Adhesives for leather and footwear materials - Preparation of bonded test pieces by moulding-on processes

This European Standard specifies procedures for the preparation of test pieces comprising adhesive coated leather or other footwear upper material onto which a soling material is moulded directly. The procedures described simulate direct vulcanising of rubber, injection moulding of thermoplastics and reaction moulding of polyurethane.
The prepared test pieces are suitable for the test procedures described in EN 1392, to meet the requirements of EN 15307.

Klebstoffe für Leder und Schuhwerkstoffe - Herstellung von Verbund-Proben nach dem Anformverfahren

Diese Europäische Norm legt Verfahren zur Herstellung von Proben aus Leder oder einem anderen Schuh-Obermaterial fest, an das ein Sohlenwerkstoff unmittelbar auf den aufgetragenen Klebstoff angeformt wird. Die beschriebenen Verfahren simulieren das Direktvulkanisieren von Kautschuk, das Spritzgießen von thermoplastischen Kunststoffen und das Reaktionsgießen von Polyurethan.
Die hergestellten Proben sind für die in EN 1392 beschriebenen Prüfverfahren und zur Erfüllung der Anforderungen von EN 15307 geeignet.
SICHERHEITSHINWEIS — Personen, die dieses Dokument anwenden, sollten mit der üblichen Laborpraxis vertraut sein. Dieses Dokument beabsichtigt nicht, alle Sicherheitsprobleme, soweit vorhanden, anzusprechen. Es liegt in der Verantwortung des Anwenders, geeignete Verhaltensregeln zur Sicherheit und Gesundheit festzulegen und deren Übereinstimmung mit den Bestimmungen aller gesetzlichen Regelungen sicherzu¬stellen.
UMWELTSCHUTZHINWEIS — Selbstverständlich können einige der in dieser Norm zugelassenen Materialien negative Auswirkungen auf die Umwelt haben. Sobald der technologische Fortschritt zu akzep¬tablen Alternativen zu diesen Materialien führt, werden sie so weit wie möglich aus der Norm entfernt. Am Ende der Prüfung sollte der Anwender der Norm für eine geeignete Entsorgung des Abfalls entsprechend den regionalen Bestimmungen Sorge tragen.

Adhésifs pour cuir et matériaux de la chaussure - Préparation d'éprouvettes collées par moulage direct sur tige

La présente Norme européenne spécifie des modes de préparation d’éprouvettes en cuir ou en toute autre matière à dessus de chaussure enduites d’adhésif et sur lesquelles un matériau solide est directement moulé. Les modes opératoires décrits simulent la vulcanisation directe du caoutchouc, l’injection de thermoplastiques et le moulage par réaction de polyuréthanne.
Les éprouvettes préparées conviennent aux modes opératoires d’essai décrits dans l’EN 1392 et respectent les exigences de l’EN 15307.
DÉCLARATION DE SÉCURITÉ – Il convient que les utilisateurs du présent document soient familiarisés avec les pratiques courantes de laboratoire, le cas échéant. Le présent document n’a pas pour but de traiter tous les problèmes de sécurité qui sont, le cas échéant, liés à son utilisation. Il incombe à l’utilisateur de la présente norme d’établir des pratiques appropriées en matière d’hygiène et de sécurité, et de s’assurer de la conformité à toutes les dispositions réglementaires.
DÉCLARATION ENVIRONNEMENTALE – Il est reconnu que certains des matériaux autorisés dans la présente norme peuvent avoir un impact négatif sur l’environnement. À mesure que les avancées technologiques mènent à d’autres solutions acceptables, ces matériaux seront autant que possible supprimés de la présente norme.
À la fin de l’essai, il convient que l’utilisateur de la norme prenne soin d’éliminer les déchets de façon appropriée, conformément à la réglementation locale.

Lepila za usnjene in obutvene materiale - Izdelava lepljenih preskušancev s postopki direktnega podplatenja

Ta evropski standard določa postopke za pripravo preskušancev, ki vključujejo z lepilom prevlečeni usnjeni ali drug obutveni zgornji material, na katerega se neposredno vlije material za podplate. Opisani postopki posnemajo neposredno vulkanizacijo gume, podplatenje plastomerov z nabrizgavanjem in reakcijsko podplatenje poliuretana. Da pripravljeni preskušanci ustrezajo zahtevam v EN 15307, morajo biti primerni za preskusne postopke, opisane v EN 1392. IZJAVA O VARNOSTI – Kjer je to primerno, morajo biti osebe, ki uporabljajo ta dokument, seznanjene z običajnimi laboratorijskimi praksami. Ta dokument nima namena obravnavati vseh varnostnih problemov, ki bi lahko bili povezani z njegovo uporabo. Odgovornost uporabnika je, da vzpostavi primerne varnostne in zdravstvene prakse in zagotovi skladnosti z vsemi zakonskimi pogoji. OKOLJSKA IZJAVA – Razume se, da imajo nekateri materiali, ki jih dovoljuje ta standard, lahko negativen učinek na okolje. Ko bo tehnološki napredek omogočil sprejemljive alternative za te materiale, bodo v največji mogoči meri izločeni iz tega standarda. Ob koncu preskusa mora uporabnik standarda poskrbeti, da odstrani odpadke na primeren način, v skladu z lokalnimi predpisi.

General Information

Status
Published
Publication Date
09-Feb-2010
Withdrawal Date
30-Aug-2010
Technical Committee
Drafting Committee
Current Stage
9093 - Decision to confirm - Review Enquiry
Completion Date
19-Dec-2019

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2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.Lepila za usnjene in obutvene materiale - Izdelava lepljenih preskušancev s postopki direktnega podplatenjaKlebstoffe für Leder und Schuhwerkstoffe - Herstellung von Verbund-Proben nach dem AnformverfahrenAdhésifs pour cuir et matériaux de la chaussure - Préparation d'éprouvettes collées par moulage direct sur tigeAdhesives for leather and footwear materials - Preparation of bonded test pieces by moulding-on processes83.180LepilaAdhesives61.060ObuvalaFootwearICS:Ta slovenski standard je istoveten z:EN 14294:2010SIST EN 14294:2010en,fr,de01-maj-2010SIST EN 14294:2010SLOVENSKI
STANDARDSIST EN 14294:20051DGRPHãþD



SIST EN 14294:2010



EUROPEAN STANDARD NORME EUROPÉENNE EUROPÄISCHE NORM
EN 14294
February 2010 ICS 83.180 Supersedes EN 14294:2004English Version
Adhesives for leather and footwear materials - Preparation of bonded test pieces by moulding-on processes
Adhésifs pour cuir et matériaux de la chaussure - Préparation d'éprouvettes collées par moulage direct sur tige
Klebstoffe für Leder und Schuhwerkstoffe - Herstellung von Verbund-Proben nach dem Anformverfahren This European Standard was approved by CEN on 28 December 2009.
CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN Management Centre or to any CEN member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN Management Centre has the same status as the official versions.
CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION EUROPÄISCHES KOMITEE FÜR NORMUNG
Management Centre:
Avenue Marnix 17,
B-1000 Brussels © 2010 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN 14294:2010: ESIST EN 14294:2010



EN 14294:2010 (E) 2 Contents Page Foreword .3Introduction .41Scope .52Normative references .53Terms and definitions .54Procedure .65Adhesives and materials .66Apparatus .77Test pieces .88Preparation of moulded-on assemblies .99Test report . 13 SIST EN 14294:2010



EN 14294:2010 (E) 3 Foreword This document (EN 14294:2010) has been prepared by Technical Committee CEN/TC 193 “Adhesives”, the secretariat of which is held by AENOR. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by August 2010, and conflicting national standards shall be withdrawn at the latest by August 2010. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. CEN [and/or CENELEC] shall not be held responsible for identifying any or all such patent rights. This document supersedes EN 14294:2004. According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and the United Kingdom. SIST EN 14294:2010



EN 14294:2010 (E) 4
Introduction EN 15307 and EN 1392 specify methods of testing and evaluation of adhesives for leather and footwear materials in "stuck-on" assemblies. Most footwear produced in Europe is manufactured using stuck-on processes, but a significant proportion is produced by "moulding-on" processes such as vulcanising, injection moulding and reaction moulding. This document specifies the preparation of bonded test pieces by moulding-on processes. The form and dimensions of the test pieces produced allows testing according to the test methods specified in EN 1392, and evaluation of the bond strength obtained according to EN 15307. This document therefore complements the above mentioned series of documents, and together they allow the simulation, testing and evaluation of almost all bonds occurring in common footwear constructions. SIST EN 14294:2010



EN 14294:2010 (E) 5 1 Scope This European Standard specifies procedures for the preparation of test pieces comprising adhesive coated leather or other footwear upper material onto which a soling material is moulded directly. The procedures described simulate direct vulcanising of rubber, injection moulding of thermoplastics and reaction moulding of polyurethane. The prepared test pieces are suitable for the test procedures described in EN 1392, to meet the requirements of EN 15307. SAFETY STATEMENT— Persons using this document should be familiar with the normal laboratory practice, if applicable. This document does not purport to address all of the safety problems, if any, associated with its use. It is the responsibility of the user to establish appropriate safety and health practices and to ensure compliance with any regulatory conditions. ENVIRONMENTAL STATEMENT— It is understood that some of the material permitted in this standard may have negative environmental impact. As technological advantages lead to acceptable alternatives for these materials, they will be eliminated from this standard to the extent possible. At the end of the test, the user of the standard should take care to carry out an appropriate disposal of the wastes, according to local regulation. 2 Normative references The following referenced documents are indispensable for the application of this document. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. EN 923:2005, Adhesives
Terms and definitions EN 1392:2006, Adhesives for leather and footwear materials
Solvent-based and dispersion adhesives
Testing of bond strength under specified conditions EN 15307, Adhesives for leather and footwear materials
Sole-upper bonds
Minimum strength requirements EN ISO 868, Plastics and ebonite
Determination of indentation hardness by means of a durometer (Shore hardness) (ISO 868:2003) 3 Terms and definitions For the purposes of this document, the terms and definitions given in EN 923:2005 and EN 1392:2006 and the following apply. 3.1 moulding-on process process for soling footwear in which the soling material is directly moulded onto the bottom of the shoe in a mould closed by the shoe upper or other footwear component
NOTE The other footwear component can be an outsole or midsole onto which another soling layer is to be moulded. 3.2 vulcanising moulding process in which uncured rubber is inserted or extruded into the mould and is shaped and crosslinked by heat and pressure SIST EN 14294:2010



EN 14294:2010 (E) 6 3.3 injection moulding moulding process in which molten thermoplastic material is injected into the mould and sets on cooling 3.4 reaction moulding moulding process in which reactive chemicals are poured or injected into the mould and polymerise and crosslink by chemical reaction 4 Procedure The surface of the leather, other footwear upper material or other footwear component material used is treated in a manner specific to the nature of the material. Strips of specified length and width are cut from the treated material. One or more of these strips are coated with adhesive and attached, with the bonding surface uppermost, to the bottom plate of a mould. Soling material is introduced to fill the mould and allowed to cure or set as appropriate to produce an assembly of soling bonded to upper material. The moulded assembly, and test pieces cut from it, are stored under specified conditions before testing. 5 Adhesives and materials 5.1 Footwear adhesives The adhesive used shall be identified in the report, in particular note name and/or designation, manufacturer, date of manufacture or supply and/or lot number, main polymer and colour. For two-part adhesives the nature of the crosslinking agent and the mixing ratio of the components shall be identified. Reference footwear test adhesives are one- or two-part adhesives with specified properties (e.g. Test adhesive CR 1, Test adhesive CR 2, Test adhesive PU 1, Test adhesive PU 2, Test adhesive PUD 1, Test adhesive PUD 2). If a reference footwear test adhesive in accordance with EN 15307 is used, record its designation in the report. NOTE For direct vulcanising processes, and injection moulding processes with styrene-butadiene-styrene thermoplastic rubber (SBSR), special types of adhesive are required.
5.2 Footwear materials 5.2.1 General Identify all footwear materials used in the report. 5.2.2 Upper materials (or other footwear materials) Record the name and/or designation, manufacturer, date of manufacture or supply and type of leather, other footwear upper material (or other footwear material) used. For leathers list colour, thickness and type of tannage (if known). If reference test material Leather 1 is used in accordance with EN 15307, record its designation. 5.2.3 Soling moulding materials 5.2.3.1 General The soling moulding material required depends on the moulding-on process to be simulated. SIST EN 14294:2010



EN 14294:2010 (E) 7 5.2.3.2 Direct vulcanising materials Record the name and/or designation, manufacturer, date of manufacture or supply, colour, polymer base and Shore hardness in accordance with EN ISO 868 of the material used. NOTE Uncured compounds of acrylonitrile-butadiene (nitrile) rubber (NBR) or styrene-butadiene rubber (SBR) are mainly used. 5.2.3.3 Injection moulding materials Record the name and/or designation, manufacturer, date of manufacture or supply, colour, polymer base and Shore hardness in accordance with EN ISO 868 of the material used. NOTE PVC compounds or styrene-butadiene-styrene thermoplastic rubber (SBSR) compounds are mainly used. 5.2.3.4 Reaction moulding materials Record the name and/or designation, manufacturer, date of manufacture or supply, colour, chemical nature of the reactive constituents and the catalysts used, if any. NOTE Polyurethane chemicals are mainly used, consisting of a prepolymer and a resin which are mixed in the appropriate proportions before moulding. If a catalyst is also required, this can be added to the resin prior to the weighing out of the constituents. 6 Apparatus 6.1 General The items required depend on the types of material used and the type of moulding-on process. 6.2 Cutting knife, sharp for cutting test pieces in accordance with 7.1. The angle between the inner and outer cutting surface shall be approximately 20°. 6.3 Adhesive applicator, brush, roller or coating machine for applying a uniform coat of the adhesive under test. 6.4 Platen press, a heated platen press suitable for direct vulcanisation of rubber, capable of: a) maintaining platen temperatures of (105 ± 5) °C for the bottom platen and (180 ± 5) °C for the top platen; b) applying a pressure up to 5 MPa to the mould. 6.5 Rectangular mould, of approximate dimensions 150 mm × 100 mm × 5 mm for direct vulcanisation. The wall of the mould base should include a 10 mm wide shelf all round, half way up, to accept excess rubber displaced from the cavity. 6.6 Surface pyrometer, suitable for measuring the operating temperatures of the press platens. 6.7 Oven, capable of maintaining a temperature of (75 ± 5) °C to pre-heat the rubber prior to moulding. 6.8 Gloves, heat resistant, suitable for handling the hot mould. 6.9 Injection moulding machine, fitted with a mould of approximate dimensions 150 mm × 100 mm × 5 mm for the preparation of flat test plaques. A commercial single station low pressure screw injection moulder is suitable. 6.10 Mould, for polyurethane reaction moulding, having: a) flat rigid base with a rectangular cavity of approximate dimensions 300 mm × 200 mm × 6,5 mm; SIST EN 14294:2010



EN 14294:2010 (E) 8 b) rigid hinged lid which can be held in place, for example by two wing nuts; c) rebate a few millimetres deep across the two corners of the base away from the hinge. This provides a gap which can assist in opening of the mould. 6.11 Oven, capable of maintaining a temperature of (50 ± 5) °C to heat the mould prior to moulding. 6.12 Mould release agent, suitable for polyurethanes. 6.13 Solvent, such as 2-butanone (MEK), suitable for removing mould release agent. 6.14 General purpose balance, reading up to 300 g with an accuracy of 0,1 g.
6.15 Metal mixing cans, of approximate volume 400 cm3 capable of holding about 300 g of the polyurethane constituents in liquid form. 6.16 Paper weighing cups, of approximate volume 200 cm3, to weigh the polyurethane prepolymer prior to mixing. 6.17 High speed stirrer, suitable for mixing the viscous polyurethane constituents in a metal can. A stirrer with a mixing head comprising a horizontal spoked metal wheel with rectangular teeth around the edge is suitable. 6.18 Polyethylene gloves. 6.19 Safety goggles. 6.20 Adhesive tape, double side adhesive tape. 7 Test pieces 7.1 General The form and dimensions of the test pieces prepared from the moulded-on assemblies shall comply with the requirements for test pieces for peel tests at (23 ± 2) °C, and test pieces for peel tests under constant load and at a constant elevated temperature ("creep test") in EN 1392. 7.2 Number of test pieces Prepare sets of test pieces in accordance with EN 1392. 7.3 Preparation of test strips 7.3.1 General Condition the footwear upper material in accordance with EN 1392. 7.3.2 Cutting of material strips Cut strips of the required size as indicated in EN 1392 from the upper mater
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