EN ISO 18856:2005

Water quality - Determination of selected phthalates using gas chromatography/mass spectrometry (ISO 18856:2004)

ISO 18856:2004 specifies a method for the determination of phthalates in water after solid phase extraction and gas chromatography/mass spectrometry.
This method is applicable to the determination of phthalates in ground water, surface water, wastewater and drinking water in mass concentrations ranging from above 0,02 microgram per litre up to 0,150 microgram per litre, depending on the individual substance and the value of the blank.
The applicability of this method to other phthalates not specified is not excluded, but it is necessary to determine its applicability in each case.

Wasserbeschaffenheit - Bestimmung ausgewählter Phthalate mittels Gaschromatographie/Massenspektrometrie (ISO 18856:2004)

Diese Internationale Norm legt ein Verfahren für die Bestimmung von Phthalaten in Wasser nach Festphasenextraktion mittels Gaschromatographie/Massenspektrometrie fest.
Das Verfahren ist anwendbar auf die Bestimmung von Phthalaten (siehe Tabelle 1) in Grundwasser, Oberflächenwasser, Abwasser und Trinkwasser in Massenkonzentrationen von 0,02 µg/l bis 0,150 µg/l, abhängig von der individuellen Substanz und der Höhe des Blindwerts.
Das Verfahren darf auch auf andere in der Tabelle 1 nicht spezifizierte Phthalate angewendet werden, die Eignung muss jedoch in jedem Fall geprüft werden (siehe Anhang A, Liste von Phthalaten).
Allgemeine Anmerkungen zur Wiederfindung und zum Gebrauch eines internen Standards sind in Anhang B enthalten.
Tabelle 1 - Nach diesem Verfahren bestimmbare Phthalate
Nr   Name   Formel   Abkürzung   Molare Masse   CASa -Nr
            g/mol   
  1   Dimethylphthalat   C10H10O4   DMP   194,2   131-11-3
  2   Diethylphthalat   C12H14O4   DEP   222,24   84-66-2
  3   Dipropylphthalat   C14H18O4   DPP   250,3   131-16-8
  4   Diisobutylphthalat   C16H22O4   DiBP   278,4   84-69-5
  5   Dibutylphthalat   C16H22O4   DBP   278,4   84-74-2
  6   Butylbenzylphthalat   C19H20O4   BBzP   312,4   85-68-7
  7   Dicyclohexylphthalat   C20H26O4   DCHP   330,4   84-61-7
  8   Di(2-ethylhexyl)phthalat   C24H38O4   DEHP   390,6   117-81-7
  9   Di-n-octylphthalat   C24H38O4   DOP   390,6   117-84-0
10   Didecylphthalat   C28H46O4   DDcP   446,7   84-77-5
11   Diundecylphthalat   C30H50O4   DUP   474,4   3648-20-2
a   CAS: Chemical Abstracts System.

Qualité de l'eau - Dosage de certains phtalates par chromatographie en phase gazeuse/spectrométrie de masse (ISO 18856:2004)

L'ISO 18856:2004 spécifie une méthode de dosage des phtalates dans l'eau après extraction en phase solide et chromatographie en phase gazeuse/spectrométrie de masse.
La présente méthode est applicable au dosage des phtalates dans les eaux souterraines, les eaux de surface, les eaux usées et l'eau potable en concentrations en masse comprises au-delà de 0,02 microgrammes par litre et jusqu'à 0,150 microgrammes par litre, en fonction de la substance considérée et de la valeur du blanc.
L'applicabilité de la présente méthode à d'autres phtalates non spécifiés n'est pas exclue mais elle doit être vérifiée dans chaque cas.

Kakovost vode – Določevanje izbranih ftalatov s plinsko kromatografijo/masno spektrometrijo (ISO 18856:2004)

General Information

• Status: Published
• Publication Date: 09-Aug-2005
• Withdrawal Date: 27-Feb-2006
• ICS: 13.060.50 - Examination of water for chemical substances
• Technical Committee: CEN/TC 230 - Water analysis
• Drafting Committee: CEN/TC 230 - Water analysis
• Current Stage: 6060 - Definitive text made available (DAV) - Publishing
• Start Date: 10-Aug-2005
• Completion Date: 10-Aug-2005
• Directive: 01/990 - Proposal for a EP and Council Decision establishing the list of priority substances in the field of water policy COM(2000)47 New version of 01/990: PE-CONS 3645/01 (2001-09-04) : PE and Council Decision on List of Priority Substances for WFD
• Directive: 2000/60/EC - Directive 2000/60/EC of the European Parliament and of the Council of 23 October 2000 establishing a framework for Community action in the field of water policy (substitutes Directive Reference 01/991 - Common Position on WFD)
• Directive: 2001/990 - Proposal for a EP and Council Decision establishing the list of priority substances in the field of water policy COM(2000)47 New version of 01/990: PE-CONS 3645/01 (2001-09-04) : PE and Council Decision on List of Priority Substances for WFD
• Ref Project: SIST EN ISO 18856:2005 - Water quality - Determination of selected phthalates using gas chromatography/mass spectrometry (ISO 18856:2004)

Standards Content (Sample)

SLOVENSKI STANDARD
SIST EN ISO 18856:2005
01-december-2005
.DNRYRVWYRGH±'RORþHYDQMHL]EUDQLKIWDODWRYVSOLQVNRNURPDWRJUDILMRPDVQR
VSHNWURPHWULMR,62
Water quality - Determination of selected phthalates using gas chromatography/mass
spectrometry (ISO 18856:2004)
Wasserbeschaffenheit - Bestimmung ausgewählter Phthalate mittels
Gaschromatographie/Massenspektrometrie (ISO 18856:2004)
Qualité de l'eau - Dosage de certains phtalates par chromatographie en phase
gazeuse/spectrométrie de masse (ISO 18856:2004)
Ta slovenski standard je istoveten z: EN ISO 18856:2005
ICS:
13.060.50 3UHLVNDYDYRGHQDNHPLþQH Examination of water for
VQRYL chemical substances
SIST EN ISO 18856:2005 en,fr,de
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

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SIST EN ISO 18856:2005

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SIST EN ISO 18856:2005
EUROPEAN STANDARD
EN ISO 18856
NORME EUROPÉENNE
EUROPÄISCHE NORM
August 2005
ICS 13.060.50

English Version
Water quality - Determination of selected phthalates using gas
chromatography/mass spectrometry (ISO 18856:2004)
Qualité de l'eau - Dosage de certains phtalates par Wasserbeschaffenheit - Bestimmung ausgewählter
chromatographie en phase gazeuse/spectrométrie de Phthalate mittels
masse (ISO 18856:2004) Gaschromatographie/Massenspektrometrie (ISO
18856:2004)
This European Standard was approved by CEN on 20 July 2005.
CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European
Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national
standards may be obtained on application to the Central Secretariat or to any CEN member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by translation
under the responsibility of a CEN member into its own language and notified to the Central Secretariat has the same status as the official
versions.
CEN members are the national standards bodies of Austria, Belgium, Cyprus, Czech Republic, Denmark, Estonia, Finland, France,
Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Slovakia,
Slovenia, Spain, Sweden, Switzerland and United Kingdom.
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EUROPÄISCHES KOMITEE FÜR NORMUNG
Management Centre: rue de Stassart, 36  B-1050 Brussels
© 2005 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN ISO 18856:2005: E
worldwide for CEN national Members.

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SIST EN ISO 18856:2005
EN ISO 18856:2005 (E)
Foreword
The text of ISO 18856:2004 has been prepared by Technical Committee ISO/TC 147 "Water quality" of the
International Organization for Standardization (ISO) and has been taken over as EN ISO 18856:2005 by
Technical Committee CEN/TC 230 “Water analysis”, the secretariat of which is held by DIN.
This European Standard shall be given the status of a national standard, either by publication of an identical
text or by endorsement, at the latest by February 2006, and conflicting national standards shall be withdrawn
at the latest by February 2006.
According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following
countries are bound to implement this European Standard: Austria, Belgium, Cyprus, Czech Republic,
Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania,
Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Slovakia, Slovenia, Spain, Sweden, Switzerland
and United Kingdom.

Endorsement notice
The text of ISO 18856:2004 has been approved by CEN as EN ISO 18856:2005 without any modifications.
2

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SIST EN ISO 18856:2005


INTERNATIONAL ISO
STANDARD 18856
First edition
2004-09-15

Water quality — Determination of
selected phthalates using gas
chromatography/mass spectrometry
Qualité de l'eau — Dosage de certains phtalates par chromatographie
en phase gazeuse/spectrométrie de masse




Reference number
ISO 18856:2004(E)
©
ISO 2004

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SIST EN ISO 18856:2005
ISO 18856:2004(E)
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