oSIST prEN IEC 62321-14:2025
(Main)Determination of certain substances in electrotechnical products - Part 14: Determination of short-chain chlorinated paraffins (SCCPs) and medium-chain chlorinated paraffins (MCCPs) in electrotechnical products by gas chromatography-negative chemical ionization-mass spectrometry (GC-NCI-MS)
Determination of certain substances in electrotechnical products - Part 14: Determination of short-chain chlorinated paraffins (SCCPs) and medium-chain chlorinated paraffins (MCCPs) in electrotechnical products by gas chromatography-negative chemical ionization-mass spectrometry (GC-NCI-MS)
DÉTERMINATION DE CERTAINES SUBSTANCES DANS LES PRODUITS ÉLECTROTECHNIQUES - Partie 14: Détermination des paraffines chlorées à chaîne courte (PCCC) et des paraffines chlorées à chaîne moyenne (PCCM) dans des produits électrotechniques par chromatographie en phase gazeuse couplée à la spectrométrie de masse avec ionisation chimique négative (GC-NCI-MS)
Določevanje posameznih snovi v elektrotehničnih izdelkih - 14. del: Določevanje kloriranih parafinov (SCCP) s kratko verigo in kloriranih parafinov s srednje dolgo verigo (MMCCP) v elektrotehničnih izdelkih s plinsko kromatografijo - negativno kemijsko ionizacijo - masno spektrometrijo (GC-NCI-MS)
General Information
Standards Content (Sample)
SLOVENSKI STANDARD
01-april-2025
Določevanje posameznih snovi v elektrotehničnih izdelkih - 14. del: Določevanje
kloriranih parafinov (SCCP) s kratko verigo in kloriranih parafinov s srednje dolgo
verigo (MMCCP) v elektrotehničnih izdelkih s plinsko kromatografijo - negativno
kemijsko ionizacijo - masno spektrometrijo (GC-NCI-MS)
Determination of certain substances in electrotechnical products - Part 14: Determination
of short-chain chlorinated paraffins (SCCPs) and medium-chain chlorinated paraffins
(MCCPs) in electrotechnical products by gas chromatography-negative chemical
ionization-mass spectrometry (GC-NCI-MS)
DÉTERMINATION DE CERTAINES SUBSTANCES DANS LES PRODUITS
ÉLECTROTECHNIQUES - Partie 14: Détermination des paraffines chlorées à chaîne
courte (PCCC) et des paraffines chlorées à chaîne moyenne (PCCM) dans des produits
électrotechniques par chromatographie en phase gazeuse couplée à la spectrométrie de
masse avec ionisation chimique négative (GC-NCI-MS)
Ta slovenski standard je istoveten z: prEN IEC 62321-14:2025
ICS:
13.020.01 Okolje in varstvo okolja na Environment and
splošno environmental protection in
general
43.040.10 Električna in elektronska Electrical and electronic
oprema equipment
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.
111/802/CDV
COMMITTEE DRAFT FOR VOTE (CDV)
PROJECT NUMBER:
IEC 62321-14 ED1
DATE OF CIRCULATION: CLOSING DATE FOR VOTING:
2025-01-31 2025-04-25
SUPERSEDES DOCUMENTS:
111/719/CD, 111/743/CC
IEC TC 111 : ENVIRONMENTAL STANDARDIZATION FOR ELECTRICAL AND ELECTRONIC PRODUCTS AND SYSTEMS
SECRETARIAT: SECRETARY:
Italy Mr Alfonso Sturchio
OF INTEREST TO THE FOLLOWING COMMITTEES: HORIZONTAL FUNCTION(S):
TC 2,TC 9,TC 18,TC 20,TC 21,TC 23,TC 34,SC 34D,TC TC 111 Horizontal Basic Environment - Assessment
59,TC 62,SC 65B,TC 80,TC 82,TC 88,TC 91,TC 100,TC
110,TC 121,TC 124,TC 125
ASPECTS CONCERNED:
Environment
SUBMITTED FOR CENELEC PARALLEL VOTING NOT SUBMITTED FOR CENELEC PARALLEL VOTING
Attention IEC-CENELEC parallel voting
The attention of IEC National Committees, members of
CENELEC, is drawn to the fact that this Committee Draft for
Vote (CDV) is submitted for parallel voting.
The CENELEC members are invited to vote through the
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This document is still under study and subject to change. It should not be used for reference purposes.
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clauses to be included should this proposal proceed. Recipients are reminded that the CDV stage is the final stage for
submitting ISC clauses. (SEE AC/22/2007 OR NEW GUIDANCE DOC).
TITLE:
DETERMINATION OF CERTAIN SUBSTANCES IN ELECTROTECHNICAL PRODUCTS – Part 14:
Determination of short-chain chlorinated paraffins (SCCPs) and medium-chain chlorinated paraffins
(MCCPs) in electrotechnical products by gas chromatography-negative chemical ionization-mass
spectrometry (GC-NCI-MS)
electronic file, to make a copy and to print out the content for the sole purpose of preparing National Committee positions.
You may not copy or "mirror" the file or printed version of the document, or any part of it, for any other purpose without
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PROPOSED STABILITY DATE: 2029
NOTE FROM TC/SC OFFICERS:
TC 111 WG 3 confirmed that this CDV document met the two criteria to skip the second IIS approved by NCs
(111/777/RQ).
- The first IIS is performed according to the IIS minimum requirements
- There are no significant technical changes in the standard
Based on the agreement at the TC 111 WG 3 meeting held on November 12, 2024, in Okayama, the CDV will
be circulated.
IEC CDV 62321-14 © IEC 2024 – 3 – 111/802/CDV
1 CONTENTS
3 FOREWORD . 5
4 INTRODUCTION . 7
5 1 Scope . 8
6 2 Normative references. 8
7 3 Terms, definitions and abbreviated terms . 8
8 3.1 Terms and definitions . 8
9 3.2 Abbreviated terms . 9
10 4 Principle . 9
11 5 Reagents and materials . 9
12 6 Apparatus . 10
13 7 Sampling. 10
14 8 Procedure . 10
15 8.1 Sample preparation . 10
16 8.2 Instrumental parameters . 11
17 8.3 Calibrants. 12
18 8.4 Calibration. 12
19 9 Calculation of SCCPs and MCCPs concentration . 14
20 9.1 General . 14
21 9.2 Calculation . 14
22 10 Precision . 16
23 11 Quality assurance and quality control . 17
24 11.1 Performance . 17
25 11.2 Method detection limit and reporting limit . 18
26 12 Test report . 18
27 Annex A (informative) Additional GC-NCI-MS conditions . 19
28 Annex B (normative) Integration with Peak Shape Evaluation (PSE) . 20
29 Annex C (informative) Results of international interlaboratory study of Pre-IIS (Pre-IIS14-
30 SCCP&MCCP) . 23
31 Bibliography . 24
33 Figure B.1 – SCCPs standard 59 % Chlorides, different ion traces. . 20
34 Figure B.2 – Examples for matching samples compared with SCCPs standard 59 % Chlorides,
35 upper chromatogram standard, lower chromatogram sample. . 21
36 Figure B.3 – Examples for partly matched samples compared with SCCPs standard 59 %
37 Chlorides, upper chromatogram standard, lower chromatogram sample. . 21
38 Figure B.4 – MCCPs standard 55 % Chlorides, different ion traces. . 21
39 Figure B.5 – Examples for matching samples compared with MCCPs standard 55 % Chlorides,
40 upper chromatogram standard, lower chromatogram sample. . 22
41 Figure B.6 – Examples for partly matched samples compared with MCCPs standard 55 %
42 Chlorides, upper chromatogram standard, lower chromatogram sample. . 22
IEC CDV 62321-14 © IEC 2024 – 4 – 111/802/CDV
44 Table 1. Mass for quantification and qualification of SCCPs and MCCPs . 11
45 Table 2 – Commercially available SCCPs and MCCPs reference material considered suitable
46 for this analysis . 12
47 Table 3 – Example mixing ratio of SCCPs 59 % Chlorides content and MCCPs 55 % Chlorides
48 content . 13
49 Table 4 – Pre-IIS 14 repeatability and reproducibility for SCCPs . 16
50 Table 5 – Pre-IIS 14 repeatability and reproducibility for MCCPs . 16
51 Table A.1 – Instrument parameters for GC-NCI-MS . 19
52 Table C.1 – Statistical data for GC-NCI-MS . 23
IEC CDV 62321-14 © IEC 2024 – 5 – 111/802/CDV
56 INTERNATIONAL ELECTROTECHNICAL COMMISSION
57 ____________
58 DETERMINATION OF CERTAIN SUBSTANCES
59 IN ELECTROTECHNICAL PRODUCTS –
61 Part 14: Short-chain chlorinated paraffins (SCCPs) and medium-chain
62 chlorinated paraffins (MCCPs) in plastics by gas chromatography-negative
63 chemical ionization-mass spectrometry (GC-NCI-MS)
65 FOREWORD
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96 International Standard IEC 62321-14 has been prepared by IEC technical committee 111: Environmental
97 standardization for electrical and electronic products and systems.
98 The text of this International Standard is based on the following documents:
FDIS Report on voting
XX/XX/XXX XX/XX/XXX
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IEC CDV 62321-14 © IEC 2024 – 6 – 111/802/CDV
The committee has de
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