ASTM E224-23

Standard Test Methods for Analysis of Hydrochloric Acid

SIGNIFICANCE AND USE
3.1 These test methods provide for the classification of various grades of hydrochloric acid and for the determination of various impurities. Acid strength and impurity levels are important factors in many uses of hydrochloric acid.
SCOPE
1.1 These test methods cover the analysis of hydrochloric acid.  
1.2 The following applies for the purposes of determining the conformance of the test results using this test method to applicable specifications, results shall be rounded off in accordance with the rounding-off method of Practice E29.  
1.3 The values stated in SI units are to be regarded as standard. The values given in parentheses are for information only.  
1.4 The analytical procedures appear in the following order:    
Sections  
Total Acidity  
8 to 16  
Baumé Gravity  
17 to 26  
Sulfated Ash  
27 to 34  
Iron  
35 to 44  
Color  
45 to 52  
Total Sulfur  
53 to 59  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Consult current OSHA regulations, suppliers’ Safety Data Sheets, and local regulations for all materials used in this specification. Specific hazards statements are given in Section 5, 30.1, 39.7, and 48.4.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

General Information

• Status: Published
• Publication Date: 31-Mar-2023
• ICS: 71.060.30 - Acids
• Technical Committee: D16 - Aromatic, Industrial, Specialty and Related Chemicals
• Drafting Committee: D16.10 - Acids

Standards Content (Sample)

This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the
Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
Designation: E224 − 23
Standard Test Methods for
1
Analysis of Hydrochloric Acid
This standard is issued under the fixed designation E224; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
This standard has been approved for use by agencies of the U.S. Department of Defense.
1. Scope* 2. Referenced Documents
2
1.1 These test methods cover the analysis of hydrochloric 2.1 ASTM Standards:
acid. D1193 Specification for Reagent Water
D1209 Test Method for Color of Clear Liquids (Platinum-
1.2 The following applies for the purposes of determining
Cobalt Scale)
the conformance of the test results using this test method to
D6809 Guide for Quality Control and Quality Assurance
applicable specifications, results shall be rounded off in accor-
Procedures for Aromatic Hydrocarbons and Related Ma-
dance with the rounding-off method of Practice E29.
terials
1.3 The values stated in SI units are to be regarded as
E1 Specification for ASTM Liquid-in-Glass Thermometers
standard. The values given in parentheses are for information
E29 Practice for Using Significant Digits in Test Data to
only.
Determine Conformance with Specifications
E60 Practice for Analysis of Metals, Ores, and Related
1.4 The analytical procedures appear in the following order:
Materials by Spectrophotometry
Sections
Total Acidity 8 to 16 E100 Specification for ASTM Hydrometers
Baumé Gravity 17 to 26
E180 Practice for Determining the Precision of ASTM
Sulfated Ash 27 to 34
Methods for Analysis and Testing of Industrial and Spe-
Iron 35 to 44
3
Color 45 to 52
cialty Chemicals (Withdrawn 2009)
Total Sulfur 53 to 59
E200 Practice for Preparation, Standardization, and Storage
1.5 This standard does not purport to address all of the
of Standard and Reagent Solutions for Chemical Analysis
safety concerns, if any, associated with its use. It is the
E300 Practice for Sampling Industrial Chemicals
responsibility of the user of this standard to establish appro-
priate safety, health, and environmental practices and deter- 3. Significance and Use
mine the applicability of regulatory limitations prior to use.
3.1 These test methods provide for the classification of
Consult current OSHA regulations, suppliers’ Safety Data
various grades of hydrochloric acid and for the determination
Sheets, and local regulations for all materials used in this
of various impurities. Acid strength and impurity levels are
specification. Specific hazards statements are given in Section
important factors in many uses of hydrochloric acid.
5, 30.1, 39.7, and 48.4.
1.6 This international standard was developed in accor-
4. Purity of Reagents
dance with internationally recognized principles on standard-
4.1 Purity of Reagents—Reagent grade chemicals shall be
ization established in the Decision on Principles for the
used in all tests. Unless otherwise indicated, it is intended that
Development of International Standards, Guides and Recom-
all reagents shall conform to the specifications of the Commit-
mendations issued by the World Trade Organization Technical
tee on Analytical Reagents of the American Chemical Society,
Barriers to Trade (TBT) Committee.
1 2
These test methods are under the jurisdiction of ASTM Committee D16 on For referenced ASTM standards, visit the ASTM website, www.astm.org, or
Aromatic, Industrial, Specialty and Related Chemicals and are the direct responsi- contact ASTM Customer Service at [e-mail]. For Annual Book of ASTM
bility of Subcommittee D16.10 on Acids. Standards volume information, refer to the standard’s Document Summary page on
Current edition approved April 1, 2023. Published May 2023. Originally the ASTM website.
3
approved in 1965. Last previous edition approved in 2016 as E224 – 16. DOI: The last approved version of this historical standard is referenced on
www.astm.org.
10.1520/E0224-23.
*A Summary of Changes section appears at the end of this standard
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1

---------------------- Page: 1 ----------------------
E224 − 23
4
where such specifications are available. Other grades may be 11. Apparatus
used, provided it is first ascertained that the reagent is of
11.1 Buret, 50 mL, Class A.
sufficiently high purity to permit its use without lessening the
11.2 Weighing Bottle, glass-stoppered, 50 mL.
accuracy of the determination.
4.2 Purity of Water—Unless otherwise indicated, references
...

This document is not an ASTM standard and is intended only to provide the user of an ASTM standard an indication of what changes have been made to the previous version. Because
it may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current version
of the standard as published by ASTM is to be considered the official document.
Designation: E224 − 16 E224 − 23
Standard Test Methods for
1
Analysis of Hydrochloric Acid
This standard is issued under the fixed designation E224; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
This standard has been approved for use by agencies of the U.S. Department of Defense.
1. Scope*
1.1 These test methods cover the analysis of hydrochloric acid.
1.2 The following applies for the purposes of determining the conformance of the test results using this test method to applicable
specifications, results shall be rounded off in accordance with the rounding-off method of Practice E29.
1.3 The values stated in SI units are to be regarded as standard. The values given in parentheses are for information only.
1.4 The analytical procedures appear in the following order:
Sections
Total Acidity 8 to 16
Baumé Gravity 17 to 26
Sulfated Ash 27 to 34
Iron 35 to 44
Color 45 to 52
Total Sulfur 53 to 59
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility
of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of
regulatory limitations prior to use. Consult current OSHA regulations, suppliers’ Safety Data Sheets, and local regulations for all
materials used in this specification. Specific hazards statements are given in Section 5 and , 30.1, 39.7, and 48.4.
1.6 This international standard was developed in accordance with internationally recognized principles on standardization
established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued
by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
2. Referenced Documents
2
2.1 ASTM Standards:
D1193 Specification for Reagent Water
D1209 Test Method for Color of Clear Liquids (Platinum-Cobalt Scale)
D6809 Guide for Quality Control and Quality Assurance Procedures for Aromatic Hydrocarbons and Related Materials
1
These test methods are under the jurisdiction of ASTM Committee D16 on Aromatic, Industrial, Specialty and Related Chemicals and are the direct responsibility of
Subcommittee D16.10 on Acids.
Current edition approved April 1, 2016April 1, 2023. Published May 2016May 2023. Originally approved in 1965. Last previous edition approved in 20082016 as
E224 – 08.E224 – 16. DOI: 10.1520/E0224-16.10.1520/E0224-23.
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or contact ASTM Customer Service at [e-mail]. For Annual Book of ASTM Standards
volume information, refer to the standard’s Document Summary page on the ASTM website.
*A Summary of Changes section appears at the end of this standard
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1

---------------------- Page: 1 ----------------------
E224 − 23
E1 Specification for ASTM Liquid-in-Glass Thermometers
E29 Practice for Using Significant Digits in Test Data to Determine Conformance with Specifications
E60 Practice for Analysis of Metals, Ores, and Related Materials by Spectrophotometry
E100 Specification for ASTM Hydrometers
E180 Practice for Determining the Precision of ASTM Methods for Analysis and Testing of Industrial and Specialty Chemicals
3
(Withdrawn 2009)
E200 Practice for Preparation, Standardization, and Storage of Standard and Reagent Solutions for Chemical Analysis
E300 Practice for Sampling Industrial Chemicals
3. Significance and Use
3.1 These test methods provide for the classification of various grades of hydrochloric acid and for the determination of various
impurities. Acid strength and impurity levels are important factors in many uses of hydrochloric acid.
4. Purity of Reagents
4.1 Purity of Reagents—Reagent grade chemicals shall be used in all tests. Unless otherwise indicated, it is intended that all
reagents shall conform to the specifications of the Committee on Analytical Reagents of the American Chemical Society, where
4
such specifications are available. Other grades may be used, provided it is first ascertained that the reagent is of sufficiently high
purity to permit its use without lessening the accuracy of the determination.
4.2 Purity of Water—Unless otherwise indicated, references to wate
...