CEN/TS 13649:2014
(Main)Stationary source emissions - Determination of the mass concentration of individual gaseous organic compounds - Sorptive sampling method followed by solvent extraction or thermal desorption
Stationary source emissions - Determination of the mass concentration of individual gaseous organic compounds - Sorptive sampling method followed by solvent extraction or thermal desorption
This Technical Specification specifies procedures for the sampling, preparation and analysis of individual volatile organic compounds (VOCs) in waste gas, such as those arising from solvent using processes. Sampling occurs by adsorption on sorbents, preparation by solvent extraction or thermodesorption and analysis by gas chromatography.
Examples of individual VOC are given in relevant industry sector BAT Reference documents (BREFs).
The results obtained are expressed as the mass concentration (mg/m3) of the individual gaseous organic compounds. This document is suitable for measuring individual VOCs whose ranges vary depending on compound and test method, refer to Annex B and C.
This Technical Specification may be used to meet the monitoring requirements of the Industrial Emission Directive (IED) and associated supporting documents.
This Technical Specification is not suitable for measuring total organic carbon (TOC). For the measurement of the mass concentration of total organic carbon then EN 12619 [3] is applicable.
Emissionen aus stationären Quellen - Bestimmung der Massenkonzentration von gasförmigen organischen Einzelverbindungen - Sorptive Probenahme und Lösemittelextraktion oder thermische Desorption
Diese Technische Spezifikation legt die Durchführung der Probenahme von einzelnen flüchtigen organischen Verbindungen (VOCs) aus Abgasen, sowie die Aufbereitung und Analyse der Proben fest. Quelle der Abgase können z. B. Prozesse sein, bei denen Lösemittel eingesetzt werden.
Beispiele von einzelnen VOC werden in den relevanten branchenspezifischen BAT-Referenzdokumenten (BREFs) genannt. Die in diesem Dokument beschriebenen Verfahren sind auf gaschromatographisch bestimmbare Verbindungen beschränkt.
Die Messergebnisse werden als Massenkonzentration (mg/m3) der gasförmigen organischen Einzelverbindungen angegeben. Die Messbereiche der VOCs, für die dieses Dokument anwendbar ist, variieren je nach Verbindung und Messverfahren (siehe Anhänge B und C).
Diese Technische Spezifikation kann angewendet werden, um die Anforderungen der Richtlinie über Industrieemissionen (IED) und zugehöriger Dokumente zu erfüllen.
Diese Technische Spezifikation ist nicht für die Messung des gesamten organisch gebundenen Kohlenstoffs (TOC) geeignet. Hierfür ist EN 12619 anzuwenden.
Emissions de sources fixes - Détermination de la concentration massique en composés organiques gazeux individuels - Échantillonnage par adsorption et extraction par solvant ou thermodésorption
La présente Norme européenne spécifie des modes opératoires pour l'échantillonnage, la préparation et l'analyse de composés organiques volatils individuels (COV) dans les effluents gazeux, tels que ceux issus des procédés utilisant des solvants. Elle constitue une méthode de référence.
Les résultats obtenus en utilisant la présente norme sont exprimés en concentration massique (mg/m3) de composés organiques gazeux individuels. La présente norme convient au mesurage des COV individuels dont la concentration avoisine les 0,5 mg/m3 (méthodes par adsorption sur/extraction par solvant) ou les 0,005 mg/m3 (méthodes de thermodésorption). La gamme supérieure varie selon la méthode sélectionnée.
Une autre méthode peut être utilisée à condition que l'utilisateur puisse démontrer l'équivalence de cette méthode, conformément à la Spécification technique CEN/TS 14793, à la satisfaction de l'organisme d'accréditation national ou de la loi en vigueur.
La présente norme peut être utilisée pour répondre aux exigences de surveillance des Directives CE applicables.
La présente norme peut être utilisée pour d'autres composés organiques, sous réserve de validation.
La présente norme ne convient pas au mesurage du carbone organique total (COT). Pour le mesurage de la concentration massique du carbone organique total, l'EN 12619 est applicable.
Emisije nepremičnih virov - Določevanje masne koncentracije posameznih organskih spojin v plinasti fazi - Vzorčenje z adsorpcijo in ekstrakcija s topilom ali termična desorpcija
Ta evropski standard določa postopke za vzorčenje, pripravo in analizo posameznih hlapnih organskih spojin (VOC) v odpadnem plinu, kot so spojine, ki nastanejo pri postopkih, pri katerih se uporablja topilo. To je referenčna metoda.
Rezultati, pridobljeni z uporabo tega standarda, so izraženi kot masna koncentracija (mg/m³) posameznih organskih spojin v plinasti fazi. Ta standard je primeren za merjenje posameznih hlapnih organskih spojin v koncentraciji od približno 0,5 mg/m³ (ekstrakcija z adsorbentom v trdni fazi/ekstrakcija s topilom) ali 0,005 mg/m3 (termična desorpcija). Zgornja meja se določi z izbrano metodo.
Alternativna metoda se lahko uporabi, če lahko uporabnik dokaže njeno enakovrednost s to metodo v skladu s tehnično specifikacijo CEN/TS 14793, ki jo priznava tudi nacionalni akreditacijski organ ali zakonodaja.
Ta standard se lahko uporablja za izpolnitev zahtev glede nadzora iz veljavnih direktiv ES.
Ta standard se lahko uporablja za druge organske spojine, kadar je to potrjeno.
Ta standard ni primeren za merjenje skupnega organskega ogljika (TOC). Za merjenje masne koncentracije skupnega organskega ogljika se uporablja standard EN 12619.
General Information
Relations
Standards Content (Sample)
SLOVENSKI STANDARD
01-februar-2015
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Stationary source emissions - Determination of the mass concentration of individual
gaseous organic compounds - Sorptive sampling method followed by solvent extraction
or thermal desorption
Emissionen aus stationären Quellen - Bestimmung der Massenkonzentration von
gasförmigen organischen Einzelverbindungen - Sorptive Probennahme mit
Lösemittelextraktion oder thermischer Desorption
Emissions de sources fixes - Détermination de la concentration massique en composés
organiques gazeux individuels - Echantillonnage par adsorption et désorption des
solvants ou désorption thermique
Ta slovenski standard je istoveten z: CEN/TS 13649:2014
ICS:
13.040.40 (PLVLMHQHSUHPLþQLKYLURY Stationary source emissions
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.
TECHNICAL SPECIFICATION
CEN/TS 13649
SPÉCIFICATION TECHNIQUE
TECHNISCHE SPEZIFIKATION
December 2014
ICS 13.040.40 Supersedes EN 13649:2001
English Version
Stationary source emissions - Determination of the mass
concentration of individual gaseous organic compounds -
Sorptive sampling method followed by solvent extraction or
thermal desorption
Emissions de sources fixes - Détermination de la Emissionen aus stationären Quellen - Bestimmung der
concentration massique en composés organiques gazeux Massenkonzentration von gasförmigen organischen
individuels - Échantillonnage par adsorption et extraction Einzelverbindungen - Sorptive Probenahme und
par solvant ou thermodésorption Lösemittelextraktion oder thermische Desorption
This Technical Specification (CEN/TS) was approved by CEN on 25 August 2014 for provisional application.
The period of validity of this CEN/TS is limited initially to three years. After two years the members of CEN will be requested to submit their
comments, particularly on the question whether the CEN/TS can be converted into a European Standard.
CEN members are required to announce the existence of this CEN/TS in the same way as for an EN and to make the CEN/TS available
promptly at national level in an appropriate form. It is permissible to keep conflicting national standards in force (in parallel to the CEN/TS)
until the final decision about the possible conversion of the CEN/TS into an EN is reached.
CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania,
Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United
Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION
EUROPÄISCHES KOMITEE FÜR NORMUNG
CEN-CENELEC Management Centre: Avenue Marnix 17, B-1000 Brussels
© 2014 CEN All rights of exploitation in any form and by any means reserved Ref. No. CEN/TS 13649:2014 E
worldwide for CEN national Members.
Contents Page
Foreword .4
1 Scope .5
2 Normative references .5
3 Terms and definitions .5
4 Principle .6
5 Apparatus and materials .6
5.1 Method of measurement .6
5.2 Sampling system .8
5.3 Sampling tubes .8
5.3.1 Sampling tubes for solvent extraction .8
5.3.2 Sampling tubes for thermal desorption.8
5.4 Pumps and other devices for sampling .8
5.5 Gas volume meter .9
5.6 Analytical reagents .9
5.6.1 General .9
5.6.2 Extraction solvent (for solvent extraction) .9
5.6.3 Reference materials for calibration of the analytical procedure .9
5.7 Analytical apparatus . 10
5.7.1 Capillary gas chromatograph (GC) . 10
5.7.2 Thermal desorber (for thermal desorption) . 10
6 Sampling procedure . 10
6.1 General . 10
6.2 Sampling conditions . 10
6.3 Measurement of waste gas sample volume . 11
6.4 Control of leakage. 11
6.5 Handling, storage, transport of sampled tubes . 11
6.5.1 General . 11
6.5.2 Activated carbon (charcoal) tubes . 11
6.5.3 Thermal desorption tubes . 12
6.6 Blanks . 12
6.6.1 Field blanks . 12
6.6.2 Analytical (laboratory) blanks . 12
6.6.3 Solvent blank . 12
7 Analytical procedure . 12
7.1 Calibration of the GC analysis . 12
7.1.1 GC calibration for analysis of solvent extracts . 12
7.1.2 Calibration for thermal desorption analysis . 13
7.2 Sample preparation (desorption/extraction) . 13
7.2.1 Solvent desorption . 13
7.2.2 Thermal desorption . 14
7.3 Analysis . 14
7.3.1 GC analysis of extract from activated carbon tubes. 14
7.3.2 Thermal desorption / GC analysis of sorbent tubes . 14
7.4 Quantification of individual organic compound concentrations . 15
8 Calculation of results . 16
8.1 Concentration . 16
8.2 Uncertainty . 16
9 Quality control . 16
9.1 General . 16
9.2 Performance requirements . 17
9.2.1 Sampling. 17
9.2.2 Analytical . 17
10 Report . 18
Annex A (normative) Sample trains . 19
Annex B (informative) Solvent extraction of activated charcoal tubes . 23
Annex C (informative) Additional information on flue gas sampling using thermal desorption
tubes . 24
Annex D (informative) Validation of monitoring methods for speciated organic substances in
stack gas . 27
Annex E (informative) Safety measures . 45
Bibliography . 46
Foreword
This document (CEN/TS 13649:2014) has been prepared by Technical Committee CEN/TC 264 “Air quality”,
the secretariat of which is held by DIN.
Attention is drawn to the possibility that some of the elements of this document may be the subject of patent
rights. CEN [and/or CENELEC] shall not be held responsible for identifying any or all such patent rights.
This document supersedes EN 13649:2001.
Significant technical changes between this Technical Specification and the previous edition of EN 13649 are:
a) the status of the document has been changed from European Standard (EN) to Technical Specification
(TS);
b) the scope has been clarified regarding the use of the TS and its applicability;
c) a decision tree for the determination of the sampling procedure has been included;
d) the sampling strategy has been aligned with EN 15259;
e) the thermal desorption technique has been added;
f) comprehensive information on the validation of monitoring methods for speciated organic substances in
stack gas is given.
According to the CEN-CENELEC Internal Regulations, the national standards organizations of the following
countries are bound to announce this Technical Specification: Austria, Belgium, Bulgaria, Croatia, Cyprus,
Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany,
Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland,
Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdom.
1 Scope
This Technical Specification specifies procedures for the sampling, preparation and analysis of individual
volatile organic compounds (VOCs) in waste gas, such as those arising from solvent using processes.
Sampling occurs by adsorption on sorbents, preparation by solvent extraction or thermodesorption and
analysis by gas chromatography.
Examples of individual VOC are given in releva
...
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