2022-01-2546 - Pravilnik o spremljanju stanja kmetijskih tal

This document specifies two methods for digestion of soil, treated biowaste, sludge and waste by the use of an aqua regia digestion.
Digestion with aqua regia will not necessarily accomplish total decomposition of the sample. The extracted analyte concentrations may not necessarily reflect the total content in the sample but represent the aqua regia soluble metals under the condition of this test procedure. It is generally agreed that for environmental analysis purposes, the results are fit for the intended purpose to protect the environment.
This document is applicable for the following elements:
Aluminium (Al), antimony (Sb), arsenic (As), barium (Ba), beryllium (Be), boron (B), cadmium (Cd), calcium (Ca), chromium (Cr), cobalt (Co), copper (Cu), iron (Fe), lead (Pb), magnesium (Mg), manganese (Mn), mercury (Hg), molybdenum (Mo), nickel (Ni), phosphorus (P), potassium (K), selenium (Se), silver (Ag), sodium (Na), strontium (Sr), sulfur (S), tellurium (Te), thallium (Tl), tin (Sn), titanium (Ti), vanadium (V), and zinc (Zn).
This document can also be applied for the digestion of other elements, provided the user has verified the applicability.

ISO 12914:2012 specifies a method for microwave-assisted extraction of elements from samples using aqua regia as the extraction solution for the determination of elements. This method is applicable to all types of soil and soil material.

ISO 14507:2003 specifies three methods for the pretreatment of soil samples in the laboratory prior to the determination of organic contaminants:
if volatile organic compounds are to be measured;
if moderately volatile to non-volatile organic compounds are to be measured, if the result of the subsequent analysis must be accurate and reproducible, and if the sample contains particles larger than 2 mm and/or the contaminant is heterogeneously distributed;
if non-volatile organic compounds are to be measured and the extraction procedure prescribes a field-moist sample, or if the largest particles of the sample are smaller than 2 mm and the contaminant is homogeneously distributed. This procedure is also applicable if reduced accuracy and repeatability are acceptable.
The pretreatment described in ISO 14507:2003 is used in combination with an extraction procedure in which the contaminant is available for the extraction liquid.
NOTE For the pretreatment of soil samples for the purposes of determining non-volatile inorganic compounds and physico-chemical soil characteristics, see ISO 11464.

This document provides guidance on the sampling of soils of
— natural and near-natural sites,
— natural arboreal areas including forests and woods,
— areas used for agriculture (arable and pasture sites),
— areas used for horticulture (including domestic gardens, allotments), and
— areas used for special crop-cultivation, orchards, vineyards, commercial plantations and forests, etc.
It is applicable to
— soil investigations and evaluations in the field, and
— collection of samples for chemical, geochemical, physical, and biological characterization of soil and soil materials in the laboratory.
This document sets out appropriate strategies for the design of sampling programmes, field procedures and subsequent treatment of samples for transport and storage prior to sample pretreatment (e.g. drying, milling). It is intended to be used in conjunction with the other parts of the ISO 18400 series. Attention is, in particular, drawn to the requirements concerning collection, handling and storage of soil for assessment of biological functions in ISO 18400-206.
NOTE 1 Groundwater and surface water can be adversely impacted by agricultural and related activities, such as nitrates and pesticides, and by translocation of soil particles. In turn, knowledge about water quality can provide information about possible sources of groundwater contamination or contaminating run-off. Investigation of groundwater and surface water quality is outside of the scope of this document; relevant guidance is given in the ISO 5667 series of standards. ISO 15175 provides guidance on the relationship between soil properties and groundwater quality.
NOTE 2 It could also be appropriate to investigate ambient air, vegetation, potable water supplies and a variety of other media depending on the findings of the preliminary investigation.

This document gives guidance on the:
— investigation of sites, where either it is known that soil contamination is present, or the presence of soil contamination is suspected;
— investigation of sites where no soil contamination is expected, but the soil quality is to be determined (e.g. to make sure that there is no contamination present);
— investigation in anticipation of a need to manage re-use or disposal of excavated soil which might be contaminated;
— collection of information that is necessary for risk assessment and/or the development of remedial action plans (e.g. whether remediation is required and suggestions as to how this might be best achieved).
Although the information on soil quality for the risk assessment and/or the development of remedial action plans is gathered by applying this document, it does not give guidance on the decisions and actions that follow from a site investigation, for example, risk assessment and decisions about the requirements for remediation (if any).

ISO 18400-105:2017 establishes general principles for packing, preservation, transport and delivery of samples of soil and related materials with an emphasis on requirements for when chemical analysis of the samples is required, but with the intention that the general procedures are to be adapted as appropriate when other forms of testing are required (e.g. biological testing, physical tests on disturbed or undisturbed samples). Special procedures for specific sampling purposes are given in other parts of ISO 18400 (see also 7.2).
ISO 18400-105:2017 is intended to be read in conjunction with ISO 18512.

ISO/IEC 17025:2017 specifies the general requirements for the competence, impartiality and consistent operation of laboratories.
ISO/IEC 17025:2017 is applicable to all organizations performing laboratory activities, regardless of the number of personnel.
Laboratory customers, regulatory authorities, organizations and schemes using peer-assessment, accreditation bodies, and others use ISO/IEC 17025:2017 in confirming or recognizing the competence of laboratories.

ISO 11464:2006 specifies the pretreatments required for soil samples that are to be subjected to physico-chemical analyses of stable and non-volatile parameters and describes the following five types of pretreatment of samples: drying, crushing, sieving, dividing and milling.
The pretreatment procedures described in ISO 11464:2006 are not applicable if they affect the results of the determinations to be made. ISO 11464:2006 is also not applicable to samples when volatile compounds are measured. In general, International Standards for analytical methods will state when it is necessary to adopt other procedures.

Specifies a method for the extraction, with aqua regia, of trace elements from soils and similar materials containing less than about 20 % (m/m) organic carbon. Materials containing more than about 20 % (m/m) organic carbon will require treatment with additional nitric acid. The resulting solution is suitable for the determination of trace elements using appropriate atomic spectrometric techniques.