Paints and varnishes - Assessment of emissions of substances from coatings into indoor air - Sampling, conditioning and testing

This document specifies a reference method for the determination of emissions from coatings into indoor air. This method is applicable to volatile organic compounds, semi-volatile organic compounds and volatile aldehydes.
NOTE 1   This document is aimed at describing the overall procedure and makes use of existing standards mainly by normative reference complemented when necessary with additional or modified normative requirements.
This document is mainly aimed at determining emission data in indoor air for the purpose of meeting national legislation requirements, and for the voluntary labelling of products.
NOTE 2   Harmonized product standards for coatings falling under the CPR can refer to this standard for the intended conditions of use.
This document applies to coatings for indoor use as listed in Clause 5.
It is not applicable for:
- coatings that are applied off site or coatings that are applied on site, prior to the structure being permanently weatherproof  except for the product type category 7 as listed in Clause 5;
- tinting pastes that are not ready for use as coating;
- non film-forming products like e.g. waxes and impregnations.

Beschichtungsstoffe - Bestimmung der Emissionen regulierter gefährlicher Stoffe von Beschichtungen in die Innenraumluft - Probenahme, Probenvorbereitung und Prüfung

Dieses Dokument legt ein Referenzverfahren zur Bestimmung der Emissionen von Beschichtungen in die Innenraumluft fest. Das Verfahren ist für flüchtige organische Verbindungen, schwerflüchtige organische Verbindungen und flüchtige Aldehyde anwendbar.
ANMERKUNG 1   Dieses Dokument zielt darauf ab, das allgemeine Verfahren unter Verwendung bestehender Normen, hauptsächlich durch normative Verweisungen, die durch weitere oder modifizierte normative Festlegungen ergänzt werden, soweit erforderlich, zu beschreiben.
Dieses Dokument ist hauptsächlich für die Bestimmung von Emissionsdaten in der Innenraumluft bestimmt, um nationaler Gesetzgebung zu entsprechen, und für die freiwillige Kennzeichnung von Produkten.
ANMERKUNG 2   Harmonisierte Produktnormen für Beschichtungen, die unter die BauPVO fallen, können sich auf diese Norm für die Bedingungen der bestimmungsgemäßen Verwendung beziehen.
Dieses Dokument gilt für Beschichtungen für Innenräume, wie in Abschnitt 5 aufgelistet.
Es gilt nicht für:
   Beschichtungen, die außerhalb des Geländes oder vor Ort angewandt werden, bevor die Struktur dauerhaft wetterbeständig ist, mit Ausnahme von Produkttypen der Kategorie 7, die in Abschnitt 5 aufgelistet sind;
   Farbpasten, die noch nicht für den Einsatz als Beschichtung geeignet sind;
   nicht filmbildende Produkte wie z. B. Wachse und Imprägnierungen.

Peintures et vernis - Évaluation des émissions de substances émanant des revêtements dans l'air intérieur - Échantillonnage, conditionnement et essais

Le présent document spécifie une méthode de référence pour la détermination des émissions des revêtements dans l’air intérieur. Cette méthode est applicable aux composés organiques volatils, aux composés organiques semi-volatils et aux aldéhydes volatils.
NOTE 1   Le présent document vise à décrire le mode opératoire global et recourt à des normes existantes, principalement sous forme de références normatives complétées, si nécessaire, par des exigences normatives supplémentaires ou modifiées.
Le présent document est principalement destiné à déterminer les données d’émission dans l’air intérieur dans le but de satisfaire aux exigences réglementaires nationales et de répondre aux besoins de l’étiquetage volontaire des produits.
NOTE 2   Les normes de produits harmonisées pour les revêtements relevant du RPC peuvent se référer à la présente norme pour les conditions d’utilisation prévues.
Le présent document s’applique aux revêtements à usage intérieur énumérés à l’Article 5.
Il n’est pas applicable :
-   aux revêtements qui sont appliqués hors site ou aux revêtements qui sont appliqués sur place, avant que la résistance permanente de la structure aux intempéries soit assurée, sauf pour la catégorie de type de produit 7 énumérée à l’Article 5 ;
-   aux pâtes colorantes qui ne sont pas préparées en vue d’une utilisation en tant que revêtement ;
-   aux produits non filmogènes tels que les cires et les imprégnations, par exemple.

Barve in laki - Ocenjevanje emisij snovi iz premazov v notranji zrak - Vzorčenje, priprava vzorcev in preskušanje

Ta evropski standard določa referenčno metodo za določanje emisij iz premazov v notranji zrak. Ta metoda se uporablja za hlapne organske spojine, polhlapne organske spojine in hlapne aldehide.
OPOMBA: Ta evropski standard je namenjen opisu celotnega postopka in uporablja obstoječe standarde večinoma kot reference, ki so po potrebi dopolnjene z dodatnimi ali spremenjenimi normativnimi zahtevami.
Ta evropski standard se uporablja za premaze za uporabo v zaprtih prostorih, kot so navedeni v točki 5. Ne uporablja se za premaze, ki se ne nanašajo na mestu uporabe, ali premaze, ki se nanašajo na mestu uporabe, preden je struktura trajno vremensko odporna. Ne uporablja se za niansirne paste, ki niso pripravljene za uporabo kot premazi.
Namenjen je predvsem določanju podatkov o emisijah v zraku v zaprtih prostorih za namen prostovoljnega označevanja proizvodov, lahko pa se uporablja tudi za oznako CE in s tem povezano potrdilo o skladnosti v primeru proizvodov, ki jih zajema direktiva o gradbenih proizvodih.

General Information

Status
Published
Publication Date
26-Feb-2019
Withdrawal Date
30-Aug-2019
Current Stage
9060 - Closure of 2 Year Review Enquiry - Review Enquiry
Start Date
02-Sep-2024
Completion Date
02-Sep-2024

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SLOVENSKI STANDARD
01-april-2019
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SIST EN 16402:2014
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SULSUDYDY]RUFHYLQSUHVNXãDQMH
Paints and varnishes - Assessment of emissions of substances from coatings into indoor
air - Sampling, conditioning and testing
Beschichtungsstoffe - Bestimmung der Emissionen regulierter gefährlicher Stoffe von
Beschichtungen in die Innenraumluft - Probenahme, Probenvorbereitung und Prüfung
Peintures et vernis - Evaluation des émissions de substances émanant des revêtements
dans l'air intérieur - Echantillonnage, conditionnement et essais
Ta slovenski standard je istoveten z: EN 16402:2019
ICS:
13.040.20 Kakovost okoljskega zraka Ambient atmospheres
87.040 Barve in laki Paints and varnishes
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

EN 16402
EUROPEAN STANDARD
NORME EUROPÉENNE
February 2019
EUROPÄISCHE NORM
ICS 13.040.20; 87.040 Supersedes EN 16402:2013
English Version
Paints and varnishes - Assessment of emissions of
substances from coatings into indoor air - Sampling,
conditioning and testing
Peintures et vernis - Évaluation des émissions de Beschichtungsstoffe - Bestimmung der Emissionen
substances émanant des revêtements dans l'air regulierter gefährlicher Stoffe von Beschichtungen in
intérieur - Échantillonnage, conditionnement et essais die Innenraumluft - Probenahme, Probenvorbereitung
und Prüfung
This European Standard was approved by CEN on 14 December 2018.

CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this
European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references
concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN
member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by
translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management
Centre has the same status as the official versions.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania,
Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland,
Turkey and United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION

EUROPÄISCHES KOMITEE FÜR NORMUNG

CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2019 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN 16402:2019 E
worldwide for CEN national Members.

Contents Page
European foreword . 4
Introduction . 5
1 Scope . 6
2 Normative references . 6
3 Terms and definitions . 7
3.1 Terms relating to sampling and product . 7
3.2 Terms relating to emissions into indoor air and associated laboratory testing . 8
3.3 Terms relating to determination of emitted substances . 10
3.4 Abbreviations . 12
4 Principle . 12
5 Product categories . 13
6 Relevant substances emitted from coatings . 14
7 Intended conditions of use, Emission scenarios and European reference room . 14
7.1 Intended conditions of use and emission scenario . 14
7.2 Reference room and emission scenario . 14
7.3 Ventilation in the reference room. 16
7.4 Climate conditions of the reference room. 16
7.5 Time schedule of emission determination . 16
8 Product sampling and transport . 16
8.1 Population of the product to be considered for testing . 16
8.2 Sampling . 16
8.3 Transport . 17
8.4 Chain of custody . 17
8.5 Dispatch of samples, time schedule . 18
9 Handling of product samples in the laboratory . 18
9.1 Storage . 18
9.2 Preparation of test specimen: Coatings . 18
9.3 Preparation of test specimen: coating systems . 22
9.4 Preconditioning . 22
10 Test chamber conditions . 23
10.1 Principle . 23
10.2 Dimensions of test specimen . 23
10.3 Loading factor . 23
10.4 Ventilation . 24
10.5 Air velocity . 24
10.6 Cleanliness of test chamber . 24
10.7 Testing climate (temperature, relative humidity of supply air) . 24
10.8 Storage of test specimen . 24
10.9 Large products or inhomogeneous products . 25
10.10 Volume of test chamber . 25
10.11 Placement of test specimen in test chamber . 25
11 Determination of vapour-phase organic compounds in test chamber air . 25
11.1 Common requirements . 25
11.2 Determination of VOCs and SVOCs in test chamber air . 26
11.3 Determination of formaldehyde and some other volatile and very volatile carbonyl
compounds in test chamber air . 34
11.4 Other general aspects of quality control . 35
12 Calculation of specific emission rates and expression of results at the reference
room . 36
13 Test report . 39
13.1 General . 39
13.2 Sampling . 39
13.3 Handling of samples in the laboratory, preparation of test specimen . 39
13.4 Test chamber conditions . 40
13.5 Determination of vapour-phase organic compounds in test chamber air . 40
13.6 Calculation of specific emission rates and expression of results in terms of air
concentration in the reference room . 40
14 "Indirect" methods . 41
Annex A (informative) Repeatability and reproducibility . 42
A.1 Repeatability . 42
A.2 Reproducibility . 42
Annex B (informative) Examples of indirect methods (also called simplified, screening,
secondary, derived or alternative methods) . 44
B.1 General . 44
B.2 Indirect methods-emissions testing . 44
B.3 Indirect methods specifying alternative procedures . 45
B.4 Other secondary methods — Prediction of results at specified time . 45
Annex C (informative) Information on very volatile organic compound (VVOC) testing . 46
Annex D (informative) Example of a form for the sampling report . 47
Annex E (informative) Example of a form for a chain of custody report . 48
Annex F (informative) Benzene artefact generation on Tenax TA . 49
Annex G (normative) List of non-carcinogenic VOCs . 50
Annex H (informative) List of carcinogenic VOCs . 58
Annex I (informative) Overview of test procedure. 60
Bibliography . 61

European foreword
This document (EN 16402:2019) has been prepared by Technical Committee CEN/TC 139 “Paints and
varnishes”, the secretariat of which is held by DIN.
This European Standard shall be given the status of a national standard, either by publication of an
identical text or by endorsement, at the latest by August 2019, and conflicting national standards shall
be withdrawn at the latest by August 2019.
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. CEN shall not be held responsible for identifying any or all such patent rights.
This d
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