EN 13130-4:2004

Materials and articles in contact with foodstuffs - Plastics substances subject to limitation - Part 4: Determination of 1,3-butadiene in plastics

This part of this European Standard specifies a method for the determination of butadiene monomer in polymers.
The method is applicable to acrylonitrile-butadiene-styrene copolymer (ABS) and to high-impact polystyrene (HIPS) as well as to other 1,3-butadiene polymers and copolymers where these are soluble in N,N-dimethylacetamide or finely dispersed, swollen suspensions in N,N-dimethylacetamide. The level of 1,3-butadiene monomer determined is expressed as milligrams of 1,3-butadiene per kilogram of polymer.  The method is appropriate for the quantitative determination of 1,3-butadiene at a level of 0,1 mg/kg in the polymer.

Werkstoffe und Gegenstände in Kontakt mit Lebensmitteln - Substanzen in Kunststoffen, die Beschränkungen unterliegen - Teil 4: Bestimmung von 1,3-Butadien in Kunststoffen

Matériaux et objets en contact avec les denrées alimentaires - Substances dans les matières plastiques soumises à des limitations - Partie 4 : Détermination du 1,3-butadiène dans les matières plastiques

La présente partie de cette Norme européenne spécifie une méthode de détermination du monomère de butadiène dans les polymères.
La méthode s'applique au copolymère d'acrylonitrile-butadiène-styrène (ABS) et au polystyrène à haute résistance au choc (HIPS) ainsi qu'aux autres polymères et copolymères de 1,3-butadiène lorsque ceux-ci sont solubles dans le N,N-diméthylacétamide ou finement dispersés et expansés en suspension, dans ce même N,N-diméthylacétamide. Le niveau du monomère de 1,3-butadiène déterminé est exprimé en milligrammes de 1,3-butadiène par kilogramme de polymère. La méthode convient au dosage quantitatif du 1,3-butadiène à un niveau de 0,1 mg/kg dans le polymère.

Materiali in predmeti v stiku z živili - Snovi v polimernih materialih, katerih koncentracija je omejena - 4. del: Določevanje 1,3-butadiena v polimernih materialih

General Information

• Status: Published
• Publication Date: 25-May-2004
• Withdrawal Date: 29-Nov-2004
• ICS: 67.250 - Materials and articles in contact with foodstuffs
• Technical Committee: CEN/TC 194 - Utensils in contact with food
• Drafting Committee: CEN/TC 194/SC 1/WG 2 - Methods of test for monomers
• Current Stage: 9092 - Decision on results of review/2YR ENQ - revise - Review Enquiry
• Completion Date: 10-Apr-2018
• Directive: 89/109/EEC - Materials and articles intended to come into contact with foodstuffs
• Mandate: M/052 - Standardization mandate to CEN concerning methods of analysis for materials and articles intended to come into contact with foodstuffs
• Ref Project: SIST EN 13130-4:2004 - Materials and articles in contact with foodstuffs - Plastics substances subject to limitation - Part 4: Determination of 1,3-butadiene in plastics

Relations

• Replaces: ENV 13130-4:1999 - Materials and articles in contact with foodstuffs - Plastics substances subject to limitation - Part 4: Determination of 1,3-butadiene in plastics
• Effective Date: 22-Dec-2008

Standards Content (Sample)

2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.OLPHUQLKPDWHULDOLKWerkstoffe und Gegenstände in Kontakt mit Lebensmitteln - Substanzen in Kunststoffen, die Beschränkungen unterliegen - Teil 4: Bestimmung von 1,3-Butadien in KunststoffenMatériaux et objets en contact avec les denrées alimentaires - Substances dans les matieres plastiques soumises a des limitations - Partie 4 : Détermination du 1,3-butadiene dans les matieres plastiquesMaterials and articles in contact with foodstuffs - Plastics substances subject to limitation - Part 4: Determination of 1,3-butadiene in plastics67.250Materiali in predmeti v stiku z živiliMaterials and articles in contact with foodstuffsICS:Ta slovenski standard je istoveten z:EN 13130-4:2004SIST EN 13130-4:2004en,fr,de01-september-2004SIST EN 13130-4:2004SLOVENSKI
STANDARDSIST ENV 13130-4:20001DGRPHãþD



SIST EN 13130-4:2004



EUROPEAN STANDARDNORME EUROPÉENNEEUROPÄISCHE NORMEN 13130-4May 2004ICS 67.250English versionMaterials and articles in contact with foodstuffs - Plasticssubstances subject to limitation - Part 4: Determination of 1,3-butadiene in plasticsMatériaux et objets en contact avec les denréesalimentaires - Substances dans les matières plastiquessoumises à des limitations - Partie 4 : Détermination du1,3-butadiène dans les matières plastiquesWerkstoffe und Gegenstände in Kontakt mit Lebensmitteln- Substanzen in Kunststoffen, die Beschränkungenunterliegen - Teil 4: Bestimmung von 1,3-Butadien inKunststoffenThis European Standard was approved by CEN on 24 March 2004.CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this EuropeanStandard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such nationalstandards may be obtained on application to the Central Secretariat or to any CEN member.This European Standard exists in three official versions (English, French, German). A version in any other language made by translationunder the responsibility of a CEN member into its own language and notified to the Central Secretariat has the same status as the officialversions.CEN members are the national standards bodies of Austria, Belgium, Cyprus, Czech Republic, Denmark, Estonia, Finland, France,Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Slovakia,Slovenia, Spain, Sweden, Switzerland and United Kingdom.EUROPEAN COMMITTEE FOR STANDARDIZATIONCOMITÉ EUROPÉEN DE NORMALISATIONEUROPÄISCHES KOMITEE FÜR NORMUNGManagement Centre: rue de Stassart, 36
B-1050 Brussels© 2004 CENAll rights of exploitation in any form and by any means reservedworldwide for CEN national Members.Ref. No. EN 13130-4:2004: ESIST EN 13130-4:2004



EN 13130-4:2004 (E) 2 Contents page Foreword.3 1 Scope.6 2 Normative references.6 3 Principle.6 4 Reagents.6 5 Apparatus.7 6 Samples.8 6.1 General.8 6.2 Sample preparation for gas chromatography.8 6.2.1 Test samples.8 6.2.2 Calibration samples for the standard addition method.8 6.2.3 Blank samples.8 7 Procedure.9 7.1 GC preparation.
...