ASTM D5931-13(2017)

Standard Test Method for Density and Relative Density of Engine Coolant Concentrates and Aqueous Engine Coolants by Digital Density Meter

SIGNIFICANCE AND USE
5.1 Density is a fundamental physical property that can be used in conjunction with other properties to characterize engine coolant concentrates and aqueous engine coolants.  
5.2 Determination of the density or relative density of these products is necessary for the conversion of measured volumes to volumes at the standard temperature of 20 °C (68 °F).
SCOPE
1.1 This test method covers the determination of the density or relative density of engine coolant concentrates and aqueous engine coolants.  
1.2 This test method should not be applied to samples so dark in color that the absence of air bubbles in the sample cell cannot be established with certainty.  
1.3 The accepted units of measure for density are grams per milliliter or kilograms per cubic meter.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements, see Note 1.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

General Information

• Status: Historical
• Publication Date: 31-Oct-2017
• ICS: 17.060 - Measurement of volume, mass, density, viscosity
• ICS: 47.020.20 - Marine engines and propulsion systems
• ICS: 71.100.45 - Refrigerants and antifreezes
• Technical Committee: D15 - Engine Coolants and Related Fluids
• Drafting Committee: D15.03 - Physical Properties

Relations

• Replaces: ASTM D5931-13 - Standard Test Method for Density and Relative Density of Engine Coolant Concentrates and Aqueous Engine Coolants by Digital Density Meter
• Effective Date: 01-Nov-2017
• Replaced By: ASTM D5931-20 - Standard Test Method for Density and Relative Density of Engine Coolant Concentrates and Aqueous Engine Coolants by Digital Density Meter
• Effective Date: 15-May-2020
• Referred By: ASTM D3306-21 - Standard Specification for Glycol Base Engine Coolant for Automobile and Light-Duty Service
• Effective Date: 01-Nov-2017
• Referred By: ASTM D8039-16(2023) - Standard Specification for Heat Transfer Fluids (HTF) for Heating and Air Conditioning (HVAC) Systems
• Effective Date: 01-Nov-2017
• Referred By: ASTM D7640-16(2021) - Standard Specification for Engine Coolant Grade Glycerin
• Effective Date: 01-Nov-2017
• Referred By: ASTM D7388-23 - Standard Specification for Engine Coolant Grade 1,3-Propanediol (PDO)
• Effective Date: 01-Nov-2017
• Referred By: ASTM D7518-20 - Standard Specification for 1,3 Propanediol (PDO) Base Engine Coolant for Automobile and Light-Duty Service
• Effective Date: 01-Nov-2017
• Referred By: ASTM D7714-11(2021) - Standard Specification for Glycerin Base Engine Coolant for Automobile and Light-Duty Service
• Effective Date: 01-Nov-2017
• Referred By: ASTM E1177-23 - Standard Specification for Engine Coolant Grade Glycol
• Effective Date: 01-Nov-2017
• Referred By: ASTM D3585-08(2020) - Standard Specification for ASTM Reference Fluid for Coolant Tests
• Effective Date: 01-Nov-2017
• Referred By: ASTM D8085-17 - Standard Specification for Non-Aqueous Engine Coolant for Automobile and Light-Duty Service
• Effective Date: 01-Nov-2017
• Referred By: ASTM D7713-18 - Standard Specification for Aqueous Engine Coolant Grade Glycol (53 % by Volume Nominal)
• Effective Date: 01-Nov-2017
• Referred By: ASTM D7896-19 - Standard Test Method for Thermal Conductivity, Thermal Diffusivity, and Volumetric Heat Capacity of Engine Coolants and Related Fluids by Transient Hot Wire Liquid Thermal Conductivity Method
• Effective Date: 01-Nov-2017
• Referred By: ASTM D4985-10(2023) - Standard Specification for Low Silicate Ethylene Glycol Base Engine Coolant for Heavy Duty Engines Requiring a Pre-Charge of Supplemental Coolant Additive (SCA)
• Effective Date: 01-Nov-2017
• Referred By: ASTM D1176-14(2019) - Standard Practice for Sampling and Preparing Aqueous Solutions of Engine Coolants or Antirusts for Testing Purposes
• Effective Date: 01-Nov-2017

Standards Content (Sample)

NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation: D5931 − 13 (Reapproved 2017)
Standard Test Method for
Density and Relative Density of Engine Coolant
Concentrates and Aqueous Engine Coolants by Digital
1
Density Meter
This standard is issued under the fixed designation D5931; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision.Anumber in parentheses indicates the year of last reapproval.A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope* 3. Terminology
3.1 Definitions:
1.1 Thistestmethodcoversthedeterminationofthedensity
3.1.1 relative density, n—the ratio of the density of a
or relative density of engine coolant concentrates and aqueous
material at a stated temperature to the density of water at the
engine coolants.
same stated temperature.
1.2 This test method should not be applied to samples so
dark in color that the absence of air bubbles in the sample cell
4. Summary of Test Method
cannot be established with certainty.
4.1 A small volume of liquid sample is introduced into an
1.3 The accepted units of measure for density are grams per
oscillatingsampletube,andthechangeinoscillatingfrequency
milliliter or kilograms per cubic meter.
caused by the change in the mass of the tube is used in
1.4 This standard does not purport to address all of the
conjunction with calibration data to determine the density of
safety concerns, if any, associated with its use. It is the the sample.
responsibility of the user of this standard to establish appro-
5. Significance and Use
priate safety, health, and environmental practices and deter-
mine the applicability of regulatory limitations prior to use.
5.1 Density is a fundamental physical property that can be
For specific hazard statements, see Note 1.
usedinconjunctionwithotherpropertiestocharacterizeengine
1.5 This international standard was developed in accor-
coolant concentrates and aqueous engine coolants.
dance with internationally recognized principles on standard-
5.2 Determination of the density or relative density of these
ization established in the Decision on Principles for the
products is necessary for the conversion of measured volumes
Development of International Standards, Guides and Recom-
to volumes at the standard temperature of 20°C (68°F).
mendations issued by the World Trade Organization Technical
Barriers to Trade (TBT) Committee.
6. Apparatus
6.1 Digital Density Analyzer, consisting of a U-shaped,
2. Referenced Documents
oscillating sample tube and a system for electronic excitation,
2
2.1 ASTM Standards:
frequency counting, and display.The analyzer must accommo-
D1193Specification for Reagent Water
date the accurate measurement of the sample temperature
D4052Test Method for Density, Relative Density, and API
duringmeasurementormustcontrolthesampletemperatureas
Gravity of Liquids by Digital Density Meter
described in 6.2. The instrument must meet the precision
E230/E230MSpecification for Temperature-Electromotive
requirements described in this test method.
Force (emf) Tables for Standardized Thermocouples
6.2 Circulating Constant—Temperature Bath, (optional) ca-
pable of maintaining the temperature of the circulating liquid
constantto 60.05°Cinthedesiredrange.Temperaturecontrol
1
This test method is under the jurisdiction ofASTM Committee D15 on Engine
can be maintained as part of the density analyzer instrument
Coolants and Related Fluids and is the direct responsibility of Subcommittee
package.
D15.03 on Physical Properties.
Current edition approved Nov. 1, 2017. Published November 2017. Originally
6.3 Syringes, at least 2 mL in volume with a tip or an
approved in 1996. Last previous edition approved in 2013 as D5931–13. DOI:
adapter tip that will fit the opening of the oscillating tube.
10.1520/D5931-13R17.
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or
6.4 Flow-Through or Pressure Adapter, for use as an alter-
contact ASTM Customer Service at [e-mail]. For Annual Book of ASTM
native means of introducing the sample into the density
Standards volume information, refer to the standard’s Document Summary page on
the ASTM website. analyzer either by a pump or by vacuum.
*A Summary of Changes section appears at the end of this standard
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1

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D5931 − 13 (2017)
6.5 Temperature Measuring Instrument, (Environmentally whenthesamplecellcontainsairandredistilled,freshlyboiled
safe thermometer or thermocouple).AnASTM Partial Immer- and cooled reagent water.
sion Thermometer, having a range from –5 to 300°C (20 to 9.2.1 While monitoring the oscillator period, (T), flush the
580°F) and conforming to
...

This document is not an ASTM standard and is intended only to provide the user of an ASTM standard an indication of what changes have been made to the previous version. Because
it may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current version
of the standard as published by ASTM is to be considered the official document.
Designation: D5931 − 13 D5931 − 13 (Reapproved 2017)
Standard Test Method for
Density and Relative Density of Engine Coolant
Concentrates and Aqueous Engine Coolants by Digital
1
Density Meter
This standard is issued under the fixed designation D5931; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope*
1.1 This test method covers the determination of the density or relative density of engine coolant concentrates and aqueous
engine coolants.
1.2 This test method should not be applied to samples so dark in color that the absence of air bubbles in the sample cell cannot
be established with certainty.
1.3 The accepted units of measure for density are grams per milliliter or kilograms per cubic meter.
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility
of the user of this standard to establish appropriate safety safety, health, and healthenvironmental practices and determine the
applicability of regulatory limitations prior to use. For specific hazard statements, see Note 1.
1.5 This international standard was developed in accordance with internationally recognized principles on standardization
established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued
by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
2. Referenced Documents
2
2.1 ASTM Standards:
D1193 Specification for Reagent Water
D4052 Test Method for Density, Relative Density, and API Gravity of Liquids by Digital Density Meter
E230E230/E230M Specification andfor Temperature-Electromotive Force (EMF)(emf) Tables for Standardized Thermocouples
3. Terminology
3.1 Definitions:
3.1.1 relative density, n—the ratio of the density of a material at a stated temperature to the density of water at the same stated
temperature.
4. Summary of Test Method
4.1 A small volume of liquid sample is introduced into an oscillating sample tube, and the change in oscillating frequency
caused by the change in the mass of the tube is used in conjunction with calibration data to determine the density of the sample.
5. Significance and Use
5.1 Density is a fundamental physical property that can be used in conjunction with other properties to characterize engine
coolant concentrates and aqueous engine coolants.
5.2 Determination of the density or relative density of these products is necessary for the conversion of measured volumes to
volumes at the standard temperature of 20°C (68°F).20 °C (68 °F).
1
This test method is under the jurisdiction of ASTM Committee D15 on Engine Coolants and Related Fluids and is the direct responsibility of Subcommittee D15.03 on
Physical Properties.
Current edition approved May 1, 2013Nov. 1, 2017. Published June 2013November 2017. Originally approved in 1996. Last previous edition approved in 20072013 as
D5931–96(2007)D5931–13. DOI: 10.1520/D5931-13.10.1520/D5931-13R17.
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or contact ASTM Customer Service at [e-mail]. For Annual Book of ASTM Standards
volume information, refer to the standard’s Document Summary page on the ASTM website.
*A Summary of Changes section appears at the end of this standard
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1

---------------------- Page: 1 ----------------------
D5931 − 13 (2017)
6. Apparatus
6.1 Digital Density Analyzer, consisting of a U-shaped, oscillating sample tube and a system for electronic excitation, frequency
counting, and display. The analyzer must accommodate the accurate measurement of the sample temperature during measurement
or must control the sample temperature as described in 6.2. The instrument must meet the precision requirements described in this
test method.
6.2 Circulating Constant—Temperature Bath, (optional) capable of maintaining the temperature of the circulating liquid
constant to 60.05°C60.05 °C in the desired range. Temperature control can be maintained as part of the density analyzer
instrument package.
6.3 Syringes, at least 2 mL in volume with a tip or an adapter tip that will fit the opening of the oscillating tube.
6.4 Flow-Through or Pressure Adapter, for use as an alternative m
...