SIST EN ISO 19403-1:2020
(Main)Paints and varnishes - Wettability - Part 1: Terminology and general principles (ISO 19403-1:2017)
Paints and varnishes - Wettability - Part 1: Terminology and general principles (ISO 19403-1:2017)
The ISO 19403 series specifies optical test methods
- for the measurement of the contact angle,
- for the determination of the free surface energy of a solid surface, including the polar and dispersive fractions,
- for the determination of the surface tension of liquids, including the polar and dispersive fractions, and
- for the checking of the measurement arrangement with reference materials.
It can be applied for the characterization of substrates, coatings and coating materials.
The applicability can be restricted for liquids with non-Newtonian rheology[1].
ISO 19403-1:2017 specifies terms and definitions and defines the general principles.
[1] This term is defined in DIN 1342-1.
Beschichtungsstoffe - Benetzbarkeit - Teil 1: Begriffe und allgemeine Grundlagen (ISO 19403-1:2017)
Peintures et vernis - Mouillabilité - Partie 1: Terminologie et principes généraux (ISO 19403-1:2017)
La série ISO 19403 spécifie des méthodes d'essai optiques permettant de:
— mesurer l'angle de contact;
— déterminer l'énergie libre de surface d'une surface solide, y compris les fractions polaire et dispersive;
— déterminer la tension superficielle des liquides, y compris les fractions polaire et dispersive; et
— contrôler le dispositif de mesure à l'aide de produits de référence.
Cette série de normes peut être utilisée pour la caractérisation de substrats, de revêtements et de produits de peinture.
Son applicabilité peut être limitée pour les produits liquides de rhéologie non newtonienne[1].
Le présent document spécifie les termes et définitions et définit les principes généraux.
[1] Ce terme est défini dans la norme DIN 1342-1.
Barve in laki - Omočljivost - 1. del: Terminologija in splošna načela (ISO 19403-1:2017)
General Information
Relations
Standards Content (Sample)
SLOVENSKI STANDARD
SIST EN ISO 19403-1:2020
01-april-2020
Barve in laki - Omočljivost - 1. del: Terminologija in splošna načela (ISO 19403-
1:2017)
Paints and varnishes - Wettability - Part 1: Terminology and general principles (ISO
19403-1:2017)
Beschichtungsstoffe - Benetzbarkeit - Teil 1: Begriffe und allgemeine Grundlagen (ISO
19403-1:2017)
Peintures et vernis - Mouillabilité - Partie 1: Terminologie et principes généraux (ISO
19403-1:2017)
Ta slovenski standard je istoveten z: EN ISO 19403-1:2020
ICS:
01.040.87 Industrija barv (Slovarji) Paint and colour industries
(Vocabularies)
87.040 Barve in laki Paints and varnishes
SIST EN ISO 19403-1:2020 en,fr,de
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.
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SIST EN ISO 19403-1:2020
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SIST EN ISO 19403-1:2020
EN ISO 19403-1
EUROPEAN STANDARD
NORME EUROPÉENNE
February 2020
EUROPÄISCHE NORM
ICS 01.040.87; 87.040
English Version
Paints and varnishes - Wettability - Part 1: Terminology
and general principles (ISO 19403-1:2017)
Peintures et vernis - Mouillabilité - Partie 1: Beschichtungsstoffe - Benetzbarkeit - Teil 1: Begriffe
Terminologie et principes généraux (ISO 19403- und allgemeine Grundlagen (ISO 19403-1:2017)
1:2017)
This European Standard was approved by CEN on 4 November 2019.
CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this
European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references
concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN
member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by
translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management
Centre has the same status as the official versions.
CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway,
Poland, Portugal, Republic of North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and
United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION
EUROPÄISCHES KOMITEE FÜR NORMUNG
CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2020 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN ISO 19403-1:2020 E
worldwide for CEN national Members.
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SIST EN ISO 19403-1:2020
EN ISO 19403-1:2020 (E)
Contents Page
European foreword . 3
2
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SIST EN ISO 19403-1:2020
EN ISO 19403-1:2020 (E)
European foreword
The text of ISO 19403-1:2017 has been prepared by Technical Committee ISO/TC 35 "Paints and
varnishes” of the International Organization for Standardization (ISO) and has been taken over as
EN ISO 19403-1:2020 by Technical Committee CEN/TC 139 “Paints and varnishes” the secretariat of
which is held by DIN.
This European Standard shall be given the status of a national standard, either by publication of an
identical text or by endorsement, at the latest by August 2020, and conflicting national standards shall
be withdrawn at the latest by August 2020.
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. CEN shall not be held responsible for identifying any or all such patent rights.
According to the CEN-CENELEC Internal Regulations, the national standards organizations of the
following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria,
Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland,
Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Republic of
North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the
United Kingdom.
Endorsement notice
The text of ISO 19403-1:2017 has been approved by CEN as EN ISO 19403-1:2020 without any
modification.
3
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SIST EN ISO 19403-1:2020
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SIST EN ISO 19403-1:2020
INTERNATIONAL ISO
STANDARD 19403-1
First edition
2017-06
Paints and varnishes — Wettability —
Part 1:
Terminology and general principles
Peintures et vernis — Mouillabilité —
Partie 1: Terminologie et principes généraux
Reference number
ISO 19403-1:2017(E)
©
ISO 2017
---------------------- Page: 7 ----------------------
SIST EN ISO 19403-1:2020
ISO 19403-1:2017(E)
COPYRIGHT PROTECTED DOCUMENT
© ISO 2017, Published in Switzerland
All rights reserved. Unless otherwise specified, no part of this publication may be reproduced or utilized otherwise in any form
or by any means, electronic or mechanical, including photocopying, or posting on the internet or an intranet, without prior
written permission. Permission can be requested from either ISO at the address below or ISO’s member body in the country of
the requester.
ISO copyright office
Ch. de Blandonnet 8 • CP 401
CH-1214 Vernier, Geneva, Switzerland
Tel. +41 22 749 01 11
Fax +41 22 749 09 47
copyright@iso.org
www.iso.org
ii © ISO 2017 – All rights reserved
---------------------- Page: 8 ----------------------
SIST EN ISO 19403-1:2020
ISO 19403-1:2017(E)
Contents Page
Foreword .iv
1 Scope . 1
2 Normative references . 1
3 Terms and definitions . 1
3.1 Determination of the surface free energy . 1
3.2 Determination of the surface tension of liquids . 3
4 General principles . 5
4.1 Principles for the determination of the surface free energy . 5
4.2 Principles for the measurement of the surface tension at the pendant drop . 6
Bibliography . 9
© ISO 2017 – All rights reserved iii
---------------------- Page: 9 ----------------------
SIST EN ISO 19403-1:2020
ISO 19403-1:2017(E)
Foreword
ISO (the International Organization for Standardization) is a worldwide federation of national standards
bodies (ISO member bodies). The work of preparing International Standards is normally carried out
through ISO technical committees. Each member body interested in a subject for which a technical
committee has been established has the right to be represented on that committee. International
organizations, governmental and non-governmental, in liaison with ISO, also take part in the work.
ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of
electrotechnical standardization.
The procedures used to develop this document and those intended for its further maintenance are
described in the ISO/IEC Directives, Part 1. In particular the different approval criteria needed for the
different types of ISO documents should be noted. This document was drafted in accordance with the
editorial rules of the ISO/IEC Directives, Part 2 (see www .iso .org/ directives).
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. ISO shall not be held responsible for identifying any or all such patent rights. Details of
any patent rights identified during the development of the document will be in the Introduction and/or
on the ISO list of patent declarations received (see www .iso .org/ patents).
Any trade name used in this document is information given for the convenience of users and does not
constitute an endorsement.
For an explanation on the voluntary nature of standards, the meaning of ISO specific terms and
expressions related to conformity assessment, as well as information about ISO’s adherence to the
World Trade Organization (WTO) principles in the Technical Barriers to Trade (TBT) see the following
URL: w w w . i s o .org/ iso/ foreword .html.
This document was prepared by Technical Committee ISO/TC 35, Paints and varnishes, Subcommittee
SC 9, General test methods for paints and varnishes.
A list of all parts in the ISO 19403 series can be found on the ISO website.
iv © ISO 2017 – All rights reserved
---------------------- Page: 10 ----------------------
SIST EN ISO 19403-1:2020
INTERNATIONAL STANDARD ISO 19403-1:2017(E)
Paints and varnishes — Wettability —
Part 1:
Terminology and general principles
1 Scope
The ISO 19403 series specifies optical test methods
— for the measurement of the contact angle,
— for the determination of the free surface energy of a solid surface, including the polar and dispersive
fractions,
— for the determination of the surface tension of liquids, including the polar and dispersive
fractions, and
— for the checking of the measurement arrangement with reference materials.
It can be applied for the characterization of substrates, coatings and coating materials.
1)
The applicability can be restricted for liquids with non-Newtonian rheology .
This document specifies terms and definitions and defines the general principles.
2 Normative references
The following documents are referred to in the text in such a way that some or all of their content
constitutes requirements of this document. For dated references, only the edition cited applies. For
undated references, the latest edition of the referenced document (including any amendments) applies.
ISO 4618, Paints and varnishes — Terms and definitions
3 Terms and definitions
For the purposes of this document, the terms and definitions given in ISO 4618 and the following apply.
ISO and IEC maintain terminological databases for use in standardization at the following addresses:
— IEC Electropedia: available at http:// www .electropedia .org/
— ISO Online browsing platform: available at http:// www .iso .org/ obp
3.1 Determination of the surface free energy
3.1.1
chemical homogeneity
chemically homogeneous composition of a surface to be examined
Note 1 to entry: The definition regards a purely qualitative assessment of the surface. Regarding the
measurement of the contact angle, a surface is considered chemically and topologically sufficiently homogeneous
if no significant differences of the contact angles can be determined when measuring on several areas on the
surface. The significance limits can be specified by the user in accordance with standard laboratory methods.
1) This term is defined in DIN 1342-1.
© ISO 2017 – All rights reserved 1
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SIST EN ISO 19403-1:2020
ISO 19403-1:2017(E)
3.1.2
topological homogeneity
uniformity of the macroscopic surface, including evenness and smoothness
Note 1 to entry: The definition regards a purely qualitative assessment of the surface. Regarding the
measurement of the contact angle, a surface is considered chemically and topologically sufficiently homogeneous
if no significant differences of the contact angles can be determined when measuring on several areas on the
surface. The significance limits can be specified by the user in accordance with standard laboratory methods.
3.1.3
interfacial free energy
interfacial tension
σ
energy or tension resulting from intermolecular forces on interfaces
Note 1 to entry: The term interfacial energy
...
SLOVENSKI STANDARD
oSIST prEN ISO 19403-1:2019
01-julij-2019
Barve in laki - Omočljivost - 1. del: Terminologija in splošna načela (ISO 19403-
1:2017)
Paints and varnishes - Wettability - Part 1: Terminology and general principles (ISO
19403-1:2017)
Beschichtungsstoffe - Benetzbarkeit - Teil 1: Begriffe und allgemeine Grundlagen (ISO
19403-1:2017)
Peintures et vernis - Mouillabilité - Partie 1: Terminologie et principes généraux (ISO
19403-1:2017)
Ta slovenski standard je istoveten z: prEN ISO 19403-1
ICS:
01.040.87 Industrija barv (Slovarji) Paint and colour industries
(Vocabularies)
87.040 Barve in laki Paints and varnishes
oSIST prEN ISO 19403-1:2019 en,fr,de
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.
---------------------- Page: 1 ----------------------
oSIST prEN ISO 19403-1:2019
---------------------- Page: 2 ----------------------
oSIST prEN ISO 19403-1:2019
INTERNATIONAL ISO
STANDARD 19403-1
First edition
2017-06
Paints and varnishes — Wettability —
Part 1:
Terminology and general principles
Peintures et vernis — Mouillabilité —
Partie 1: Terminologie et principes généraux
Reference number
ISO 19403-1:2017(E)
©
ISO 2017
---------------------- Page: 3 ----------------------
oSIST prEN ISO 19403-1:2019
ISO 19403-1:2017(E)
COPYRIGHT PROTECTED DOCUMENT
© ISO 2017, Published in Switzerland
All rights reserved. Unless otherwise specified, no part of this publication may be reproduced or utilized otherwise in any form
or by any means, electronic or mechanical, including photocopying, or posting on the internet or an intranet, without prior
written permission. Permission can be requested from either ISO at the address below or ISO’s member body in the country of
the requester.
ISO copyright office
Ch. de Blandonnet 8 • CP 401
CH-1214 Vernier, Geneva, Switzerland
Tel. +41 22 749 01 11
Fax +41 22 749 09 47
copyright@iso.org
www.iso.org
ii © ISO 2017 – All rights reserved
---------------------- Page: 4 ----------------------
oSIST prEN ISO 19403-1:2019
ISO 19403-1:2017(E)
Contents Page
Foreword .iv
1 Scope . 1
2 Normative references . 1
3 Terms and definitions . 1
3.1 Determination of the surface free energy . 1
3.2 Determination of the surface tension of liquids . 3
4 General principles . 5
4.1 Principles for the determination of the surface free energy . 5
4.2 Principles for the measurement of the surface tension at the pendant drop . 6
Bibliography . 9
© ISO 2017 – All rights reserved iii
---------------------- Page: 5 ----------------------
oSIST prEN ISO 19403-1:2019
ISO 19403-1:2017(E)
Foreword
ISO (the International Organization for Standardization) is a worldwide federation of national standards
bodies (ISO member bodies). The work of preparing International Standards is normally carried out
through ISO technical committees. Each member body interested in a subject for which a technical
committee has been established has the right to be represented on that committee. International
organizations, governmental and non-governmental, in liaison with ISO, also take part in the work.
ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of
electrotechnical standardization.
The procedures used to develop this document and those intended for its further maintenance are
described in the ISO/IEC Directives, Part 1. In particular the different approval criteria needed for the
different types of ISO documents should be noted. This document was drafted in accordance with the
editorial rules of the ISO/IEC Directives, Part 2 (see www .iso .org/ directives).
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. ISO shall not be held responsible for identifying any or all such patent rights. Details of
any patent rights identified during the development of the document will be in the Introduction and/or
on the ISO list of patent declarations received (see www .iso .org/ patents).
Any trade name used in this document is information given for the convenience of users and does not
constitute an endorsement.
For an explanation on the voluntary nature of standards, the meaning of ISO specific terms and
expressions related to conformity assessment, as well as information about ISO’s adherence to the
World Trade Organization (WTO) principles in the Technical Barriers to Trade (TBT) see the following
URL: w w w . i s o .org/ iso/ foreword .html.
This document was prepared by Technical Committee ISO/TC 35, Paints and varnishes, Subcommittee
SC 9, General test methods for paints and varnishes.
A list of all parts in the ISO 19403 series can be found on the ISO website.
iv © ISO 2017 – All rights reserved
---------------------- Page: 6 ----------------------
oSIST prEN ISO 19403-1:2019
INTERNATIONAL STANDARD ISO 19403-1:2017(E)
Paints and varnishes — Wettability —
Part 1:
Terminology and general principles
1 Scope
The ISO 19403 series specifies optical test methods
— for the measurement of the contact angle,
— for the determination of the free surface energy of a solid surface, including the polar and dispersive
fractions,
— for the determination of the surface tension of liquids, including the polar and dispersive
fractions, and
— for the checking of the measurement arrangement with reference materials.
It can be applied for the characterization of substrates, coatings and coating materials.
1)
The applicability can be restricted for liquids with non-Newtonian rheology .
This document specifies terms and definitions and defines the general principles.
2 Normative references
The following documents are referred to in the text in such a way that some or all of their content
constitutes requirements of this document. For dated references, only the edition cited applies. For
undated references, the latest edition of the referenced document (including any amendments) applies.
ISO 4618, Paints and varnishes — Terms and definitions
3 Terms and definitions
For the purposes of this document, the terms and definitions given in ISO 4618 and the following apply.
ISO and IEC maintain terminological databases for use in standardization at the following addresses:
— IEC Electropedia: available at http:// www .electropedia .org/
— ISO Online browsing platform: available at http:// www .iso .org/ obp
3.1 Determination of the surface free energy
3.1.1
chemical homogeneity
chemically homogeneous composition of a surface to be examined
Note 1 to entry: The definition regards a purely qualitative assessment of the surface. Regarding the
measurement of the contact angle, a surface is considered chemically and topologically sufficiently homogeneous
if no significant differences of the contact angles can be determined when measuring on several areas on the
surface. The significance limits can be specified by the user in accordance with standard laboratory methods.
1) This term is defined in DIN 1342-1.
© ISO 2017 – All rights reserved 1
---------------------- Page: 7 ----------------------
oSIST prEN ISO 19403-1:2019
ISO 19403-1:2017(E)
3.1.2
topological homogeneity
uniformity of the macroscopic surface, including evenness and smoothness
Note 1 to entry: The definition regards a purely qualitative assessment of the surface. Regarding the
measurement of the contact angle, a surface is considered chemically and topologically sufficiently homogeneous
if no significant differences of the contact angles can be determined when measuring on several areas on the
surface. The significance limits can be specified by the user in accordance with standard laboratory methods.
3.1.3
interfacial free energy
interfacial tension
σ
energy or tension resulting from intermolecular forces on interfaces
Note 1 to entry: The term interfacial energy pertains to the interaction with solid surfaces and is indicated as
2
free energy in relation to the surface (unit mJ/m ). The term interfacial tension pertains to the interaction with
liquids and is indicated as force per length unit (mN/m). The respective indices “l” for “liquid” and “s” for “solid”
indicate the phases involved.
3.1.4
surface free energy
free energy of the surface
σ
s
interfacial free energy (3.1.3) of a solid surface
3.1.5
surface tension
σ
l
interfacial tension of a liquid surface in equilibrium with its vapour phase
Note 1 to entry: The surface tension is indicated as force per length unit (mN/m). Its numerical value corresponds
to the free energy of the interface or surface.
Note 2 to entry: The surface tension corresponds to the work which shall be done in order to enlarge a given
surface by a specific value.
3.1.6
interfacial energy
σ
sl
energy on the phase interface between a solid and a liquid phase
3.1.7
three-phase point
point at which solid phase, liquid phase and vapour phase are in contact with each other
Note 1 to entry: See Figure 1.
3.1.8
base line
straight line through both three-phase points (3.1.7)
Note 1 to entry: See Figure 1.
3.1.9
contact angle
θ
angle to the base line (3.1.8) within the drop, formed by means of a tangent on the drop contour through
one of the three-phase points (3.1.7)
Note 1 to entry: See Figure 1.
2 © ISO 2017 – All rights reserved
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oSIST prEN ISO 19403-1:2019
ISO 19403-1:2017(E)
Note 2 to entry: The contact angle is preferably indicated in degrees (°). 1° = (π/180)°. If the system is in
thermodynamic equilibrium, this contact angle is also referred to as thermodynamic equilibrium contact angle.
Key
1 three-phase point
2 liquid
σ surface tension of the liquid
l
σ surface free energy of the solid surface
s
σ interfacial energy between solid surface and l
...
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