Standard Practice for Separation of Ignitable Liquid Residues from Fire Debris Samples by Passive Headspace Concentration with Activated Charcoal

SIGNIFICANCE AND USE
4.1 This practice is useful for preparing extracts from fire debris for later analysis by gas chromatography mass spectrometry.  
4.2 This is a very sensitive separation procedure, capable of isolating quantities smaller than 1/10 μL of ignitable liquid residue from a sample.
SCOPE
1.1 This practice describes the procedure for separation of small quantities of ignitable liquid residues from samples of fire debris using an adsorbent material to extract the residue from the static headspace above the sample, then eluting the adsorbent with a solvent.  
1.2 While this practice is suitable for successfully extracting ignitable liquid residues over the entire range of concentration, the headspace concentration methods are best used when a high level of sensitivity is required due to a very low concentration of ignitable liquid residues in the sample.  
1.2.1 Unlike other methods of separation and concentration, this practice is essentially nondestructive.  
1.3 Alternate separation and concentration procedures are listed in the referenced documents (see Practices E1386, E1388, E1413, and E2154).  
1.4 This practice does not replace knowledge, skill, ability, experience, education, or training and should be used in conjunction with professional judgment.  
1.5 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.7 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

General Information

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Published
Publication Date
14-Nov-2019
Technical Committee
Drafting Committee
Current Stage
Ref Project

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This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the
Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
Designation: E1412 − 19 An American National Standard
Standard Practice for
Separation of Ignitable Liquid Residues from Fire Debris
Samples by Passive Headspace Concentration with
1
Activated Charcoal
This standard is issued under the fixed designation E1412; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope 2. Referenced Documents
2
2.1 ASTM Standards:
1.1 This practice describes the procedure for separation of
small quantities of ignitable liquid residues from samples of E1386 Practice for Separation of Ignitable Liquid Residues
fire debris using an adsorbent material to extract the residue from Fire Debris Samples by Solvent Extraction
E1388 Practice for Static Headspace Sampling of Vapors
from the static headspace above the sample, then eluting the
adsorbent with a solvent. from Fire Debris Samples
E1413 Practice for Separation of Ignitable Liquid Residues
1.2 Whilethispracticeissuitableforsuccessfullyextracting
from Fire Debris Samples by Dynamic Headspace Con-
ignitable liquid residues over the entire range of concentration,
centration onto an Adsorbent Tube
theheadspaceconcentrationmethodsarebestusedwhenahigh
E1459 Guide for Physical Evidence Labeling and Related
level of sensitivity is required due to a very low concentration
Documentation
of ignitable liquid residues in the sample.
E1492 Practice for Receiving, Documenting, Storing, and
1.2.1 Unlike other methods of separation and concentration,
Retrieving Evidence in a Forensic Science Laboratory
this practice is essentially nondestructive.
E1618 TestMethodforIgnitableLiquidResiduesinExtracts
1.3 Alternate separation and concentration procedures are
from Fire Debris Samples by Gas Chromatography-Mass
listed in the referenced documents (see Practices E1386,
Spectrometry
E1388, E1413, and E2154).
E2154 Practice for Separation and Concentration of Ignit-
able Liquid Residues from Fire Debris Samples by Pas-
1.4 This practice does not replace knowledge, skill, ability,
sive Headspace Concentration with Solid Phase Microex-
experience, education, or training and should be used in
traction (SPME)
conjunction with professional judgment.
E2451 Practice for Preserving Ignitable Liquids and Ignit-
1.5 The values stated in SI units are to be regarded as
able Liquid Residue Extracts from Fire Debris Samples
standard. No other units of measurement are included in this
standard. 3. Summary of Practice
1.6 This standard does not purport to address all of the
3.1 Charcoal in some form of an adsorption package is
safety concerns, if any, associated with its use. It is the
placed in the sample container to adsorb ignitable liquid
responsibility of the user of this standard to establish appro-
residues. The container can be heated or left at ambient
priate safety, health, and environmental practices and deter-
temperature. The charcoal is removed and eluted with a
mine the applicability of regulatory limitations prior to use.
suitable elution solvent as listed in 6.3.
1.7 This international standard was developed in accor-
4. Significance and Use
dance with internationally recognized principles on standard-
4.1 This practice is useful for preparing extracts from fire
ization established in the Decision on Principles for the
debris for later analysis by gas chromatography mass spec-
Development of International Standards, Guides and Recom-
trometry.
mendations issued by the World Trade Organization Technical
Barriers to Trade (TBT) Committee.
4.2 This is a very sensitive separation procedure, capable of
1
isolating quantities smaller than ⁄10 µL of ignitable liquid
residue from a sample.
1
This practice is under the jurisdiction of ASTM Committee E30 on Forensic
2
Sciences and is the direct responsibility of Subcommittee E30.01 on Criminalistics. For referenced ASTM standards, visit the ASTM website, www.astm.org, or
Current edition approved Nov. 15, 2019. Published December 2019. Originally contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
approved in 1991. Last previous edition approved in 2016 as E1412 – 16. DOI: Standards volume information, refer to the standard’s Document Summary page on
10.1520/E1412-19. the ASTM website.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1

---------------------- Page: 1 ----------------------
E1412 − 19
5. Apparatus 7. Sample Preparation/Adsorption Procedure
5.1 Hea
...

This document is not an ASTM standard and is intended only to provide the user of an ASTM standard an indication of what changes have been made to the previous version. Because
it may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current version
of the standard as published by ASTM is to be considered the official document.
Designation: E1412 − 16 E1412 − 19
Standard Practice for
Separation of Ignitable Liquid Residues from Fire Debris
Samples by Passive Headspace Concentration Withwith
1
Activated Charcoal
This standard is issued under the fixed designation E1412; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope
1.1 This practice describes the procedure for separation of small quantities of ignitable liquid residues from samples of fire
debris using an adsorbent material to extract the residue from the static headspace above the sample, then eluting the adsorbent
with a solvent.
1.2 While this practice is suitable for successfully extracting ignitable liquid residues over the entire range of concentration, the
headspace concentration methods are best used when a high level of sensitivity is required due to a very low concentration of
ignitable liquid residues in the sample.
1.2.1 Unlike other methods of separation and concentration, this practice is essentially nondestructive.
1.3 Alternate separation and concentration procedures are listed in the referenced documents (see Practices E1386, E1388,
E1413, and E2154).
1.4 This practice does not replace knowledge, skill, ability, experience, education, or training and should be used in conjunction
with professional judgment.
1.5 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility
of the user of this standard to establish appropriate safety safety, health, and healthenvironmental practices and determine the
applicability of regulatory limitations prior to use.
1.7 This international standard was developed in accordance with internationally recognized principles on standardization
established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued
by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
2. Referenced Documents
2
2.1 ASTM Standards:
E1386 Practice for Separation of Ignitable Liquid Residues from Fire Debris Samples by Solvent Extraction
E1388 Practice for Static Headspace Sampling of Vapors from Fire Debris Samples
E1413 Practice for Separation of Ignitable Liquid Residues from Fire Debris Samples by Dynamic Headspace Concentration
onto an Adsorbent Tube
E1459 Guide for Physical Evidence Labeling and Related Documentation
E1492 Practice for Receiving, Documenting, Storing, and Retrieving Evidence in a Forensic Science Laboratory
E1618 Test Method for Ignitable Liquid Residues in Extracts from Fire Debris Samples by Gas Chromatography-Mass
Spectrometry
E2154 Practice for Separation and Concentration of Ignitable Liquid Residues from Fire Debris Samples by Passive Headspace
Concentration with Solid Phase Microextraction (SPME)
E2451 Practice for Preserving Ignitable Liquids and Ignitable Liquid Residue Extracts from Fire Debris Samples
1
This practice is under the jurisdiction of ASTM Committee E30 on Forensic Sciences and is the direct responsibility of Subcommittee E30.01 on Criminalistics.
Current edition approved Jan. 15, 2016Nov. 15, 2019. Published February 2016December 2019. Originally approved in 1991. Last previous edition approved in 20122016
as E1412 – 12.E1412 – 16. DOI: 10.1520/E1412-16.10.1520/E1412-19.
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM Standards
volume information, refer to the standard’sstandard’s Document Summary page on the ASTM website.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1

---------------------- Page: 1 ----------------------
E1412 − 19
3. Summary of Practice
3.1 Charcoal in some form of an adsorption package is placed in the sample container to adsorb ignitable liquid residues. The
container maycan be heated or left at ambient temperature. The charcoal is removed and eluted with a suitable elution solvent as
listed in 6.3.
4. Significance and Use
4.1 This practice is useful for preparing extracts from fire debris for later analysis by gas chromatography mass spectrometry.
1
4.2 This is a ver
...

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