Standard Test Method for Oxidation Characteristics of Inhibited Mineral Oils

SIGNIFICANCE AND USE
This test method is widely used for specification purposes and is considered of value in estimating the oxidation stability of lubricants, especially those that are prone to water contamination. It should be recognized, however, that correlation between results of this method and the oxidation stability of a lubricant in field service may vary markedly with field service conditions and with various lubricants. The precision statement for this method was determined on steam turbine oils.
Note 1—Furthermore, in the course of testing a lubricant by this method, other signs of deterioration, such as sludge formation or catalyst coil corrosion, may appear that are not reflected in the calculated oxidation lifetime. The subcommittee responsible for this method is investigating the application of alternative criteria for evaluation of lubricants using this test apparatus. Test Method D 4310 is now available for sludge measurement.
SCOPE
1.1 This test method covers the evaluation of oxidation stability of inhibited steam-turbine oils in the presence of oxygen, water, and copper and iron metals at an elevated temperature. The test method is also used for testing other oils such as hydraulic oils and circulating oils having a specific gravity less than that of water and containing rust and oxidation inhibitors.
1.2 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For specific warning statements, see Section 6.

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31-Oct-2004
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ASTM D943-04a - Standard Test Method for Oxidation Characteristics of Inhibited Mineral Oils
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NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
BS 2000-280:1999
Designation:D943–04a
Standard Test Method for
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Oxidation Characteristics of Inhibited Mineral Oils
This standard is issued under the fixed designation D943; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
This standard has been approved for use by agencies of the Department of Defense.
1. Scope* D4310 Test Method for Determination of Sludging and
Corrosion Tendencies of Inhibited Mineral Oils
1.1 This test method covers the evaluation of the oxidation
D5770 Test Method for Semiquantitative Micro Determina-
stability of inhibited steam-turbine oils in the presence of
tion ofAcid Number of Lubricating Oils During Oxidation
oxygen, water, and copper and iron metals at an elevated
Testing
temperature. This test method is limited to a maximum testing
E1 Specification for ASTM Liquid-in-Glass Thermometers
time of 10 000 h.This test method is also used for testing other
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2.2 Energy Institute Standards:
oils,suchashydraulicoilsandcirculatingoilshavingaspecific
Specifications for IP Standard Thermometers
gravitylessthanthatofwaterandcontainingrustandoxidation
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2.3 British Standard:
inhibitors.
BS 1829
1.2 The values stated in SI units are to be regarded as
standard. No other units of measurement are included in this
3. Summary of Test Method
standard.
3.1 The oil sample is contacted with oxygen in the presence
1.3 This standard does not purport to address all of the
ofwaterandaniron-coppercatalystat95°C.Thetestcontinues
safety concerns, if any, associated with its use. It is the
until the measured acid number of the oil is 2.0 mg KOH/g or
responsibility of the user of this standard to establish appro-
above. The number of test hours required for the oil to reach
priate safety and health practices and determine the applica-
2.0 mg KOH/g is the “oxidation lifetime.”
bility of regulatory limitations prior to use. For specific
warning statements, see Section 6.
4. Significance and Use
4.1 This test method is widely used for specification pur-
2. Referenced Documents
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poses and is considered of value in estimating the oxidation
2.1 ASTM Standards:
stability of lubricants, especially those that are prone to water
A510 Specification for General Requirements for Wire
contamination. It should be recognized, however, that correla-
Rods and Coarse Round Wire, Carbon Steel
tion between results of this method and the oxidation stability
B1 Specification for Hard-Drawn Copper Wire
of a lubricant in field service may vary markedly with field
D664 Test Method forAcid Number of Petroleum Products
service conditions and with various lubricants. The precision
by Potentiometric Titration
statement for this method was determined on steam turbine
D1193 Specification for Reagent Water
oils.
D3244 Practice for Utilization of Test Data to Determine
Conformance with Specifications
NOTE 1—Furthermore, in the course of testing a lubricant by this
D3339 Test Method for Acid Number of Petroleum Prod- method, other signs of deterioration, such as sludge formation or catalyst
coilcorrosion,mayappearthatarenotreflectedinthecalculatedoxidation
ucts by Semi-Micro Color Indicator Titration
lifetime. The subcommittee responsible for this method is investigating
D4057 Practice for Manual Sampling of Petroleum and
theapplicationofalternativecriteriaforevaluationoflubricantsusingthis
Petroleum Products
test apparatus. Test Method D4310 is now available for sludge measure-
ment.
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This test method is under the jurisdiction of ASTM Committee D02 on
5. Apparatus
Petroleum Products and Lubricants and is the direct responsibility of Subcommittee
D02.09 on Oxidation.
5.1 Oxidation Cell, of borosilicate glass, as shown in Fig. 1,
Current edition approved Nov. 1, 2004. Published November 2004. Originally
consisting of a test tube, condenser, and oxygen delivery tube.
approved in 1947. Last previous edition approved in 2004 as D943–04.
In 1976, this test method ceased to be a joint ASTM-IP standard. DOI:
10.1520/D0943-04A.
2 3
For referenced ASTM standards, visit the ASTM website, www.astm.org, or Available from Energy Institute, 61 New Cavendish St., London, W1G 7AR,
contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM United Kingdom.
4
Standards volume information, refer to the standard’s Document Summary page on Available from British Standards Institute, 389 Chiswick High Rd., London,
the ASTM website. W4 4AL, United Kingdom.
*A Summary of Changes section appears at the end of this standard.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.
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