Expression of performance of electrochemical analyzers - Part 1: General

specifies general test procedures to determine and verify the performance characteristics of electrochemical analyzers, taking into account the differences of approach in IEC documents specifying test methods (EN 60359, EN 60770, EN 61298); provides basic documents to support the application of standards of quality assurance: ISO 9001, ISO 9002 and ISO 9003.

Angabe zum Betriebsverhalten von elektrochemischen Analysatoren - Teil 1: Allgemeines

Expression des qualités de fonctionnement des analyseurs électrochimiques - Partie 1: Généralités

La CEI 60746-1:2003 spécifie la terminologie et les définitions des termes relatifs aux caractéristiques fonctionnelles des analyseurs électrochimiques utilisés pour la détermination en continu de certains aspects de solutions (généralement aqueuses); les méthodes uniformes à utiliser pour les indications concernant les caractéristiques fonctionnelles de tels analyseurs; les procédures générales d'essai pour déterminer et vérifier les caractéristiques fonctionnelles des analyseurs électrochimiques, en tenant compte des différences d'approche dans les documents CEI spécifiant les méthodes d'essai (CEI 60359, CEI 60770, CEI 61298). Elle fournit des documents de base dans le cadre de l'application des normes d'assurance qualité: ISO 9001, ISO 9002 et ISO 9003. Cette deuxième édition annule et remplace la première édition, parue en 1982, et constitue une révision technique.

Expression of performance of electrochemical analyzers - Part 1: General

General Information

Status
Published
Publication Date
06-Feb-2003
Withdrawal Date
31-Jan-2006
Current Stage
6060 - Document made available - Publishing
Start Date
07-Feb-2003
Completion Date
07-Feb-2003

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SLOVENSKI SIST EN 60746-1:2004

STANDARD
marec 2004
Expression of performance of electrochemical analyzers - Part 1: General
ICS 71.040.40 Referenčna številka
©  Standard je založil in izdal Slovenski inštitut za standardizacijo. Razmnoževanje ali kopiranje celote ali delov tega dokumenta ni dovoljeno

EUROPEAN STANDARD EN 60746-1
NORME EUROPÉENNE
EUROPÄISCHE NORM February 2003

ICS 71.040; 19.040
English version
Expression of performance of electrochemical analyzers
Part 1: General
(IEC 60746-1:2003)
Expression des qualités  Angabe zum Betriebsverhalten
de fonctionnement des analyseurs von elektrochemischen Analysatoren
électrochimiques Teil 1: Allgemeines
Partie 1: Généralités (IEC 60746-1:2003)
(CEI 60746-1:2003)
This European Standard was approved by CENELEC on 2003-02-01. CENELEC members are bound to
comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European
Standard the status of a national standard without any alteration.

Up-to-date lists and bibliographical references concerning such national standards may be obtained on
application to the Central Secretariat or to any CENELEC member.

This European Standard exists in three official versions (English, French, German). A version in any other
language made by translation under the responsibility of a CENELEC member into its own language and
notified to the Central Secretariat has the same status as the official versions.

CENELEC members are the national electrotechnical committees of Austria, Belgium, Czech Republic,
Denmark, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Luxembourg, Malta,
Netherlands, Norway, Portugal, Slovakia, Spain, Sweden, Switzerland and United Kingdom.

CENELEC
European Committee for Electrotechnical Standardization
Comité Européen de Normalisation Electrotechnique
Europäisches Komitee für Elektrotechnische Normung

Central Secretariat: rue de Stassart 35, B - 1050 Brussels

© 2003 CENELEC - All rights of exploitation in any form and by any means reserved worldwide for CENELEC members.

Ref. No. EN 60746-1:2003 E
Foreword
The text of document 65D/89A/FDIS, future edition 2 of IEC 60746-1, prepared by SC 65D, Analysing
equipment, of IEC TC 65, Industrial-process measurement and control, was submitted to the
IEC-CENELEC parallel vote and was approved by CENELEC as EN 60746-1 on 2003-02-01.

The following dates were fixed:

– latest date by which the EN has to be implemented
at national level by publication of an identical
national standard or by endorsement (dop) 2003-11-01

– latest date by which the national standards conflicting
with the EN have to be withdrawn (dow) 2006-02-01

Annexes designated "normative" are part of the body of the standard.
Annexes designated "informative" are given for information only.
In this standard, annex ZA is normative and annex A is informative.
Annex ZA has been added by CENELEC.
__________
Endorsement notice
The text of the International Standard IEC 60746-1:2003 was approved by CENELEC as a European
Standard without any modification.
__________
- 3 - EN 60746-1:2003
Annex ZA
(normative)
Normative references to international publications
with their corresponding European publications
This European Standard incorporates by dated or undated reference, provisions from other
publications. These normative references are cited at the appropriate places in the text and the
publications are listed hereafter. For dated references, subsequent amendments to or revisions of any
of these publications apply to this European Standard only when incorporated in it by amendment or
revision. For undated references the latest edition of the publication referred to applies (including
amendments).
NOTE When an international publication has been modified by common modifications, indicated by (mod), the relevant
EN/HD applies.
Publication Year Title EN/HD Year
1) 2)
IEC 60068-1 - Environmental testing EN 60068-1 1994
Part 1: General and guidance
IEC 60359 2001 Electrical and electronic measurement EN 60359 2002
equipment - Expression of performance

1) 2)
IEC 60381-1 - Analogue signals for process control HD 452.1 S1 1984
systems
Part 1: Direct current signals

1) 2)
IEC 60382 - Analogue pneumatic signal for process EN 60382 1993
control systems
1) 2)
IEC 60654-1 - Industrial-process measurement and EN 60654-1 1993
control equipment - Operating
conditions
Part 1: Climatic conditions
1) 2)
IEC 60770-1 - Transmitters for use in industrial- EN 60770-1 1999
process control systems
Part 1: Methods for performance
evaluation
IEC 61298 Series Process measurement and control EN 61298 Series
devices - General methods and
procedures for evaluating performance

1) 2)
ISO 9001 - Quality management systems - EN ISO 9001 2000
Requirements
1) 2)
ISO 9002 - Quality systems - Model for quality EN ISO 9002 1994
assurance in production, installation and
servicing
1)
Undated reference.
2)
Valid edition at date of issue.

Publication Year Title EN/HD Year
1) 2)
ISO 9003 - Quality systems - Model for quality EN ISO 9003 1994
assurance in final inspection and test

INTERNATIONAL IEC
STANDARD 60746-1
Second edition
2003-01
Expression of performance of
electrochemical analyzers –
Part 1:
General
Expression des qualités de fonctionnement
des analyseurs électrochimiques –
Partie 1:
Généralités
© IEC 2003 ⎯ Copyright - all rights reserved
No part of this publication may be reproduced or utilized in any form or by any means, electronic or
mechanical, including photocopying and microfilm, without permission in writing from the publisher.
International Electrotechnical Commission, 3, rue de Varembé, PO Box 131, CH-1211 Geneva 20, Switzerland
Telephone: +41 22 919 02 11 Telefax: +41 22 919 03 00 E-mail: inmail@iec.ch  Web: www.iec.ch
PRICE CODE
Commission Electrotechnique Internationale T
International Electrotechnical Commission
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For price, see current catalogue

– 2 – 60746-1 © IEC:2003(E)
CONTENTS
FOREWORD . 3
INTRODUCTION .4
1 Scope . 5
2 Normative references. 5
3 Terms and definitions . 6
4 Comparison of IEC Standards for Specification and Evaluation.10
5 Procedure for specification .11
5.1 Specification of values and ranges .11
5.2 General .11
5.3 Performance characteristics requiring statements of rated values .12
5.4 Uncertainty limits to be stated for each specified range .12
5.5 Other performance characteristics .13
6 Verification of values .13
6.1 General .13
6.2 Test procedures.15
6.2.1 Intrinsic uncertainty.15
6.2.2 Linearity uncertainty.15
6.2.3 Repeatability.15
6.2.4 Output fluctuation .15
6.2.5 Drift .15
6.2.6 Delay (T ) and 90 % (T ) response times .16
10 90
6.2.7 Warm-up time .16
6.2.8 Variations .16
6.2.9 Primary influence quantities.17
6.2.10 Other influence quantities .17
Annex A (informative) Recommended standard values of influence –
Quantities affecting performance from IEC 60359 .19

60746-1 © IEC:2003(E) – 3 –
INTERNATIONAL ELECTROTECHNICAL COMMISSION
___________
EXPRESSION OF PERFORMANCE OF
ELECTROCHEMICAL ANALYZERS –
Part 1: General
FOREWORD
1) The IEC (International Electrotechnical Commission) is a worldwide organization for standardization comprising
all national electrotechnical committees (IEC National Committees). The object of the IEC is to promote
international co-operation on all questions concerning standardization in the electrical and electronic fields. To
this end and in addition to other activities, the IEC publishes International Standards. Their preparation is
entrusted to technical committees; any IEC National Committee interested in the subject dealt with may
participate in this preparatory work. International, governmental and non-governmental organizations liaising
with the IEC also participate in this preparation. The IEC collaborates closely with the International
Organization for Standardization (ISO) in accordance with conditions determined by agreement between the
two organizations.
2) The formal decisions or agreements of the IEC on technical matters express, as nearly as possible, an
international consensus of opinion on the relevant subjects since each technical committee has representation
from all interested National Committees.
3) The documents produced have the form of recommendations for international use and are published in the form
of standards, technical specifications, technical reports or guides and they are accepted by the National
Committees in that sense.
4) In order to promote international unification, IEC National Committees undertake to apply IEC International
Standards transparently to the maximum extent possible in their national and regional standards. Any
divergence between the IEC Standard and the corresponding national or regional standard shall be clearly
indicated in the latter.
5) The IEC provides no marking procedure to indicate its approval and cannot be rendered responsible for any
equipment declared to be in conformity with one of its standards.
6) Attention is drawn to the possibility that some of the elements of this International Standard may be the subject
of patent rights. The IEC shall not be held responsible for identifying any or all such patent rights.
International Standard IEC 60746-1 has been prepared by subcommittee 65D: Analysing
equipment, of IEC technical committee 65: Industrial-process measurement and control.
This second edition cancels and replaces the first edition published in 1982 and constitutes
a technical revision.
The text of this standard is based on the following documents:
FDIS Report on voting
65D/89A/FDIS 65D/93/RVD
Full information on the voting for the approval of this standard can be found in the report on
voting indicated in the above table.
For this second edition, the text has been changed to reflect revision and introduction of Inter-
national Standards since 1982. An Informative Annex A has been introduced.
This publication has been drafted in accordance with the ISO/IEC Directives, Part 2.
The committee has decided that the contents of this publication will remain unchanged until
2007. At this date, the publication will be
• reconfirmed;
• withdrawn;
• replaced by a revised edition, or
• amended.
– 4 – 60746-1 © IEC:2003(E)
INTRODUCTION
This standard specifies the statements which manufacturers should make to describe
analyzers so that users may compare the performance characteristics of any analyzer to their
requirements. It includes the terminology and definitions of the terms to be used in such
statements. It describes the tests that are applicable to all types of electrochemical analyzers,
which may be used to determine these performance characteristics by either the manufacturer
or the user.
This standard is applicable to electrochemical analyzers used for the determination of certain
properties of (generally aqueous) solutions such as pH value, electrical conductivity, dissolved
oxygen content, the concentration of specified ions and redox potential. Other standards in this
series describe those aspects that are particular to specific types of analyzer, for example
IEC 60746-2. It is in accordance with the general principles set out in IEC 60359 and takes into
account documents specifying methods for evaluating performance, IEC 60770 and IEC 61298.
This standard is applicable to analyzers specified for installation in any location and to
analyzers having either flow-through or immersible type sensors. It is applicable to the
complete analyzer when supplied by one manufacturer as an integral unit comprised of all
mechanical, electrical and electronic portions. It also applies to sensor units alone and
electronic units alone when supplied separately or by different manufacturers. For the
purposes of this standard, any regulator for mains-supplied power or any non-mains power
supply, provided with the analyzer or specified by the manufacturer, is considered part of the
analyzer whether it is integral with the analyzer or housed separately.
It does not apply t
...

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