SIST EN 16900:2017

Fast pyrolysis bio-oils for industrial boilers - Requirements and test methods

This European Standard specifies requirements and test methods for fast pyrolysis bio-oils for boiler use at industrial scale (>1 MW thermal capacity), not for domestic use. Two different grades are specified.
It is recommended to draw attention to differences especially in those properties, which can have an effect on the required flue gas treatment system, such as ash, nitrogen, and sulfur content. National and local regulations determine the requirements for flue gas treatment system.
In addition to the quality requirements and test methods for fast pyrolysis bio-oils, further instructions on storage (Annex A), sampling, and materials compatibility (Annex B) are given.
NOTE   For the purposes of this European Standard, the term "% (m/m)" is used to represent respectively the mass fraction.

Fast Pyrolyse-Öle für die stationäre Wärmeerzeugung - Anforderungen und Prüfverfahren

Diese Europäische Norm legt Anforderungen und Prüfverfahren für Schnellpyrolyse-Bioöle für industrielle Kesselanlagen (> 1 MW Wärmekapazität), nicht jedoch für den häuslichen Gebrauch fest. Es werden zwei verschiedene Klassen bestimmt.
Es wird empfohlen die Unterschiede insbesondere derjenigen Eigenschaften zu beachten, die einen Einfluss auf das erforderliche Abgasbehandlungssystem haben können, wie Asche-, Stickstoff- und Schwefelgehalt. Nationale und lokale Regelungen bestimmen die Anforderungen an das Abgasbehandlungssystem.
Zusätzlich zu den Qualitätsanforderungen und Prüfverfahren für Schnellpyrolyse-Bioöle sind weitere Hinweise zur Lagerung (Anhang A), Probenahme und Kompatibilität der Materialien (Anhang B) angegeben.
ANMERKUNG   Für die Zwecke dieser Europäischen Norm wird der Ausdruck "% (m/m)" zur Darstellung des jeweiligen Massenanteils genutzt.

Huiles de pyrolyse rapide pour application chaudières - Spécifications et méthodes d’analyses

La présente Norme européenne spécifie les exigences et méthodes d'essai applicables aux bio-huiles de pyrolyse rapide destinées à être utilisées dans des chaudières à usage industriel (> 1 MW de capacité thermique), et non dans des chaudières à usage domestique. Elle spécifie deux niveaux de qualité différents.
Il est recommandé de souligner les différences existantes, notamment au niveau des propriétés pouvant avoir un impact sur le système de traitement des gaz de combustion requis, telles que les teneurs en cendres, en azote et en soufre. Les réglementations locales et nationales fixent les exigences applicables en termes de système de traitement des gaz de combustion.
Outre les exigences de qualité et les méthodes d'essai applicables aux bio-huiles de pyrolyse rapide, des instructions relatives au stockage (Annexe A), à l'échantillonnage et à la compatibilité du matériel (Annexe B) sont données.
NOTE   Pour les besoins de la présente Norme européenne, l’expression «% (m/m)» est utilisée pour désigner les fractions massiques.

Bioolja, pridobljena s hitro pirolizo, za industrijske kotle - Zahteve in preskusne metode

Ta evropski standard določa zahteve in preskusne metode za trženo in dobavljeno gorivo, pridobljeno s postopki hitre pirolize olja. Uporablja se za olja, pridobljena s hitro pirolizo, za uporabo v industrijskih kotlih in povezani opremi, ki proizvaja toploto ali elektriko. Predstavlja alternativo ali komponento za mešanje v težkem ali lahkem kurilnem olju, ki se uporablja za podobne namene.

General Information

• Status: Published
• Public Enquiry End Date: 04-Oct-2015
• Publication Date: 14-May-2017
• ICS: 75.160.40 - Biofuels
• Technical Committee: NAD - Petroleum products, lubricants and related products
• Current Stage: 6060 - National Implementation/Publication (Adopted Project)
• Start Date: 13-Apr-2017
• Due Date: 18-Jun-2017
• Completion Date: 15-May-2017
• Mandate: M/525 - Standards on pyrolysis oils produced from biomass feedstocks to be used in various energy applications or intermediate products for subsequent processing,
• Ref Project: EN 16900:2017 - Fast pyrolysis bio-oils for industrial boilers - Requirements and test methods

Standards Content (Sample)

2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.Bioolja, pridobljena s hitro pirolizo, za industrijske kotle - Zahteve in preskusne metodeFast Pyrolyse-Öle für die stationäre Wärmeerzeugung - Anforderungen und PrüfverfahrenHuiles de pyrolyse rapide pour application chaudières - Spécifications et méthodes d’analysesFast pyrolysis bio-oils for industrial boilers - Requirements and test methods75.160.40BiogorivaBiofuelsICS:Ta slovenski standard je istoveten z:EN 16900:2017SIST EN 16900:2017en,fr,de01-junij-2017SIST EN 16900:2017SLOVENSKI
STANDARD
EUROPEAN STANDARD NORME EUROPÉENNE EUROPÄISCHE NORM
EN 16900
March
t r s y ICS
y wä s x rä v r English Version
Fast pyrolysis bioæoils for industrial boilers æ Requirements and test methods Huiles de pyrolyse rapide pour application chaudières æSpécifications et méthodes d 5analyses
SchnellpyrolyseæBioöle für industrielle Kesselanlagen æAnforderungen und Prüfverfahren This European Standard was approved by CEN on
s x January
t r s yä
egulations which stipulate the conditions for giving this European Standard the status of a national standard without any alterationä Upætoædate lists and bibliographical references concerning such national standards may be obtained on application to the CENæCENELEC Management Centre or to any CEN memberä
translation under the responsibility of a CEN member into its own language and notified to the CENæCENELEC Management Centre has the same status as the official versionsä
CEN members are the national standards bodies of Austriaá Belgiumá Bulgariaá Croatiaá Cyprusá Czech Republicá Denmarká Estoniaá Finlandá Former Yugoslav Republic of Macedoniaá Franceá Germanyá Greeceá Hungaryá Icelandá Irelandá Italyá Latviaá Lithuaniaá Luxembourgá Maltaá Netherlandsá Norwayá Polandá Portugalá Romaniaá Serbiaá Slovakiaá Sloveniaá Spainá Swedená Switzerlandá Turkey and United Kingdomä
EUROPEAN COMMITTEE FOR STANDARDIZATION COMITÉ EUROPÉEN DE NORMALISATION EUROPÄISCHES KOMITEE FÜR NORMUNG
CEN-CENELEC Management Centre:
Avenue Marnix 17,
B-1000 Brussels
t r s y CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Membersä Refä Noä EN
s x { r rã t r s y ESIST EN 16900:2017

page European foreword . 3 Introduction . 4 1 Scope . 5 2 Normative references . 5 3 Terms and definitions . 6 4 Sampling and sample handling . 7 5 Requirements and test methods . 7 5.1 Additives . 7 5.2 Generally applicable requirements and related test methods . 7 5.3 Transport and general safety requirements and related test methods . 8 5.4 Emission and burner dependent requirements and related test methods . 8 5.5 Precision and dispute . 9 Annex A (informative)
Storage of fast pyrolysis bio-oil . 10 A.1 Temperature . 10 A.2 Mixing . 10 A.3 Ageing . 10 Annex B (normative)
Compatible materials . 11 Annex C (normative)
Details of inter-laboratory test programme . 12 Annex D (normative)
Information on test method procedures . 19 Bibliography . 21
According to the CEN-CENELEC Internal Regulations, the national standards organisations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdom.
14,0 Water content, on wet basis %(m/m) ASTM E203
30 pH
ASTM E70
2,0 Density at 15 °C kg/m3 EN ISO 12185
1 300 Pour point °C ISO 3016
- 9 Nitrogen content, (d.b.b). % (m/m) ASTM D5291 report a Net calorific value on wet basis is calculated from the gross calorific value according to DIN 51900–1. b d.b. is on dry basis. 5.3 Transport and general safety requirements and related test methods The UN transport of goods regulation [16] considers liquids with a flash point of more than 35 °C which do not sustain combustion as flammable liquids. Due to their consistency and water content (see Table 1 and Annex C) FPBO are in general non-flammable liquids and would not sustain combustion at a test temperature above 60,5 °C (as prescribed in EN ISO 9038 [17]). In line with the above FPBO that fulfils the following requirements are considered to be able to sustain combustion: — Flash point as measured by Procedure B of EN ISO 2719 is higher than 35 °C; and — Sustained combustibility passes the test procedure as in EN ISO 9038. NOTE Results of ILS analysis (Annex C) show that flash point is not suitable analysis method for FPBO. Also, according other research results [17] FPBO is non-flammable liquid. 5.4 Emission and burner dependent requirements and related test methods For emission and burner dependent requirements [6], options are given to allow grades to be set locally or chosen by the user. The options are two grades, of which Grade 1 requires more flue gas treatment than Grade 2. When tested by the methods indicated in Table 2, fast pyrolysis bio-oils shall be in accordance with the maximum limit specified in the Table 2 for the Grade applicable. The test methods listed in Table 2 have been assessed for application in boiler use. SIST EN 16900:2017

Storage of fast pyrolysis bio-oil A.1 Temperature Recommended storage conditions for large batches of bio-oil are 15 °C to 20 °C and maximum of six months. Storage at a minimum temperature of 15 °C is recommended to maintain adequate fluidity, but not higher than 20 °C for long-term storage. Long time at relatively high storage temperatures accelerate viscosity increase of the fuel [3, 6]. A.2 Mixing There are always some solids in FPBO but they are not considered as a separate phase in FPBO. After mixing solids are evenly distributed in the bio-oil. An extractive-rich phase may be gradually separated to top layer of the liquid. The stratification to top and bottom phase is slow and can be avoided by constant mixing. Similar type of phenomena is observed also with some agro-biomass. If moderate mixing is provided the fast pyrolysis bio-oil is a homogenous liquid [3, 14]. A.3 Ageing Ageing can lead to phase separation. All fast pyrolysis bi
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