Influence of cementitious products on water intended for human consumption — Test methods — Part 2: Influence of migration from siteapplied cementitious products and associated noncementitious products on the organoleptic parameters

This standard describes a test method for laboratory evaluation of possible adverse effects of siteapplied cementitious products on drinking water quality with respect to organoleptic parameters

Einfluss zementgebundener Produkte auf Wasser für den menschlichen Gebrauch - Prüfverfahren - Teil 2: Einfluss der Migration von bauseits angewendeten zementgebundenen Produkten und zugehörigen nicht zementgebundenen Produkten auf organoleptische Parameter

Vpliv cementnih proizvodov na pitno vodo - Preskusne metode - 2. del: Vpliv prehajanja snovi iz cementnih proizvodov, uporabljenih na terenu, in pripadajočih necementnih proizvodov na organoleptične parametre

General Information

Status
Not Published
Public Enquiry End Date
13-Jul-2023
Current Stage
4020 - Public enquire (PE) (Adopted Project)
Start Date
04-May-2023
Due Date
21-Sep-2023
Completion Date
02-Aug-2023

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SLOVENSKI STANDARD
oSIST prEN 14944-2:2023
01-julij-2023
Vpliv cementnih proizvodov na pitno vodo - Preskusne metode - 2. del: Vpliv
prehajanja snovi iz cementnih proizvodov, uporabljenih na terenu, in pripadajočih
necementnih proizvodov na organoleptične parametre
Influence of cementitious products on water intended for
human consumption — Test methods — Part 2: Influence of migration from
siteapplied cementitious products and associated noncementitious
products on the organoleptic parameters
Einfluss zementgebundener Produkte auf Wasser für den menschlichen Gebrauch -
Prüfverfahren - Teil 2: Einfluss der Migration von bauseits angewendeten
zementgebundenen Produkten und zugehörigen nicht zementgebundenen Produkten
auf organoleptische Parameter
Ta slovenski standard je istoveten z: prEN 14944-2
ICS:
13.060.20 Pitna voda Drinking water
67.250 Materiali in predmeti v stiku z Materials and articles in
živili contact with foodstuffs
91.100.10 Cement. Mavec. Apno. Malta Cement. Gypsum. Lime.
Mortar
oSIST prEN 14944-2:2023 en,fr,de
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

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oSIST prEN 14944-2:2023

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oSIST prEN 14944-2:2023


DRAFT
EUROPEAN STANDARD
prEN 14944-2
NORME EUROPÉENNE

EUROPÄISCHE NORM

April 2023
ICS
English Version

Influence of cementitious products on water intended for
human consumption - Test methods - Part 2: Influence of
migration from siteapplied cementitious products and
associated noncementitious products on the organoleptic
parameters
 Einfluss zementgebundener Produkte auf Wasser für
den menschlichen Gebrauch - Prüfverfahren - Teil 2:
Einfluss der Migration von bauseits angewendeten
zementgebundenen Produkten und zugehörigen nicht
zementgebundenen Produkten auf organoleptische
Parameter
This draft European Standard is submitted to CEN members for enquiry. It has been drawn up by the Technical Committee
CEN/TC 164.

If this draft becomes a European Standard, CEN members are bound to comply with the CEN/CENELEC Internal Regulations
which stipulate the conditions for giving this European Standard the status of a national standard without any alteration.

This draft European Standard was established by CEN in three official versions (English, French, German). A version in any other
language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC
Management Centre has the same status as the official versions.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway,
Poland, Portugal, Republic of North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Türkiye and
United Kingdom.

Recipients of this draft are invited to submit, with their comments, notification of any relevant patent rights of which they are
aware and to provide supporting documentation.

Warning : This document is not a European Standard. It is distributed for review and comments. It is subject to change without
notice and shall not be referred to as a European Standard.


EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATIO N

EUROPÄISCHES KOMITEE FÜR NORMUN G

CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2023 CEN All rights of exploitation in any form and by any means reserved Ref. No. prEN 14944-2:2023 E
worldwide for CEN national Members.

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oSIST prEN 14944-2:2023
prEN 14944-2:2023(E)
Contents Page
European foreword . 6
1 Scope . 7
2 Normative references . 7
3 Terms and definitions . 8
4 Principle . 12
5 Reagents . 12
5.1 Chlorine neutralization reagents . 12
5.2 Waters to be used for testing . 13
5.3 Cleaning liquids for apparatus . 14
6 Apparatus . 14
6.1 General. 14
6.2 Apparatus and materials for test piece preparation (see Annexes A, B and C) . 14
6.3 Apparatus and materials for preconditioning and migration procedure . 15
6.4 Apparatus for odour and flavour assessment . 15
6.5 Apparatus for colour and turbidity assessment . 15
7 Samples and test pieces . 16
7.1 Sampling, transport and storage of samples. 16
7.2 Preparation of test pieces . 16
7.3 Surface area to volume ratio (S/V) for use in the test procedure . 16
8 Pre-treatment of samples (curing and preconditioning) . 17
8.1 General. 17
8.2 Preconditioning . 17
9 Test procedure . 17
9.1 General. 17
9.2 Preparation of migration water for the assessment of odour, flavour, colour, turbidity
and TOC . 18
9.3 Control samples (blank test) . 18
10 Determination of odour as TON and flavour as TFN . 18
11 Determination of colour and turbidity . 19
12 Determination of TOC and calculation of test results . 19
12.1 Determination of TOC. 19
12.2 Calculation of test results. 19
13 Expression of results . 20
14 Test report . 20
14.1 General. 20
14.2 General information . 20
14.3 Information on the product . 21
14.4 Information on the test procedure . 21
14.5 Test results . 22
2

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oSIST prEN 14944-2:2023
prEN 14944-2:2023 (E)
Annex A (informative) Testing and assessing organoleptic parameters and migration of
organic substances (TOC) from the constituents of concrete . 23
A.1 Introduction . 23
A.2 Scope . 23
A.3 Normative references . 24
A.4 Terms and definitions . 24
A.5 Principle . 24
A.6 Reagents . 25
A.7 Apparatus . 25
A.8 Reference (or control) concrete . 25
A.9 Sampling of constituents . 26
A.10 Control mix, test mixes and test pieces . 26
A.11 Concrete mixing and compacting procedure . 28
A.12 Curing and preconditioning of test pieces . 28
A.13 Surface area to volume (S/V) ratio . 29
A.14 Test procedure . 29
A.15 Test arrangement . 29
A.16 Assessment of unapproved constituents . 29
A.17 Test report . 31
Annex B (informative) Testing and assessing organoleptic parameters and migration of
organic substances (TOC) from the constituents of mortars . 32
B.1 Introduction . 32
B.2 Scope . 32
B.3 Normative references . 33
B.4 Terms and definitions . 33
B.5 Principle . 33
B.6 Reagents . 34
B.7 Apparatus . 34
B.8 Reference (or control) mortar . 34
B.9 Sampling of constituents . 35
B.10 Control mix, test mix and test pieces . 35
B.11 Mortar mixing and compacting procedure . 37
B.12 Curing and preconditioning of test pieces . 37
B.13 Surface area to volume (S/V) ratio . 37
B.14 Test procedure . 37
B.15 Test arrangement . 37
B.16 Assessment of unapproved constituents . 38
B.17 Test report . 39
Annex C (normative) Testing and assessing organoleptic parameters and migration of
organic substances (TOC) from associated non-cement based products/materials . 40
3

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oSIST prEN 14944-2:2023
prEN 14944-2:2023(E)
C.1 Introduction . 40
C.2 Scope . 40
C.3 Normative references . 41
C.4 Terms and definitions . 41
C.5 Principle . 41
C.6 Reagents . 41
C.7 Apparatus . 41
C.8 Reference (or control) concrete/mortar. 41
C.9 Sampling of constituents and unapproved products . 41
C.10 Control mix, test mix and test pieces . 41
C.11 Concrete/mortar mixing and compacting procedure . 42
C.12 Curing and preconditioning of test pieces . 42
C.13 Surface area to volume (S/V) ratio . 43
C.14 Test procedure . 43
C.15 Test arrangement . 43
C.16 Assessment of unapproved products . 43
C.17 Test report . 43
Annex D (informative) Examples of typical test pieces and test conditions as a function of
S/V ratio . 44
Annex E (informative) Test arrangements for site-applied cement based materials and
associated non-cement based products/materials . 45
Annex F (informative) Additional procedures for testing site-applied cement based products
at elevated temperature . 47
F.1 General. 47
F.2 Test procedure at elevated temperature . 47
F.3 Control samples (blank test) . 47
F.4 Expression of results . 47
F.5 Reporting . 47
Annex G (informative) Discrimination between porous and non-porous coating on site
applied cement based products . 48
G.1 Principle . 48
G.2 Apparatus . 48
G.3 Materials and reagents . 48
G.4 Test procedure . 48
G.5 Determination of pH . 49
G.6 Expression of results . 49
G.7 Classification criteria . 49
Annex H (informative) Schematic description of the test procedure . 50
H.1 Preconditioning . 50
4

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oSIST prEN 14944-2:2023
prEN 14944-2:2023 (E)
H.2 Production of migration water at 23 °C . 51
H.3 Typical Schedule . 52
Annex I (informative) Procedural tests using standard additions (positive control) . 53
Bibliography . 54

5

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oSIST prEN 14944-2:2023
prEN 14944-2:2023(E)
European foreword
This document (prEN 14944-2:2023) has been prepared by Technical Committee CEN/TC 164 “Water
supply”, the secretariat of which is held by AFNOR.
This document is currently submitted to the CEN Enquiry.
This document describes a test method to determine the influence(s) of site-applied cement based
materials and associated non-cement based products/materials on organoleptic parameters and the
migration of organic substances (TOC) in water intended for human consumption.
This document will result in one of a series of standards that support standards for the approval of
products and materials in contact with water intended for human consumption.
This document is part of a series dealing with the influence of cement based and associated non-cement
based products/materials on water intended for human consumption, including:
— Part 1: Influence of factory-made cement based products on organoleptic parameters and migration of
organic substances (TOC)
— Part 2: Influence of site-applied cement based materials and associated non-cement based
products/materials on organoleptic parameters and migration of organic substances (TOC)
— Part 3: Migration of substances from factory-made cement based products.
— Part 4: Migration of substances from site-applied cement based materials and associated non-cement
based products/materials.
6

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oSIST prEN 14944-2:2023
prEN 14944-2:2023 (E)
1 Scope
This document specifies a method to determine the influence of site-applied cement based materials and
associated non-cement based products/materials (including pre-packaged mortars) on the odour,
flavour, colour, turbidity and total organic carbon (TOC) of test waters after contact with the products.
This document is applicable to site-applied or site-formed cement based materials intended to be used
for the transport and storage of water intended for human consumption, including raw water used for
the production of drinking water. It is also applicable to individual constituents of cement based
products/materials and to associated non-cement based products/materials.
Site-applied or site-formed cement based materials which cannot be cast as cubes or prisms e.g. some
spray applied systems, should be tested as factory made cement based products according to
EN 14944−1.
NOTE Tests with the specified test water will not necessarily be representative of materials used in different
kinds of waters and especially very soft waters.
2 Normative references
The following documents are referred to in the text in such a way that some or all of their content
constitutes requirements of this document. For dated references, only the edition cited applies. For
undated references, the latest edition of the referenced document (including any amendments) applies.
EN 196-1, Methods of testing cement - Part 1: Determination of strength
EN 197-1, Cement - Part 1: Composition, specifications and conformity criteria for common cements
EN 206-1, Concrete - Part 1:- Specification, performance, production and conformity
EN 450-1, Fly ash for concrete - Part 1: Definition, specifications and conformity criteria
EN 480-1, Admixtures for concrete, mortar and grout - Test methods - Part 1: Reference concrete and
reference mortar for testing
EN 1420:2016, Influence of organic materials on water intended for human consumption - Determination
of odour and flavour assessment of water in piping systems
EN 1484, Water analysis - Guidelines for the determination of total organic carbon (TOC) and dissolved
organic carbon (DOC)
EN 1622:2006, Water quality - Determination of the threshold odour number (TON) and threshold flavour
number (TFN)
EN 10088-1:2014, Stainless steels - Part 1: List of stainless steels
EN 12350-1, Testing fresh concrete - Part 1: Sampling and common apparatus
EN 12390-1, Testing hardened concrete - Part 1: Shape, dimensions and other requirements for specimens
and moulds
EN 12620, Aggregates for concrete
EN 12878, Pigments for the colouring of building materials based on cement and/or lime - Specifications
and methods of test
7

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oSIST prEN 14944-2:2023
prEN 14944-2:2023(E)
EN 13055, Lightweight aggregates
EN 13263-1, Silica fume for concrete - Part 1: Definitions, requirements and conformity criteria
EN 13639, Determination of total organic carbon in limestone
EN 14944-1, Influence of cementitious products on water intended for human consumption - Test methods
- Part 1: Influence of factory made cementitious products on organoleptic parameters
EN 14944-3, Influence of cementitious products on water intended for human consumption - Test methods
- Part 3: Migration of substances from factory-made cementititous products
EN 15167-1, Ground granulated blast furnace slag for use in concrete, mortar and grout - Part 1:
Definitions, specifications and conformity criteria
EN 16421, Influence of materials on water for human consumption - Enhancement of microbial growth
(EMG)
EN 27888, Water quality - Determination of electrical conductivity (ISO 7888:1985)
EN ISO 3696, Water for analytical laboratory use - Specification and test methods (ISO 3696)
EN ISO 7027, Water quality - Determination of turbidity (ISO 7027)
EN ISO 7393-1, Water quality - Determination of free chlorine and total chlorine - Part 1: Titrimetric
method using N, N-diethyl-1,4-phenylenediamine (ISO 7393)
EN ISO 7393-2, Water quality - Determination of free chlorine and total chlorine - Part 2: Colorimetric
method using N,N-dialkyl-1,4-phenylenediamine, for routine control purposes (ISO 7393-2:2017)
EN ISO 7887:2011, Water quality - Examination and determination of colour (ISO 7887:2011)
EN ISO 9963-2, Water quality - Determination of alkalinity - Part 2: Determination of carbonate alkalinity
(ISO 9963-2)
EN ISO 10523, Water quality - Determination of pH (ISO 10523)
EN ISO 16264, Water quality - Determination of soluble silicates by flow analysis (FIA and CFA) and
photometric detection (ISO 16264)
ISO 6058, Water quality — Determination of calcium content — EDTA titrimetric method
3 Terms and definitions
For the purposes of this document, the following terms and definitions apply.
ISO and IEC maintain terminology databases for use in standardization at the following addresses:
— ISO Online browsing platform: available at https://www.iso.org/obp/
— IEC Electropedia: available at https://www.electropedia.org/
3.1
appropriate body
certification body, inspection body or test laboratory, as relevant to a particular requirement
8

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oSIST prEN 14944-2:2023
prEN 14944-2:2023 (E)
3.2
cement based product
factory-made product containing a cement based material supplied in the hardened state with a formed
surface prior to its incorporation into the construction works
3.3
cement based material
material that contains a hydraulic cement in sufficient proportion to act as the main binder by forming a
hydrate structure which governs the performance of the material
3.4
associated non-cement based product
product which is applied to the surface of a cement based product, directly or indirectly, during
manufacture (or construction) and which either provides a porous seal to the product or which remains
as a residue in contact with water, e.g. porous seal coats, formwork release agents and curing compounds
3.5
porous seal coat
polymeric (usually organic) materials applied in a thin (25 μm – 200 μm thickness) surface layer to a
cement mortar lining in order to restrict (but not prevent) interactions between the mortar and conveyed
water (see Annex G)
Note 1 to entry: See also ISO 16132.
3.6
proxy sample
sample of fresh mortar or fresh concrete taken from material to be used for the production of a factory-
made product, either applied to one face of a stainless steel plate (6.2.1) using the same process of
application used in the factory (mortar only) or cast into a mould (mortar or concrete) of appropriate
dimensions (e.g. standard cube, cylinder or prism, etc.) and compacted (where appropriate), cured and
hardened under conditions representative of those intended for the product
3.7
fresh concrete
concrete that is fully mixed
...

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