SIST EN ISO 20764:2004

Petroleum and related products - Preparation of a test portion of high-boiling liquids for the determination of water content - Nitrogen purge method (ISO 20764:2003)

This  International Standard specifies two procedures for the preparation of test portions from petroleum and related products boiling above 200°C, which can then be used for the determination of total water content within the range of 3 mg/kg to 1000 mg/kg. The method is applicable to unused and used lubricating oils, non-aqueous hydrolic fluids and high-boiling solvents. The test portions generated by these procedures are suitable for standard Karl Fischer water content determinations, such as those described in ISO 6296
and ISO 12937.

Mineralölerzeugnisse und verwandte Produkte - Herstellung eines Probenteiles von hochsiedenden Flüssigkeiten für die Bestimmung des Wassergehaltes - Verfahren mit Stickstoff-Spülung (ISO 20764:2003)

Diese Internationale Norm legt zwei Verfahren zur Herstellung von Probenteilen von Erdöl und verwandten Produkten, die bei mehr als 200 °C sieden, fest. Die Probenteile können dann für die Bestimmung des Gesamtwassergehaltes im Bereich vom 3 mg/kg bis 1000 mg/kg verwendet werden. Dieses Verfahren ist auf gebrauchte und ungebrauchte Schmieröle, nichtwässrige Druckflüssigkeiten und hochsiedende Lösungsmittel anwendbar. Die Probenteile, die mit diesen Verfahren erzeugt werden, sind für standardmäßige Bestimmungen des Wassergehaltes nach Karl Fischer wie z.B. für diejenige Bestimmungen geeignet, die in ISO 6296 (siehe [1] im Literaturverzeichnis) oder ISO 12937 (siehe [2] im Literatur-verzeichnis) beschrieben sind.

Pétrole et produits connexes - Préparation d'une prise d'essai de liquides a haut point d'ébullition en vue du dosage de l'eau - Méthode par purge a l'azote (ISO 20764:2003)

L'ISO 20764:2003 spécifie deux méthodes permettant la préparation de prises d'essai à partir de pétrole et de produits connexes distillant au-dessus de 200 degrés Celsius. Celles-ci peuvent alors faire l'objet d'une détermination de leur teneur totale en eau dans la plage comprise entre 3 mg/kg et 1 000 mg/kg. La méthode est applicable à la fois aux huiles lubrifiantes neuves et usagées, aux fluides hydrauliques non aqueux et aux solvants de haut point d'ébullition. Les prises d'essai obtenues au moyen de ces méthodes conviennent pour la détermination de leur teneur en eau par une méthode de Karl Fischer standard, telle que celle décrite dans l'ISO 6296 ou dans l'ISO 12937.

Naftni in sorodni proizvodi - Priprava preskusnega vzorca tekočine z visokim vreliščem za določevanje vode - Metoda prepihovanja z dušikom (ISO 20764:2003)

General Information

• Status: Published
• Publication Date: 30-Jun-2004
• ICS: 75.080 - Petroleum products in general
• Technical Committee: NAD - Petroleum products, lubricants and related products
• Current Stage: 6060 - National Implementation/Publication (Adopted Project)
• Start Date: 01-Jul-2004
• Due Date: 01-Jul-2004
• Completion Date: 01-Jul-2004
• Directive: 92/104/EC - Council Directive 92/104/EEC of 3 December 1992 on the minimum requirements for improving the safety and health protection of workers in surface and underground mineral-extracting industries (twelfth individual Directive within the meaning of Article 16 (1) of Directive 89/391/EEC)
• Mandate: M/238 - Mandate to CEN for standardization in the field of fire-resistant hydraulic fluids used for power transmission and control (hydrostatic and hydrokinetic)
• Ref Project: EN ISO 20764:2003 - Petroleum and related products - Preparation of a test portion of high-boiling liquids for the determination of water content - Nitrogen purge method (ISO 20764:2003)

Standards Content (Sample)

SLOVENSKI STANDARD
SIST EN ISO 20764:2004
01-julij-2004
1DIWQLLQVRURGQLSURL]YRGL3ULSUDYDSUHVNXVQHJDY]RUFDWHNRþLQH]YLVRNLP
YUHOLãþHP]DGRORþHYDQMHYRGH0HWRGDSUHSLKRYDQMD]GXãLNRP,62
Petroleum and related products - Preparation of a test portion of high-boiling liquids for
the determination of water content - Nitrogen purge method (ISO 20764:2003)
Mineralölerzeugnisse und verwandte Produkte - Herstellung eines Probenteiles von
hochsiedenden Flüssigkeiten für die Bestimmung des Wassergehaltes - Verfahren mit
Stickstoff-Spülung (ISO 20764:2003)
Pétrole et produits connexes - Préparation d'une prise d'essai de liquides a haut point
d'ébullition en vue du dosage de l'eau - Méthode par purge a l'azote (ISO 20764:2003)
Ta slovenski standard je istoveten z: EN ISO 20764:2003
ICS:
75.080 Naftni proizvodi na splošno Petroleum products in
general
SIST EN ISO 20764:2004 en
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

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SIST EN ISO 20764:2004

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SIST EN ISO 20764:2004
EUROPEAN STANDARD
EN ISO 20764
NORME EUROPÉENNE
EUROPÄISCHE NORM
October 2003
ICS 75.080
English version
Petroleum and related products - Preparation of a test portion of
high-boiling liquids for the determination of water content -
Nitrogen purge method (ISO 20764:2003)
Pétrole et produits connexes - Préparation d'une prise Mineralölerzeugnisse und verwandte Produkte -
d'essai de liquides à haut point d'ébullition en vue du Herstellung eines Probenteiles von hochsiedenden
dosage de l'eau - Méthode par purge à l'azote (ISO Flüssigkeiten für die Bestimmung des Wassergehaltes -
20764:2003) Verfahren mit Stickstoff-Spülung (ISO 20764:2003)
This European Standard was approved by CEN on 1 October 2003.
CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European
Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national
standards may be obtained on application to the Management Centre or to any CEN member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by translation
under the responsibility of a CEN member into its own language and notified to the Management Centre has the same status as the official
versions.
CEN members are the national standards bodies of Austria, Belgium, Czech Republic, Denmark, Finland, France, Germany, Greece,
Hungary, Iceland, Ireland, Italy, Luxembourg, Malta, Netherlands, Norway, Portugal, Slovakia, Spain, Sweden, Switzerland and United
Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION
EUROPÄISCHES KOMITEE FÜR NORMUNG
Management Centre: rue de Stassart, 36  B-1050 Brussels
© 2003 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN ISO 20764:2003 E
worldwide for CEN national Members.

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SIST EN ISO 20764:2004
EN ISO 20764:2003 (E)
Foreword
This document (EN ISO 20764:2003) has been prepared by Technical Committee ISO/TC 28
"Petroleum products and lubricants" in collaboration with Technical Committee CEN/TC 19
"Petroleum products, lubricants and related products", the secretariat of which is held by NEN.
This European Standard shall be given the status of a national standard, either by publication of
an identical text or by endorsement, at the latest by April 2004, and conflicting national
standards shall be withdrawn at the latest by April 2004.
According to the CEN/CENELEC Internal Regulations, the national standards organizations of
the following countries are bound to implement this European Standard: Austria, Belgium, Czech
Republic, Denmark, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy,
Luxembourg, Malta, Netherlands, Norway, Portugal, Slovakia, Spain, Sweden, Switzerland and
the United Kingdom.
Endorsement notice
The text of ISO 20764:2003 has been approved by CEN as EN ISO 20764:2003 without any
modifications.
NOTE Normative references to International Standards are listed in Annex ZA (normative).
2

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SIST EN ISO 20764:2004
EN ISO 20764:2003 (E)
Annex ZA
(normative)
Normative references to international publications
with their relevant European publications
This European Standard incorporates by dated or undated reference, provisions from other
publications. These normative references are cited at the appropriate places in the text and the
publications are listed hereafter. For dated references, subsequent amendments to or revisions of
any of these publications apply to this European Standard only when incorporated in it by
amendment or revision. For undated references the latest edition of the publication referred to
applies (including amendments).
NOTE Where an International Publication has been modified by common modifications, indicated
by (mod.), the relevant EN/HD applies.
Publication Year Title EN Year
ISO 3170 1998 Petroleum liquids - Manual EN ISO 3170 1988
sampling
3

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SIST EN ISO 20764:2004

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SIST EN ISO 20764:2004


INTERNATIONAL ISO
STANDARD 20764
First edition
2003-10-15


Petroleum and related products —
Preparation of a test portion of high-
boiling liquids for the determination of
water content — Nitrogen purge method
Pétrole et produits connexes — Préparation d'une prise d'essai de
liquides à haut point d'ébullition en vue du dosage de l'eau — Méthode
par purge à l'azote




Reference number
ISO 20764:2003(E)
©
ISO 2003

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SIST EN ISO 20764:2004
ISO 20764:2003(E)
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ii © ISO 2003 — All rights reserved

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SIST EN ISO 20764:2004
ISO 20764:2003(E)
Foreword
ISO (the International Organization for Standardization) is a worldwide federation of national standards bodies
(ISO member bodies). The work of preparing International Standards is normally carried out through ISO
technical committees. Each member body interested in a subject for which a technical committee has been
established has the right to be represented on that committee. International organizations, governmental and
non-governmental, in liaison with ISO, also take part in the work. ISO collaborates closely with the
International Electrotechnical Commission (IEC) on all matters of electrotechnical standardization.
International Standards are drafted in accordance with the rules given in the ISO/IEC Directives, Part 2.
The main task of technical committees is to prepare International Standards. Draft International Standards
adopted by the technical committees are circulated to the member bodies for voting. Publication as an
International Standard requires approval by at least 75 % of the member bodies casting a vote.
Attention is drawn to the possibility that some of the elements of this document may be the subject of patent
rights. ISO shall not be held responsible for identifying any or all such patent rights.
ISO 20764 was prepared by Technical Committee ISO/TC 28, Petroleum products and lubricants.

© ISO 2003 — All rights reserved iii

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SIST EN ISO 20764:2004

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SIST EN ISO 20764:2004
INTERNATIONAL STANDARD ISO 20764:2003(E)

Petroleum and related products — Preparation of a test portion
of high-boiling liquids for the determination of water content —
Nitrogen purge method
WARNING — The use of this International Standard may involve hazardous materials, operations and
equipment. This International Standard does not purport to address all of the safety problems
associated with its use. It is the responsibility of the user of this International Standard to establish
appropriate safety and health practices and determine the applicability of regulatory limitations prior
to use.
1 Scope
This International Standard specifies two procedures for the preparation of test portions from petroleum and
related products boiling above 200 °C, which can then be used for the determination of total water content
within the range of 3 mg/kg to 1 000 mg/kg. The method is applicable to unused and used lubricating oils,
non-aqueous hydraulic fluids and high-boiling solvents. The test portions generated by these procedures are
suitable for standard Karl Fischer water-content determinations, such as those described in ISO 6296 (see [1]
in the Bibliography) and ISO 12937 (see [2] in the Bibliography).
2 Normative references
The following referenced documents are indispensable for the application of this document. For dated
references, only the edition cited applies. For undated references, the latest edition of the referenced
document (including any amendments) applies.
ISO 383:1976, Laboratory glassware — Interchangeable conical ground joints
1)
ISO 3170:— , Petroleum liquids — Manual sampling
3 Principle
3.1 Atmospheric pressure
The water is driven out of a weighed portion of the material under test by a nitrogen purge at 120 °C. It is then
condensed in methanol (4.2) held in a titration vessel (5.4) at approximately − 77 °C. The resulting
water/methanol solution is immediately available for the determination of water content by Karl Fischer titration.
3.2 Reduc
...