Ethanol as a blending component for petrol - Determination of water content - Karl Fischer coulometric titration method

This European Standard specifies a method for the direct determination of water in ethanol to be used in gasoline blends. It is applicable to ethanol having water contents in the range 0,039 % (m/m) to 0,5 % (m/m).
NOTE   For the purposes of this document, the term “% (m/m)” is used to represent the mass fraction.
WARNING — Use of this standard may involve hazardous materials, operations and equipment. This standard does not purport to address all of the safety problems associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

Ethanol zur Verwendung als Blendkomponente in Ottokraftstoff - Bestimmung des Wassergehaltes - Coulometrisches Titrationsverfahren nach Karl Fischer

Diese Europäische Norm beschreibt ein Verfahren zur direkten Bestimmung von Wasser in Ethanol zur Verwendung als Blendkomponente in Ottokraftstoff. Es ist für Ethanol mit einem Wassergehalt im Bereich von 0,02 % (m/m) bis 0,5 % (m/m) anwendbar.
ANMERKUNG 1   Weitere Angaben zum Blendvorgang und zur Anwendbarkeit, siehe Vorwort.
ANMERKUNG 2   Für den Zweck dieses Dokumentes wird der Massenanteil in Prozent durch % (m/m) ausgedrückt.
WARNUNG  Die Anwendung dieser Norm kann möglicherweise den Einsatz gefährlicher Materialien, Geräte oder Arbeitsschritte erfordern. Dieses Dokument gibt nicht vor, alle möglicherweise bei seiner Anwendung auftretenden Sicherheitsprobleme anzusprechen. Es liegt in der Verantwortung des Anwenders, vor der Anwendung dieser Norm zutreffende Verhaltensregeln zur Sicherheit und Gesundheit festzulegen und deren Übereinstimmung mit den Bestimmungen aller europäischen und nationalen Regelungen sicherzustellen.

Ethanol comme base de mélange a l'essence - Détermination de la teneur en eau - Méthode de titrage Karl Fischer par coulométrie

La présente Norme européenne prescrit une méthode de détermination de la teneur en eau dans l’éthanol utilisé comme constituant d’essence pour automobiles. Elle s’applique aux échantillons d’éthanol dont la teneur en eau est comprise entre 0,039 % (m/m) et 0,500 % (m/m).
NOTE   Pour les besoins du présent document, le terme « % (m/m) » représente la fraction massique.
AVERTISSEMENT  L'utilisation de la présente Norme européenne peut impliquer l'intervention de produits, d'opérations et d'équipements à caractère dangereux. La présente Norme européenne n'est pas censée aborder tous les problèmes de sécurité concernés par son usage. Il est de la responsabilité de l'utilisateur de consulter et d'établir des règles de sécurité et d'hygiène appropriées et de déterminer l'applicabilité des restrictions réglementaires avant utilisation.

Etanol kot komponenta za dodajanje motornemu bencinu – Določevanje vsebnosti vode - Metoda s kulometrično titracijo po Karlu Fischerju

General Information

Status
Published
Publication Date
24-Oct-2007
Current Stage
6060 - National Implementation/Publication (Adopted Project)
Start Date
04-Oct-2007
Due Date
09-Dec-2007
Completion Date
25-Oct-2007

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2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.Ethanol as a blending component for petrol - Determination of water content - Karl Fischer coulometric titration methodMHMXEthanol comme base de mélange a l'essence - Détermination de la teneur en eau - Méthode de titrage Karl Fischer par coulométrieEthanol zur Verwendung als Blendkomponente in Ottokraftstoff - Bestimmung des Wassergehaltes - Coulometrisches Titrationsverfahren nach Karl FischerTa slovenski standard je istoveten z:EN 15489:2007SIST EN 15489:2007en75.160.20Liquid fuels71.080.60Alkoholi. EtriAlcohols. EthersICS:SLOVENSKI

STANDARDSIST EN 15489:200701-december-2007

EUROPEAN STANDARDNORME EUROPÉENNEEUROPÄISCHE NORMEN 15489August 2007ICS 71.080.60 English VersionEthanol as a blending component for petrol - Determination ofwater content - Karl Fischer coulometric titration methodEthanol comme base de mélange à l'essence -Détermination de la teneur en eau - Méthode de titragecoulométrique Karl FischerEthanol zur Verwendung als Blendkomponente inOttokraftstoff - Bestimmung des Wassergehaltes -Coulometrisches Titrationsverfahren nach Karl FischerThis European Standard was approved by CEN on 30 June 2007.CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this EuropeanStandard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such nationalstandards may be obtained on application to the CEN Management Centre or to any CEN member.This European Standard exists in three official versions (English, French, German). A version in any other language made by translationunder the responsibility of a CEN member into its own language and notified to the CEN Management Centre has the same status as theofficial versions.CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Cyprus, Czech Republic, Denmark, Estonia, Finland,France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal,Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom.EUROPEAN COMMITTEE FOR STANDARDIZATIONCOMITÉ EUROPÉEN DE NORMALISATIONEUROPÄISCHES KOMITEE FÜR NORMUNGManagement Centre: rue de Stassart, 36

B-1050 Brussels© 2007 CENAll rights of exploitation in any form and by any means reservedworldwide for CEN national Members.Ref. No. EN 15489:2007: E

EN 15489:2007 (E) 2 Contents Page Foreword.............................................................................................................................................................3 1 Scope......................................................................................................................................................4 2 Normative references...........................................................................................................................4 3 Terms and definitions...........................................................................................................................4 4 Principle.................................................................................................................................................4 5 Reagents and materials........................................................................................................................4 6 Apparatus..............................................................................................................................................5 7 Sampling and sample handling...........................................................................................................5 8 Apparatus preparation..........................................................................................................................5 9 Apparatus verification..........................................................................................................................6 10 Procedure..............................................................................................................................................6 11 Calculation.............................................................................................................................................7 12 Expression of results............................................................................................................................7 13 Precision................................................................................................................................................7 13.1 General...................................................................................................................................................7 13.2 Repeatability, r......................................................................................................................................7 13.3 Reproducibility, R.................................................................................................................................7 14 Test report.............................................................................................................................................8 Bibliography.......................................................................................................................................................9

EN 15489:2007 (E) 3 Foreword This document (EN 15489:2007) has been prepared by Technical Committee CEN/TC 19 “Gaseous and liquid fuels, lubricants and related products of petroleum, synthetic and biological origin”, the secretariat of which is held by NEN. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by February 2008, and conflicting national standards shall be withdrawn at the latest by February 2008. This document was prepared by CEN/TC 19’s Ethanol Task Force and is based on the Energy Institute standard IP 539 [1]. According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom. .

EN 15489:2007 (E) 4 1 Scope This European Standard specifies a method for the direct determination of water in ethanol to be used in gasoline blends. It is applicable to ethanol having water contents in the range 0,039 % (m/m) to 0,500 % (m/m). NOTE For the purposes of this document, the term “% (m/m)” is used to represent the mass fraction. WARNING — Use of this standard may involve hazardous materials, operations and equipment. This standard does not purport to address all of the safety problems associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. 2 Normative references The following referenced documents are indispensable for the application of this document. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. EN ISO 3170, Petroleum liquids — Manual sampling (ISO 3170:2004) EN ISO 3696, Water for analytical laboratory use – Specification and test methods (ISO 3696:1987) 3 Terms and definitions For the purposes of this European Standard, the following terms and definitions apply. 3.1 water content content of water determined by coulometric Karl Fischer procedure as given in this document 4 Principle A weighed test portion is injected into the titration vessel of a coulometric Karl Fischer apparatus in which iodine for the Karl Fischer reaction is generated coulometrically at the anode. When all the water has been titrated, excess iodine is detected by an electrometric end-point detector and the titration is terminated. Based on the stoich

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