SIST EN ISO 24966:2026

Determination of flash point - Modified continuously closed cup flash point (MCCCFP) method (ISO 24966:2026)

This document describes a test method for the determination of the flash point of chemicals, lube oils, fuels including aviation turbine fuel, diesel fuel, diesel/biodiesel blends and related products. The precision of this method has been determined over the range of 24,5 °C to 229,5 °C.
NOTE            Apparatus can determine the flash point at higher or lower temperatures than the precision range, however the precision has not been determined.

Flammpunktbestimmung - Modifizierte Methode dauerhaft geschlossener Tiegel (MCCCFP) (ISO 24966:2026)

Dieses Dokument legt ein Prüfverfahren zur Bestimmung des Flammpunkts von Chemikalien, Schmierölen, Kraftstoffen, einschließlich Flugturbinenkraftstoff, Dieselkraftstoff und Diesel/Biodiesel-Kraftstoffgemischen, sowie verwandten Produkten fest. Die Präzision dieses Verfahrens wurde im Bereich von 24,5 °C bis 229,5 °C bestimmt.
ANMERKUNG   Das Prüfgerät kann zur Bestimmung des Flammpunkts bei höheren oder niedrigeren Temperaturen außerhalb des Präzisionsbereichs verwendet werden. Die Präzision wurde jedoch nicht bestimmt.
WARNUNG — Die Anwendung dieses Dokuments kann die Anwendung gefährlicher Stoffe, Arbeitsgänge und Geräte mit sich bringen. Dieses Dokument beansprucht nicht, alle damit verbundenen Sicherheitsprobleme zu behandeln. Es liegt in der Verantwortung der Person, die das Dokument anwendet, vor der Anwendung geeignete Maßnahmen für die Sicherheit und den Gesundheitsschutz des Personals zu ergreifen und die Geltung weiterer diesbezüglicher Auflagen zu prüfen.

Détermination du point d'éclair - Méthode modifiée du point d'éclair en vase clos en continu (MCCCFP) (ISO 24966:2026)

Le présent document décrit une méthode d'essai pour la détermination du point d'éclair de produits chimiques, d'huiles lubrifiantes, de carburants, y compris les carburéacteurs, le carburant diesel, les mélanges diesel/biodiesel et les produits connexes. La fidélité de cette méthode a été déterminée dans la plage de 24,5 °C à 229,5 °C.
NOTE            L'appareillage peut déterminer le point d'éclair à des températures supérieures ou inférieures à la plage de fidélité, mais la fidélité n'a pas été déterminée.

Določanje plamenišča - Modificirana metoda plamenišča v neprekinjeno zaprti posodi (MCCCFP) (ISO 24966:2026)

Ta dokument opisuje preskusno metodo za določanje plamenišča kemikalij, mazalnih olj, goriv, vključno z letalskim turbinskim gorivom, dizelskim gorivom, mešanicami dizelskega goriva in biodizla ter sorodnimi proizvodi. Natančnost te metode je bila določena v območju od 24,5 °C do 229,5 °C.
OPOMBA Aparatura lahko določi plamenišče pri višjih ali nižjih temperaturah od območja natančnosti, vendar natančnost ni bila določena.

General Information

• Status: Published
• Public Enquiry End Date: 03-Aug-2025
• Publication Date: 04-May-2026
• ICS: 75.100 - Lubricants, industrial oils and related products
• ICS: 75.160.20 - Liquid fuels
• ICS: 75.160.40 - Biofuels
• Technical Committee: NAD - Petroleum products, lubricants and related products
• Current Stage: 6060 - National Implementation/Publication (Adopted Project)
• Start Date: 09-Apr-2026
• Due Date: 14-Jun-2026
• Completion Date: 05-May-2026
• Ref Project: EN ISO 24966:2026 - Determination of flash point - Modified continuously closed cup flash point (MCCCFP) method (ISO 24966:2026)

Overview

SIST EN ISO 24966:2026 defines a standardized test method for the determination of flash point in chemicals, lube oils, fuels, including aviation turbine fuel, diesel fuel, diesel/biodiesel blends, and related petroleum products. Utilizing the Modified Continuously Closed Cup Flash Point (MCCCFP) method, this standard is essential for accurate and repeatable measurement of flash points in a wide variety of liquid fuels and lubricants. The method is validated for samples with flash points ranging from 24.5 °C to 229.5 °C, with detailed guidance on apparatus, procedures, precision, and test reporting.

Key Topics

• Flash Point Determination: Outlines a uniform procedure using a modified continuously closed cup apparatus, ensuring safety and comparability of results.
• Precision and Reliability: Includes precision data based on inter-laboratory studies, with specific repeatability and reproducibility values in the stated temperature range.
• Sample Handling: Provides detailed instructions for sample collection, handling, sub-sampling, and storage to minimize volatility losses and contamination.
• Safety Considerations: Emphasizes that users must conduct risks assessments, especially when handling hazardous, unstable, or flammable materials.
• Apparatus Verification: Requires periodic verification and calibration of equipment using certified reference materials, ensuring accuracy and compliance.
• Data Correction and Expression: Explains procedures for correcting flash point readings for atmospheric pressure and accurate reporting.

Applications

SIST EN ISO 24966:2026 is a vital reference across industries where the flash point of liquids governs transportation, storage, classification, and safety compliance. Typical applications include:

• Quality control for fuels and lubricants by manufacturers, refiners, and suppliers.
• Regulatory compliance for shipping and labeling of chemicals and fuels, aligning with national and international safety regulations.
• Research and development in product formulation, ensuring new products meet minimum flash point requirements for their intended use.
• Customs and border control for classifying dangerous goods.
• Environmental and safety assessments to prevent fire or explosion hazards in storage and transport.
• Verification and proficiency testing in laboratories accredited for testing petroleum products and fuels.

Adhering to this standard supports the consistent assessment of flammability characteristics, which is crucial for hazard communication and operational safety.

Related Standards

• ISO 3170: Petroleum liquids - Manual sampling (covers representative sampling protocols)
• ISO 3171: Petroleum liquids - Automatic pipeline sampling (for automated sample collection)
• ISO/TR 29662: Guidance for performing flash point tests and interpreting results
• ISO 17034 & ISO Guide 35: Quality standards for certified reference materials, supporting apparatus calibration
• ISO 4259-3: Procedures for establishing and using accepted reference values in test methods
• ISO 17043: Proficiency testing requirements, relevant for laboratory verification
• ICS Codes: 75.100 (Lubricants, industrial oils, and related products), 75.160.20 (Liquid fuels), 75.160.40 (Fuels from biological sources)

Practical Value

Implementing SIST EN ISO 24966:2026 ensures repeatable, accurate flash point determination in quality assurance, regulatory compliance, and R&D across the fuel, chemical, and lubricants industries. The adoption of the MCCCFP method under this ISO standard strengthens fire safety, hazard classification, and efficient international trade by harmonizing the measurement of a key property - the flash point - for a wide range of products.

Efficient use of this standard supports improved safety protocols, product consistency, and alignment with global trade and transport regulations for hazardous liquids.

Standards Content (Sample)

SLOVENSKI STANDARD
01-junij-2026
Določanje plamenišča - Modificirana metoda plamenišča v neprekinjeno zaprti
posodi (MCCCFP) (ISO 24966:2026)
Determination of flash point - Modified continuously closed cup flash point (MCCCFP)
method (ISO 24966:2026)
Flammpunktbestimmung - Modifizierte Methode dauerhaft geschlossener Tiegel
(MCCCFP) (ISO 24966:2026)
Détermination du point d'éclair - Méthode modifiée du point d'éclair en vase clos en
continu (MCCCFP) (ISO 24966:2026)
Ta slovenski standard je istoveten z: EN ISO 24966:2026
ICS:
75.100 Maziva Lubricants, industrial oils and
related products
75.160.20 Tekoča goriva Liquid fuels
75.160.40 Biogoriva Biofuels
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

EN ISO 24966
EUROPEAN STANDARD
NORME EUROPÉENNE
April 2026
EUROPÄISCHE NORM
ICS 75.100; 75.160.20; 75.160.40
English Version
Determination of flash point - Modified continuously
closed cup flash point (MCCCFP) method (ISO
24966:2026)
Détermination du point d'éclair - Méthode modifiée du Flammpunktbestimmung - Modifizierte Methode
point d'éclair en vase clos en continu (MCCCFP) (ISO dauerhaft geschlossener Tiegel (MCCCFP) (ISO
24966:2026) 24966:2026)
This European Standard was approved by CEN on 2 April 2026.

CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this
European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references
concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN
member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by
translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management
Centre has the same status as the official versions.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway,
Poland, Portugal, Republic of North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Türkiye and
United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION

EUROPÄISCHES KOMITEE FÜR NORMUNG

CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2026 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN ISO 24966:2026 E
worldwide for CEN national Members.

Contents Page
European foreword . 3

European foreword
This document (EN ISO 24966:2026) has been prepared by Technical Committee ISO/TC 28 "Petroleum
and related products, fuels and lubricants from natural or synthetic sources" in collaboration with
Technical Committee CEN/TC 19 “Gaseous and liquid fuels, lubricants and related products of
petroleum, synthetic and biological origin” the secretariat of which is held by NEN.
This European Standard shall be given the status of a national standard, either by publication of an
identical text or by endorsement, at the latest by October 2026, and conflicting national standards shall
be withdrawn at the latest by October 2026.
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. CEN shall not be held responsible for identifying any or all such patent rights.
Any feedback and questions on this document should be directed to the users’ national standards
body/national committee. A complete listing of these bodies can be found on the CEN website.
According to the CEN-CENELEC Internal Regulations, the national standards organizations of the
following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria,
Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland,
Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Republic of
North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Türkiye and the
United Kingdom.
Endorsement notice
The text of ISO 24966:2026 has been approved by CEN as EN ISO 24966:2026 without any modification.

International
Standard
ISO 24966
First edition
Determination of flash point —
2026-03
Modified continuously closed cup
flash point (MCCCFP) method
Détermination du point d'éclair — Méthode modifiée du point
d'éclair en vase clos en continu (MCCCFP)
Reference number
ISO 24966:2026(en) © ISO 2026
ISO 24966:2026(en)
© ISO 2026
All rights reserved. Unless otherwise specified, or required in the context of its implementation, no part of this publication may
be reproduced or utilized otherwise in any form or by any means, electronic or mechanical, including photocopying, or posting on
the internet or an intranet, without prior written permission. Permission can be requested from either ISO at the address below
or ISO’s member body in the country of the requester.
ISO copyright office
CP 401 • Ch. de Blandonnet 8
CH-1214 Vernier, Geneva
Phone: [phone]
Email: [e-mail]
Website: www.iso.org
Published in Switzerland
ii
ISO 24966:2026(en)
Contents Page
Foreword .iv
Introduction .v
1 Scope . 1
2 Normative references . 1
3 Terms and definitions . 1
4 Principle . 2
5 Reagents and materials . 2
6 Apparatus . 2
7 Apparatus preparation . 2
7.1 General .2
7.2 Location of the apparatus .2
7.3 Cleaning the test chamber and sample cup .2
7.4 Apparatus assembly .3
7.5 Apparatus verification .3
8 Sampling . 3
9 Sample handling . 4
9.1 Sub-sampling .4
9.2 Sample containing undissolved water.4
9.3 Samples that are liquid at ambient temperature .4
9.4 Samples that are very viscous, semi-solid or solid at ambient temperature.4
10 Procedure . 4
10.1 General preparations .4
10.1.1 Settings .4
10.1.2 Dry cup heating procedure .5
10.1.3 Selection of initial temperature .5
10.2 Flash point test procedure .5
11 Calculation . 6
11.1 Conversion of barometric pressure reading .6
11.2 Correction of detected flash point to flash point at standard atmospheric pressure .6
12 Expression of results . 7
13 Precision . 7
13.1 General .7
13.2 Repeatability, r.7
13.3 Reproducibility, R .7
14 Test report . 7
Annex A (normative) Apparatus verification using reference materials . 9
Annex B (normative) Flash point apparatus .12
Bibliography .16

iii
ISO 24966:2026(en)
Foreword
ISO (the International Organization for Standardization) is a worldwide federation of national standards
bodies (ISO member bodies). The work of preparing International Standards is normally carried out through
ISO technical committees. Each member body interested in a subject for which a technical committee
has been established has the right to be represented on that committee. International organizations,
governmental and non-governmental, in liaison with ISO, also take part in the work. ISO collaborates closely
with the International Electrotechnical Commission (IEC) on all matters of electrotechnical standardization.
The procedures used to develop this document and those intended for its further maintenance are described
in the ISO/IEC Directives, Part 1. In particular, the different approval criteria needed for the different types
of ISO document should be noted. This document was drafted in accordance with the editorial rules of the
ISO/IEC Directives, Part 2 (see www.iso.org/directives).
ISO draws attention to the possibility that the implementation of this document may involve the use of (a)
patent(s). ISO takes no position concerning the evidence, validity or applicability of any claimed patent
rights in respect thereof. As of the date of publication of this document, ISO had not received notice of (a)
patent(s) which may be required to implement this document. However, implementers are cautioned that
this may not represent the latest information, which may be obtained from the patent database available at
www.iso.org/patents. ISO shall not be held responsible for identifying any or all such patent rights.
Any trade name used in this document is information given for the convenience of users and does not
constitute an endorsement.
For an explanation of the voluntary nature of standards, the meaning of ISO specific terms and expressions
related to conformity assessment, as well as information about ISO's adherence to the World Trade
Organization (WTO) principles in the Technical Barriers to Trade (TBT), see www.iso.org/iso/foreword.html.
This document was prepared by Technical Committee ISO/TC 28, Petroleum and related products, fuels and
lubricants from natural or synthetic sources, in collaboration with the European Committee for Standardization
(CEN) Technical Committee CEN/TC 19, Gaseous and liquid fuels, lubricants and related products of petroleum,
synthetic and biological origin, in accordance with the Agreement on technical cooperation between ISO and
CEN (Vienna Agreement).
Any feedback or questions on this document should be directed to the user’s national standards body. A
complete listing of these bodies can be found at www.iso.org/members.html.

iv
ISO 24966:2026(en)
Introduction
Flash point values are used in shipping, storage, handling, and safety regulations, as a classification property
to define flammable and combustible materials.
A flash point value can indicate the presence of highly volatile material(s) in a relatively non-volatile or
non-flammable material. Flash point testing can be a preliminary step to other investigations into the
composition of unknown materials.
It is not appropriate for flash point determinations to be carried out on potentially unstable, decomposable,
or explosive materials, unless it has been previously established that heating the specified quantity of such
materials in contact with the metallic components of the flash point apparatus, within the temperature
range required for the method, does not induce decomposition, explosion or other adverse effects.
Flash point values are not a constant physical-chemical property of materials tested. They are a function of
the apparatus design, the condition of the apparatus used, and the operational procedure carried out. Flash
point can therefore be defined only in terms of a standard test method, and no general valid correlation can
be guaranteed between results obtained by different test methods or with test apparatus different from
that specified.
[8]
ISO/TR 29662 gives useful guidance on carrying out flash point tests and interpreting their results.

v
International Standard ISO 24966:2026(en)
Determination of flash point — Modified continuously closed
cup flash point (MCCCFP) method
WARNING — The use of this document can involve hazardous materials, operations and equipment.
This document does not purport to address all of the safety problems associated with its use. It is
the responsibility of users of this document to take appropriate measures to ensure the safety and
health of personnel prior to the application of the standard, and to determine the applicability of any
other restrictions for this purpose.
1 Scope
This document describes a test method for the determination of the flash point of chemicals, lube oils, fuels
including aviation turbine fuel, diesel fuel, diesel/biodiesel blends and related products. The precision of
this method has been determined over the range of 24,5 °C to 229,5 °C.
NOTE Apparatus can determine the flash point at higher or lower temperatures than the precision range, however
the precision has not been determined.
2 Normative references
The following documents are referred to in the text in such a way that some or all of their content constitutes
requirements of this document. For dated references, only the edition cited applies. For undated references,
the latest edition of the referenced document (including any amendments) applies.
ISO 3170, Hydrocarbon Liquids — Manual sampling
ISO 3171, Petroleum liquids — Automatic pipeline sampling
3 Terms and definitions
For the purposes of this document, the following terms and definitions apply.
ISO and IEC maintain terminology databases for use in standardization at the following addresses:
— ISO Online browsing platform: available at https://www.iso.org/obp
— IEC Electropedia: available at https://www.electropedia.org/
3.1
flash point
lowest temperature of the test portion, adjusted to account for variations in atmospheric pressure from
101,3 kPa, at which application of an ignition source causes the vapours of the test portion to ignite under
specified conditions of test
Note 1 to entry: For the purpose of this test method, the test portion is deemed to have flashed when the ignited
vapour causes an instantaneous pressure increase of at least 20,0 kPa inside the closed test chamber.
3.2
arc
luminous discharge of electrical current that is formed when a strong current jumps a gap between two
electrodes
ISO 24966:2026(en)
4 Principle
A 2 ml test portion is introduced into the sample cup, which is then raised and pressed onto the lid to form
the continuously closed but unsealed test chamber. The lid is heated at a prescribed, constant rate. For the
flash tests, a high voltage arc of defined energy is discharged inside the test chamber at regular intervals.
After each arc application, the instantaneous pressure increase above the barometric pressure inside the
test chamber is monitored. When the pressure increase is equal to or exceeds 20,0 kPa, the temperature
at that point is recorded as the detected flash point. The detected flash point temperature is corrected for
the variation in ambient pressure from a standard pressure of 101,3 kPa. When no flash point is detected,
a defined amount of air dependent on the test portion temperature is introduced into the test chamber to
provide the necessary oxygen for the next flash test.
5 Reagents and materials
5.1 Cleaning solvent, for removal of traces of the sample from the sample cup and lid.
The choice of solvent depends upon the previous material tested, and the tenacity of the residue. Low
volatility aromatic (benzene free) solvents may be used to remove traces of oil, and mixed solvents such as
toluene-acetone-methanol can be efficacious for the removal of gum-type deposits.
5.2 Reference material (RM) for flash point, i.e. either a certified reference material (CRM) or secondary
working standard (SWS), or both, as specified in Annex A.
6 Apparatus
6.1 Apparatus specified in Annex B, including the details of the test chamber and sample cup together
with dimensions. The critical elements are shown in Figure B.1 and Figure B.2.
6.2 Circulating bath or tap water (optional), can be required for cooling the heat sink of the apparatus
for flash point test temperatures below 5 °C.
6.3 Cooling cup (optional), cup made of plastic material to avoid ice formation during cooling to initial
temperatures equal to or less than 0 °C.
6.4 Pipette or syringe, for the introduction of 2,0 ml ± 0,2 ml test portion.
7 Apparatus preparation
7.1 General
Follow the manufacturer’s instructions for the correct set-up, calibration, verification (7.5) and operation of
the apparatus.
7.2 Location of the apparatus
Support the apparatus (6.1) on a level and steady surface in a draught-free position.
7.3 Cleaning the test chamber and sample cup
Clean the sample cup, sample temperature sensor, lid, arc pins and stirring magnet with a tissue or with
an appropriate solvent (5.1) to remove any traces of gum or residue remaining from a previous test. When
solvents are used, dry with a stream of clean air to ensure complete removal.

ISO 24966:2026(en)
Cleaning arcs may be selected to burn off residuals from the arc pins. These cleaning arcs are automatically
initiated before the flash point test is started.
7.4 Apparatus assembly
Examine the sample cup and other parts to ensure that they are free from signs of damage and deposits.
7.5 Apparatus verification
7.5.1 Check the temperature sensors used to monitor the temperature of the test portion and of the
lid against a certified reference thermometer at least once a year. Use only reference thermometers with
calibration/verification traceable to a national certification organization. If the displayed temperature
readings deviate from the reference thermometer by more than 0,2 °C for the sample sensor and 0,5 °C for
the lid sensor, at either of the two temperature calibration points, follow the manufacturer's instructions for
corrections.
7.5.2 Check the pressure transducer at least once a year using the atmospheric barometric pressure as a
reference.
If the displayed atmospheric pressure deviates from the atmospheric pressure by more than 0,5 kPa, follow
the manufacturer's instructions for corrections.
WARNING — Many aneroid barometers, such as those used at weather stations and airports, are
pre-corrected to give sea level readings. These shall not be used for verification of the pressure
transducer.
7.5.3 Verify the correct amount of air being introduced at least once per year. Follow the manufacturer’s
instructions.
7.5.4 Verify the correct functioning of the apparatus at least once a year by testing a certified reference
material (CRM) (as specified in 5.2 and Annex A). It is recommended that more frequent verification checks
are made using an RM (as specified in 5.2 and Annex A).
7.5.5 The result of a single test obtained for an RM shall be equal to or less than R /√2 from the certified
value of the CRM or from the accepted reference value (ARV) of the SWS, where R is the reproducibility.
7.5.6 The numerical values obtained during the verification check shall not be used to provide a bias
statement, nor shall they be used to make any correction to the flash points subsequently determined using
the
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