EN 17306:2019
(Main)Liquid petroleum products - Determination of distillation characteristics at atmospheric pressure - Micro-distillation
Liquid petroleum products - Determination of distillation characteristics at atmospheric pressure - Micro-distillation
This document specifies a laboratory method for the determination of the distillation characteristics of light and middle distillates derived from petroleum and related products of synthetic or biological origin with initial boiling points above 20 °C and end-points below approximately 400 °C, at atmospheric pressure utilizing an automatic micro distillation apparatus.
This test method is applicable to such products as; light and middle distillates, automotive spark-ignition engine fuels, automotive spark-ignition engine fuels containing up to 20 % ethanol, aviation gasolines, aviation turbine fuels, (paraffinic) diesel fuels, FAME (B100), diesel blends up to 30 % fatty acid methyl esters (FAME), special petroleum spirits, naphtha’s, white spirits, kerosene’s, burner fuels, and marine fuels.
The test method is also applicable to hydrocarbons with a narrow boiling range, like organic solvents or oxygenated compounds.
The test method is designed for the analysis of distillate products; it is not applicable to products containing appreciable quantities of residual material.
Flüssige Mineralölerzeugnisse - Bestimmung der Destillationseigenschaften bei atmosphärischem Druck - Mikrodestillation
Dieses Dokument legt ein Laborverfahren zur Bestimmung der Destillationseigenschaften von leichten und mittleren Destillaten aus Erdöl und verwandten Produkten mit biologischem oder synthetischem Ursprung, die bei atmosphärischem Druck einen Destillationsbeginn oberhalb von 20 °C und Destillationsendpunkte unterhalb von etwa 400 °C haben, unter Verwendung eines automatischen Mikrodestillationsgerätes fest.
Dieses Prüfverfahren ist anwendbar auf Produkte wie Leicht- und Mitteldestillate, Ottokraftstoffe, Ottokraftstoffe mit einem Ethanolgehalt von bis zu 20 % (V/V), Flugbenzine, Flugturbinenkraftstoffe, (paraffinische) Dieselkraftstoffe, FAME (B100), Dieselkraftstoffmischungen mit bis zu 30 % (V/V) Fettsäure-methylester (FAME), spezielle Petroleumbenzine, Naphthas (Rohbenzine), Testbenzine, Kerosin, Brennstoffe für Brenner und Schifffahrtsbrennstoffe.
Das Prüfverfahren ist auch auf Kohlenwasserstoffe mit einem engen Siedebereich anwendbar, wie z. B. organische Lösemittel oder sauerstoffhaltige Verbindungen.
Das Prüfverfahren ist für die Analyse von Destillaten ausgelegt; es ist nicht auf Produkte anwendbar, die beträchtliche Mengen an Rückstandsmaterial enthalten.
ANMERKUNG Für den Zweck dieser Norm wird der Ausdruck „% (V/V)“ verwendet, um den Volumenanteil darzustellen.
Produits pétroliers liquides - Détermination des caractéristiques de distillation à la pression atmosphérique - Micro-distillation
Le présent document spécifie une méthode de laboratoire pour l'identification des caractéristiques de distillation des distillats pétroliers légers et moyens, ainsi que des produits connexes d'origine biologique ou synthétique, ayant un point initial de distillation supérieur à 20 °C et un point final inférieur à environ 400 °C, à la pression atmosphérique en utilisant un appareillage de micro-distillation automatique.
Cette méthode d'essai s'applique aux produits tels que les distillats légers et moyens, les carburants automobiles pour moteurs à allumage par étincelle, les carburants automobiles pour moteurs à allumage par étincelle contenant jusqu'à 20 % (V/V) d'éthanol, les essences aéronautiques, les carburéacteurs, les carburants diesel (paraffiniques), les EMAG (B100), les mélanges de diesel contenant jusqu'à 30 % (V/V) d'esters méthyliques d'acides gras (EMAG), les essences pétrolières spéciales, le naphta, le white-spirit, le kérosène, les combustibles de chauffe et les combustibles pour la marine.
Cette méthode d'essai s'applique également aux hydrocarbures présentant un intervalle de distillation étroit, tels que les solvants organiques ou les composés oxygénés.
La méthode d'essai est conçue pour l'analyse des produits de distillation ; elle ne s'applique pas aux produits qui contiennent des quantités appréciables de matières résiduelles.
NOTE Pour les besoins de la présente norme, le terme «% (V/V)» est utilisé pour représenter la fraction volumique.
Tekoči naftni proizvodi - Določevanje destilacijskih značilnosti pri atmosferskem tlaku - Mikrodestilacija
Ta dokument zajema postopek za določevanje destilacijskih značilnosti naftnih proizvodov, ki imajo pri atmosferskem tlaku območje vrelišča med 20 °C in 400 °C, z avtomatsko aparaturo za mikrodestilacijo. Preskusna metoda se uporablja za proizvode, kot so lahki in srednji destilati, gorivo za motorna vozila z motorjem z vžiganjem na iskro, gorivo za motorna vozila z motorjem z vžiganjem na iskro, ki vsebuje do 10 % (vol.) etanola, letalski bencin, gorivo za letalske turbine, dizelsko gorivo z običajno in nizko vsebnostjo žvepla, mešanice biodizla z do 30 % (vol.) biodizla, specialni petroleter, nafta, beli špirit, kerozin, kurilna olja in ladijska goriva. Uporablja se tudi za ogljikovodike z majhnim območjem vrelišča, kot so organska topila ali kisikove spojine.
General Information
Relations
Standards Content (Sample)
SLOVENSKI STANDARD
01-november-2019
Tekoči naftni proizvodi - Določevanje destilacijskih značilnosti pri atmosferskem
tlaku - Mikrodestilacija
Liquid petroleum products - Determination of distillation characteristics at atmospheric
pressure - Micro-distillation
Flüssige Mineralölerzeugnisse - Bestimmung der Destillationseigenschaften bei
atmosphärischem Druck - Mikrodestillation
Produits pétroliers - Distillation des produits pétroliers et de combustibles liquides à la
pression atmosphérique - Méthode Micro Distillation
Ta slovenski standard je istoveten z: EN 17306:2019
ICS:
75.160.20 Tekoča goriva Liquid fuels
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.
EN 17306
EUROPEAN STANDARD
NORME EUROPÉENNE
September 2019
EUROPÄISCHE NORM
ICS 75.160.20
English Version
Liquid petroleum products - Determination of distillation
characteristics at atmospheric pressure - Micro-distillation
Produits pétroliers liquides - Détermination des Flüssige Mineralölerzeugnisse - Bestimmung der
caractéristiques de distillation à la pression Destillationseigenschaften bei atmosphärischem Druck
atmosphérique - Micro-distillation - Mikrodestillation
This European Standard was approved by CEN on 21 June 2019.
CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this
European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references
concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN
member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by
translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management
Centre has the same status as the official versions.
CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway,
Poland, Portugal, Republic of North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and
United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION
EUROPÄISCHES KOMITEE FÜR NORMUNG
CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2019 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN 17306:2019 E
worldwide for CEN national Members.
Contents Page
European foreword . 3
Introduction . 4
1 Scope . 5
2 Normative references . 5
3 Terms and definitions . 5
4 Principle . 7
5 Reagents and materials . 7
6 Apparatus . 7
6.1 Micro distillation unit . 7
6.2 Barometer for calibration . 8
6.3 Sampling device . 8
6.4 Waste beaker . 8
7 Sampling . 8
8 Apparatus preparation . 9
9 Calibration, verification and quality control. 9
9.1 General . 9
9.2 Calibration . 9
9.3 Instrument verification . 9
9.4 Quality control . 10
10 Procedure. 10
11 Calculation . 11
12 Expression of results . 11
13 Precision . 11
13.1 General . 11
13.2 Repeatability, r . 12
13.3 Reproducibility, R . 13
13.4 Bias . 15
13.5 Relative bias . 15
13.6 Repeatability and reproducibility for FAME . 15
13.7 Relative bias for FAME . 16
14 Test report . 17
Annex A (normative) Micro distillation apparatus . 18
A.1 Detailed description of apparatus . 18
Annex B (normative) Precision of the volume percent evaporated or recovered at a
prescribed temperature . 22
Annex C (informative) Typical samples and group classification . 23
Bibliography . 24
European foreword
This document (EN 17306:2019) has been prepared by Technical Committee CEN/TC 19 “Gaseous and
liquid fuels, lubricants and related products of petroleum, synthetic and biological origin”, the secretariat
of which is held by NEN.
This European Standard shall be given the status of a national standard, either by publication of an
identical text or by endorsement, at the latest by March 2020, and conflicting national standards shall be
withdrawn at the latest by March 2020.
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. CEN not be held responsible for identifying any or all such patent rights.
According to the CEN/CENELEC Internal Regulations, the national standards organizations of the
following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia,
Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland,
Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Republic of North
Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United
Kingdom.
Introduction
The distillation (volatility) characteristics of hydrocarbons and other liquids have an important effect on
their safety and performance, especially in the case of fuels and solvents. The boiling range gives
information on the composition, the properties, and the behaviour of the fuel during storage and use.
Volatility is the major determinant of the tendency of a hydrocarbon mixture to produce potentially
explosive vapours.
The distillation characteristics are critically important for both automotive and aviation gasolines,
affecting starting, warm-up and tendency to vapour lock at high operating temperature or at high altitude,
or both. The presence of high boiling point components in these and other fuels can significantly affect
the degree of formation of solid combustion deposits.
Distillation limits are often included in petroleum product specifications, in commercial contract
agreements, process refinery/control applications, and for compliance to regulatory rules.
This test method can be applied to contaminated products or hydrocarbon mixtures. This is valuable for
fast product quality screening, refining process monitoring, fuel adulteration control, or other purposes
including use as a portable apparatus for field testing.
This document is as of the time of publication technically equivalent to ASTM D7345 [1], on which it is
based.
This test method uses an automatic micro distillation apparatus, provides fast results using small sample
volume, and eliminates much of the operator time and subjectivity in comparison to EN ISO 3405 or ASTM
D1160 [2].
WARNING — The use of this standard can involve hazardous materials, operations and equipment. This
standard does not purport to address all of the safety problems associated with its use. It is the
responsibility of users of this standard to take appropriate measures to ensure the safety and health of
personnel prior to application of the standard, and fulfil statutory and regulatory requirements for this
purpose.
1 Scope
This document specifies a laboratory method for the determination of the distillation characteristics of
light and middle distillates derived from petroleum and related products of synthetic or biological origin
with initial boiling points above 20 °C and end-points below approximately 400 °C, at atmospheric
pressure utilizing an automatic micro distillation apparatus.
This test method is applicable to such products as light and middle distillates, automotive spark-ignition
engine fuels, automotive spark-ignition engine fuels containing up to 20 % (V/V) ethanol, aviation
gasolines, aviation turbine fuels, (paraffinic) diesel fuels, FAME (B100), diesel blends up to 30 % (V/V)
fatty acid methyl esters (FAME), special petroleum spirits, naphtha’s, white spirits, kerosene’s, burner
fuels, and marine fuels.
The test method is also applicable to hydrocarbons with a narrow boiling range, like organic solvents or
oxygenated compounds.
The test method is designed for the analysis of distillate products; it is not applicable to products
containing appreciable quantities of residual material.
NOTE For the purpose of this standard, the expression “% (V/V)” is used to represent the volume fraction.
2 Normative references
The following documents are referred to in the text in such a way that some or all of their content
constitutes requirements of this document. For dated references, only the edition cited applies. For
undated references, the latest edition of the referenced document (including any amendments) applies.
EN ISO 3170, Petroleum liquids - Manual sampling (ISO 3170)
EN ISO 3171, Petroleum liquids - Automatic pipeline sampling (ISO 3171)
EN ISO 3405, Petroleum and related products from natural or synthetic sources - Determination of
distillation characteristics at atmospheric pressure (ISO 3405)
EN ISO 4259-1, Petroleum and related products - Precision of measurement methods and results - Part 1:
Determination of precision data in relation to methods of test (ISO 4259-1)
3 Terms and definitions
For the purposes of this document, the following terms and definitions apply.
ISO and IEC maintain terminological databases for use in standardization at the following addresses:
— IEC Electropedia: available at http://www.electropedia.org/
— ISO Online browsing platform: available at http://www.iso.org/obp
3.1
automatic apparatus
microprocessor -controlled unit that performs
...
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