Standard Test Method for Determination of Metals and Metalloids in Airborne Particulate Matter by Inductively Coupled Plasma Atomic Emission Spectrometry (ICP-AES)

SIGNIFICANCE AND USE
5.1 The health of workers in many industries is at risk through exposure by inhalation to toxic metals and metalloids. Industrial hygienists and other public health professionals need to determine the effectiveness of measures taken to control workers’ exposures, and this is generally achieved by making workplace air measurements. This test method has been promulgated in order to make available a standard methodology for making valid exposure measurements for a wide range of metals and metalloids that are used in industry. It will be of benefit to agencies concerned with health and safety at work; industrial hygienists and other public health professionals; analytical laboratories; industrial users of metals and metalloids and their workers, and other groups.  
5.2 This test method specifies a generic method for determination of the mass concentration of metals and metalloids in workplace air using ICP-AES.  
5.3 The analysis results can be used for the assessment of workplace exposures to metals and metalloids in workplace air.  
5.4 When sampling and analysis is carried out in accordance with this test method, the overall procedure normally satisfies the performance requirements of ISO 20581.
Note 2: Refer to Guide E1370 for guidance on the development of appropriate exposure assessment and measurement strategies.
SCOPE
1.1 This test method specifies a procedure for collection, sample preparation, and analysis of airborne particulate matter for the content of metals and metalloids using inductively coupled plasma-atomic emission spectrometry (ICP-AES). The method is generally applicable to occupational exposure monitoring.  
1.2 This test method is applicable to personal sampling of the inhalable or respirable fraction of airborne particles and to area sampling.  
1.3 This test method should be used by analysts experienced in the use of ICP-AES, the interpretation of spectral and matrix interferences, and procedures for their correction.  
1.4 This test method specifies a number of alternative methods for preparing test solutions from samples of airborne particulate matter. One of the specified sample preparation methods is applicable to the measurement of soluble metal or metalloid compounds. Other specified methods are applicable to the measurement of total metals and metalloids.  
1.5 It is the user's responsibility to ensure the validity of this test method for sampling materials of untested matrices.  
1.6 The following is a non-exclusive list of metals and metalloids for which one or more of the sample dissolution methods specified in this document is applicable. However, there is insufficient information available on the effectiveness of dissolution methods for those elements in italics.    
Aluminum  
Indium  
Sodium  
Antimony  
Iron  
Strontium  
Arsenic  
Lead  
Tantalum  
Barium  
Lithium  
Tellurium  
Beryllium  
Magnesium  
Thallium  
Bismuth  
Manganese  
Tin  
Boron  
Molybdenum  
Titanium  
Cadmium  
Nickel  
Tungsten  
Calcium  
Phosphorus  
Uranium  
Cesium  
Platinum  
Vanadium  
Chromium  
Potassium  
Yttrium  
Cobalt  
Rhodium  
Zinc  
Copper  
Selenium  
Zirconium  
Hafnium  
Silver  
1.7 This test method is not applicable to the sampling of elemental mercury, or to inorganic compounds of metals and metalloids that are present in the gaseous or vapor state.  
1.8 No detailed operating instructions are provided because of differences among various makes and models of suitable ICP-AES instruments. Instead, the analyst shall follow the instructions provided by the manufacturer of the particular instrument. This test method does not address comparative accuracy of different devices or the precision between instruments of the same make and model.  
1.9 This test method contains notes that are explanatory and are not part of the mandatory requirements of this test method.  
1.10 The values stated in S...

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ASTM D7035-21 - Standard Test Method for Determination of Metals and Metalloids in Airborne Particulate Matter by Inductively Coupled Plasma Atomic Emission Spectrometry (ICP-AES)
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Standards Content (Sample)

This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the
Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
Designation: D7035 − 21
Standard Test Method for
Determination of Metals and Metalloids in Airborne
Particulate Matter by Inductively Coupled Plasma Atomic
1
Emission Spectrometry (ICP-AES)
This standard is issued under the fixed designation D7035; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision.Anumber in parentheses indicates the year of last reapproval.A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope
Calcium Phosphorus Uranium
Cesium Platinum Vanadium
1.1 This test method specifies a procedure for collection,
Chromium Potassium Yttrium
sample preparation, and analysis of airborne particulate matter Cobalt Rhodium Zinc
Copper Selenium Zirconium
for the content of metals and metalloids using inductively
Hafnium Silver
coupledplasma-atomicemissionspectrometry(ICP-AES).The
1.7 This test method is not applicable to the sampling of
method is generally applicable to occupational exposure moni-
elemental mercury, or to inorganic compounds of metals and
toring.
metalloids that are present in the gaseous or vapor state.
1.2 This test method is applicable to personal sampling of
1.8 No detailed operating instructions are provided because
the inhalable or respirable fraction of airborne particles and to
of differences among various makes and models of suitable
area sampling.
ICP-AES instruments. Instead, the analyst shall follow the
1.3 Thistestmethodshouldbeusedbyanalystsexperienced
instructions provided by the manufacturer of the particular
intheuseofICP-AES,theinterpretationofspectralandmatrix
instrument. This test method does not address comparative
interferences, and procedures for their correction.
accuracy of different devices or the precision between instru-
1.4 This test method specifies a number of alternative ments of the same make and model.
methods for preparing test solutions from samples of airborne
1.9 Thistestmethodcontainsnotesthatareexplanatoryand
particulate matter. One of the specified sample preparation
are not part of the mandatory requirements of this test method.
methods is applicable to the measurement of soluble metal or
1.10 The values stated in SI units are to be regarded as
metalloid compounds. Other specified methods are applicable
standard. No other units of measurement are included in this
to the measurement of total metals and metalloids.
standard.
1.5 Itistheuser’sresponsibilitytoensurethevalidityofthis
1.11 This standard does not purport to address all of the
test method for sampling materials of untested matrices.
safety concerns, if any, associated with its use. It is the
1.6 The following is a non-exclusive list of metals and
responsibility of the user of this standard to establish appro-
metalloids for which one or more of the sample dissolution
priate safety, health, and environmental practices and deter-
methods specified in this document is applicable. However,
mine the applicability of regulatory limitations prior to use.
there is insufficient information available on the effectiveness
1.12 This international standard was developed in accor-
of dissolution methods for those elements in italics.
dance with internationally recognized principles on standard-
Aluminum Indium Sodium
ization established in the Decision on Principles for the
Antimony Iron Strontium
Development of International Standards, Guides and Recom-
Arsenic Lead Tantalum
mendations issued by the World Trade Organization Technical
Barium Lithium Tellurium
Beryllium Magnesium Thallium Barriers to Trade (TBT) Committee.
Bismuth Manganese Tin
Boron Molybdenum Titanium
2. Referenced Documents
Cadmium Nickel Tungsten
2
2.1 ASTM Standards:
D1193Specification for Reagent Water
1
This test method is under the jurisdiction of ASTM Committee D22 on Air
Quality and is the direct responsibility of Subcommittee D22.04 on WorkplaceAir
2
Quality. For referenced ASTM standards, visit the ASTM website, www.astm.org, or
Current edition approved Sept. 1, 2021. Published October 2021. Originally contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
approved in 2004. Last previous edition approved in 2016 as D7035–16. DOI: Standards volume information, refer to the standard’s Document Summary page on
10.1520/D7035-21. the ASTM website.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1

---------------------- Page: 1 ----------------------
D7035 − 21
D1356Terminology Relating to Sampling and Analysis of ISO20581Workplaceatmospheres—Generalrequirements
Atmospheres for the performance o
...

This document is not an ASTM standard and is intended only to provide the user of an ASTM standard an indication of what changes have been made to the previous version. Because
it may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current version
of the standard as published by ASTM is to be considered the official document.
Designation: D7035 − 16 D7035 − 21
Standard Test Method for
Determination of Metals and Metalloids in Airborne
Particulate Matter by Inductively Coupled Plasma Atomic
1
Emission Spectrometry (ICP-AES)
This standard is issued under the fixed designation D7035; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope
1.1 This test method specifies a procedure for collection, sample preparation, and analysis of airborne particulate matter for the
content of metals and metalloids using inductively coupled plasma-atomic emission spectrometry (ICP-AES). The method is
generally applicable to occupational exposure monitoring.
1.2 This test method is applicable to personal sampling of the inhalable or respirable fraction of airborne particles and to area
sampling.
1.3 This test method should be used by analysts experienced in the use of ICP-AES, the interpretation of spectral and matrix
interferences, and procedures for their correction.
1.4 This test method specifies a number of alternative methods for preparing test solutions from samples of airborne particulate
matter. One of the specified sample preparation methods is applicable to the measurement of soluble metal or metalloid
compounds. Other specified methods are applicable to the measurement of total metals and metalloids.
1.5 It is the user’s responsibility to ensure the validity of this test method for sampling materials of untested matrices.
1.6 The following is a non-exclusive list of metals and metalloids for which one or more of the sample dissolution methods
specified in this document is applicable. However, there is insufficient information available on the effectiveness of dissolution
methods for those elements in italics.
Aluminum Indium Sodium
Antimony Iron Strontium
Arsenic Lead Tantalum
Barium Lithium Tellurium
Beryllium Magnesium Thallium
Bismuth Manganese Tin
Boron Molybdenum Titanium
Cadmium Nickel Tungsten
Calcium Phosphorus Uranium
Cesium Platinum Vanadium
Chromium Potassium Yttrium
Cobalt Rhodium Zinc
1
This test method is under the jurisdiction of ASTM Committee D22 on Air Quality and is the direct responsibility of Subcommittee D22.04 on Workplace Air Quality.
Current edition approved Oct. 1, 2016Sept. 1, 2021. Published October 2016October 2021. Originally approved in 2004. Last previous edition approved in 20102016 as
D7035 – 10.D7035 – 16. DOI: 10.1520/D7035-16.10.1520/D7035-21.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1

---------------------- Page: 1 ----------------------
D7035 − 21
Copper Selenium Zirconium
Hafnium Silver
1.7 This test method is not applicable to the sampling of elemental mercury, or to inorganic compounds of metals and metalloids
that are present in the gaseous or vapor state.
1.8 No detailed operating instructions are provided because of differences among various makes and models of suitable ICP-AES
instruments. Instead, the analyst shall follow the instructions provided by the manufacturer of the particular instrument. This test
method does not address comparative accuracy of different devices or the precision between instruments of the same make and
model.
1.9 This test method contains notes that are explanatory and are not part of the mandatory requirements of this test method.
1.10 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.11 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility
of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of
regulatory limitations prior to use.
1.12 This international standard was developed in accordance with internationally recognized principles on standardization
established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued
by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
2. Referenced Documents
2
2.1 ASTM Standards:
D1193 Specification for Reagent Water
D1356 Terminology Relating to Sampling and Analysis of Atmospheres
D4185 Test Method for Measurement of Metals in Workplace Atmospheres by Flame Atomic Absorpt
...

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