oSIST prEN 14331:2024

Liquid petroleum products - Separation and characterisation of fatty acid methyl esters (FAME) from middle distillates - Liquid chromatography (LC)/gas chromatography (GC) method

This document specifies a method for the separation of fatty acid methyl esters (FAME) from middle distillates by liquid chromatography (LC) and for the quantitative determination of individual esters by gas chromatography (GC).
Independently from the origin of the middle distillate, this method is applicable to FAME of vegetable or animal origin that contain fatty acid methyl esters between C6 and C24. The method is suitable for the separation and determination of FAME from middle distillates with FAME contents of at least 2 % (V/V).

Flüssige Mineralölerzeugnisse - Trennung und Bestimmung von Fettsäure-Methylestern (FAME) aus Mitteldestillaten - Flüssigchromatographie (LC)/Gaschromatographie (GC)

Dieses Dokument legt ein Verfahren zur Trennung von Fettsäure-Methylestern (FAME, en: fatty acid methyl esters) aus Mitteldestillaten durch Flüssigchromatographie (LC) sowie zur Bestimmung des Musters der Fettsäure-Methylester durch Gaschromatographie (GC) nach EN 14103 fest.
Das Muster der Fettsäure-Methylester könnte für die Berechnung der mittleren molaren Masse von Fettsäure-Methylestern (FAME) nach EN 14078 [1] verwendet werden.
Dieses Verfahren ist unabhängig von der Herkunft des Mitteldestillates anwendbar auf FAME pflanzlichen oder tierischen Ursprungs, die Fettsäure-Methylester mit Kettenlängen zwischen C6:0 und C24:1 enthalten. Das Verfahren ist geeignet zur Trennung und Bestimmung von FAME aus Mitteldestillaten mit FAME-Gehalten von mindestens 2 %(V/V).
ANMERKUNG   Für den Zweck dieses Dokuments werden die Angaben % (V/V) bzw. % (m/m) verwendet, um Volumenanteile in % oder Massenanteile in % auszudrücken.

Produits pétroliers liquides - Séparation et caractérisation des esters méthyliques d'acides gras (EMAG) dans les distillats moyens - Méthode par chromatographie liquide (CL) et chromatographie en phase gazeuse (CPG)

Le présent document spécifie une méthode pour la séparation des esters méthyliques d'acides gras (EMAG) dans les distillats moyens par chromatographie liquide (CL) et pour la caractérisation des esters méthyliques d'acides gras par chromatographie gazeuse (CG) selon l’EN 14103.
Le profil des esters méthyliques d'acides gras peut être utilisé pour calculer la masse moléculaire moyenne des EMAG selon l'EN 14078 [1].
Indépendamment de l’origine des distillats moyens, cette méthode est applicable aux EMAG d'origine végétale ou animale qui contiennent des esters méthyliques d’acides gras entre C6:0 et C24:1. La méthode est adaptée à la séparation et à la caractérisation des EMAG dans les distillats moyens dont la teneur en EMAG est d'au moins 2 % (V/V).
NOTE   Pour les besoins du présent document, les termes « % (V/V) » et « % (m/m) » sont utilisés pour représenter les fractions volumiques en % et les fractions massiques en %.

Tekoči naftni proizvodi - Ločba in opredelitev metil estrov maščobnih kislin (FAME) v srednjih destilatih - Metoda tekočinske (LH)/plinske kromatografije (GC)

General Information

• Status: Not Published
• Public Enquiry End Date: 01-Aug-2024
• ICS: 75.080 - Petroleum products in general
• Technical Committee: NAD - Petroleum products, lubricants and related products
• Current Stage: 4020 - Public enquire (PE) (Adopted Project)
• Start Date: 29-May-2024
• Due Date: 16-Oct-2024
• Ref Project: prEN 14331 - Liquid petroleum products - Separation and characterisation of fatty acid methyl esters (FAME) from middle distillates - Liquid chromatography (LC)/gas chromatography (GC) method

Relations

• Revises: SIST EN 14331:2004 - Liquid petroleum products - Separation and characterisation of fatty acid methyl esters (FAME) from middle distillates - Liquid chromatography (LC)/gas chromatography (GC) method
• Effective Date: 01-Jul-2024

Standards Content (Sample)

SLOVENSKI STANDARD
01-julij-2024
Tekoči naftni proizvodi - Ločba in opredelitev metil estrov maščobnih kislin
(FAME) v srednjih destilatih - Metoda tekočinske (LH)/plinske kromatografije (GC)
Liquid petroleum products - Separation and characterisation of fatty acid methyl esters
(FAME) from middle distillates - Liquid chromatography (LC)/gas chromatography (GC)
method
Flüssige Mineralölerzeugnisse - Trennung und Bestimmung von Fettsäure-Methylestern
(FAME) aus Mitteldestillaten - Flüssigchromatographie (LC)/Gaschromatographie (GC)
Produits pétroliers liquides - Séparation et caractérisation des esters méthyliques
d'acides gras (EMAG) dans les distillats moyens - Méthode par chromatographie liquide
(CL) et chromatographie en phase gazeuse (CPG)
Ta slovenski standard je istoveten z: prEN 14331
ICS:
75.080 Naftni proizvodi na splošno Petroleum products in
general
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

DRAFT
EUROPEAN STANDARD
NORME EUROPÉENNE
EUROPÄISCHE NORM
July 2024
ICS 75.080 Will supersede EN 14331:2004
English Version
Liquid petroleum products - Separation and
characterisation of fatty acid methyl esters (FAME) from
middle distillates - Liquid chromatography (LC)/gas
chromatography (GC) method
Produits pétroliers liquides - Séparation et Flüssige Mineralölerzeugnisse - Trennung und
caractérisation des esters méthyliques d'acides gras Bestimmung von Fettsäure-Methylestern (FAME) aus
(EMAG) dans les distillats moyens - Méthode par Mitteldestillaten - Flüssigchromatographie
chromatographie liquide (CL) et chromatographie en (LC)/Gaschromatographie (GC)
phase gazeuse (CPG)
This draft European Standard is submitted to CEN members for enquiry. It has been drawn up by the Technical Committee
CEN/TC 19.
If this draft becomes a European Standard, CEN members are bound to comply with the CEN/CENELEC Internal Regulations
which stipulate the conditions for giving this European Standard the status of a national standard without any alteration.

This draft European Standard was established by CEN in three official versions (English, French, German). A version in any other
language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC
Management Centre has the same status as the official versions.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway,
Poland, Portugal, Republic of North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Türkiye and
United Kingdom.
Recipients of this draft are invited to submit, with their comments, notification of any relevant patent rights of which they are
aware and to provide supporting documentation.

Warning : This document is not a European Standard. It is distributed for review and comments. It is subject to change without
notice and shall not be referred to as a European Standard.

EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION

EUROPÄISCHES KOMITEE FÜR NORMUNG

CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2024 CEN All rights of exploitation in any form and by any means reserved Ref. No. prEN 14331:2024 E
worldwide for CEN national Members.

Contents Page
European foreword . 3
1 Scope . 4
2 Normative references . 4
3 Terms and definitions . 4
4 Principle . 4
5 Reagents and materials . 4
6 Apparatus . 5
7 Sampling . 5
8 Procedure . 5
8.1 Separation on silica column . 5
8.2 Gas chromatographic analysis . 5
9 Analysis . 5
9.1 Calculation of the pattern of the fatty acid methyl esters . 5
10 Expression of results . 6
11 Precision . 6
12 Interpretation of results . 6
13 Test report . 6
Annex A (informative) Typical compositional data for fatty acids in vegetable oils . 8
Bibliography . 9

European foreword
This document (prEN 14331:2024) has been prepared by Technical Committee CEN/TC 19 “Gaseous and
liquid fuels, lubricants and related products of petroleum, synthetic and biological origin”, the secretariat
of which is held by NEN.
This document is currently submitted to the CEN Enquiry.
This document will supersede EN 14331:2004.
— modification to include short chain methyl ethers (C6:0 to C14:0);
— deletion of Annex A and Annex B because they have become unnecessary, as reference is made to
EN 14103 for the determination of the pattern of the fatty acid methyl esters by gas chromatography
(GC).
Any feedback and questions on this document should be directed to the users’ national standards body.
A complete listing of these bodies can be found on the CEN website.

1 Scope
This document specifies a method for the separation of fatty acid methyl esters (FAME) from middle
distillates by liquid chromatography (LC) and for the determination of the pattern of the fatty acid methyl
esters by gas chromatography (GC) according to EN 14103.
The pattern of the fatty acid methyl esters might be used for calculation of the average molecular mass of
FAME according to EN 14078 [1].
Independently from the origin of the middle distillate, this method is applicable to FAME of vegetable or
animal origin that contain fatty acid methyl esters between C6:0 and C24:1. The method is suitable for
the separation and determination of FAME from middle distillates with FAME contents of at least
2 % (V/V
...