Fertilizers - Determination of perchlorate in mineral fertilizers by liquid chromatography and tandem mass spectrometry detection (LC-MS/MS)

This document specifies a method for the determination of traces of perchlorate with liquid chromatography and tandem mass spectrometry detection (LC‐MS/MS). The method is applicable to mineral fertilizers.

Düngemittel - Bestimmung von Perchlorat in mineralischen Düngemitteln - Bestimmung mittels Flüssig-Chromatographie und Tandem-Massenspektrometrischer Detektion (LC-MS/MS)

Dieses Dokument legt ein Verfahren zur Bestimmung von Perchloratspuren mittels Flüssigchromatographie und Tandem-Massenspektrometrie-Detektion (LC MS/MS) fest. Das Verfahren ist für mineralische Düngemittel anwendbar.

Engrais - Dosage du perchlorate dans les engrais minéraux par chromatographie liquide couplée à la spectrométrie de masse (LCMS/MS)

Le présent document spécifie une méthode de détermination des traces de perchlorate par chromatographie liquide couplée à la spectrométrie de masse (LC-MS/MS). La méthode est applicable aux engrais minéraux.

Gnojila - Določevanje perklorata v mineralnih gnojilih s tekočinsko kromatografijo in tandemsko masno spektrometrijo (LC-MS/MS)

General Information

Status
Published
Public Enquiry End Date
02-Oct-2019
Publication Date
07-Dec-2020
Technical Committee
Current Stage
6060 - National Implementation/Publication (Adopted Project)
Start Date
23-Nov-2020
Due Date
28-Jan-2021
Completion Date
08-Dec-2020

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SLOVENSKI STANDARD
SIST EN 17411:2021
01-januar-2021

Gnojila - Določevanje perklorata v mineralnih gnojilih s tekočinsko kromatografijo

in tandemsko masno spektrometrijo (LC-MS/MS)

Fertilizers - Determination of perchlorate in mineral fertilizers by liquid chromatography

and tandem mass spectrometry detection (LC-MS/MS)

Düngemittel - Bestimmung von Perchlorat in mineralischen Düngemitteln - Bestimmung

mittels Flüssig-Chromatographie und Tandem-Massenspektrometrischer Detektion (LC-

MS/MS)

Engrais - Dosage du perchlorate dans les engrais minéraux par chromatographie liquide

couplée à la spectrométrie de masse (LCMS/MS)
Ta slovenski standard je istoveten z: EN 17411:2020
ICS:
65.080 Gnojila Fertilizers
71.040.50 Fizikalnokemijske analitske Physicochemical methods of
metode analysis
SIST EN 17411:2021 en,fr,de

2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

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SIST EN 17411:2021
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SIST EN 17411:2021
EN 17411
EUROPEAN STANDARD
NORME EUROPÉENNE
November 2020
EUROPÄISCHE NORM
ICS 65.080
English Version
Fertilizers - Determination of perchlorate in mineral
fertilizers by liquid chromatography and tandem mass
spectrometry detection (LC-MS/MS)

Engrais - Dosage du perchlorate dans les engrais Düngemittel - Bestimmung von Perchlorat in

minéraux par chromatographie liquide couplée à la mineralischen Düngemitteln - Bestimmung mittels

spectrométrie de masse (LC-MS/MS) Flüssig-Chromatographie und Tandem-
Massenspektrometrischer Detektion (LC-MS/MS)
This European Standard was approved by CEN on 4 October 2020.

CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this

European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references

concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN

member.

This European Standard exists in three official versions (English, French, German). A version in any other language made by

translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management

Centre has the same status as the official versions.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,

Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway,

Poland, Portugal, Republic of North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and

United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION
EUROPÄISCHES KOMITEE FÜR NORMUNG
CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels

© 2020 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN 17411:2020 E

worldwide for CEN national Members.
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SIST EN 17411:2021
EN 17411:2020 (E)
Contents Page

European foreword ....................................................................................................................................................... 3

1 Scope .................................................................................................................................................................... 4

2 Normative references .................................................................................................................................... 4

3 Terms and definitions ................................................................................................................................... 4

4 Principle ............................................................................................................................................................. 4

5 Reagents ............................................................................................................................................................. 4

6 Apparatus and equipment ........................................................................................................................... 5

7 Procedure........................................................................................................................................................... 5

7.1 Sampling and sample preparation ............................................................................................................ 5

7.2 Matrix calibration curve ............................................................................................................................... 5

7.3 Determination of perchlorate in test solutions .................................................................................... 6

8 Calculation ......................................................................................................................................................... 7

9 Precision ............................................................................................................................................................. 7

9.1 Inter-laboratory test ...................................................................................................................................... 7

9.2 Repeatability ..................................................................................................................................................... 7

9.3 Reproducibility ................................................................................................................................................ 7

10 Additional remarks ........................................................................................................................................ 8

11 Test report ......................................................................................................................................................... 8

Annex A (informative) Results of the inter-laboratory test .......................................................................... 9

Bibliography ................................................................................................................................................................. 10

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SIST EN 17411:2021
EN 17411:2020 (E)
European foreword

This document (EN 17411:2020) has been prepared by Technical Committee CEN/TC 260 “Fertilizers

and liming materials”, the secretariat of which is held by DIN.

This European Standard shall be given the status of a national standard, either by publication of an

identical text or by endorsement, at the latest by May 2021, and conflicting national standards shall be

withdrawn at the latest by May 2021.

Attention is drawn to the possibility that some of the elements of this document may be the subject of

patent rights. CEN shall not be held responsible for identifying any or all such patent rights.

According to the CEN-CENELEC Internal Regulations, the national standards organisations of the

following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria,

Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland,

Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Republic of

North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the

United Kingdom.
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SIST EN 17411:2021
EN 17411:2020 (E)
1 Scope

This document specifies a method for the determination of traces of perchlorate by liquid

chromatography and tandem mass spectrometry detection (LC-MS/MS). The method is applicable to

mineral fertilizers.
2 Normative references

The following documents are referred to in the text in such a way that some or all of their content

constitutes requirements of this document. For dated references, only the edition cited applies. For

undated references, the latest edition of the referenced document (including any amendments) applies.

EN 1482-2, Fertilizers and liming materials — Sampling and sample preparation — Part 2: Sample

preparation

EN 12944-1, Fertilizers and liming materials and soil improvers — Vocabulary — Part 1: General terms

EN 12944-2, Fertilizers and liming materials and soil improvers — Vocabulary — Part 2: Terms relating

to fertilizers

EN ISO 3696, Water for analytical laboratory use — Specification and test methods (ISO 3696)

3 Terms and definitions

For the purposes of this document, the terms and definitions given in EN 12944-1 and EN 12944-2

apply.

ISO and IEC maintain terminological databases for use in standardization at the following addresses:

— IEC Electropedia: available at http://www.electropedia.org/
— ISO Online browsing platform: available at https://www.iso.org/obp
4 Principle
The perchlorate content of the fertilizer sample is determined by li
...

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