeatability and reproducibility for FAME. 17
13.7 Relative bias for FAME . 17
14 Test report . 18
Annex A (normative) Micro distillation apparatus . 19
A.1 Detailed description of apparatus . 19
Annex B (normative) Precision of the volume percent evaporated or recovered at a prescribed
temperature . 23
Annex C (informative) Typical samples. 24
Bibliography . 25
European foreword
This document (EN 17306:2023) has been prepared by Technical Committee CEN/TC 19
“Gaseous and liquid fuels, lubricants and related products of petroleum, synthetic and
biological origin”, the secretariat of which is held by NEN.
This European Standard shall be given the status of a national standard, either by publication of
an identical text or by endorsement, at the latest by May 2024, and conflicting national standards
shall be withdrawn at the latest by May 2024.
Attention is drawn to the possibility that some of the elements of this document may be the
subject of patent rights. CEN shall not be held responsible for identifying any or all such patent
rights.
This document supersedes EN 17306:2019.
In comparison with the previous edition, a bias correction explanation has been introduced,
which has no effect on the method precision.
Any feedback and questions on this document should be directed to the users’ national standards
body. A complete listing of these bodies can be found on the CEN website.
According to the CEN-CENELEC Internal Regulations, the national standards organisations of the
following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria,
Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary,
Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland,
Portugal, Republic of North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden,
Switzerland, Türkiye and the United Kingdom.
Introduction
The distillation (volatility) characteristics of hydrocarbons and other liquids have an important
effect on their safety and performance, especially in the case of fuels and solvents. The boiling
range gives information on the composition, the properties, and the behaviour of the fuel during
storage and use. Volatility is the major determinant of the tendency of a hydrocarbon mixture to
produce potentially explosive vapours.
The distillation characteristics are critically important for both automotive and aviation
gasolines, affecting starting, warm-up and tendency to vapour lock at high operating temperature
or at high altitude, or both. The presence of high boiling point components in these and other fuels
can significantly affect the degree of formation of solid combustion deposits.
Distillation limits are often included in petroleum product specifications, in commercial contract
agreements, process refinery/control applications, and for compliance to regulatory rules.
This test method can be applied to contaminated products or hydrocarbon mixtures. This is
valuable for fast product quality screening, refining process monitoring, fuel adulteration control,
or other purposes including use as a portable apparatus for field testing.
This document is at of the time of publication technically equivalent to ASTM D7345 [1], on which
it is based.
This test method uses an automatic micro distillation apparatus, provides fast results using small
sample volume, and eliminates much of the operator time and subjectivity in comparison to
EN ISO 3405 or ASTM D1160 [2].
1 Scope
This document specifies a laboratory method for the determination of the distillation
characteristics of light and middle distillates derived from petroleum and related products of
synthetic or biological origin with initial boiling points above 20 °C and end-points below
approximately 400 °C, at atmospheric pressure utilizing an automatic micro distillation
apparatus.
This test method is applicable to such products as light and middle distillates, automotive spark-
ignition engine fuels, automotive spark-ignition engine fuels containing up to 20 % (V/V) ethanol,
aviation gasolines, aviation turbine fuels, (paraffinic) diesel fuels, FAME (B100), diesel blends up
to 30 % (V/V) fatty acid methyl esters (FAME), special petroleum spirits, naphtha’s, white spirits,
kerosene’s, burner fuels, and marine fuels.
The test method is also applicable to hydrocarbons with a narrow boiling range, like organic
solvents or oxygenated compounds.
The test method is designed for the analysis of distillate products; it is not applicable to products
containing appreciable quantities of residual material.
WARNING — The use of this document can involve hazardous materials, operations and
equipment. This document does not purport to address all of the safety problems
associated with its use. It is the responsibility of user of this document to take appropriate
measures to ensure the safety and health of personnel prior to application of the
document, and to fulfil statutory and regulatory requirements for this purpose.
NOTE For the purpose of this document, the expression “% (V/V)” is used to represent the volume
fraction.
2 Normative references
The following documents are referred to in the text in such a way that some or all of their content
constitutes requirements of this document. For dated references, only the edition cited applies.
For undated references, the latest edition of the referenced document (including any
amendments) applies.
EN ISO 3170, Petroleum liquids — Man
...
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