Construction products: Assessment of release of dangerous substances - Determination of emissions into indoor air

This European Standard specifies a horizontal reference method for the determination of emissions of regulated dangerous substances from construction products into indoor air. This method is applicable to volatile organic compounds, semi-volatile organic compounds, and very volatile aldehydes. It is based on the use of a test chamber and subsequent analysis of the organic compounds by GC-MS or HPLC.
NOTE 1   Supplemental information is given on indirect test methods (see Annex B) and on measuring very volatile organic compounds (see Annex C).
NOTE 2   This European Standard describes the overall procedure and makes use of existing standards mainly by normative reference, complemented when necessary with additional or modified normative requirements.

Bauprodukte: Bewertung der Freisetzung von gefährlichen Stoffen - Bestimmung der Emissionen in die Innenraumluft

Dieses Dokument legt ein horizontales Referenzverfahren zur Bestimmung der Emission regulierter gefährlicher Stoffe aus Bauprodukten in die Innenraumluft fest. Das Verfahren ist für flüchtige organische Verbindungen, schwerflüchtige organische Verbindungen, leicht flüchtige Aldehyde und Ammoniak anwendbar. Es basiert auf der Nutzung einer Prüfkammer und der nachfolgenden Analyse der organischen Verbindungen anhand von GC-MS, HPLC und, im Fall von Ammoniak, der nachfolgenden Analyse durch spektrophotometrische Verfahren oder durch andere gleichwertige Analyseverfahren (wie zum Beispiel Ionenchromatographie und ammoniakspezifische Elektrode).
ANMERKUNG 1 Zusätzliche Informationen über indirekte Prüfverfahren werden in Anhang B und über die Messung leicht flüchtiger organischer Verbindungen in Anhang C gegeben.
ANMERKUNG 2 Diese Europäische Norm beschreibt das allgemeine Verfahren unter Verwendung bestehender Normen, hauptsächlich durch normative Verweisungen, die durch weitere oder modifizierte normative Festlegungen ergänzt werden, soweit erforderlich.

Produits de construction : Évaluation de l'émission de substances dangereuses - Détermination des émissions dans l'air intérieur

Le présent document décrit une méthode de référence horizontale pour la détermination des émissions de substances dangereuses réglementées générées par les produits de construction dans l’air intérieur. Cette méthode est applicable aux composés organiques volatils, aux composés organiques semi-volatils, aux aldéhydes très volatils et à l’ammoniac. Elle est basée sur l’utilisation d’une chambre d’essai et sur l’analyse ultérieure des composés organiques par chromatographie en phase gazeuse couplée à la spectrométrie de masse (CG/SM), par chromatographie liquide à haute performance (CLHP), et pour l’ammoniac, sur l’analyse ultérieure par des méthodes spectrophotométriques ou toute autre méthode analytique équivalente (telle que la chromatographie ionique ou une électrode sélective de l’ion ammonium).
NOTE 1   Des informations supplémentaires sont disponibles sur les méthodes d’essai indirectes (voir l’Annexe B) et sur la mesure des composés organiques très volatils (voir l’Annexe C).
NOTE 2   La présente Norme européenne décrit le mode opératoire global et utilise des normes existantes, principalement par référence normative, complétées, si nécessaire, par des exigences normatives supplémentaires ou modifiées.

Gradbeni proizvodi - Ocenjevanje sproščanja nevarnih snovi - Določevanje emisije v notranji zrak (vključuje dopolnilo A1)

General Information

Status
Published
Publication Date
21-Jul-2020
Withdrawal Date
30-Jan-2021
Current Stage

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SLOVENSKI STANDARD
01-september-2020
Nadomešča:
SIST EN 16516:2018
Gradbeni proizvodi - Ocenjevanje sproščanja nevarnih snovi - Določevanje emisije
v notranji zrak (vključuje dopolnilo A1)
Construction products: Assessment of release of dangerous substances - Determination
of emissions into indoor air
Bauprodukte: Bewertung der Freisetzung von gefährlichen Stoffen - Bestimmung von
Emissionen in die Innenraumluft
Produits de construction : Évaluation de l'émission de substances dangereuses -
Détermination des émissions dans l'air intérieur
Ta slovenski standard je istoveten z: EN 16516:2017+A1:2020
ICS:
13.040.20 Kakovost okoljskega zraka Ambient atmospheres
91.100.01 Gradbeni materiali na Construction materials in
splošno general
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

EN 16516:2017+A1
EUROPEAN STANDARD
NORME EUROPÉENNE
July 2020
EUROPÄISCHE NORM
ICS 13.040.20; 91.100.01 Supersedes EN 16516:2017
English Version
Construction products: Assessment of release of
dangerous substances - Determination of emissions into
indoor air
Produits de construction : Évaluation de l'émission de Bauprodukte: Bewertung der Freisetzung von
substances dangereuses - Détermination des émissions gefährlichen Stoffen - Bestimmung von Emissionen in
dans l'air intérieur die Innenraumluft
This European Standard was approved by CEN on 9 July 2017 and includes Amendment 1 approved by CEN on 24 May 2020.

CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this
European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references
concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN
member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by
translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management
Centre has the same status as the official versions.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway,
Poland, Portugal, Republic of North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and
United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION

EUROPÄISCHES KOMITEE FÜR NORMUNG

CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2020 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN 16516:2017+A1:2020 E
worldwide for CEN national Members.

Contents Page
European foreword . 4
Introduction . 5
1 Scope . 7
2 Normative references . 7
3 Terms, definitions and abbreviations . 8
3.1 Terms and definitions . 8
3.2 Abbreviations . 14
4 Intended conditions of use, emission scenarios and European reference room . 14
4.1 Intended conditions of use and emission scenario . 14
4.2 Reference room and emission scenario . 15
4.3 Time schedule of emission(s) determination . 16
5 Product sampling and transport to the laboratory . 16
5.1 General . 16
5.2 Objective of sampling . 16
5.3 Preparation of a sampling plan and sampling strategy . 16
5.4 Information from the testing laboratory needed to complement the product
sampling plan . 18
5.5 Packaging and transport of laboratory sample. 18
5.6 Sample description, marking of laboratory samples and the sampling report . 19
5.7 Chain of custody report . 19
5.8 Dispatch of product samples, time schedule . 19
6 Handling of product samples in the laboratory . 20
6.1 Storage of sample in the testing laboratory . 20
6.2 Preparation of the test specimen . 20
7 Test chamber conditions . 21
7.1 Principles . 21
7.2 Dimensions of test specimen . 21
7.3 Loading factor . 21
7.4 Ventilation . 22
7.5 Air velocity . 22
7.6 Cleanliness of test chamber . 22
7.7 Testing climate (temperature, relative humidity of supply air) . 22
7.8 Storage of test specimen . 22
7.9 Large products or inhomogeneous products . 23
7.10 Volume of test chamber . 23
7.11 Placement of test specimen in test chamber . 23
8 Determination of vapour-phase !deleted text" compounds in test chamber air. 23
8.1 Common requirements . 23
8.2 Determination of VOCs and SVOCs in test chamber air . 24
8.3 Determination of formaldehyde and some other volatile and very volatile carbonyl
compounds in test chamber air . 32
8.4 !Determination of ammonia in test chamber air . 33
8.5 Other general aspects of quality control . 35
9 Calculation of specific emission rates and expression of results at the reference
room . 35
10 Reporting for the horizontal reference method . 38
10.1 General . 38
10.2 Sampling . 38
10.3 Handling of samples in the laboratory, preparation of test specimen . 38
10.4 Test chamber conditions . 39
10.5 Determination of vapour-phase organic compounds !and ammonia" in test
chamber air . 39
10.6 Calculation and reporting of test results. 39
11 Indirect methods . 40
Annex A (informative)  . 41
Repeatability and reproducibility
A.1 Repeatability . 41
A.2 Reproducibility . 41
Annex B (informative) Examples of indirect methods (also called simplified, screening,
secondary, derived or alternative methods) . 43
B.1 General . 43
B.2 Indirect methods-emissions testing . 43
B.3 Indirect methods specifying alternative procedures . 44
B.4 Other secondary methods — Prediction of results at specified time . 44
Annex C (informative) Information on very volatile organic compound (VVOC) testing . 45
Annex D (informative) Example of a form for the sampling report. 46
Annex E (informative) Example form for a chain of custody report . 47
Annex F (informative) Benzene artefact generation on Tenax . 48
Annex G (normative) List of non-carcinogenic VOCs . 49
Annex H (informative) List of carcinogenic VOCs . 57

European foreword
This document (EN 16516:2017+A1:2020) has been prepared by Technical Committee CEN/TC 351
“Construction Products: Assessment of release of dangerous substances”, the secretariat of which is
held by NEN.
!Amendment 1 is a complement to EN 16516:2017. It concerns the measurement of ammonia
emissions from construction products."
This European Standard shall be given the status of a national standard, either by publication of an
identical text or by endorsement, at the latest by January 2021, and conflicting national standards shall
be withdrawn at the latest by January 2021.
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. CEN shall not be held responsible for identifying any or all such patent rights.
This document includes Amendment 1 approved by CEN on 24 May 2020.
This document supersedes !EN 16516:2017".
The start and finish of text introduced or altered by amendment is indicated in the text by tags !".
This document has been prepared under a mandate given to CEN by the European Commission and the
European Free Trade Association.
According to the CEN-CENELEC Internal Regulations, the national standards organisations of the
following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria,
Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland,
Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Republic of
North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the
United Kingdom.
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