SIST-TS CEN/TS 18020:2024
(Main)Construction products - Assessment of release of dangerous substances - Sampling and quantitative determination of asbestos in construction products
Construction products - Assessment of release of dangerous substances - Sampling and quantitative determination of asbestos in construction products
This document summarizes methods for sampling, sample preparation and identification of asbestos in construction products. This document specifies appropriate sample preparation procedures for the quantitative analysis of the asbestos mass fraction in natural, manufactured or recycled large mineral aggregates and construction products of fine mineral particle size materials. This document describes the identification of asbestos by polarized light microscopy (PLM) and dispersion staining, scanning electron microscopy (SEM) with energy dispersive X-ray analysis or transmission electron microscopy (TEM) with energy dispersive X-ray and electron diffraction analysis.
NOTE This document is intended for microscopists familiar with polarized light, transmission electron- and scanning electron microscopy methods and the other analytical techniques specified (see ISO 10312, ISO 13794, ISO 14966, [McCrone et al., 1984], [Su et al., 1995]). It is not the intention of this document to provide instructions on basic analytical techniques.
Bauprodukte - Bewertung der Freisetzung von gefährlichen Stoffen - Probenahme und qualitative Bestimmung von Asbest in Bauprodukten
Dieses Dokument fasst die Probenahmeverfahren, die Probenvorbereitung und die Identifizierung von Asbest in Bauprodukten zusammen. Dieses Dokument legt geeignete Verfahren zur Probenvorbereitung für die quantitative Analyse des Massenanteils von Asbest in natürlichen, hergestellten oder rezyklierten großen mineralischen Gesteinskörnungen und Bauprodukten aus mineralischen Feinkornmaterialien fest. Dieses Dokument beschreibt die Identifizierung von Asbest durch Polarisationsmikroskopie (PLM) und Dispersionsfärbung, Rasterelektronenmikroskopie (REM) mit energiedispersiver Röntgenanalyse oder Transmissionselektronenmikroskopie (TEM) mit energiedispersiver Röntgen- und Elektronenbeugungsanalyse.
ANMERKUNG Dieses Dokument richtet sich an Mikroskopiker, die mit den Verfahren der Polarisations-, Transmissions- und Rasterelektronenmikroskopie und den anderen festgelegten Analyseverfahren vertraut sind (siehe ISO 10312, ISO 13794, ISO 14966, [McCrone et al., 1984], [Su et al., 1995]). Es ist nicht Zweck dieses Dokuments, Anleitungen zu grundlegenden Analyseverfahren zu geben.
Produits de construction - Evaluation de l'émission de substances dangereuses - Échantillonnage et dosage qualitatif de lamiante dans les produits de construction
Gradbeni proizvodi - Ocenjevanje sproščanja nevarnih snovi - Vzorčenje in kvantitativno določanje azbesta v gradbenih proizvodih
V tem dokumentu so povzete metode za vzorčenje, pripravo vzorcev in določevanje azbesta v gradbenih proizvodih. Ta dokument določa ustrezne postopke priprave vzorcev za kvantitativno analizo masnega deleža azbesta v naravnih, umetnih ali recikliranih velikih mineralnih agregatih in gradbenih proizvodih iz mineralnih materialov z zelo majhno velikostjo delcev. Opisuje določevanje azbesta s polarizirano svetlobno mikroskopijo (PLM) in disperzijskim obarvanjem, vrstično elektronsko mikroskopijo (SEM) z energijsko-disperzivno rentgensko analizo oziroma presevno elektronsko mikroskopijo (TEM) z energijsko-disperzivno rentgensko analizo in elektronsko difrakcijsko analizo.
OPOMBA: Ta dokument je namenjen mikroskopistom, ki poznajo metode polarizirane svetlobne mikroskopije, presevne elektronske mikroskopije in vrstične elektronske mikroskopije ter druge navedene analitske tehnike (glej standarde ISO 10312, ISO 13794, ISO 14966, [McCrone et al., 1984], [Su et al., 1995]). Namen tega dokumenta ni zagotavljanje navodil za osnovne analitske tehnike.
General Information
Standards Content (Sample)
SLOVENSKI STANDARD
01-september-2024
Gradbeni proizvodi - Ocenjevanje sproščanja nevarnih snovi - Vzorčenje in
kvantitativno določanje azbesta v gradbenih proizvodih
Construction products - Assessment of release of dangerous substances - Sampling and
quantitative determination of asbestos in construction products
Bauprodukte - Bewertung der Freisetzung von gefährlichen Stoffen - Probenahme und
qualitative Bestimmung von Asbest in Bauprodukten
Produits de construction - Evaluation de l'émission de substances dangereuses -
Échantillonnage et dosage qualitatif de lamiante dans les produits de construction
Ta slovenski standard je istoveten z: CEN/TS 18020:2024
ICS:
13.300 Varstvo pred nevarnimi Protection against dangerous
izdelki goods
91.100.01 Gradbeni materiali na Construction materials in
splošno general
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.
CEN/TS 18020
TECHNICAL SPECIFICATION
SPÉCIFICATION TECHNIQUE
March 2024
TECHNISCHE SPEZIFIKATION
ICS 13.300; 91.100.01
English Version
Construction products: Assessment of release of
dangerous substances - Sampling and quantitative
determination of asbestos in construction products
Produits de construction: Evaluation de l'émission de Bauprodukte: Bewertung der Freisetzung von
substances dangereuses - Échantillonnage et dosage gefährlichen Stoffen - Probenahme und qualitative
qualitatif de l'amiante dans les produits de Bestimmung von Asbest in Bauprodukten
construction
This Technical Specification (CEN/TS) was approved by CEN on 12 February 2024 for provisional application.
The period of validity of this CEN/TS is limited initially to three years. After two years the members of CEN will be requested to
submit their comments, particularly on the question whether the CEN/TS can be converted into a European Standard.
CEN members are required to announce the existence of this CEN/TS in the same way as for an EN and to make the CEN/TS
available promptly at national level in an appropriate form. It is permissible to keep conflicting national standards in force (in
parallel to the CEN/TS) until the final decision about the possible conversion of the CEN/TS into an EN is reached.
CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway,
Poland, Portugal, Republic of North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Türkiye and
United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION
EUROPÄISCHES KOMITEE FÜR NORMUNG
CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2024 CEN All rights of exploitation in any form and by any means reserved Ref. No. CEN/TS 18020:2024 E
worldwide for CEN national Members.
Contents Page
European foreword . 5
Introduction . 6
1 Scope . 8
2 Normative references . 8
3 Terms and definitions . 8
4 Abbreviations . 14
5 Principle . 15
6 Asbestos . 16
6.1 Regulated asbestos minerals . 16
6.2 Physical and morphological properties of asbestos minerals. 16
6.3 Naturally occurring asbestos (NOA) . 17
6.4 Asbestos containing construction products . 18
7 Method detection limit . 18
8 Limit of quantification . 19
9 Requirements for sampling, sample preparation and analysis . 19
9.1 Materials and equipment for sampling . 19
9.1.1 Equipment for sampling construction products of fine grain size . 19
9.1.2 Equipment for sampling of large aggregates . 20
9.1.3 Materials and supplies for sampling . 20
9.2 Materials and equipment for sample preparation . 20
9.3 Materials and equipment for analysis . 22
10 Representative sample . 23
11 Sampling . 24
11.1 General. 24
11.2 Safety precaution . 24
11.3 Sampling of large mineral aggregates . 25
11.4 Sampling of construction products of mineral aggregates of fine grain size . 25
11.5 Sampling of construction products of monolithic natural stones . 25
11.6 Sample taking . 26
11.7 Sample protocol . 26
11.8 Storage and transport . 26
12 Sample preparation . 27
12.1 General. 27
12.2 Sample preparation of construction products of fine grain size material . 27
12.2.1 General. 27
12.2.2 Preliminary examination of the sample . 27
12.2.3 Estimation of the mass fraction of commercially added asbestos in known
construction products . 28
12.2.4 Sample preparation procedures . 29
12.2.5 Sample filter preparation for quantitative analysis of the asbestos content . 29
12.3 Sample preparation of large mineral aggregates . 30
12.3.1 Sample preparation of recycled mineral aggregates . 30
12.3.2 Sieving of large mineral aggregates . 30
12.3.3 Sample preparation of sieve fractions for the detection and quantification of NOAs 31
12.3.4 Sample preparation of primary aggregates . 32
12.4 Sample preparation of construction products of natural stones . 32
13 Identification of asbestos . 32
13.1 General . 32
13.2 Reference materials . 32
13.3 Identification of asbestos by polarized light microscopy . 33
13.3.1 General . 33
13.3.2 Discrimination between asbestos and other elongated mineral fragments . 34
13.3.3 Limitation in the detection of asbestos. 34
13.3.4 PLM-specific sample preparation . 34
13.3.5 Interferences . 35
13.4 Identification of asbestos by scanning electron microscopy and EDXA . 35
13.4.1 General . 35
13.4.2 Analysis via EDXA spectra and peak height ratios normalized on silica (Si) with
reference spectra . 35
13.4.3 Discrimination between asbestos and other elongated mineral fragments . 36
13.4.4 Limitation in the detection of asbestos. 36
13.4.5 SEM specific sample preparation . 36
13.5 Identification of asbestos by transmission electron microscopy. 37
13.5.1 General . 37
13.5.2 Discrimination between asbestos and other elongated mineral fragments . 37
13.5.3 Limitation in the detection of asbestos. 37
13.5.4 Preparation of isolated fibres on TEM grids . 37
13.5.5 Preparation of filter . 37
14 Quantitative determination of asbestos mass fraction . 38
14.1 Quantitative determination of asbestos mass fraction from pulverised test sample on
a filter preparation . 38
14.1.1 General . 38
14.1.2 Calculation of mass fraction percentage of asbestos . 38
14.1.3 Method detection limit . 39
14.2 Determination of asbestos mass fraction of sieve fraction from mineral aggregates
................................................................................................................................................................... 39
14.2.1 Analysis of sieving fractions . 39
14.2.2 Calculation of mass fraction percentage of asbestos . 40
14.2.3 Method detection limit . 41
15 The comparability of the analytical methods . 41
16 Test report . 42
Annex A (informative) Types of commercial asbestos-containing material and optimum
analytical procedures . 44
Annex B (informative) Energy dispersive X-ray spectrum obtained from UICC reference
standard .
...
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