Natural gas - Determination of water by the Karl Fischer method - Part 1: General requirements (ISO 10101-1:2022)

This document specifies general requirements for the determination of water in natural gas using the
Karl Fischer method (see Reference [1]).
ISO 10101-2 and ISO 10101-3 specify two individual methods of determination, a titration procedure
and a coulometric procedure, respectively.

Erdgas - Bestimmung des Wassergehaltes nach Karl Fischer - Teil 1: Einführung (ISO 10101-1:2022)

Dieses Dokument legt allgemeine Anforderungen an die Bestimmung des Wassergehaltes von Erdgas nach Karl Fischer fest (siehe Literaturhinweis [1]).
ISO 10101 2 und ISO 10101 3 legen zwei verschiedene Bestimmungsverfahren, nämlich ein Titrations¬verfahren und ein coulometrisches Verfahren, fest.

Gaz naturel - Dosage de l'eau par la méthode de Karl Fischer - Partie 1: Exigences générales (ISO 10101-1:2022)

Zemeljski plin - Določevanje vode po Karl-Fischerjevi metodi - 1. del: Splošne zahteve (ISO 10101-1:2022)

General Information

Status
Published
Public Enquiry End Date
01-Feb-2021
Publication Date
14-Nov-2022
Technical Committee
Current Stage
6060 - National Implementation/Publication (Adopted Project)
Start Date
26-Oct-2022
Due Date
31-Dec-2022
Completion Date
15-Nov-2022

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SLOVENSKI STANDARD
SIST EN ISO 10101-1:2022
01-december-2022
Nadomešča:
SIST EN ISO 10101-1:2000
Zemeljski plin - Določevanje vode po Karl-Fischerjevi metodi - 1. del: Splošne
zahteve (ISO 10101-1:2022)
Natural gas - Determination of water by the Karl Fischer method - Part 1: General
requirements (ISO 10101-1:2022)
Erdgas - Bestimmung des Wassergehaltes nach Karl Fischer - Teil 1: Einführung (ISO
10101-1:2022)
Gaz naturel - Dosage de l'eau par la méthode de Karl Fischer - Partie 1: Exigences
générales (ISO 10101-1:2022)
Ta slovenski standard je istoveten z: EN ISO 10101-1:2022
ICS:
75.060 Zemeljski plin Natural gas
SIST EN ISO 10101-1:2022 en,fr,de
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

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SIST EN ISO 10101-1:2022

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SIST EN ISO 10101-1:2022


EN ISO 10101-1
EUROPEAN STANDARD

NORME EUROPÉENNE

September 2022
EUROPÄISCHE NORM
ICS 75.060 Supersedes EN ISO 10101-1:1998
English Version

Natural gas - Determination of water by the Karl Fischer
method - Part 1: General requirements (ISO 10101-
1:2022)
Gaz naturel - Dosage de l'eau par la méthode de Karl Erdgas - Bestimmung des Wassergehaltes nach Karl
Fischer - Partie 1: Exigences générales (ISO 10101- Fischer - Teil 1: Einführung (ISO 10101-1:2022)
1:2022)
This European Standard was approved by CEN on 26 August 2022.

CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this
European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references
concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN
member.

This European Standard exists in three official versions (English, French, German). A version in any other language made by
translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management
Centre has the same status as the official versions.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway,
Poland, Portugal, Republic of North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Türkiye and
United Kingdom.





EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION

EUROPÄISCHES KOMITEE FÜR NORMUNG

CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2022 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN ISO 10101-1:2022 E
worldwide for CEN national Members.

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SIST EN ISO 10101-1:2022
EN ISO 10101-1:2022 (E)
Contents Page
European foreword . 3

2

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SIST EN ISO 10101-1:2022
EN ISO 10101-1:2022 (E)
European foreword
This document (EN ISO 10101-1:2022) has been prepared by Technical Committee ISO/TC 193
"Natural gas" in collaboration with Technical Committee CEN/TC 238 “Test gases, test pressures,
appliance categories and gas appliance types” the secretariat of which is held by AFNOR.
This European Standard shall be given the status of a national standard, either by publication of an
identical text or by endorsement, at the latest by March 2023, and conflicting national standards shall
be withdrawn at the latest by March 2023.
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. CEN shall not be held responsible for identifying any or all such patent rights.
This document supersedes EN ISO 10101-1:1998.
Any feedback and questions on this document should be directed to the users’ national standards
body/national committee. A complete listing of these bodies can be found on the CEN website.
According to the CEN-CENELEC Internal Regulations, the national standards organizations of the
following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria,
Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland,
Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Republic of
North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Türkiye and the
United Kingdom.
Endorsement notice
The text of ISO 10101-1:2022 has been approved by CEN as EN ISO 10101-1:2022 without any
modification.

3

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SIST EN ISO 10101-1:2022

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SIST EN ISO 10101-1:2022
INTERNATIONAL ISO
STANDARD 10101-1
Second edition
2022-08
Natural gas — Determination of water
by the Karl Fischer method —
Part 1:
General requirements
Gaz naturel — Dosage de l'eau par la méthode de Karl Fischer —
Partie 1: Exigences générales
Reference number
ISO 10101-1:2022(E)
© ISO 2022

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SIST EN ISO 10101-1:2022
ISO 10101-1:2022(E)
COPYRIGHT PROTECTED DOCUMENT
© ISO 2022
All rights reserved. Unless otherwise specified, or required in the context of its implementation, no part of this publication may
be reproduced or utilized otherwise in any form or by any means, electronic or mechanical, including photocopying, or posting on
the internet or an intranet, without prior written permission. Permission can be requested from either ISO at the address below
or ISO’s member body in the country of the requester.
ISO copyright office
CP 401 • Ch. de Blandonnet 8
CH-1214 Vernier, Geneva
Phone: +41 22 749 01 11
Email: copyright@iso.org
Website: www.iso.org
Published in Switzerland
ii
  © ISO 2022 – All rights reserved

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SIST EN ISO 10101-1:2022
ISO 10101-1:2022(E)
Contents Page
Foreword .iv
Introduction .v
1 Scope . 1
2 Normative references . 1
3 Terms and definitions . 1
4 Principle . 1
4.1 General . 1
4.2 Principle of the titration method . 1
4.3 Principle of the coulometric method . 2
5 Reactions and interferences .2
6 Sampling . 3
7 Measurement uncertainty .3
Bibliography . 4
iii
© ISO 2022 – All rights reserved

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SIST EN ISO 10101-1:2022
ISO 10101-1:2022(E)
Foreword
ISO (the International Organization for Standardization) is a worldwide federation of national standards
bodies (ISO member bodies). The work of preparing International Standards is normally carried out
through ISO technical committees. Each member body interested in a subject for which a technical
committee has been established has the right to be represented on that committee. International
organizations, governmental and non-governmental, in liaison with ISO, also take part in the work.
ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of
electrotechnical standardization.
The procedures used to develop this document and those intended for its further maintenance are
described in the ISO/IEC Directives, Part 1. In particular the different approval criteria needed for the
different types of ISO documents should be noted. This document was drafted in accordance with the
editorial rules of the ISO/IEC Directives, Part 2 (see www.iso.org/directives).
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. ISO shall not be held responsible for identifying any or all such patent rights. Details of
any patent rights identified during the development of the document will be in the Introduction and/or
on the ISO list of patent declarations received (see www.iso.org/patents).
Any trade name used in this document is information given for the convenience of users and does not
constitute an endorsement.
For an explanation on the voluntary nature of standards, the meaning of ISO specific terms and
expressions related to conformity assessment, as well as information about ISO's adherence to the
World Trade Organization (WTO) principles in the Technical Barriers to Trade (TBT) see the following
URL: www.iso.org/iso/foreword.html.
This document was prepared by Technical Committee ISO/TC 193, Natural Gas, Subcommittee SC 1,
Analysis o
...

SLOVENSKI STANDARD
oSIST prEN ISO 10101-1:2021
01-januar-2021
Zemeljski plin - Določevanje vode po Karl-Fischerjevi metodi - 1. del: Uvod
(ISO/DIS 10101-1:2020)
Natural gas - Determination of water by the Karl Fischer method - Part 1: Introduction
(ISO/DIS 10101-1:2020)
Erdgas - Bestimmung des Wassergehaltes nach Karl Fischer - Teil 1: Einführung
(ISO/DIS 10101-1:2020)
Gaz naturel - Dosage de l'eau par la méthode de Karl Fischer - Partie 1: Introduction
(ISO/DIS 10101-1:2020)
Ta slovenski standard je istoveten z: prEN ISO 10101-1
ICS:
75.060 Zemeljski plin Natural gas
oSIST prEN ISO 10101-1:2021 en,fr,de
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

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oSIST prEN ISO 10101-1:2021

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oSIST prEN ISO 10101-1:2021
DRAFT INTERNATIONAL STANDARD
ISO/DIS 10101-1
ISO/TC 193/SC 1 Secretariat: NEN
Voting begins on: Voting terminates on:
2020-11-13 2021-02-05
Natural gas — Determination of water by the Karl Fischer
method —
Part 1:
Introduction
Gaz naturel — Dosage de l'eau par la méthode de Karl Fischer —
Partie 1: Introduction
ICS: 75.060
THIS DOCUMENT IS A DRAFT CIRCULATED
This document is circulated as received from the committee secretariat.
FOR COMMENT AND APPROVAL. IT IS
THEREFORE SUBJECT TO CHANGE AND MAY
NOT BE REFERRED TO AS AN INTERNATIONAL
STANDARD UNTIL PUBLISHED AS SUCH.
IN ADDITION TO THEIR EVALUATION AS
ISO/CEN PARALLEL PROCESSING
BEING ACCEPTABLE FOR INDUSTRIAL,
TECHNOLOGICAL, COMMERCIAL AND
USER PURPOSES, DRAFT INTERNATIONAL
STANDARDS MAY ON OCCASION HAVE TO
BE CONSIDERED IN THE LIGHT OF THEIR
POTENTIAL TO BECOME STANDARDS TO
WHICH REFERENCE MAY BE MADE IN
Reference number
NATIONAL REGULATIONS.
ISO/DIS 10101-1:2020(E)
RECIPIENTS OF THIS DRAFT ARE INVITED
TO SUBMIT, WITH THEIR COMMENTS,
NOTIFICATION OF ANY RELEVANT PATENT
RIGHTS OF WHICH THEY ARE AWARE AND TO
©
PROVIDE SUPPORTING DOCUMENTATION. ISO 2020

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oSIST prEN ISO 10101-1:2021
ISO/DIS 10101-1:2020(E)

COPYRIGHT PROTECTED DOCUMENT
© ISO 2020
All rights reserved. Unless otherwise specified, or required in the context of its implementation, no part of this publication may
be reproduced or utilized otherwise in any form or by any means, electronic or mechanical, including photocopying, or posting
on the internet or an intranet, without prior written permission. Permission can be requested from either ISO at the address
below or ISO’s member body in the country of the requester.
ISO copyright office
CP 401 • Ch. de Blandonnet 8
CH-1214 Vernier, Geneva
Phone: +41 22 749 01 11
Email: copyright@iso.org
Website: www.iso.org
Published in Switzerland
ii © ISO 2020 – All rights reserved

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oSIST prEN ISO 10101-1:2021
ISO/DIS 10101-1:2020(E)

Contents Page
Foreword .iv
Introduction .v
1 Scope . 1
2 Normative references . 1
3 Terms and definitions . 1
4 Method basics . 1
4.1 General . 1
4.2 Principle of the titration method (ISO 10101-2) . 2
4.3 Principle of the coulometric method (ISO 10101-3) . 2
5 Reactions and interferences . 2
6 Sampling . 3
Bibliography . 4
© ISO 2020 – All rights reserved iii

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oSIST prEN ISO 10101-1:2021
ISO/DIS 10101-1:2020(E)

Foreword
ISO (the International Organization for Standardization) is a worldwide federation of national standards
bodies (ISO member bodies). The work of preparing International Standards is normally carried out
through ISO technical committees. Each member body interested in a subject for which a technical
committee has been established has the right to be represented on that committee. International
organizations, governmental and non-governmental, in liaison with ISO, also take part in the work.
ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of
electrotechnical standardization.
The procedures used to develop this document and those intended for its further maintenance are
described in the ISO/IEC Directives, Part 1. In particular the different approval criteria needed for the
different types of ISO documents should be noted. This document was drafted in accordance with the
editorial rules of the ISO/IEC Directives, Part 2 (see www .iso .org/ directives).
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. ISO shall not be held responsible for identifying any or all such patent rights. Details of
any patent rights identified during the development of the document will be in the Introduction and/or
on the ISO list of patent declarations received (see www .iso .org/ patents).
Any trade name used in this document is information given for the convenience of users and does not
constitute an endorsement.
For an explanation on the voluntary nature of standards, the meaning of ISO specific terms and
expressions related to conformity assessment, as well as information about ISO's adherence to the
World Trade Organization (WTO) principles in the Technical Barriers to Trade (TBT) see the following
URL: www .iso .org/ iso/ foreword .html.
This document was prepared by Technical Committee [or Project Committee] ISO/TC [or ISO/PC] 193,
Natural Gas, Subcommittee SC 1, Analysis of Natural Gas.
ISO 10101 consists of the following parts, under the general title Natural gas — Determination of water
by the Karl Fischer method:
— Part 1: Introduction
— Part 2: Volumetric procedure
— Part 3: Coulometric procedure
Annex A of this part of ISO 10101 is for information only.
A list of all parts in the ISO 10101 series can be found on the ISO website.
iv © ISO 2020 – All rights reserved

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oSIST prEN ISO 10101-1:2021
ISO/DIS 10101-1:2020(E)

Introduction
Water vapour may be present in natural gas due to, for example, natural occurrence in the well
production stream, the storage of gas in underground res
...

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