CEN/TS 16171:2012

Sludge, treated biowaste and soil - Determination of elements using inductively coupled plasma mass spectrometry (ICP-MS)

This Technical Specification specifies a method for the determination of the following elements in aqua regia or nitric acid digests of sludge, treated biowaste and soil:
Aluminium (Al), antimony (Sb), arsenic (As), barium (Ba), beryllium (Be), bismuth (Bi), boron (B), cadmium (Cd), calcium (Ca), cerium (Ce), cesium (Cs), chromium (Cr), cobalt (Co), copper (Cu), dysprosium (Dy), erbium (Er), europium (Eu), gadolinium (Gd), gallium (Ga), germanium (Ge), gold (Au), hafnium (Hf), holmium (Ho), indium (In), iridium (Ir), iron (Fe), lanthanum (La), lead (Pb), lithium (Li), lutetium (Lu), magnesium (Mg), manganese (Mn), mercury (Hg), molybdenum (Mo), neodymium (Nd), nickel (Ni), palladium (Pd), phosphorus (P), platinum (Pt), potassium (K), praseodymium (Pr), rhenium (Re), rhodium (Rh), rubidium (Rb), ruthenium (Ru), samarium (Sm), scandium (Sc), selenium (Se), silicon (Si), silver (Ag), sodium (Na), strontium (Sr), sulfur (S), tellurium (Te), terbium (Tb), thallium (Tl), thorium (Th), thulium (Tm), tin (Sn), titanium (Ti), tungsten (W), uranium (U), vanadium (V), ytterbium(Yb), yttrium (Y), zinc (Zn), and zirconium (Zr).
The working range depends on the matrix and the interferences encountered.
The limit of detection of the method is between 0,1 mg/kg dry matter and 2,0 mg/kg dry matter for most elements.
The limit of detection will be higher in cases where the determination is likely to be interfered (see Clause 4) or in case of memory effects (see e.g. 8.2 of EN ISO 17294-1:2006).

Schlamm, behandelter Bioabfall und Boden - Bestimmung von Elementen mittels Massenspektrometrie mit induktiv gekoppeltem Plasma (ICP-MS)

Diese Technische Spezifikation legt ein Verfahren fest, nach dem in Aufschlusslösungen von Schlamm, behandeltem Bioabfall und Boden nach Königswasser  und Salpetersäureaufschluss die folgenden Elemente bestimmt werden:
Aluminium (Al), Antimon (Sb), Arsen (As), Barium (Ba), Beryllium (Be), Blei (Pb), Bor (B), Cadmium (Cd), Caesium (Cs), Calcium (Ca), Cer (Ce), Chrom (Cr), Dysprosium (Dy), Eisen (Fe), Erbium (Er), Europium (Eu), Gadolinium (Gd), Gallium (Ga), Germanium (Ge), Gold (Au), Hafnium (Hf), Holmium (Ho), Indium (In), Iridium (Ir), Kalium (K), Kobalt (Co), Kupfer (Cu), Lanthan (La), Lithium (Li), Lutetium (Lu), Magnesium (Mg), Mangan (Mn), Molybdän (Mo), Natrium (Na), Neodym (Nd), Nickel (Ni), Palladium (Pd), Phosphor (P), Platin (Pt), Praseodym (Pr), Quecksilber (Hg), Rhenium (Re), Rhodium (Rh), Rubidium (Rb), Ruthenium (Ru), Samarium (Sm), Scandium (Sc), Schwefel (S), Selen (Se), Silber (Ag), Silicium (Si), Strontium (Sr), Tellur (Te), Terbium (Tb), Thallium (Tl), Thorium (Th), Thulium (Tm), Titan (Ti), Uran (U), Vanadium (V), Wolfram (W), Wismut (Bi), Ytterbium (Yb), Yttrium (Y), Zink (Zn), Zinn (Sn) und Zirkonium (Zr).
Der Arbeitsbereich hängt von der Matrix und den zu erwartenden Störungen ab.
Die Nachweisgrenze des Verfahrens für die meisten Elemente liegt zwischen 0,1 mg/kg Trockenmasse und 2,0 mg/kg Trockenmasse.
Die Nachweisgrenze wird höher ausfallen, wenn bei der Bestimmung Störungen möglich sind (siehe Abschnitt 4), oder Memoryeffekte (Verschleppungseffekte) auftreten (siehe 8.2 in EN ISO 17294 1:2006).

Boues, bio-déchets traités et sols - Détermination des éléments en traces par spectrométrie de masse avec plasma induit par haute fréquence (ICP-MS)

La présente Spécification technique spécifie une méthode de détermination des éléments suivants dans des digestats d’eau régale ou d’acide nitrique de boues, de bio-déchets traités et de sols :
Aluminium (Al), antimoine (Sb), arsenic (As), baryum (Ba), béryllium (Be), bismuth (Bi), bore (B), cadmium (Cd), calcium (Ca), cérium (Ce), chrome (Cr), cobalt (Co), cuivre (Cu), dysprosium (Dy), erbium (Er), europium (Eu), gadolinium (Gd), gallium (Ga), germanium (Ge), or (Au), hafnium (Hf), holmium (Ho), indium (In), iridium (Ir), fer (Fe), lanthane (La), plomb (Pb), lithium (Li), lutécium (Lu), magnésium (Mg), manganèse (Mn), mercure (Hg), molybdène (Mo), néodyme (Nd), nickel (Ni), palladium (Pd), phosphore (P), platine (Pt), potassium (K), praseodyme (Pr), rhénium (Re), rhodium (Rh), rubidium (Rb), ruthénium (Ru), samarium (Sm), scandium (Sc), sélénium (Se), silicium (Si), argent (Ag), sodium (Na), strontium (Sr), soufre (S), tellure (Te), terbium (Tb), thallium (Tl), thulium (Tm), étain (Sn), titane (Ti), tungstène (W), uranium (U), vanadium (V), ytterbium(Yb), yttrium (Y), zinc (Zn) et zirconium (Zr).
L’étendue de mesure dépend de la matrice et des interférences rencontrées.
Les limites de détection de la méthode sont comprises entre 0,1 mg/kg de matière sèche et 2,0 mg/kg de matière sèche pour la plupart des éléments.
La limite de détection est plus élevée lorsque la détermination est sujette à des interférences (voir l’Article 4) ou en cas d’effets mémoire (voir 8.2 de l’EN ISO 17294-1:2006, par exemple).

Blato, obdelani biološki odpadki in tla - Določevanje elementov z masno spektrometrijo z induktivno sklopljeno plazmo (ICP/MS)

Ta tehnična specifikacija opredeljuje metodo za določevanje naslednjih elementov v zlatotopki ali izvlečku dušikove kisline blata, obdelanih bioloških odpadkov in tal: aluminij (Al), antimon (Sb), arzen (As), barij (Ba), berilij (Be), bizmut (Bi), bor (B), kadmij (Cd), kalcij (Ca), cerij (Ce), cezij (Cs), krom (Cr), kobalt (Co), baker (Cu), disprozij (Dy), erbij (Er), evropij (Eu), gadolinij (Gd), galij (Ga), germanij (Ge), zlato (Au), hafnij (Hf), holmij (Ho), indij (In), iridij (Ir), železo (Fe), lantan (La), svinec (Pb), litij (Li), lutecij (Lu), magnezij (Mg), mangan (Mn), živo srebro (Hg), molibden (Mo), neodim (Nd), nikelj (Ni), paladij (Pd), fosfor (P), platina (Pt), kalij (K), prazeodim (Pr), renij (Re), rodij (Rh), rutenij (Ru), samarij (Sm), skandij (Sc), selen (Se), silicij (Si), srebro (Ag), natrij (Na), stroncij (Sr), žveplo (S), telurij (Te), terbij (Tb), talij (Tl), torij (Th), tulij (Tm), kositer (Sn), titan (Ti), volfram (W), uran (U), vanadij (V), iterbij (Yb), itrij (Y), cink (Zn) in cirkonij (Zr). Delovni razpon je odvisen od matrice in motenj, ki se pojavijo. Meja detekcije te metode za večino elementov je med 0,1 in 2,0 mg/kg suhe snovi. Meja detekcije bo višja v primerih, ko obstaja možnost motnje določevanja (glej točko 4), ali v primeru spominskih učinkov (glej npr. točko 8.2 standarda EN ISO 17294-1:2006).

General Information

• Status: Withdrawn
• Publication Date: 20-Nov-2012
• Withdrawal Date: 18-Oct-2016
• ICS: 13.030.01 - Wastes in general
• ICS: 13.030.20 - Liquid wastes. Sludge
• ICS: 13.080.10 - Chemical characteristics of soils
• Technical Committee: CEN/TC 444 - Environmental characterization
• Drafting Committee: CEN/TC 444/WG 3 - Inorganic analysis
• Current Stage: 9960 - Withdrawal effective - Withdrawal
• Completion Date: 19-Oct-2016
• Directive: 86/278/EEC - Protection of the environment, and in particular of the soil, when sewage sludge is used in agriculture
• Mandate: M/330 - Mandate given to CEN for the development of horizontal standards in the fields of sludge, biowaste and soil.
• Ref Project: SIST-TS CEN/TS 16171:2013 - Sludge, treated biowaste and soil - Determination of elements using inductively coupled plasma mass spectrometry (ICP-MS)

Relations

• Replaced By: EN 16171:2016 - Sludge, treated biowaste and soil - Determination of elements using inductively coupled plasma mass spectrometry (ICP-MS)
• Effective Date: 21-Jan-2015

Standards Content (Sample)

SLOVENSKI STANDARD
SIST-TS CEN/TS 16171:2013
01-februar-2013
%ODWRREGHODQLELRORãNLRGSDGNLLQWOD'RORþHYDQMHHOHPHQWRY]PDVQR
VSHNWURPHWULMR]LQGXNWLYQRVNORSOMHQRSOD]PR,&306
Sludge, treated biowaste and soil - Determination of elements using inductively coupled
plasma mass spectrometry (ICP-MS)
Schlamm, behandelter Bioabfall und Boden - Bestimmung von Elementen mittels
Massenspektrometrie mit induktiv gekoppeltem Plasma (ICP-MS)
Boues, bio-déchets traités et sols - Détermination des éléments en traces par
spectrométrie de masse avec plasma induit par haute fréquence (ICP-MS)
Ta slovenski standard je istoveten z: CEN/TS 16171:2012
ICS:
13.030.20 7HNRþLRGSDGNL%ODWR Liquid wastes. Sludge
13.080.10 .HPLMVNH]QDþLOQRVWLWDO Chemical characteristics of
soils
SIST-TS CEN/TS 16171:2013 en,fr,de
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

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SIST-TS CEN/TS 16171:2013

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SIST-TS CEN/TS 16171:2013


TECHNICAL SPECIFICATION
CEN/TS 16171

SPÉCIFICATION TECHNIQUE

TECHNISCHE SPEZIFIKATION
November 2012
ICS 13.030.01; 13.080.10
English Version
Sludge, treated biowaste and soil - Determination of elements
using inductively coupled plasma mass spectrometry (ICP-MS)
Boues, bio-déchets traités et sols - Détermination des Schlamm, behandelter Bioabfall und Boden - Bestimmung
éléments en traces par spectrométrie de masse avec von Elementen mittels Massenspektrometrie mit induktiv
plasma induit par haute fréquence (ICP-MS) gekoppeltem Plasma (ICP-MS)
This Technical Specification (CEN/TS) was approved by CEN on 16 July 2012 for provisional application.

The period of validity of this CEN/TS is limited initially to three years. After two years the members of CEN will be requested to submit their
comments, particularly on the question whether the CEN/TS can be converted into a European Standard.

CEN members are required to announce the existence of this CEN/TS in the same way as for an EN and to make the CEN/TS available
promptly at national level in an appropriate form. It is permissible to keep conflicting national standards in force (in parallel to the CEN/TS)
until the final decision about the possible conversion of the CEN/TS into an EN is reached.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania,
Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United
Kingdom.





EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION

EUROPÄISCHES KOMITEE FÜR NORMUNG

Management Centre: Avenue Marnix 17, B-1000 Brussels
© 2012 CEN All rights of exploitation in any form and by any means reserved Ref. No. CEN/TS 16171:2012: E
worldwide for CEN national Members.

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SIST-TS CEN/TS 16171:2013
CEN/TS 16171:2012 (E)
Contents Page
Foreword .3
Introduction .4
1 Scope .5
2 Normative references .5
3 Principle .5
4 Interferences .6
4.1 General .6
4.2 Spectral interferences .6
4.2.1 Isobaric elemental interferences .6
4.2.2 Isobaric molecular and doubly-charged ion interferences .6
4.2.3 Non-spectral interferences .6
5 Reagents .
...