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ASTM D6352-19e1

(Test Method)

Standard Test Method for Boiling Range Distribution of Petroleum Distillates in Boiling Range from 174 °C to 700 °C by Gas Chromatography

Standard Test Method for Boiling Range Distribution of Petroleum Distillates in Boiling Range from 174 °C to 700 °C by Gas Chromatography

SIGNIFICANCE AND USE
5.1 The boiling range distribution of medium and heavy petroleum distillate fractions provides an insight into the composition of feed stocks and products related to petroleum refining processes (for example, hydrocracking, hydrotreating, visbreaking, or deasphalting). The gas chromatographic simulation of this determination can be used to replace conventional distillation methods for control of refining operations. This test method can be used for product specification testing with the mutual agreement of interested parties.  
5.2 This test method extends the scope of boiling range determination by gas chromatography to include medium and heavy petroleum distillate fractions beyond the scope of Test Method D2887 (538 °C).  
5.3 Boiling range distributions obtained by this test method have not been analyzed for correlation to those obtained by low efficiency distillation, such as with Test Method D86 or D1160.
SCOPE
1.1 This test method covers the determination of the boiling range distribution of petroleum distillate fractions. The test method is applicable to petroleum distillate fractions having an initial boiling point greater than 174 °C (345 °F) and a final boiling point of less than 700 °C (1292 °F) (C10 to C90) at atmospheric pressure as measured by this test method.  
1.2 The test method is not applicable for the analysis of petroleum or petroleum products containing low molecular weight components (for example naphthas, reformates, gasolines, crude oils). Materials containing heterogeneous components (for example alcohols, ethers, acids, or esters) or residue are not to be analyzed by this test method. See Test Methods D3710, D2887, or D5307 for possible applicability to analysis of these types of materials.  
1.3 The values stated in SI units are to be regarded as standard. The values stated in inch-pound units are for information only and may be included as parenthetical values.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

General Information

Status
Published
Publication Date
30-Nov-2019
ICS
75.080 - Petroleum products in general
Technical Committee
D02 - Petroleum Products, Liquid Fuels, and Lubricants
Drafting Committee
D02.04.0H - Chromatographic Distribution Methods
Current Stage
Ref Project

Relations

Replaces
ASTM D6352-19 - Standard Test Method for Boiling Range Distribution of Petroleum Distillates in Boiling Range from 174 °C to 700 °C by Gas Chromatography
Effective Date
01-Dec-2019
Refers
ASTM D2892-15 - Standard Test Method for Distillation of Crude Petroleum (15-Theoretical Plate Column)
Effective Date
01-Apr-2015
Refers
ASTM E594-96(2019) - Standard Practice for Testing Flame Ionization Detectors Used in Gas or Supercritical Fluid Chromatography
Effective Date
01-Sep-2019
Refers
ASTM D2887-19 - Standard Test Method for Boiling Range Distribution of Petroleum Fractions by Gas Chromatography
Effective Date
01-Jul-2019
Refers
ASTM D4626-95(2019) - Standard Practice for Calculation of Gas Chromatographic Response Factors
Effective Date
01-Dec-2019
Refers
ASTM D2892-20 - Standard Test Method for Distillation of Crude Petroleum (15-Theoretical Plate Column)
Effective Date
01-Jun-2020
Refers
ASTM D1160-15 - Standard Test Method for Distillation of Petroleum Products at Reduced Pressure
Effective Date
01-Feb-2015
Refers
ASTM D2892-18 - Standard Test Method for Distillation of Crude Petroleum (15-Theoretical Plate Column)
Effective Date
01-Apr-2018
Refers
ASTM D2892-17 - Standard Test Method for Distillation of Crude Petroleum (15-Theoretical Plate Column)
Effective Date
01-May-2017
Refers
ASTM D6299-17 - Standard Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance
Effective Date
01-Jan-2017
Refers
ASTM D2887-15 - Standard Test Method for Boiling Range Distribution of Petroleum Fractions by Gas Chromatography
Effective Date
01-Jul-2015
Refers
ASTM D86-16 - Standard Test Method for Distillation of Petroleum Products and Liquid Fuels at Atmospheric Pressure
Effective Date
01-Jul-2016
Refers
ASTM D2892-16 - Standard Test Method for Distillation of Crude Petroleum (15-Theoretical Plate Column)
Effective Date
01-Dec-2016
Refers
ASTM D6299-17a - Standard Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance
Effective Date
15-Nov-2017
Refers
ASTM D6299-17b - Standard Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance
Effective Date
15-Dec-2017
Referred By
ASTM F3337-19 - Standard Guide for Taking Property and Behavior Measurements on Weathered Fractions of Oil
Effective Date
01-Dec-2019
Referred By
ASTM D7213-15(2019) - Standard Test Method for Boiling Range Distribution of Petroleum Distillates in the Boiling Range from 100 °C to 615 °C by Gas Chromatography
Effective Date
01-Dec-2019
Referred By
ASTM D7169-23 - Standard Test Method for Boiling Point Distribution of Samples with Residues Such as Crude Oils and Atmospheric and Vacuum Residues by High Temperature Gas Chromatography
Effective Date
01-Dec-2019
Referred By
ASTM D7798-20 - Standard Test Method for Boiling Range Distribution of Petroleum Distillates with Final Boiling Points up to 538 °C by Ultra Fast Gas Chromatography (UF GC)
Effective Date
01-Dec-2019
Referred By
ASTM D7398-21 - Standard Test Method for Boiling Range Distribution of Fatty Acid Methyl Esters (FAME) in the Boiling Range from 100 °C to 615 °C by Gas Chromatography
Effective Date
01-Dec-2019
Referred By
ASTM D7807-20 - Standard Test Method for Determination of Boiling Range Distribution of Hydrocarbon and Sulfur Components of Petroleum Distillates by Gas Chromatography and Chemiluminescence Detection
Effective Date
01-Dec-2019
Referred By
ASTM D7500-15(2019) - Standard Test Method for Determination of Boiling Range Distribution of Distillates and Lubricating Base Oils—in Boiling Range from 100 °C to 735 °C by Gas Chromatography
Effective Date
01-Dec-2019
Referred By
ASTM D6417-15(2019) - Standard Test Method for Estimation of Engine Oil Volatility by Capillary Gas Chromatography
Effective Date
01-Dec-2019

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ASTM D6352-19e1 - Standard Test Method for Boiling Range Distribution of Petroleum Distillates in Boiling Range from 174 °C to 700 °C by Gas ChromatographyASTM D6352-19e1 - Standard Test Method for Boiling Range Distribution of Petroleum Distillates in Boiling Range from 174 °C to 700 °C by Gas Chromatography
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ASTM D6352-19e1 - Standard Test Method for Boiling Range Distribution of Petroleum Distillates in Boiling Range from 174 °C to 700 °C by Gas Chromatography
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Standards Content (Sample)

This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the
Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
´1
Designation: D6352 − 19
Standard Test Method for
Boiling Range Distribution of Petroleum Distillates in
Boiling Range from 174 °C to 700 °C by Gas
1
Chromatography
This standard is issued under the fixed designation D6352; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision.Anumber in parentheses indicates the year of last reapproval.A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1
ε NOTE—Editorially added research report information to Table 3 in May 2020.
1. Scope* 2. Referenced Documents
2
2.1 ASTM Standards:
1.1 Thistestmethodcoversthedeterminationoftheboiling
D86Test Method for Distillation of Petroleum Products and
range distribution of petroleum distillate fractions. The test
Liquid Fuels at Atmospheric Pressure
methodisapplicabletopetroleumdistillatefractionshavingan
D1160TestMethodforDistillationofPetroleumProductsat
initial boiling point greater than 174°C (345°F) and a final
Reduced Pressure
boiling point of less than 700°C (1292°F) (C10 to C90) at
D2887Test Method for Boiling Range Distribution of Pe-
atmospheric pressure as measured by this test method.
troleum Fractions by Gas Chromatography
1.2 The test method is not applicable for the analysis of D2892Test Method for Distillation of Crude Petroleum
(15-Theoretical Plate Column)
petroleum or petroleum products containing low molecular
D3710TestMethodforBoilingRangeDistributionofGaso-
weight components (for example naphthas, reformates,
line and Gasoline Fractions by Gas Chromatography
gasolines, crude oils). Materials containing heterogeneous
3
(Withdrawn 2014)
components (for example alcohols, ethers, acids, or esters) or
D4626Practice for Calculation of Gas Chromatographic
residue are not to be analyzed by this test method. See Test
Response Factors
MethodsD3710,D2887,orD5307forpossibleapplicabilityto
D5307Test Method for Determination of Boiling Range
analysis of these types of materials.
Distribution of Crude Petroleum by Gas Chromatography
3
1.3 The values stated in SI units are to be regarded as (Withdrawn 2011)
D6299Practice for Applying Statistical Quality Assurance
standard. The values stated in inch-pound units are for infor-
and Control Charting Techniques to Evaluate Analytical
mation only and may be included as parenthetical values.
Measurement System Performance
1.4 This standard does not purport to address all of the
E355PracticeforGasChromatographyTermsandRelation-
safety concerns, if any, associated with its use. It is the
ships
responsibility of the user of this standard to establish appro-
E594Practice for Testing Flame Ionization Detectors Used
priate safety, health, and environmental practices and deter-
in Gas or Supercritical Fluid Chromatography
mine the applicability of regulatory limitations prior to use.
E1510Practice for Installing Fused Silica Open Tubular
1.5 This international standard was developed in accor- Capillary Columns in Gas Chromatographs
dance with internationally recognized principles on standard-
3. Terminology
ization established in the Decision on Principles for the
Development of International Standards, Guides and Recom-
3.1 Definitions—This test method makes reference to many
mendations issued by the World Trade Organization Technical common gas chromatographic procedures, terms, and relation-
Barriers to Trade (TBT) Committee. ships. For definitions of these terms used in this test method,
refer to Practices E355, E594, and E1510.
1 2
This test method is under the jurisdiction of ASTM Committee D02 on For referenced ASTM standards, visit the ASTM website, www.astm.org, or
Petroleum Products, Liquid Fuels, and Lubricants and is the direct responsibility of contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
Subcommittee D02.04.0H on Chromatographic Distribution Methods. Standards volume information, refer to the standard’s Document Summary page on
Current edition approved Dec. 1, 2019. Published February 2020. Originally the ASTM website.
3
approved in 1998. Last previous edition approved in 2015 as D6352–15. DOI: The last approved version of this historical standard is referenced on
10.1520/D6352-19E01. www.astm.org.
*A Summary of Changes section appears at the end of this standard
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1

---------------------- Page: 1 ----------------------
´1
D6352 − 19
3.2 Definitions of Terms Specific to This Standard: 4.4 Retentiontimesofknownnormalparaffinhydrocarbons,
3.2.1 areaslice,n—thearearesultingfromtheintegration
...

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5.1 Sulfur present as mercaptans or as hydrogen sulfide in distillate fuels and solvents can attack many metallic and non-metallic materials in fuel and other distribution systems. A negative result in the doctor test ensures that the concentration of these compounds is insufficient to cause such problems in normal use.
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1.1 This test method covers the determination of acidic components in crude oil and petroleum products including waxes, bitumen, base stocks, and asphalts that are soluble in mixtures of xylenes and propan-2-ol. It is applicable for the determination of acids whose dissociation constants in water are larger than 10–9; extremely weak acids whose dissociation constants are smaller than 10–9 do not interfere. The values obtained by this test method may not be numerically equivalent to other acid value measurements. The range of KOH acid numbers included in the precision statement is 0.1 mg/g to 16 mg/g.  
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1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Some specific hazards statements are given in Section 7 on Safety Precautions.  
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5.1 For petroleum products and biodiesel fuels, cloud point of a petroleum product is an index of the lowest temperature of their utility for certain applications.
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1.1 This test method covers only petroleum products and biodiesel fuels that are transparent in layers 40 mm in thickness, and with a cloud point below 49 °C.
Note 1: The interlaboratory program consisted of petroleum products of Test Method D1500 color of 3.5 and lower. The precisions stated in this test method may not apply to samples with ASTM color higher than 3.5.  
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.3 WARNING—Mercury has been designated by many regulatory agencies as a hazardous substance that can cause serious medical issues. Mercury, or its vapor, has been demonstrated to be hazardous to health and corrosive to materials. Use caution when handling mercury and mercury-containing products. See the applicable product Safety Data Sheet (SDS) for additional information. The potential exists that selling mercury or mercury-containing products, or both, is prohibited by local or national law. Users must determine legality of sales in their location.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements, see Section 7.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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ASTM D2549-23(Test Method)
Standard Test Method for Separation of Representative Aromatics and Nonaromatics Fractions of High-Boiling Oils by Elution Chromatography

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5.1 The determination of compound types by mass spectrometry requires, in some instances, a preliminary separation of the petroleum sample into representative aromatics and nonaromatics fractions, as in Test Methods D2425, D2786, and D3239. This test method provides a suitable separation technique for this application.
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1.1 This test method covers the separation and determination of representative aromatics and nonaromatics fractions from hydrocarbon mixtures that boil between 232 °C and 538 °C (450 °F and 1000 °F). Alternative procedures are provided for the separation of 2 g or 10 g of hydrocarbon mixture.  
Note 1: Some components may not be eluted from the chromatographic column for some types of samples under the conditions used in this method.
Note 2: Test Method D2007 is an alternative method of separating high-boiling oils into polar compounds, aromatics, and saturates fractions.  
1.2 An alternative procedure is provided to handle samples boiling below 232 °C (450 °F), but whose 5 % point is above 178 °C (350 °F) as determined by Test Method D2887. This procedure is given in Appendix X1.  
1.3 The values stated in acceptable SI units are to be regarded as the standard. The values given in parentheses are provided for information purposes only.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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