SIST EN ISO 4829-2:2016

Steel and iron - Determination of total silicon content - Reduced molybdosilicate spectrophotometric method - Part 2: Silicon contents between 0,01 and 0,05 % (ISO 4829-2:2016)

This part of ISO 4829 specifies a spectrophotometric method for the determination of total silicon in
steels using reduced molybdosilicate.
The method is applicable to silicon contents between 0,01 % and 0,05 % (mass fraction) in steels.

Stahl - Bestimmung des Gesamtsiliciumanteils - Spektrophotometrische Methode mit reduziertem Molybdatosilicat - Teil 2: Siliciumanteile zwischen 0,01 und 0,05 % (ISO 4829-2:2016)

Diese Internationale Norm legt ein spektrophotometrisches Verfahren mit reduziertem Molybdatosilicat zur Bestimmung des Gesamtsiliciumanteils in Stahl fest.
Dieses Verfahren lässt sich auf Siliciumgehalte im Bereich von 0,01 % bis 0,05 % Massenanteil in Stählen anwenden.

Aciers et fontes - Dosage du silicium total - Méthode spectrophotométrique au molybdosilicate réduit - Partie 2: Teneurs en silicium comprises entre 0,01 et 0,05 % (ISO 4829-2:2016)

ISO 4829-2:2016 spécifie une méthode spectrophotométrique au silicomolybdate réduit pour la détermination du silicium total dans les aciers.
La méthode est applicable aux teneurs en silicium comprises entre 0,01 % et 0,05 % (fraction massique) dans les aciers.

Jeklo in železo - Določevanje celotnega silicija - Spektrofotometrijska metoda z reduciranim molibdo-silikatom - 2. del: Deleži silicija od 0,01 do 0,05 % (ISO 4829-2:2016)

Ta del standarda ISO 4829 določa spektrofotometrijsko metodo za določevanje celotnega silicija v
jeklih z reduciranim molibdo-silikatom.
Ta metoda se uporablja za vsebnosti silicija med 0,01 % in 0,05 % (masni delež) v jeklih.

General Information

• Status: Published
• Public Enquiry End Date: 28-Feb-2014
• Publication Date: 04-Apr-2016
• ICS: 77.040.30 - Chemical analysis of metals
• ICS: 77.080.01 - Ferrous metals in general
• Technical Committee: IFEK - Ferrous metals
• Current Stage: 6060 - National Implementation/Publication (Adopted Project)
• Start Date: 24-Mar-2016
• Due Date: 29-May-2016
• Completion Date: 05-Apr-2016
• Mandate: M/BC/CEN/89/10 - ECISS - 3rd programme
• Ref Project: EN ISO 4829-2:2016 - Steels - Determination of total silicon contents - Reduced molybdosilicate spectrophotometric method - Part 2: Silicon contents between 0,01 % and 0,05 % (ISO 4829-2:2016)

Relations

• Replaces: SIST EN 24829-2:1998/AC1:1998 - Steel and cast iron - Determination of total silicon content - Reduced molybdosilicate spectrophotometric method - Part 2: Silicon content between 0,01 and 0,05% (ISO 4829-2:1988)
• Effective Date: 01-May-2016
• Replaces: SIST EN 24829-2:1998 - Steel and cast iron - Determination of total silicon content - Reduced molybdosilicate spectrophotometric method - Part 2: Silicon content between 0,01 and 0,05% (ISO 4829-2:1988)
• Effective Date: 01-May-2016
• Replaces: SIST EN 24829-2:1998 - Steel and cast iron - Determination of total silicon content - Reduced molybdosilicate spectrophotometric method - Part 2: Silicon content between 0,01 and 0,05% (ISO 4829-2:1988)
• Effective Date: 08-Jun-2022

Standards Content (Sample)

SLOVENSKI STANDARD
SIST EN ISO 4829-2:2016
01-maj-2016
1DGRPHãþD
SIST EN 24829-2:1998
SIST EN 24829-2:1998/AC1:1998
-HNORLQåHOH]R'RORþHYDQMHFHORWQHJDVLOLFLMD6SHNWURIRWRPHWULMVNDPHWRGD]
UHGXFLUDQLPPROLEGRVLOLNDWRPGHO'HOHåLVLOLFLMDRGGR,62

Steel and iron - Determination of total silicon content - Reduced molybdosilicate
spectrophotometric method - Part 2: Silicon contents between 0,01 and 0,05 % (ISO
4829-2:2016)
Stahl - Bestimmung des Gesamtsiliciumanteils - Spektrophotometrische Methode mit
reduziertem Molybdatosilicat - Teil 2: Siliciumanteile zwischen 0,01 und 0,05 % (ISO
4829-2:2016)
Aciers et fontes - Dosage du silicium total - Méthode spectrophotométrique au
molybdosilicate réduit - Partie 2: Teneurs en silicium comprises entre 0,01 et 0,05 %
(ISO 4829-2:2016)
Ta slovenski standard je istoveten z: EN ISO 4829-2:2016
ICS:
77.040.30 Kemijska analiza kovin Chemical analysis of metals
77.080.01 Železne kovine na splošno Ferrous metals in general
SIST EN ISO 4829-2:2016 en,fr,de
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

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SIST EN ISO 4829-2:2016

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SIST EN ISO 4829-2:2016


EN ISO 4829-2
EUROPEAN STANDARD

NORME EUROPÉENNE

March 2016
EUROPÄISCHE NORM
ICS 77.080.01 Supersedes EN 24829-2:1990
English Version

Steels - Determination of total silicon contents - Reduced
molybdosilicate spectrophotometric method - Part 2:
Silicon contents between 0,01 % and 0,05 % (ISO 4829-
2:2016)
Aciers - Détermination du silicium total - Méthode Stahl - Bestimmung des Gesamtsiliciumanteils -
spectrophotométrique au silicomolybdate réduit - Spektrophotometrische Methode mit reduziertem
Partie 2: Teneurs en silicium comprises entre 0,01 % et Molybdatosilicat - Teil 2: Siliciumanteile zwischen 0,01
0,05 % (ISO 4829-2:2016) % und 0,05 % (ISO 4829-2:2016)
This European Standard was approved by CEN on 21 November 2015.

CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this
European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references
concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN
member.

This European Standard exists in three official versions (English, French, German). A version in any other language made by
translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management
Centre has the same status as the official versions.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania,
Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and
United Kingdom.





EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION

EUROPÄISCHES KOMITEE FÜR NORMUNG

CEN-CENELEC Management Centre: Avenue Marnix 17, B-1000 Brussels
© 2016 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN ISO 4829-2:2016 E
worldwide for CEN national Members.

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SIST EN ISO 4829-2:2016
EN ISO 4829-2:2016 (E)
Contents Page
European foreword . 3

2

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SIST EN ISO 4829-2:2016
EN ISO 4829-2:2016 (E)
European foreword
This document (EN ISO 4829-2:2016) has been prepared by Technical Committee ISO/TC 17 “Steel” in
collaboration with Technical Committee ECISS/TC 102 “Methods of chemical analysis for iron and steel”
the secretariat of which is held by SIS.
This European Standard shall be given the status of a national standard, either by publication of an
identical text or by endorsement, at the latest by September 2016, and conflicting national standards
shall be withdrawn at the latest by September 2016.
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. CEN [and/or CENELEC] shall not be held responsible for identifying any or all such patent
rights.
This document supersedes EN 24829-2:1990.
This document has been prepared under a mandate given to CEN by the European Commission and the
European Free Trade Association.
According to the CEN-CENELEC Internal Regulations, the national standards organizations of the
following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria,
Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia,
France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta,
Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland,
Turkey and the United Kingdom.
Endorsement notice
The text of ISO 4829-2:2016 has been approved by CEN as EN ISO 4829-2:2016 without any
modification.
3

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SIST EN ISO 4829-2:2016

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SIST EN ISO 4829-2:2016
INTERNATIONAL ISO
STANDARD 4829-2
Second edition
2016-02-15
Steels — Determination of total silicon
contents — Reduced molybdosilicate
spectrophotometric method —
Part 2:
Silicon contents between 0,01 % and
0,05 %
Aciers — Détermination du silicium total — Méthode
spectrophotométrique au silicomolybdate réduit —
Partie 2: Teneurs en silicium comprises entre 0,01 % et 0,05 %
Reference number
ISO 4829-2:2016(E)
©
ISO 2016

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SIST EN ISO 4829-2:2016
ISO 4829-2:2016(E)

COPYRIGHT PROTECTED DOCUMENT
© ISO 2016, Published in Switzerland
All rights reserved. Unless otherwise specified, no part of this publication may be reproduced or utilized otherwise in any form
or by any means, electronic or mechanical, including photocopying, or posting on the internet or an intranet, without prior
written permission. Permission can be requested from either ISO at the address below or ISO’s member body in the country of
the requester.
ISO copyright office
Ch. de Blandonnet 8 • CP 401
CH-1214 Vernier, Geneva, Switzerland
Tel. [phone]
Fax [phone]
[e-mail]
www.iso.org
ii © ISO 2016 – All rights reserved

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SIST EN ISO 4829-2:2016
ISO 4829-2:2016(E)

Contents Page
Foreword .iv
1 Scope . 1
2 Normative references . 1
3 Principle . 1
4 Reagents . 1
5 Apparatus . 3
6 Sampling . 4
7 Procedure. 4
7.1 Test portion . 4
7.2 Blank test . 4
7.3 Determination . 4
7.3.1 Dissolution of the test portion . 4
7.3.2 Treatment of insoluble residue . 4
7.3.3 Preparation of the test solution . 4
7.3.4 Development of the colour . 5
7.3.5 Spectrophotometric measurements . 5
7.4 Establishment of the calibration curve . 6
7.4.1 Preparation of the calibration solutions . 6
7.4.2 Spectrophotometric measurements . 6
7.4.3 Plotting of the calibration curve . 6
8 Expression of results . 6
8.1 Method of calculation . 6
8.2 Precision . 7
9 Test report . 7
Annex A (informative) Additional information on the interlaboratory test .9
Bibliography .10
© ISO 2016 – All rights reserved iii

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SIST EN ISO 4829-2:2016
ISO 4829-2:2016(E)

Foreword
ISO (the International Organization for Standardization) is a worldwide federation of national standards
bodies (ISO member bodies). The work of preparing International Standards is normally carried out
through ISO technical committees. Each member body interested in a subject for which a technical
committee has been established has the right to be represented on that committee. International
organizations, governmental and non-governmental, in liaison with ISO, also take part in the work.
ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of
electrotechnical standardization.
The procedures used to develop this document and those intended for its further maintenance are
described in the ISO/IEC Directives, Part 1. In particular the different approval criteria needed for the
different types of ISO documents should be noted. This document was drafted in accordance with the
editorial rules of the ISO/IEC Directives, Part 2 (see www.iso.org/directives).
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. ISO shall not be held responsible for identifying any or all such patent rights. Details of
any patent rights identified during the development of the document will be in the Introduction and/or
on the ISO list of patent declarations received (see www.iso.org/patents).
Any trade name used in this document is information given for the convenience of users and does not
constitute an endorsement.
For an explanation on the meaning of ISO specific terms and expressions related to conformity
assessment, as well as information about ISO’s adherence to the WTO principles in the Technical
Barriers to Trade (TBT) see the following URL: Foreword - Supplementary information.
The committee responsible for this document is ISO/TC 17, Steel, Subcommittee SC 1, Methods of
determination of chemical composition.
This second edition cancels and replaces the first edition (ISO 4829-2:1988), which has been
technically revised.
ISO 4829 consists of the following parts, under the general title Steels — Determination of total silicon
contents — Reduced molybdosilicate spectrophotometric method:
— Part 1: Silicon contents between 0,05 % and 1,0 %
— Part 2: Silicon contents between 0,01 % and 0,05 %
iv © ISO 2016 – All rights reserved

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SIST EN ISO 4829-2:2016
INTERNATIONAL STANDARD ISO 4829-2:2016(E)
Steels — Determination of total silicon contents —
Reduced molybdosilicate spectrophotometric method —
Part 2:
Silicon contents between 0,01 % and 0,05 %
1 Scope
This part of ISO 4829 specifies a spectrophotometric method for the determination of total silicon in
steels using reduced molybdosilicate.
The method is applicable to silicon contents between 0,01 % and 0,05 % (mass fraction) in steels.
2 Normative references
The following documents, in whole or in part, are normatively referenced in this document and are
indispensable for its application. For dated references, only the edition cited applies. For undated
references, the latest edition of the referenced document (including any amendments) applies.
ISO 648, Laboratory glassware — Single-volume pipettes
ISO 1042, Laboratory glassware — One-mark volumetric flasks
ISO 3696, Water for analytical laboratory use — Specification and test methods
ISO 14284, Steel and iron — Sampling and preparation of samples for the determination of chemical
composition
3 Principle
Dissolution of a test portion in a hydrochloric/nitric acids mixture.
Fusion of the acid-insoluble residue with sodium peroxide. Formation of the oxidized molybdosilicate
(yellow) complex in weak acid solution.
Selective reduction of the molybdosilicate complex to a blue complex with ascorbic acid, after increasing
the sulphuric acid concentration and adding oxalic acid to prevent the interference of phosphorus,
arsenic and vanadium.
Spectrophotometric measurement of the reduced blue complex at a wavelength of about 810 nm.
4 Reagents
During the analysis, unless otherwise specified, use only reagents of recognized analytical grade and
only grade 2 water as specified in ISO 3696. Water demineralized by ion-exchange shall not be used as
it may contain significant amounts of colloidal silica.
Reagents supplied in glass bottles, once opened, might absorb moisture and become reactive to
glassware. Alkaline reagents, e.g. sodium carbonate and sodium peroxide, are particularly susceptible.
To avoid the risk of significant contamination arising from this source, it is recommended that only
freshly opened bottles of all reagents be used for the preparation of reagent solutions.
© ISO 2016 – All rights reserved 1

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SIST EN ISO 4829-2:2016
ISO 4829-2:2016(E)

To avoid adventitious contamination, the water shall be prepared, as required, for the specific purpose
an
...