SIST EN IEC 62321-11:2024

Determination of certain substances in electrotechnical products - Part 11: Tris (2-chloroethyl) phosphate (TCEP) in plastics by gas chromatography-mass spectrometry (GC-MS) and liquid chromatography-mass spectrometry (LC-MS)

This part of IEC 62321 specifies two different techniques for the determination of
tris(2-chloroethyl) phosphate (TCEP) in plastics, the GC-MS or LC-MS method, both of which
are applicable to quantitative analysis.
These two techniques are applicable to use with polyurethane, polyvinylchloride, and
polyethylene materials containing TCEP between 200 mg/kg to 2 000 mg/kg.
These test methods do not apply to plastic materials having a processing temperature higher
than 230 °C.
GC-MS using a pyrolyser/thermal desorption accessory (Py/TD-GC-MS) technique is described
in Annex A and can be used for the screening of TCEP in plastics.
NOTE TCEP starts thermal decomposition at approximately 230 °C. Polymer types that have a processing
temperature into shapes of plastics (e.g. pellets, moulded parts or sheets) not exceeding the decomposition
temperature can contain TCEP.

Določevanje posameznih snovi v elektrotehničnih izdelkih - 11. del: Določevanje ? tris (2-kloroetil) fosfata (TCEP) v plastiki ? polimernih materialih ? s plinsko kromatografijo-masno spektrometrijo (GC-MS) in tekočinsko kromatografijo-masno spektrometrijo (LC-MS)

Détermination de certaines substances dans les produits électrotechniques - Partie 11: Phosphate de tris(2-chloroéthyle) (TCEP) dans les plastiques par chromatographie en phase gazeuse-spectrométrie de masse (GC-MS) et chromatographie en phase liquide-spectrométrie de masse (LC-MS)

L'IEC 62321-11:2023 spécifie deux techniques différentes pour la détermination du phosphate de tris(2‑chloroéthyle) (TCEP) dans les plastiques, à savoir la méthode GC-MS et la méthode LC-MS, qui s'appliquent toutes les deux pour une analyse quantitative. Ces deux techniques s'appliquent aux matériaux en polyuréthane, en polychlorure de vinyle et en polyéthylène qui contiennent entre 200 mg/kg et 2 000 mg/kg de TCEP. Ces méthodes d'essai ne s'appliquent pas aux matières plastiques dont la température de mise en œuvre est supérieure à 230 °C. La technique de GC-MS à l'aide d'un pyrolyseur/accessoire de désorption thermique (Py/TD-GC-MS) est décrite à l'Annexe A et peut être utilisée pour la détection du TCEP dans les plastiques.

Določevanje posameznih snovi v elektrotehničnih izdelkih - 11. del: Določevanje tri(2-kloroetil) fosfata (TCEP) v polimernih materialih s plinsko kromatografijo in masno spektrometrijo (GC-MS) ter tekočinsko kromatografijo in masno spektrometrijo (LC-MS)

Ta del standarda IEC 62321 določa različni tehniki za določevanje tri(2-kloroetil) fosfata (TCEP) v polimernih materialih s plinsko kromatografijo in masno spektrometrijo (GC-MS) ter tekočinsko kromatografijo in masno spektrometrijo (LC-MS), oba postopka pa se uporabljata za kvantitativno analizo.
Obe tehniki se uporabljata s poliuretanskimi, polivinilkloridnimi in polietilenskimi materiali z vsebnostjo tri(2-kloroetil) fosfata med 200 mg/kg in 2000 mg/kg.
Metodi se ne uporabljata za polimerne materiale, ki imajo temperaturo obdelave večjo od 230 °C.
Plinska kromatografija in masna spektrometrija, ki uporablja tehniko za pirolizo/toplotno desorpcijo (Py/TD-GC-MS), je opisana v dodatku A in jo je mogoče uporabiti za presejanje tri(2-kloroetil) fosfata v polimernih materialih.
OPOMBA: Tri(2-kloroetil) fosfat sproži termično razgradnjo pri približno 230 °C. Vrste polimerov, ki imajo temperaturo obdelave v oblike polimernih materialov (npr. kroglice, vliti deli ali pločevina), ki ne presega temperature razgradnje, lahko vsebujejo tri(2-kloroetil) fosfat.

General Information

• Status: Published
• Public Enquiry End Date: 23-Mar-2022
• Publication Date: 14-Feb-2024
• ICS: 13.020.01 - Environment and environmental protection in general
• ICS: 29.020 - Electrical engineering in general
• ICS: 31.020 - Electronic components in general
• ICS: 43.040.10 - Electrical and electronic equipment
• ICS: 71.040.50 - Physicochemical methods of analysis
• Technical Committee: ITIV - Electronics assembly technology and Environmental standardization
• Current Stage: 6060 - National Implementation/Publication (Adopted Project)
• Start Date: 31-Jan-2024
• Due Date: 06-Apr-2024
• Completion Date: 15-Feb-2024
• Ref Project: EN IEC 62321-11:2024 - Determination of certain substances in electrotechnical products - Part 11: Tris(2-chloroethyl) phosphate (TCEP) in plastics by gas chromatography-mass spectrometry (GC-MS) and liquid chromatography-mass spectrometry (LC-MS)

Standards Content (Sample)

SLOVENSKI STANDARD
SIST EN IEC 62321-11:2024
01-marec-2024
Določevanje posameznih snovi v elektrotehničnih izdelkih - 11. del: Določevanje
tri(2-kloroetil) fosfata (TCEP) v polimernih materialih s plinsko kromatografijo in
masno spektrometrijo (GC-MS) ter tekočinsko kromatografijo in masno
spektrometrijo (LC-MS)
Determination of certain substances in electrotechnical products - Part 11: Tris (2-
chloroethyl) phosphate (TCEP) in plastics by gas chromatography-mass spectrometry
(GC-MS) and liquid chromatography-mass spectrometry (LC-MS)
Določevanje posameznih snovi v elektrotehničnih izdelkih - 11. del: Določevanje ? tris (2-
kloroetil) fosfata (TCEP) v plastiki ? polimernih materialih ? s plinsko kromatografijo-
masno spektrometrijo (GC-MS) in tekočinsko kromatografijo-masno spektrometrijo (LC-
MS)
Détermination de certaines substances dans les produits électrotechniques - Partie 11:
Phosphate de tris(2-chloroéthyle) (TCEP) dans les plastiques par chromatographie en
phase gazeuse-spectrométrie de masse (GC-MS) et chromatographie en phase liquide-
spectrométrie de masse (LC-MS)
Ta slovenski standard je istoveten z: EN IEC 62321-11:2024
ICS:
29.020 Elektrotehnika na splošno Electrical engineering in
general
31.020 Elektronske komponente na Electronic components in
splošno general
71.040.50 Fizikalnokemijske analitske Physicochemical methods of
metode analysis
SIST EN IEC 62321-11:2024 en
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

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SIST EN IEC 62321-11:2024


EUROPEAN STANDARD EN IEC 62321-11

NORME EUROPÉENNE

EUROPÄISCHE NORM January 2024
ICS 13.020.01; 43.040.10

English Version
Determination of certain substances in electrotechnical products
- Part 11: Tris(2-chloroethyl) phosphate (TCEP) in plastics by
gas chromatography-mass spectrometry (GC-MS) and liquid
chromatography-mass spectrometry (LC-MS)
(IEC 62321-11:2023)
Détermination de certaines substances dans les produits Verfahren zur Bestimmung von bestimmten Substanzen in
électrotechniques - Partie 11: Phosphate de tris(2- Produkten der Elektrotechnik - Teil 11: Tris(2-
chloroéthyle) (TCEP) dans les plastiques par chlorethyl)phosphat (TCEP) in Kunststoffen mit
chromatographie en phase gazeuse-spectrométrie de Gaschromatographie-Massenspektrometrie (GC-MS) und
masse (GC-MS) et chromatographie en phase liquide- Flüssigkeitschromatographie-Massenspektrometrie
spectrométrie de masse (LC-MS) (LC-MS)
(IEC 62321-11:2023) (IEC 62321-11:2023)
This European Standard was approved by CENELEC on 2024-01-19. CENELEC members are bound to comply with the CEN/CENELEC
Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration.
Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN-CENELEC
Management Centre or to any CENELEC member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by translation
under the responsibility of a CENELEC member into its own language and notified to the CEN-CENELEC Management Centre has the
same status as the official versions.
CENELEC members are the national electrotechnical committees of Austria, Belgium, Bulgaria, Croatia, Cyprus, the Czech Republic,
Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, the
Netherlands, Norway, Poland, Portugal, Republic of North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland,
Türkiye and the United Kingdom.


European Committee for Electrotechnical Standardization
Comité Européen de Normalisation Electrotechnique
Europäisches Komitee für Elektrotechnische Normung
CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2024 CENELEC All rights of exploitation in any form and by any means reserved worldwide for CENELEC Members.
 Ref. No. EN IEC 62321-11:2024 E

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SIST EN IEC 62321-11:2024
EN IEC 62321-11:2024 (E)
European foreword
The text of document 111/723/FDIS, future edition 1 of IEC 62321-11, prepared by IEC/TC 111
"Environmental standardization for electrical and electronic products and systems" was submitted to
the IEC-CENELEC parallel vote and approved by CENELEC as EN IEC 62321-11:2024.
The following dates are fixed:
• latest date by which the document has to be implemented at national (dop) 2024-10-19
level by publication of an identical national standard or by endorsement
• latest date by which the national standards conflicting with the (dow) 2027-01-19
document have to be withdrawn

Attention is drawn to the possibility that some of the
...