EN 16143:2013

Petroleum products - Determination of content of Benzo(a)pyrene (BaP) and selected polycyclic aromatic hydrocarbons (PAH) in extender oils - Procedure using double LC cleaning and GC/MS analysis

This European Standard specifies a procedure for the determination of the content of benzo[a]pyrene (BaP) in extender oils which are commonly used in the rubber industry for the production of tyres or parts of tyres. The method also yields the sum of the eight individual polycyclic aromatic hydrocarbons (PAHs) listed in Table 1.
The procedure has been tested and verified for the PAHs listed in Table 1 (those required by the European Commission [1]) and additional PAHs as listed in Table A.2.
Analysis of other PAHs is possible in principle, but sufficient quality assurance performed by the user is necessary to secure the analysis.
The application range for this method is from approximately 4 mg/kg to approximately 15 mg/kg for the eight individual PAHs and from approximately 0,5 mg/kg to approximately 2 mg/kg for BaP.
NOTE 1   The intended working range for this method is in the 0,1 mg/kg to 15 mg/kg range. For the lower levels precision has not yet been established.
NOTE 2   For the purposes of this European Standard, the term "% (m/m)" is used to represent the mass fraction (...).
(...)

Mineralölerzeugnisse - Bestimmung des Gehaltes an Benzo(a)pyren (BaP) und ausgewählten polycyclischen Kohlenwasserstoffen (PAKs) in Extenderölen - Verfahren mittels doppelter LC-Vorreinigung und GC/MS-Analyse

Diese Europäische Norm legt ein Verfahren zur Bestimmung des Gehaltes an Benzo[a]pyren (BaP) in Extenderölen fest, die in der Gummiindustrie üblicherweise zur Produktion von Reifen oder Reifenteilen benutzt werden. Dieses Verfahren ergibt auch die Summe der acht einzelnen polycyclischen Kohlenwasserstoffe (PAKs), die in der Tabelle 1 enthalten sind.
Dieses Verfahren wurde für die von der Europäischen Kommission [1] geforderten PAKs in Tabelle 1 und die zusätzlichen PAKs in Tabelle A.2 geprüft und verifiziert.
Die Bestimmung anderer PAKs ist grundsätzlich möglich, eine hinreichende Qualitätskontrolle durch den Anwender ist jedoch zur Absicherung der Analyse erforderlich.
Der Anwendungsbereich dieser Methode reicht von 4 mg/kg bis etwa 15 mg/kg für die acht einzelnen PAKs und von 0,5 mg/kg bis etwa 2 mg/kg für BaP.
ANMERKUNG 1   Der beabsichtigte Arbeitsbereich für diese Methode liegt von 0,1 mg/kg bis 15 mg/kg. Für die unteren Ebenen wurde jedoch keine Präzision ermittelt.  
ANMERKUNG 2   Für den Zweck dieser Europäischen Norm wird zur Angabe des Massenanteils einer Substanz () der Ausdruck „% (m/m)“ verwendet.

Produits petroliers - Détermination de la teneur en Benzo(a)pyrène (BaP) et en certains hydrocarbures aromatiques polycycliques (HAP) dans les huiles de dilution - Méthode par double purification chromatographique en phase liquide et par GC/MS

La présente Norme européenne prescrit une méthode de détermination de la teneur en benzo[a]pyrène (BaP)
dans les huiles de dilution couramment utilisées dans l’industrie de l’élastomère pour la production des
pneumatiques ou de parties de pneumatiques. Cette méthode permet aussi de déterminer la teneur totale en
les huit hydrocarbures aromatiques polycycliques (HAP) figurant dans le Tableau 1.
Cette procédure a été testée et vérifiée pour les HAP du Tableau 1 (ceux spécifiés par la Commission
européenne [1]) et du Tableau 2 pour d’autres HAP.
NOTE 1 L’analyse d’autres HAP est en principe possible mais il est nécessaire que l’utilisateur mette en place une
assurance qualité suffisante pour sécuriser l’analyse.
Le domaine d’application pour cette méthode est d’environ 4 mg/kg à environ 15 mg/kg pour les huit HAP
individuels et d’environ 0,5 mg/kg à environ 2 mg/kg pour le BaP.
NOTE 2 Cette méthode peut être appliquée sur des échantillons dont la teneur est de 0,1 mg/kg à 15 mg/kg. Cependant,
pour les faibles teneurs, les valeurs de fidélité n’ont pas encore été établies.
NOTE 3 Pour les besoins du présent document, le terme «% (m/m)» représente la fraction massique (ω).

Naftni proizvodi - Določevanje benzo(a)pirena (BaP) in izbranih policikličnih aromatskih ogljikovodikov (PAO) v polnilnih oljih - Postopek uporabe dvojnega LC-čiščenja in analize GC/MS

Ta evropski standard določa postopek za določevanje benzo(a)pirena (BaP) v polnilnih oljih, ki se pogosto uporabljajo v gumarski industriji za izdelavo pnevmatik ali delov pnevmatik. S to metodo dobimo tudi vsoto osmih posameznih policikličnih aromatskih ogljikovodikov (PAH), ki so navedeni v preglednici 1. Postopek je bil preskušen in preverjen za policiklične aromatske ogljikovodike, ki so navedeni v preglednici 1 (tisti, ki jih zahteva Evropska komisija [1]) in dodatne policiklične aromatske ogljikovodike, ki so navedeni v preglednici A.2. Analiza drugih policikličnih aromatskih ogljikovodikov je načeloma mogoča, vendar mora pri tem uporabnik zagotoviti zadostno kakovost, da zaščiti analizo. Obseg uporabe za to metodo je od približno 4 mg/kg do približno 15 mg/kg za osem posameznih policikličnih aromatskih ogljikovodikov in od približno 0,5 mg/kg do približno 2 mg/kg za benzo(a)piren. OPOMBA 1 Predviden delovni obseg za to metodo je od 0,1 mg/kg do 15 mg/kg. Natančnost postopka za nižje stopnje še ni določena. OPOMBA 2 V tem evropskem standardu je uporabljena oznaka »% (m/m)« in pomeni delež mase (ω).

General Information

• Status: Published
• Publication Date: 12-Feb-2013
• Withdrawal Date: 30-Aug-2013
• ICS: 75.100 - Lubricants, industrial oils and related products
• Technical Committee: CEN/TC 19 - Petroleum products, lubricants and related products
• Drafting Committee: CEN/TC 19/WG 9 - Chromatographic test methods
• Current Stage: 9093 - Decision to confirm - Review Enquiry
• Completion Date: 27-Dec-2018
• Mandate: M/413 - M/413 standardisation mandate addressed to CEN for methods of analysis to detect polycyclic aromatic hydrocarbons (PAH) in extender oils.
• Ref Project: SIST EN 16143:2013 - Petroleum products - Determination of content of Benzo(a)pyrene (BaP) and selected polycyclic aromatic hydrocarbons (PAH) in extender oils - Procedure using double LC cleaning and GC/MS analysis

Standards Content (Sample)

2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.ROLFLNOLþQLKMineralölerzeugnisse - Bestimmung des Gehaltes an Benzo(a)pyren (BaP) und ausgewählten polycyclischen Kohlenwasserstoffen (PAH) in Extenderölen - Verfahren mittels doppelter LC-Vorreinigung und GC/MS-AnalyseProduits petroliers - Détermination de la teneur en Benzo(a)pyrene (BaP) et polcyclic hydrocarbons aromatique selective en huiles extender - Méthodes par spectrométrie d'absorption atomique (SAA)Petroleum products - Determination of content of Benzo(a)pyrene (BaP) and selected polycyclic aromatic hydrocarbons (PAH) in extender oils - Procedure using double LC cleaning and GC/MS analysis75.100MazivaLubricants, industrial oils and related productsICS:Ta slovenski standard je istoveten z:EN 16143:2013SIST EN 16143:2013en,de01-april-2013SIST EN 16143:2013SLOVENSKI
STANDARD
EUROPEAN STANDARD NORME EUROPÉENNE EUROPÄISCHE NORM
EN 16143
February 2013 ICS 75.100 English Version
Petroleum products - Determination of content of Benzo(a)pyrene (BaP) and selected polycyclic aromatic hydrocarbons (PAH) in extender oils - Procedure using double LC cleaning and GC/MS analysis
Produits petroliers - Détermination de la teneur en Benzo(a)pyrène (BaP) et en certains hydrocarbures aromatiques polycycliques (HAP) dans les huiles de dilution - Méthode
par double purification chromatographique en phase liquide
et par GC/MS
Mineralölerzeugnisse - Bestimmung des Gehaltes an Benzo(a)pyren (BaP) und ausgewählten polycyclischen Kohlenwasserstoffen (PAKs) in Extenderölen - Verfahren mittels doppelter LC-Vorreinigung und GC/MS-Analyse This European Standard was approved by CEN on 14 December 2012.
CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same status as the official versions.
CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION EUROPÄISCHES KOMITEE FÜR NORMUNG
Management Centre:
Avenue Marnix 17,
B-1000 Brussels © 2013 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN 16143:2013: ESIST EN 16143:2013

Relevant physical chemical data for PAHs . 15 Annex B (informative)
Additional user information . 17 Bibliography. 22
The complexity of the sample preparation steps and subsequent GC-MS analysis showed that laboratories need sufficient expertise to properly perform the analyses described in this document. Therefore, only a limited number of laboratories were able to participate in and contribute to the Round Robin test conducted by CEN/TC 19. In consideration of the progression of the standardization project, no additional time or resources were left e.g. to conduct additional Round Robin Tests, and the test method therefore is produced in its actual form. Further experience in the future may lead to improved precision and a more comprehensive scope. SIST EN 16143:2013

The procedure has been tested and verified for the PAHs listed in Table 1 (those required by the European Commission [1]) and additional PAHs as listed in Table A.2.
Analysis of other PAHs is possible in principle, but sufficient quality assurance performed by the user is necessary to secure the analysis.
The application range for this method is from approximately 4 mg/kg to approximately 15 mg/kg for the eight individual PAHs and from approximately 0,5 mg/kg to approximately 2 mg/kg for BaP. NOTE 1 The intended working range for this method is in the 0,1 mg/kg to 15 mg/kg range. For the lower levels precision has not yet been established. NOTE 2 For the purposes of this European Standard, the term “% (m/m)” is used to represent the mass fraction (). Table 1 — List of individual PAHs in extender oils Name of PAH Abbreviation CAS Registry number benzo(a)pyrene BaP 50-32-8 benzo(e)pyrene BeP 192-97-2 benzo(a)anthracene BaA 56-55-3 chrysene CHR 218-01-9 benzo(b)fluoranthene BbFA 205-99-2 benzo(j)fluoranthene BjFA 205-82-3 benzo(k)fluoranthene BkFA 207-08-9 dibenzo(a,h)anthracene DBahA 53-70-3 See Table A.1 for additional data on some PAH.
2 Normative references The following documents, in whole or in part, are normatively referenced in this document and are indispensable for its application. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. EN ISO 3170, Petroleum liquids — Manual sampling (ISO 3170) EN ISO 3171, Petroleum liquids — Automatic pipeline sampling (ISO 3171) 3 Terms and definitions For the purposes of this document, the following terms and definitions apply. SIST EN 16143:2013
...